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Activity 1
1. State the meaning of electrolyte:
An electrolyte is a substance that can conduct (e)in
state or (a) . (s). and undergo (c)
(c).......................
2. A non-electrolyte is a substance that cannot conduct (e). either in
(m). state or (a).. solution.
3. Ionic compounds in molten state or in aqueous solution are electrolytes
because these substances contain freely (m) . (i) .
4. Covalent compounds are non-electrolytes and these substances contain neutral
(m) ................... and no freely (m) (i) However,
certain covalent compounds such as hydrogen chloride, ammonia and ethanoic
acid when dissolved in water are electrolytes. This is because these compounds react
with water to produce freely
..
Activity 2
Classify the substances below into electrolyte and non-electrolyte
Solid lead(II) chloride, molten aluminium oxide, lead(II) nitrate solution, solid sodium
chloride, sodium chloride solution, magnesium, molten lead(II) chloride, glucose
solution, glacial ethanoic acid, dilute ethanoic acid, molten naphthalene, ethanol, silver,
tetrachloromethane, sodium hydroxide solution, aqueous ammonia
Electrolyte
Non-electrolyte
Learning Outcomes:
You should be able to:
describe electrolysis,
describe electrolytic cell,
identify cations and anions in a molten compound,
describe evidence for the existence of ions held in a lattice in solid state but move freely in
molten state,
describe electrolysis of a molten compound,
write half-equations for the discharge of ions at anode and cathode,
predict products of the electrolysis of molten compounds.
Activity 3
Set-up of apparatus of electrolysis of molten lead(II) iodide. Name the main apparatus and
materials in the diagram.
Activity 4
Write ionic formula of anion and cation in each electrolyte (molten) and write its half equation
Electrolyte
Anion
Cation
(Molten)
Ionic
formula
Half equation
Ionic
formula
Half equation
Sodium chloride
NaCl
Lead(II) oxide
PbO
Potassium iodide
KI
Zinc bromide
ZnBr2
Lead(II) iodide
PbI2
Magnesium oxide
MgO
Activity 5
The flow chart below is used to predict the products formed at the electrodes during the
electrolysis of molten lead(II) iodide.
( Movement of ions)
To cathode
(Half equation)
At Cathode
(Products formed)
At Cathode
Activity 6
The flow chart below is used to predict the products formed at the electrodes during the
electrolysis of molten Zinc oxide
( Movement of ions)
To cathode
(Half equation)
At Cathode
(Products formed)
At Cathode
Learning Outcomes:
You should be able to:
1. Molten electrolyte contains only solute. So that means 2 ions exists. But electrolyte of
aqueous solution contains solute and solution (water). So 4 ions present. 2 ions from solute
and another 2 ions from water
2. 3 factors that affecting electrolysis of aqueous solution are:
(a)
(b) .
(c) .
3. List the electrochemistry series (cations and anions) in order of increasing ease of
discharge.
4. The following statements refer to the factors that affect the electrolysis of an aqueous
solution. Fill in the blanks.
Activity 7
The diagram below shows the set-up of apparatus of an electrolytic cell containing concentrated
copper(II) sulphate solution. Two test tubes filled with copper(II) sulphate solution were placed
over the electrodes J and K to collect any gas evolved. The switch is then turned on so that
electrolysis of copper(II) sulphate solution can occur.
(a) Identify the cations and the anions present in the aqueous solution.
Cations: .. Anions: ..
(b) Identify which electrode ( J or K ) is the anode and the cathode:
Anode .. Cathode .
(c) (i) Which ion is selectively discharge at the anode?
(ii) Give a reason for your answer in (c) (i). ..
...
(iii) What do you observe at the anode?
(iv) Give one test to confirm the gas released at K.
.
(v) Write a half equation to represent the discharge of ions at anode.
.
(d) (i) Which ion is selectively discharge at the cathode?
(ii)
(iii)
(a) The table below shows two electrolytic cells with electrolytes of different
concentration. You are required to answer each section by writing your answer in
the spaces provided.
(b) The table below shows two electrolytic cells with the same electrolytes with
different electrodes. You are required to answer each section by writing your
answer in the spaces provided.
electrolyte.
