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Compositional analysis
Techniques
Two analytical techniques were used in the investigation of the
jewellery: energy dispersive X-ray fluorescence (XRF) and Xray diffraction (XRD). X-ray fluorescence (XRF) was used to
determine the metal composition of the artefacts and, since
many of the artefacts are composite, in some cases the
individual components were analysed to establish their
integrity. X-ray diffraction analysis was used to identify the
inlay materials.
The instrument used for XRF analysis was a modified Link
Analytical 290 spectrometer incorporating a molybdenum
target X-ray tube operated at 45kV which analyses an area
about 1.5 mm in diameter on the artefact.1 XRF is essentially a
surface method since, due to the low penetration of X-rays, the
analysed depth rarely exceeds 100 m (0.1 mm). Hence, to
obtain an accurate analysis of an artefact, the exposed surface
must be representative of the bulk composition. The surface
compositions of most ancient artefacts have usually been
altered by corrosion processes, either through leaching of less
noble metals (e.g. copper, leading to an apparent surface
enrichment of the more noble metals, such as silver and gold) or
a build-up of corrosion products. Consequently the surfaces are
not representative of the bulk. These problems can be
overcome by preparing the surface, for example by abrasion, to
expose a representative surface, but this was not generally
possible with these artefacts. Those analyses carried out with
no surface preparation (i.e. non-destructively) are therefore at
best semiquantitative (i.e. approximate) or only qualitative.
For the gold jewellery, where corrosion deposits are usually
absent, there will be some alteration of the surface composition
so that only semiquantitative analysis is possible. The nondestructive analysis results are likely to show an
overestimation of the gold and possibly the silver contents and
a corresponding under-estimation of the copper. The precision
(reproducibility) of these analyses is about 1-2% relative for
the major component (gold) and about 5-20% relative for
silver and copper; the accuracy cannot be defined because of
the uncertain surface enrichment effects. In the case of
artefacts made of silver or copper-based alloys, the surface
alteration may be more extensive so that only a qualitative
analysis was justifiable. Thus, only the alloy type was recorded
with a note of any traces of other metals. The alloy terminology
is as follows:
brass
leaded bronze
gunmetal
leaded gunmetal
The Berthier-Delagarde Collection of Crimean Jewellery in the British Museum and Related Material | 151
152 | The Berthier-Delagarde Collection of Crimean Jewellery in the British Museum and Related Material
Cowell 1998
Morrisson et al. 1985
Pekarskaja and Kidd 1994
