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Q1.IITJEE2012Paper2
Fourfairdice
and
,eachhavingsixfacesnumbered1,2,3,4,5and6,are
rolledsimultaneously.Theprobabilitythat
and
showsanumberappearingononeof
is
(a)
(b)
(c)
(d)
CorrectAnswer
:OptionA
CaseI:
When
allshowsdifferentnumberandoneofthenumberisshownby
CaseII:
When
allshowsamenumberandthatnumberisshownby
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CaseIII:
Whentwonumbersshownby
thenumbersisshownby
aresameandoneisdifferentandoneof
Requiredprobability
Q2.IITJEE2012Paper1
Thevalueof
is
CorrectAnswer
:4
Solution:
Let
SolvingtheequationforSweget,
As,thelogofthenegativevaluesisnotdefined.
NowputtingthevalueofSweget
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Hence,thevalueofthegivenexpressionis4.
Q3.JEEAdvanced2013paper2
Considerthelines
andtheplanes
Let
ax
+
by
+
cz
=
d
betheequationofthe
planepassingthroughthepointofintersectionoflines
L
and
L
,andperpendiculartoplanes
1
2
P
and
P
.
1
2
MatchListIwithListIIandselectthecorrectanswerusingthecodegivenbelowthelists:
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CorrectAnswer
:OptionA
Thegivenlinesandplanesare:
NormaltotheplanePis
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Let
and
Since,L
andL
intersect,therefore,
1
2
2
k
+1=
k
+4...(1)
1
2
k
=
k
3(2)
1
2
k
3=2
k
3(3)
1
2
Solvingequation(1)and(2),weget
k
=2,
k
=1
1
2
Thus,thepointofintersectionofthelinesL
andL
is
1
2
Therefore,equationoftheplanePis
a
=1,
b
=3,
c
=2,
d
=13
Hence,thecorrectcodeisA.
Q4.JEEAdvanced2013Paper1
Theareaenclosedbythecurves
y
=sin
x
+cos
x
and
y
=|cos
x
sin
x
|overtheinterval
is
(a)
(b)
(c)
(d)
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CorrectAnswer
:OptionB
Thegivencurvesovertheinterval
are
(1)
(2)
Withthehelpofshiftingoforiginthegraphsof
and
is
Now,
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Areaenclosedbythegivencurves,Ais
Hence,thecorrectoptionisB.
Q5.IIT2010SolvedPaper2
LetfbeafunctiondefinedonR(thesetofallrealnumbers)suchthat
forall
afunctiondefinedonRwithvaluesintheinterval
suchthat
,thenthenumberofpointsinRatwhichghasalocalmaximumis
CorrectAnswer
:0
Solution:
f(x)
g(x)=e
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.Ifgis
forall
Sothereisonlyonepointoflocalmaxima.
Q6.IITJEE2011Paper1
Let
and
betherootsof
thenthevalueof
,with
.If
is
(a)1
(b)2
(c)3
(d)4
CorrectAnswer
:OptionC
Itisgiventhat,
and
aretherootsof
.Therefore,
Weshallusetheaboveequationstosimplifytheexpressiongivenintheproblem.
Thus,
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forn
Hence,thecorrectoptionisC.
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Physics>
Q1.JEEAdvanced2014paper1
Attime
t
=0,terminalAinthecircuitshowninthefigureisconnectedtoBbyakeyandan
1
alternatingcurrent
I
(
t
)=
I
cos(
t
),with
I
=1Aand
=500rads
startsflowinginitwith
0
0
theinitialdirectionshowninthefigure.At
,thekeyisswitchedfromBtoD.Now
onwardsonlyAandDareconnected.AtotalchargeQflowsfromthebatterytochargethe
capacitorfully.If
C
=20
F,
R
=10andthebatteryisidealwith
emf
of50V
,
identifythe
correctstatement(s).
3
is110
C
.
(A)Magnitudeofthemaximumchargeonthecapacitorbefore
(B)Thecurrentintheleftpartofthecircuitjustbefore
isclockwise.
(C)ImmediatelyafterAisconnectedtoD,thecurrentin
R
is10
A
.
3
(D)Q=210
C
.
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Solution
:
Variationofcurrentinthecircuitwithtimeisgivenasfollows:
Asshowninthefigure,from
t
=0to
currentinthecircuitiszero.
Chargeatthispoint
thechargewillbemaximumat
t
=
,when
isgivenby
At
t
=
,thedirectionofcurrentwillbeoppositetotheinitialdirection.And,thecharge
ontheupperplateisgivenby
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ApplyingKVL,whentheswitchisshiftedtoD,weget:
50+
Finalchargeon
C
isgivenby
=
Totalchargeflownfromthebatterywillbe2
Hence,thecorrectoptionsareCandD.
