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ISSN 1693-0533
INTRODUCTION
Biodiesel production is expected to increase in
future with the depletion fossil fuels, leading to an
increase in by products of biodiesel production,
approximately 10% of which is glycerol. Glycerol
is widely used in various fields such as food,
pharmacy, and cosmetics. An excessive amount
of glycerol will put downward pressure on its price;
thus, its conversion into added value products is
interest. Decomposition of glycerol produce
varieties of added value products such as acrolein,
acetaldehyde, propionaldehyde, allyl alcohol,
methanol, ethanol, formaldehyde (Buhler et
al.2002), and gas products, such as syngas
(Adhikari et al. 2007; Bird et al. 2008; Slinn et al.
2008; Vallyapan et al. 2008).
Decomposition of glycerol has been widely
carried out with or without catalyst. Reactions of
glycerol decomposition have been studied with
Lailatul et.al.
INDUSTRI
ISSN 1693-0533
Lailatul et.al.
Power (Watt)
T( C)
200
70.5
300
97
400
117.1
500
181
600
215.7
Kinetic Analysis
The effect of reaction time on conversion of
glycerol can be seen in Figure 5. The conversion
INDUSTRI
ISSN 1693-0533
Table 2.
Method
k1
-1
(min )
Microwave heating with
catalyst
Microwave heating
without catalyst
Hydrothermal treatment
0.012
0.008
0.009
CONCLUSIONS
REFERENCES
Adhikari, S., Fernando, S., and Haryanto, A.
(2007),Production of hydrogen by steam
dC A
a
b
reforming of glycerin over alumina-supported
= k1 C A CB
(1)
dt
metal catalysts, Catalysis Today, Vol. 129, pp.
355-364.
dC
'
A = k1 CA , a = 1
Antal, Jr, M. J., Mok, W.S.L., Roy, J.C., and
(2)
dt
T-Raissi, A. (1985),Pyrolytic sources of
hydrocarbons from biomass, J. Anal. Appl.
Here k 1 is kinetic constants of glycerol
Pyrolysis,
Vol. 8, pp. 291-303.
consumption and k1 is k1[CB]b, respectively, and Bird, A.J., Pant, K.K., and Gupta, R.B. (2008),
CA, CB are the concentration of glycerol, water.
Hydrogen production from glycerol by
The rate constant, k1, was determined from
reforming in supercritical water over Ru/Al2O3
equation (2) can be seen in Table 2.
catalyst, Fuel, Vol. 87, pp. 2956-2960.
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