Oddy 1993
Meeks and Tite 1980
Bowditch 1973
Sazanov 1995
Ogden 1982, 40
Whitfield 1990; Oddy 1977
Azaroff and Buerger 1958
Sax 1996, 6372
Arrhenius 1985, 38
La Niece 1988
Arrhenius 1971, 7897
The Berthier-Delagarde Collection of Crimean Jewellery in the British Museum and Related Material | 153
Description
Earring
Earring
Earring
Earring
Earring
Earring
Earring (Inv. no. 64)
Earring (Inv. no. 65)
Earring
Necklace
Pendant
Pendant
Finger-ring
Finger-ring
Brooch
Brooch
Mounts
Mount
Strap-attachment
Stud
Stud
Stud
Stud
Stud
Stud
Stud
Stud
Stud
Stud
Stud
Stud
Buckle
Buckle-tongue
Buckle
Earring
Earring
Pendant
Kolt
Brooch
Brooch
Brooch
Brooch
Pendant
Pendant
Earring
Earring
Earring
Earring
Pendant/Earring
Earring
Part
Back sheet
Backing sheet
Loop
Body
Twisted wire
Back-plate
Cell side
Granulation area
Hoop
Cell side
Cell side
Cell side
Sheet around pendants
Spacers
Base-plate
Base-plate main part
Base-plate addition
Sheet around cell
Sheet around cells
Hoop
Back hinge
Back catch-plate
Back sheet, ungilded
Cell side
Bird: gold strip
Body, front
Beaded rim
Cell side
Back of cell
Back of cell
Back of cell
Back of cell
Back of cell
Back of cell
Back of cell
Back of cell
Back of cell
Back of cell
Loop
Side of cell
Body
Cell side
Body
Body
Body
Body
Body
Body
Body
Body
Body
Loop
Pyramid
Large ring
Loop
Body
Bead
Suspension loop
Back-plate
Body
Body
Wire hook
Back sheet
Twisted wire
Wire hook
Back-plate
Body
Body, side
Backing plate
Backing plate
Loop
%Au
75
91
91
88
88
93
91
90
78
93
62
86
79
85
90
90
90
83
85
84
64
64
1
99
86
79
81
86
74
78
89
79
78
71
40
95
94
96
89
88
92
84
95
90
89
97
82
91
88
66
83
81
97
73
69
72
74
76
83
84
76
76
92
95
93
95
93
95
93
94
93
%Ag
22
4
7
10
10
6
8
7
19
5
32
9
10
11
8
8
8
14
11
11
32
33
68
0.7
11
19
18
12
22
19
10
18
19
25
51
1
1
1
9
9
7
12
4
8
7
1
15
7
10
30
13
14
3
23
24
24
23
21
14
14
19
22
6
4
6
4
6
4
5
5
7
%Cu
3
5.4
2.0
2.0
1.3
1
1
3
3
2
6
5
11
4
2
2
2
3
4
5
3
3
32
0.2
3
3
2
2
3
3
1
3
3
4
9
4
5
3
2
2
1
4
2
2
5
2
2.9
2.2
1.5
3.9
3.9
5.0
0.7
4.4
7.2
4.1
2.9
2.8
2.3
1.7
5.0
3.0
2.0
0.8
1.0
0.7
0.7
1.2
1.5
0.8
0.4
Comments
Abraded
Note: The majority of analyses are on the unabraded surface and are therefore approximate. There may be some bias in the results due to
surface enrichment.
154 | The Berthier-Delagarde Collection of Crimean Jewellery in the British Museum and Related Material
Description
Brooch (Inv. no. 39)
Brooch (Inv. no. 40)
Brooch (Inv. no. 41)
Brooch (Inv. no. 42)
Brooch (Inv. no. 43)
Brooch (Inv. no. 44)
Brooch
Mount
Buckle
Buckle
Mount
Ag
69
61
58
56
57
58
<0.1
75
<0.1
64
46
Cu
23
32
38
41
35
37
81
23
99
27
46
Pb
3
2
1
0.5
2
0.5
2
<0.1
0.1
2
2
Zn
1
1
2
1
3
3
16
0.5
<0.1
3
3
Sn
1
2
<0.1
<0.1
2
0.5
0.5
<0.1
0.5
2
1
Au
3
2
1
1
1
1
<0.1
0.5
<0.1
2
0.5
The precision of major elements (e.g. Ag, Cu) is 1-2%, others 10-25%. The accuracy is similar.
Table3
Cat. no.