Q2.JEEAdvanced2014Paper1
Astudentisperforminganexperimentusingaresonancecolumnandatuningforkof
1
frequency244s
.Heistoldthattheairinthetubehasbeenreplacedbyanothergas
(assumethatthecolumnremainsfilledwiththegas).Iftheminimumheightatwhich
resonanceoccursis(0.3500.005)m,thegasinthetubeis
.
(
Usefulinformation:
Themolarmasses
M
ingramsaregivenintheoptions.Takethevaluesof
gasasgiventhere.)
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foreach
(A)
(B)
(C)
(D)
CorrectAnswer
:OptionD
Weknow:
Minimumlengthfortheoccurrenceofresonance,
l
=
/4
or
=4
l
Now,fundamentalfrequencyisgivenasfollows:
(A)Neon:
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(B)Nitrogen:
(C)Oxygen:
(D)Argon:
Fromtheabovecalculations,theonlypossiblegasisArgonbecauseitsfrequencyof
vibrationiscomparabletothefrequencyofthetuningforkused.
Hence,thecorrectoptionisD.
Q3.JEEAdvanced2013Paper2
Paragraph:
Apointcharge
Q
ismovinginacircularorbitofradius
R
inthe
x
y
planewithanangular
velocity.Thiscanbeconsideredasequivalenttoaloopcarryingasteadycurrent
A
uniformmagneticfieldalongthepositive
z
axisisnowswitchedon,whichincreasesata
constantratefrom0to
B
inonesecond.Assumethattheradiusoftheorbitremainsconstant.
Theapplicationofthemagneticfieldinducesanemfintheorbit.Theinducedemfisdefined
astheworkdonebyaninducedelectricfieldinmovingaunitpositivechargearoundaclosed
loop.Itisknownthat,foranorbitingcharge,themagneticdipolemomentisproportionalto
theangularmomentumwithaproportionalityconstant.
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Thechangeinthemagneticdipolemomentassociatedwiththeorbit,attheendofthetime
intervalofthemagneticfieldchangeis
(a)
BQR2
(b)
(c)
(d)
BQR2
CorrectAnswer
:OptionB
Givenmagneticdipolemoment,M=L
And,L=I=
Now,changeinmagneticdipole,M=
Negativesignshowsthatthechangeisinoppositedirectionofmagneticfield.
Q4.IITJEE2012Paper1
Athinuniformrod,pivotedat
O,
isrotatinginthehorizontalplanewithconstantangular
speed
,asshowninthefigure,attime
t
=0asmallinsectfrom
O
andmoveswithconstant
speed
v
withrespecttotherodtowardstheotherend.Itreachestheendoftherodat
t
=
T
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andstops.Theangularspeedofthesystemremains
torque
throughout.Themagnitudeofthe
onthesystemabout
O
,asafunctionoftimeisbestrepresentedbywhichplot?
(a)
(b)
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(c)
(d)
Solution
:
constantthroughout
Asweknowthat
WhereL=Angularmomentum
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=Torque
Now
Differentiatingtheequationwithrespecttotime
Hencethegraphwouldbeastraightlinewithaconstantslopetilltheinsectmoves.
Wheninsectstops
I
becomesconstant
Hencethegraphwouldbethexaxis.
Q5.IITJEE2011Paper1
Alongcirculartubeoflength10mandradius0.3mcarriesacurrent/alongitscurvedsurface
asshown.Awireloopofresistance0.005ohmandofradius0.1misplacedinsidethetube
withitsaxiscoincidingwiththeaxisofthetube.ThecurrentvariesasI=I
cos(300t)whereI
0
0
isconstant.Ifthemagneticmomentoftheloopis
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,thenNis
Solution
:
[N:No.ofturnsperunitlengthassumingthetubeassolenoid]
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Chemistry>
Q1.JEEAdvanced2014Paper1
Thepair(s)ofreagentsthatyieldparamagneticspeciesis/are
(A)NaandexcessofNH
3
(B)KandexcessofO
2
(C)CuanddiluteHNO
3
(D)O
and2ethylanthraquinol
2
Solution
:
Na,onreactionwithexcessofNH
,givesasolutionofalkalimetalscontainingfree
3
ammoniatedelectronsthatareparamagneticinnature.
K,onreactionwithexcessofO
,givessuperoxide,whichisparamagneticinnaturedueto
2
thepresenceofasingleunpairedelectron.
CuanddiluteHNO
giveNO,whichisparamagneticinnature.
3
O
and2ethylanthraquinolwillgive2ethylanthraquinoneandhydrogenperoxide.Hydrogen
2
peroxideisdiamagneticinnature.
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Hence,thecorrectoptionsare(A),(B)and(C).
