Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Everett
and Harvey
J.
Everett
agitation is impaired, reduced, or misM o d i f y i n g effects of small containers on mixmay define agitation as a unit operaapplied, t h e consequent. chemical
ing action are given. Minimum dimensions are
tion, we are here concerned with the
change will be affected accordingly.
shown to be related to physical characteristics
application of a unit operation t o a
For simplifying the discussion,
of materials. The pilot plant for studying agitaunit process. To be successful, such an
the general physical effect,s of agitation is contrasted with the pilot plant requiring
installation must be capable of production can be divided into the six groups
agitation for carrying on the process. General
ing the predicted or expected chemical
of Table I. However, in even a simple
design data are given for vessel shape, dimenchange or changes in the unit proceds
case, such as hydrogenation of a,
sions, variable-speed drive, horsepower range,
itself, and must be able to be varied and
vegetable oil in the presence of a finely
impeller selection, method of supporting vessel.
controlled so as to enable the optimum
divided metallic catalyst, a t least three
Photographs show several typical designs of
points in the unit process t o be achieved.
of these functions of agitation are prespilot plant. Methods are also outlined for obThe characteristics and performance
ent-namely, gas dispersion, suspension
taining quantitative data and for extending
of the agitation equipment must
of catalyst in a uniform manner, and
Dilot Dlant to commercial scale operation.
be capable of being recorded quanthe mat,ter of heat transfer t o be imtitatively so that larger scale equipproved by the circulation of the liquid
ment, for commercial size installations, can be designed from the
in the tank against the side walls or coils.
Let us assume that we are t o consider a pilot plant for a btudy
data obtained from the pilot plant operation.
I n certain cases, before the pilot plant for the unit process is
of this kind. Because of the use of hydrogen gas, it might be
set up, it will be desirable or necessary to provide a pilot plant
arbitrarily decided that the vessel was t o be kept as small as
possible. I n considering the application of a n agitator, however,
for the at,udy of agitation as a unit operation so as t,o reduce the
it would be found that the dispersion of the hydrogen gas was the
number of variables which ~ ~ o i i otherwise
ld
be necessary in the
unit process pilot plant.
most difficult or controlling factor. h type of impeller would
have to be used which would produce refinement of gas bubbles
VESSEL SIZE
and also be capable of recirculation of the supernatant gas
R-hile commercial plants for a given unit process w-ill generally
throughout the entire vessel-in other words, of providin,: the
fall Tvithin relatively narrow limits of size, capacity, etc., this,
physical conditions necessary for the chemical change. Iuadeunfortunately, is not, true n i t h pilot plants. The greatest variaquate agitation a t this point would result either in incomplete
tion in pilot plant design a t present lies in the great range of
hydrogenation or prolonged time for hydrogenation, possibly conphysical size. The term pilot plant has acquired the connotacurrent with excessive amounts of catalyst required. Data derived
tion in some quarters of miniature so that any extremely small
from such results would lead to erroneous conclusions regarding
piece of equipment, made of metal, is apt to be considered pilot
the economic factors involved and, if translated t o a large scale,
plant, equipment. I t is not rare to encounter autoclaves and rewould result in a totally inefficient commercial process.
artion vessels as small as 4 inches in diameter and 6 inches in
MINIMUM VESSEL AND IMPELLER SIZE
height. I n the absence of any guide or data which illustrate t,he
I n the pilot plant unit, it is desirable to use an impellei v,hich
difficulties to be encountered in deriving information from reis geonietrically similar to that of the full scale plant in order to
sults obtained in such small vesels, it is not surprising that the
scale-up the pilot plant results successfully. The considerations
physical size of t,he reaction vessel is most frequently decided by
needed t o be given a n impeller are: (1) the circulation pattern
ot,her factors. Consideration of materials available, safety hazin the vessel, ( 2 ) discharge velocity, (3) discharge capacity, and
ards involved, amount of room available, and disposal of end(4) a Reynolds number relation.
and by-products play an important part in size determination of
Experience has indicated that the ratio of tank diameter to
the vessel.
impeller diameter should be between 3 and 4. This ratio leaves
The purpose of t,his paper is to set, fort!h a desirable minimum
a clearance of approximately 1 to 1.5 impeller diameters between
size of reaction vessel, together with the reasons involved in arthe impeller and tank wall. I n the usual solutions (under 400
riving a t this size and the handicaps t o be expected in dealing with
centipoises) a decreased clearance of impeller to tank wall would
smaller vessels. It will be shown that, while the function of mixcause a large energy loss a t the tank wall. More clearance would
ing or agitation is primarily to produce physical changes, these
result in an insufficient velocity to create turbulence throughout
physical changes are invariably associated tvith chemical changes
the tank.
inherent in a unit process; consequently, if the physical effect of
Table 1.
BLENDIXG
MISCIBLELIQUIDS
MIXINGI m m CIBLE
LIQCIDS
Washing of liquids
Extraction
Contacting
Emulsifying
CRYSTAL
SIZE
CONTROL
Precipitation
Evaporation systems
426
GASABSORPTIOX
AND DISPERSIOX
Hydrogenation
Aeration
Gas scrubbing
Chlorination
Gas washing
SUSPENSION
OF SOLIDE
Slurries
Suspension of filter aid,
activated C, fullern
earth, crystals while
dissolving
HEAT
TRANSFER
Heating
Cooling
May, 1945
427
A1Vl = AzV2
where A = cross section area of stream
V = velocity of stream
428
MACHINE COMPANY
and speeds, viscosity and density of fluid, and tank sizes and
baffling. Our tests have shown that this Reynolds number
function is relatively independent of the tank diameter and is
remarkably consistent for changes of impeller diameter, speed,
density, and viscosity.
This function indicates only the flow in the impeller, and is affected by factors such as tank dimensions and baffles only as they
influence the flow through the impeller. For Reynolds number
in agitation, laminar flow occurs in numbers up to 2 , a transition
between 2 and 20, and turbulent flow from 20 up. We have obtained numbers in turbulent range as high as 1,000,000. The
Reynolds number alone is no more a measure of agitation than
any other factor. It is used in the selection of a favorable diameter and speed to perform the mixing operation.
These minimum sizes of impellers and vessels should be closely
adhered to. The reaction vessel need not, necessarily, have the
same capacity of preceding or following equipment. Material
may be accumulated or stored ordinarily so that smaller or
larger equipment may precede or follow the reaction vessel.
G E N E R A L M E C H A N I C A L REQUIREMENTS
The matter of access to the interior of the vessel is of prime importance. With the weight involved in the minimum size vessel
recorded, mechanical aids should be provided. It is possible t o
design t h e vessel so that it may alternately: (1) be raised, levered, or tipped for emptying or (2) support the vessel in a fixed
position, and raise and lower the head.
May, 1945
429
(2) Gibson, A. H., Hydraulics and Its Application, 4th ed., 1930.
UNIVERSITY
The factors controlling the oxidation of the ferrous iron in a solution OF ferrous sulfate, ferric sulfate, and sulfuric
acid have been studied, using both oxygen and air. The percentage oxidation of ferrous sulfate is shown
here graphically on curves with respect to time, partial press!re of oxygen, temperature, acid concentration, and catalyst
concentration. The oxidation OF ferrous sulFate in acid solution by oxygen is a very difficult reaction, and good
conversions to ferric sulfate occur only at quite high temperatures and pressures over a considerable time period.