16
17
18
19
19
20
20
21
21
22
27
27
30
30
30
31
31
31
32
32
32
33
33
33
34
34
34
34
35
35
36
36
37
38
39
40
40
41
41
41
42
42
42
43
43
44
44
45
45
46
46
47
48
48
49
49
50
Description
Brooch
Armlet
Armlet
Brooch (Inv. no. 39)
(Inv. no. 40)
Brooch (Inv. no. 41)
Brooch (Inv. no. 42)
Brooch (Inv. no. 43)
Brooch (Inv. no. 44)
Brooch
Mount
Stud (Inv. no. 99)
Stud (Inv. no. 100)
Mount
Mount
Mount
Mount
Mount
Mount
Mount
Mount
Mount
Mount
Mount
Mount
Mount
Mount
Buckle
Buckle
Buckle
Buckle
Buckle
Buckle loop (Inv. no. 138)
Part
Body
Body
Body
Body
Body
Body
Body
Body
Body
Body (abraded)
Side panel
Back
Base
Collar
Body
Back-plate
Tongue backing
Rivet on tongue
Back-plate
Front sheet
Domed rivets
Back-plate
Front sheet
Rivet
Back-plate
Front sheet
Rivet
Silver sheet
Back-plate
Rivet
Back-plate
Rivet
Back-plate
Silver sheet
Silver sheet
Back-plate
Rivet
Cell at back
Outer base-plate
Backing plate
Inner base-plate
Outer back-plate
Side joint solder
Underlying base
Front sheet
Front sheet
Back sheet
Rivet-head
Loop
Rivet-head
Loop
Loop
Tongue
Loop
Body
Tongue
Body
Analysis
Silver-copper, traces of lead, zinc, gold
Silver-copper alloy with traces of zinc, tin
Silver-copper alloy with traces of zinc
Base silver-copper, traces of lead, zinc, tin, gold
Base silver-copper, traces of lead, zinc, tin, gold
Base silver-copper, traces of lead, gold
Base silver-copper, traces of lead, gold
Base silver-copper, traces of lead, zinc, tin, gold
Base silver-copper, traces of lead, zinc, tin, gold
Brass with trace of lead
Gilded copper
Copper with traces of zinc and tin
Brass
Mercury gilded brass
Gilded copper
Base silver-copper, traces of zinc and tin
Copper
Copper
Copper with traces of lead
Mercury gilded silver
Silver-copper alloy, traces of gold
Copper
Gilded silver (mercury not detected by XRF)
Silver
Copper
Mercury gilded silver
Silver
Silver-copper alloy, traces of gold and lead
Copper
Silver-copper alloy
Copper
Silver-copper alloy
Copper with traces of tin
Silver-copper alloy, traces of lead and gold
Silver-copper alloy, traces of lead and gold
Silver-copper alloy, traces of zinc
Base silver-copper alloy with zinc
Base silver-copper alloy, traces of lead, zinc, tin
Base silver-copper, traces of zinc and tin
Copper with traces of tin
Tin bronze with traces of arsenic
Base silver-copper, traces of zinc and lead
Tin-lead solder
copper with traces of tin
Silver-copper alloy, traces of lead and tin
Silver-copper alloy, traces of zinc and gold
Base silver-copper alloy, traces of zinc and gold
Gold-silver alloy
Silver-copper alloy, trace of lead and gold
Silver-copper alloy, trace of gold
Silver-copper alloy, trace of gold
Copper
Silver-copper alloy
Silver-copper alloy
Brass with trace of tin
Brass with trace of tin
Base silver-copper, traces of gold, zinc
The Berthier-Delagarde Collection of Crimean Jewellery in the British Museum and Related Material | 155
Part
Analysis
50
51
52
53
53
53
54
55
56
57
58
59
60
60
60
61
62
63
64
65
66
67
68
69
73
74
75
75
75
76
76
77
77
78
78
79
79
80
80
81
81
81
81
83
88
88
89
90
91
91
92
92
92
114
115
117
118
118
131
131
131
132
132
132
133
133
135
136
136
137
137
137
Body
Loop
Loop
Loop
Loop
Loop attachment
Body
Body
Loop
Body
Body
Loop
Attachment
Ring
Attachment
Body
Body
Body metal strip
Body metal strip
Body
Backing sheet
Backing sheet
Sheet strip
Sheet strip
Plate
Loop front hinge
Front-plate
Back-plate
Tongue
Body
Loop
Body, side
Tongue
Body
Loop
Tongue
Loop
Body
Rivet
Body
Tongue
Garnet setting base
Folded flap
Sling
Plate
Tongue
Body
Body
Body
Body
Body
Body
Pin
Body
Body
Body
Body
Pin
Hoop
Sphere
Large sphere
Body surface
Body surface
Sample of interior
Body