Q2.JEEAdvanced2014Paper1
Thecorrectstatement(s)fororthoboricacidis/are
(A)Itbehavesasaweakacidinwaterduetoselfionisation.
(B)Acidityofitsaqueoussolutionincreasesuponadditionofethyleneglycol.
(C)Ithasathreedimensionalstructureduetohydrogenbonding.
(D)Itisaweakelectrolyteinwater.
Solution
:
OrthoboricacidisH
BO
orB(OH)
.
3
3
3
+
ItpartiallyreactswithwaterandformsH
O
and[B(OH)
]
.Itissolubleinwaterandbehaves
3
4
asaweakmonobasicacid.Orthoboricacidisatypeofacidwhichdoesnotdonateproton
rather,itacceptshydroxylionandbehavesasaLewisacid.
+
B(OH)
+2H
OH
O
+[B(OH)
]
3
2
3
4
Thus,orthoboricaciddoesnotbehaveasaweakacidduetoselfionisation.
Inaqueoussolutionoforthoboricacid,ifacertainorganicpolyhydroxycompoundsuchas
glycerol,mannitolorsugarisadded,thenitbehavesasstrongmonobasicacid.
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3
3
BO
3 unitshaveaplanarstructure.Insolidstate,BO
3 unitsarehydrogenbonded,giving
risetoatwodimensionalsheetwithalmosthexagonalsymmetry.
3
OrthoboricacidislesssolubleincoldwaterandfurnishesBO
3 ions,soitisaweak
electrolyteinwater.
Hence,thecorrectoptionsare(B)and(D).
Q3.JEEAdvanced2014Paper2
Fortheprocess
H2O(l)H2O(g)
atT=100Cand1atmospherepressure,thecorrectchoiceis
(A)Ssystem>0andSsurroundings>0
(B)Ssystem>0andSsurroundings<0
(C)Ssystem<0andSsurroundings>0
(D)Ssystem<0andSsurroundings<0
CorrectAnswer
:OptionB
Thetotalentropychangeforasystemandthesurroundingforanyreactionisgivenby
...(1)
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o
At100
Cand1atmpressure,H
Ochangesfromliquidtogaseousstate.Thistemperatureis
2
termedastheboilingpointofwater.Atthistemperature,theliquidwaterandthegaseous
watervapourexistinequilibrium.
Foranequilibriumreaction,
Onsubstitutingthevalueof
inequation(1),weget:
Asthewaterisundergoingachangeinphase(i.e.,fromliquidtogas),thedegreeof
randomnessincreases.Hence,forthisprocess,
Asthechangeinentropyofthesystemispositive,thechangeinentropyofthesurrounding
willbenegative(
).
Hence,thecorrectoptionis(B).
Q4.JEEAdvanced2014Paper2
1
1
X
and
Y
aretwovolatileliquidswithmolarweights10gmol
and40gmol
,respectively.
Twocottonplugs,onesoakedin
X
andtheothersoakedin
Y
,aresimultaneouslyplacedat
theendsofatubeoflength
L
=24cm,asshowninthefigure.Thetubeisfilledwithaninert
gasat1atmospherepressureandatemperatureof300K.Vapoursof
X
and
Y
reacttoform
aproduct,whichisfirstobservedatadistance
d
cmfromtheplugsoakedin
X
.Take
X
and
Y
tohaveequalmoleculardiametersandassumeidealbehaviourfortheinertgasandthetwo
vapours.
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Thevalueof
d
incm(showninthefigure),asestimatedfromGraham'sLaw,is
(A)8
(B)12
(C)16
(D)20
CorrectAnswer
:OptionC
AccordingtoGraham'sLawofDiffusion,"undersimilarconditionsoftemperatureand
pressure,therateofdiffusionofagasisinverselyproportionaltothesquarerootofits
density."
Inotherwords,itcanalsobewrittenas
gas.
,where
M
isthemolecularmassofthe
Inthegivenreaction,vapoursofgasXandgasYdiffuseinthetubetoformaproductat
distance
d
fromtheplugsoakedinX.
Thus,accordingtoGraham'sLawofDiffusion,
Hence,thecorrectoptionis(C).
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Q5.JEEAdvanced2013Paper1
+
ThearrangementofX
ionsaroundA
ioninsolidAXisgiveninthefigure(notdrawnto
+
scale).IftheradiusofXis250
pm
,theradiusofA
is
(A)104
pm
(B)125
pm
(C)183
pm
(D)57
pm
CorrectAnswer
:OptionA
+
Fromthegivenfigure,itcanbesaidthatcationA
occupiestheoctahedralvoidformedbythe
X
anions.Theradiusratiorangeis0.4140.732,Therefore,
Sinceminimumvalueforacationtoaccommodateanoctahedralvoidwithoutdistortionis
0.414,thereforeradiusofcationis103.5~104pm.
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