Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Electrical Engineering Universitas Sultan Ageng Tirtayasa, 2Research Centre LIPI Kimia
I.
PREFACE
Average Voltage=
T on
Vfull
(T on+Toff )
(1)
Duty cycle=
Vreference
100
Vcarrier
(2)
below, there are two electrode that will drain electrical power
anter electrolysis process started, will show diferential volume
at cathode and anode this case show that theres gas that fill
the room in the tube.
G=
1
R
(4)
III. STUDY DESIGN
This study comprehend some block of tool design thet used
to do electrolysis process. In this study, we use oscillated DC
source in PMW sognal form as electricity power source, with
variable as frequency and signal width. PMW generation in
this study used Arduino Uno. Output pulse Arduino Uno then
connected to switching circuit with DC voltage source 15 Volt.
Electrolysis process occurs at electrolysis process reactor, in
this study use Hoffman Voltameter method. In this reactor is
required some supported elements such as electrode and
electrolyte solution.
(6)
Volume=n V STP
(7)
Description:
G
= mass of matter (gr)
i
= electricity flow (A)
t
= time (detik)
ME = relative atomic mass divided by the oxidation state
n
= number of moles (mol)
Mr = relative molecular mass
VSTP = volume of gas in a state of STP (22,4 L)
k =C
l
A
(8)
description:
k
= conductivity, mho/cm
C
= conductance, mho
A
= electrode width, cm3
l
= distance between the electrodes, cm
Picture 8. Blokc diagram of study
G=
ME i t
96500
(5)
G
n=
Mr
B. Reaction Process
Based at equation (9) water dissociation reaction shows that
the ratio between the hydrogen and oxygen that is 2: 1, but in
this test the result does not form a comparison like that. This is
due to formation such gas ratio by using H2SO4 require
higher concentrations, unlike using NaOH or KOH that can
approach a ratio of 2: 1 using only 1% concentration.
2 H 2 O 2 H 2+O2
Picture 9. The graphic of electrode test results by using H2SO4 as the
electrolyte solution
(9)
Tabel 1. Comparison of the formation of hydrogen with oxygen as results of
electrolysis
Percentage
(%)
0.25
0.50
0.75
1.00
NaOH
NaCl
H2SO4
KOH
1,6 : 1
2,7 : 1
2,6 : 1
2,5 : 1
0:0
0:0
0:0
0:0
8,2 : 1
7,5 : 1
5,6 : 1
6,5 : 1
3,0 : 1
3,0 : 1
2,6 : 1
2,5 : 1
No.
Pengukuran 1
Pengukuran 2
24,3o C
94,2 mS/cm
24,4 o C
94,9 mS/cm
Pengukuran 3
Konduktivitas
93,4 mS /cm
24,3 C
Parameter
Top diameter
Top Height
Plug thickness
Bottom diameter
Bottom height
Total height
Anode
Before
After
(mm)
(mm)
39
31
23
23
14
14
39
39
18
18
55
55
cathode
Before
After
(mm)
(mm)
39
39
43
43
14
14
39
39
18
18
75
75
Pulse
Width
Vref
Arduino
(Volt)
10%
30%
50%
70%
90%
5
5
5
5
5
Vin
regulato
r
(Volt)
15
15
15
15
15
Vratarata
(Volt)
Vhoffma
n
(Volt)
3,8
5,9
7,9
11,1
12,7
2,5
4,8
6,6
8,7
10,5
()
1,92mL
Picture 14. Correlation between duty cycle and hydrogen production volume
(a)
(b)
Picture 16. (a) The release of hydrogen with DC source (b) The release of
hydrogen with pulse source
bubbles that formed very small and almost invisible to the eye
thus speeding the bubbles rise to the empty space. It is
affecting hydrogen production increases faster than the DC
source.
V. CONCLUSION
From the research that has been done about the effect of
pulse width modulation (PWM) generation in the process of
water electrolysis into hydrogen obtained the following
conclusion.
1) Generation of PWM can be used as a regulator of the
production of hydrogen in the electrolysis process
without adding to the concentration of electrolytes.
2) The formation of hydrogen gas at a pulse width of
50% tends to be increased compared to the pulse
width of 70%.
3) Establishment of the highest hydrogen gas occurs at a
frequency of 8 kHz with a pulse width of 90%.
4) The amount of electricity flow in the reactor is also
influenced by the type and concentration of the
electrolyte..
BIBLIOGRAPHY
[1] S. Goklas, Elektrolisis Air dengan Sel Surya, Universitas
Gajah Mada, 2013.
[2] C. maulani, Studi Unjuk Kerja Generator Gas Hydroxy
dengan Penerapan Arus Pulsa Train sebagai Sumber
Energi, Universitas Brawijaya, 2013.
[3] A. Robbani, Elektrolisis dengan Sumber DC Terosilasi
Menggunakan IC Timer 555 untuk Produksi Gas
Hidrogen, Universitas Gajah Mada, 2013.
[4] R. Prayogo, Pengaturan PWM, Universitas Brawijaya,
Malang,
2012,
Tersedia
dari
:
http://maulana.lecture.ub.ac.id/files/2012/12/PWMRudito.pdf [URL dikunjungi pada 1 Juni 2015]
[5] ______,Water electrolysis & Renewable Energy Systems,
Fuel Cell Today, United kingdom, 2013.
[6] S.K. Dogra dan S. Dogra, Kimia Fisik dan Soal-soal.
Jakarta : Universitas Indonesia (UI-Press), 2008.
[7] M. Kaveh, An Investigation into the Impedance of Water
Electrolysis Cells With a View to Saving Energy,
Universitas Putra Malaysia. 2012.
[8] A. Budiman, Studi Eksperimental Pengaruh Konsentrasi
larutan Terhadap Laju Pelepasan Material pada Proses
Electrochemical Machining, Institut Teknologi Sepuluh
Nopember, Surabaya, 2012.