Body
Body
Front
Backing sheet
Body
Body
Body
Silver-copper alloy
Silver-copper alloy
Silver-copper alloy
Silver-copper alloy with gold
Silver-copper alloy with gold
Silver-copper alloy with gold
Tin bronze
Tin bronze
Copper with trace of tin
Copper
Copper
Tin bronze
Silver-copper alloy, traces of lead and gold
Leaded bronze, traces of zinc
Base silver-copper alloy, traces of tin and gold
Bronze
Brass with trace of tin
Silver-copper alloy, traces of lead, tin, gold
Silver-copper alloy, traces of lead, zinc, tin
Silver-copper alloy, traces of lead, tin
Base silver-copper alloy, traces of lead, tin
Silver-copper alloy, traces of lead, gold
Base silver-copper alloy, traces of lead, tin
Base silver-copper alloy, traces of tin, lead
Silver
Base silver-copper, traces of lead, tin
Mercury gilded silver
Base silver-copper alloy, traces of zinc
Base silver-copper alloy, traces of zinc
Copper with traces of lead
Leaded gunmetal
Brass
Brass
Brass
Brass
Brass with some tin
Mercury gilded silver
Base silver-copper with zinc, lead and tin
Brass
Base silver-copper alloy, traces of tin, lead and zinc
Gilded silver-copper, traces of tin and lead
Copper with traces of zinc
Copper
Silver-copper alloy, traces of lead, tin and gold
Leaded gunmetal
Brass
Leaded gunmetal
Base silver-copper, traces of gold
Silver-copper, traces of gold and lead
Silver-copper, traces of gold, lead and zinc
Silver-copper, traces of gold, lead and zinc
Silver-copper, traces of gold, lead and zinc
Copper
Brass
Leaded gunmetal
Silver-copper alloy
Base silver-copper alloy, traces of lead and tin
Base silver-copper alloy, traces of lead and tin
Silver-copper alloy, trace of lead
Silver-copper alloy, trace of lead
Silver-copper alloy
Mercury gilded (includes silver) on copper
Mercury gilded (includes silver) on copper
Silver and copper detected
Silver-copper alloy, traces of lead and gold
Silver-copper alloy trace of gold
Silver-copper alloy, traces of gold
Silver-copper alloy, trace of gold
Copper with trace of tin
Silver-copper alloy, traces of tin and lead
Silver-copper alloy
Silver-copper alloy, traces of gold
Buckle
Buckle
Buckle
Buckle
Buckle
Buckle
Sword fitting
Buckle
Buckle
Strap-end
Belt mount (Inv. no. 36)
Belt mount (Inv. no. 37)
Belt mount (Inv. no. 34)
Belt mount (Inv. no. 35)
Buckle-plate
Belt mount
Earring
Brooch
Earring (Inv. no. 114)
Earring (Inv. no. 115)
Earring (Inv. no. 96)
Earring (Inv. no. 97)
Armlet (Inv. no. 117)
Armlet (Inv. no. 118)
Ring
Mount
Mount (Inv. no. 146)
Mount (Inv. no. 147)
Mount (Inv. no. 148)
156 | The Berthier-Delagarde Collection of Crimean Jewellery in the British Museum and Related Material
Plate 68 Detail of the hoop of ring P&E 1923,7-16,15 (cat. no. 13). It is decorated with a
false-plait, bordered with beaded wire and shows evidence of wear.
Plate67 Garnet stud with beaded-wire border, P&E 1923,7-16,32
(cat. no. 29D).
The Berthier-Delagarde Collection of Crimean Jewellery in the British Museum and Related Material | 157
Plate 71 Detail of a garnet bird-head mount, P&E 1923,7-16,12 (cat. no. 24A). This circular
garnet has been recut note the straight edge on the right. The ring in the centre once held a
gold inlay.
158 | The Berthier-Delagarde Collection of Crimean Jewellery in the British Museum and Related Material
Glossary
Agate
Amethyst
Beaded wire
Brass
Bronze
Buckle
Burnishing
Cabochon
Carnelian
Chalcedony
Chasing
Chip-carving
Cloison
Cloisonn
Drawn wire
Earring
Engraving
The Berthier-Delagarde Collection of Crimean Jewellery in the British Museum and Related Material | 159
160 | The Berthier-Delagarde Collection of Crimean Jewellery in the British Museum and Related Material