Explain
ELECTROLYSIS IN INDUSTRIES
Learning Outcomes:
You should be able to:
Activity 9
1.
In electroplating of metals, the (h) ...is made the anode and the (i)
to be (j) ...... is made the cathode. The electrolyte
used is an aqueous salt solution of the electroplating metal.
The purposes of electroplating metals are to make the electroplated object more (k)
.. and (l) .. to corrosion.
2. Below are shown the three uses of electrolysis in industries. Fill in the blanks.
Extraction of aluminium
from bauxites
1. Substance
used as cathode
and anode
Electroplating of iron
spoon with silver
Cathode:
Purification of copper
from impure mined
copper
Cathode:
Anode:
Anode:
Anode
Cathode:
Cathode:
Cathode:
Anode:
Anode:
Anode:
Cathode:
2. Electrolyte
used
3. Half
equation
representing
the process.
VOLTAIC CELLS
Learning outcomes:
You should be able to:
Activity 10
In the text box below are sentences explaining the production of electricity from a simple voltaic
cell. The sentences are listed in random order. You are required to arrange these sentences in
the best possible order so as to give a clear description of the reactions occurring in a simple
voltaic cell.
An example of a simple voltaic cell is a magnesium strip and a copper strip immersed in
dilute sodium chloride solution.
The electrons then flows from the magnesium ribbon to the copper plate through the wire
and this results in the flow of electrical current.
Hence magnesium atom releases electrons more easily than a copper atom and the
magnesium act as the negative terminal of the cell.
The overall equation for the reaction is given as follows.
Mg(s) + 2H+(aq) Mg2+(aq) + H2(g)
Magnesium is placed higher than copper in the electrochemical series.
At the negative terminal, each magnesium atom releases two electrons and the Mg2+
formed moved into the solution.
Mg(s) Mg2+ (aq) + 2e
At the positive terminal which is the copper plate, the electrons are accepted by the H+
ions in sodium chloride solution.
2H+ + 2e H2 (g)
Answer:
(a)
(b)
(c)
..
(d)
(e)
(f)
(g)
.
Activity 11
1. (a) Draw and label the set-up of apparatus of a Daniell cell consisting of a salt bridge.
(b) (i) Which metal in the Daniell cell is the negative terminal?
(iii) Write a half equation to represent the reaction occurring at the negative terminal.
.
(c) Write a half equation to represent reaction at positive terminal.
Activity 12
What are the differences between an electrolytic cell and a voltaic cell?. Complete table below.
current.
Chemical energy electrical energy
Learning Outcomes:
You should be able to:
50 cm3 of 1.0 mol dm-3 sodium nitrate solution is poured into a beaker as electrolyte.
Experiment I
The electrodes P and Q are immersed into the solution. The two electrodes are connected to a
voltmeter using copper wires. Electrode Q is the positive terminal. The voltmeter reading is
recorded.
Experiment II
The electrodes Q and S are immersed into the solution. The two electrodes are connected to a
voltmeter using copper wire. Electrode Q is the positive terminal. The voltmeter reading is
recorded.
Experiment III
The electrodes S and T are immersed into the solution. The two electrodes are connected to a
voltmeter using copper wire. Electrode T is the positive terminal. The voltmeter reading is
recorded.
Experiment II
1 2
6
Voltmeter reading: .
Experiment III
4
1 2
6
Voltmeter reading:
(b) Construct a table to record the data from the above experiments.
(c) List the apparatus and materials that you will need to carry out this experiment.
Apparatus: .
..
Materials: ..
(g) Write a half equation for the reaction occurring in negative of Experiment I, assuming the
cation has a +2 charge.
.
(h) Arrange the metals P, Q, S and T in descending order of their tendency to donate electrons.
...
(i) Another voltaic cell is set-up using metals T and Q as electrodes. Predict the potential
difference produced in the cell.
..
(j) Given that metal X is placed between metal S and metal Q in the electrochemical series,
can metal X displace metal S from its salt solution? Give an explanation for your answer
.
.
(k) Given that copper is more electropositive than metal T, a displacement reaction will occur
when copper is immersed into a salt solution of metal T, TNO3.
Write the chemical equation for this reaction.
(l)
.
State three important uses of the electrochemical series
..
.
...