1.

Molecular speed distributions for a gas at two different temperatures are shown below. Which of the
graphs correctly describes the distributions at the two temperatures, where T2 > T1? (Note: small vertical
lines indicate average speed.)

(A)

(B)

(C)

(D)

1. If x g of an unknown metal combines with chlorine to form y g of a metal chloride, the equivalent weight of
the metal is
35 .5 x
y

x y
35 .5 x

35 .5 y
x y

(A)

(B)

(C)

35 .5 x
x y

(D)

1.

Consider the following radial distribution function

diagrams. Which of the following has the correct matching
of curve and orbital?
(A) I(3s), II(3p), III(3d)
(B) I(3d), II(3p), III(3s)
(C) I(3p), II(3d), III(3s)
(D) I(3s), II(3d), III(3p)

14.

In the dissociation of N2O4 into NO2. (1 + x) values with the vapour densities ratio (D/d) is as given by: (xdegree of dissociation, D-vapour density before dissociation, d-vapour density after dissociation].

(A)

(B)

(C)

(D)

15. Let f1 and f2 be the fractions of molecules in the range c and c + dc for SO 2 at 2T and O2 at T,
respectively. Which of the following expressions is correct?
(a) f1 > f2

(b) f1 < f2

(c) f1 = f2

(d) f1 and f2 cannot be correlated

NUCLEUS ORGANIC CHEMISTRY

ORGANIC CHEMISTRY IIT MAINS 11 QUESTIONS

1.

In the given reactions:

A and B are

2. Match the List I (polymer) with List II (constitutents) and select the correct answer using the codes
given below
List I

List II

(A) Buna S

(1) Isoprene

(B) Bakelite

(2) propylene

(C) nylon 6

(3) Butadiene and styrene

(D) Natural rubber

(4) Phenol and formaldehyde

Codes:

3.

(a) 3

(b) 3

(c) 4

(d) 3

Match List I and List II and select the answer using the codes given below the lists:
List I

Codes:
A
(a) 2
(b) 1
(c) 2

List II

B
1
2
1

C
3
3
4

D
4
4
3

(d) 1
2
4
3
4.
In the given reaction

[X] will be:

5.

6.

Match reaction and reagent used and select the correct answer from the codes given below the list

(a) 1

(b) 1

(c) 1

(d) 5

In the given reaction:

[X] will be:

7.

In the reaction

Product is:

8.

The given reaction is known as

(a) Benzoin condensation

(b) Perkin reaction

(c) Reformatsky reaction

(d) Knoevenagel condensation

9.

Which of the following diazonium salts is most stable?

10.

Consider the following statements:

(1) Ketene is an intermediate compound of Arnt-Eistert synthesis
(2) In arnt-Eistert synthesis an acid converts into its next higher homologous acid
(3) Wolff rearrangement is involved in Arnt-Eistert synthesis
(4) Wolff rearrangement is given by - keto aldehydes
Of these statements, the correct statements is/are
(a) only 1 and 2

(b) 2 and 3

(c) 1, 2 and 3

(d) 1, 2, 3 and 4

11. In the given reaction sequence

[X] will be:

(a) antiaromatic compound

(b) Benzenoid compound

(c) Nonbenzenoid aromatic anion

(d) Nonbenzenoid aromatic cation

PROBLEMS FOR ADVANCE

PARAGRAPH SINGLE CHOICE

Alcohol (F) is:

Acid (E) is:

Compound (D) is:

MORE THAN ONE

1.
Which of the following statements are correct for the above reaction?
a. The product is a mixture of

b. The product (II) is a cine-substitution product.

c. The reaction proceeds via benzene intermediate

d. The reaction is ArSN (addition elimination).

1.

Which of the following statements is/are correct about the above reaction?

SUBJECTIVE PROBLEMS
1.

How many different ketones on treatment with Grignards reagent followed by hydrolysis can give 2cyclopentyl-2, butanol?

1.

Select from the following molecules or ions which is/are aromatic.

(a)

(a)

(b)

(b)

(c)

(c)

(d)

(d)