Material Safety Data Sheet

Accepta 2610
1.

Company Identification and Product Information

Product Name:

Accepta 2610

Application

Cyclohexylamine for Industrial Water Treatment

Supplier:

Accepta Ltd
Statham House
Talbot Road
Manchester
M32 0FP

Telephone
Fax
Email
Website

0161 877 2334

0870 135 6389
info@accepta.com
www.accepta.com

Emergency (only) Telephone: 0161 877 2334

2.

Hazard Identification
2.1. Classification of the substance or mixture
2.2. Label elements
Contains
CYCLOHEXYLAMINE
MORPHOLINE
Labelling

Risk Phrases
R21/22

Harmful in contact with skin and if swallowed.

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R34
R62
Safety Phrases
S24/25
S26
S36/37/39
S45
S60
2.3. Other hazards

3.

Causes burns.
Possible risk of impaired fertility.
Avoid contact with skin and eyes.
In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell, seek medical advice immediately
(show label where possible).
This material and its container must be disposed of as hazardous waste.

Composition Information
3.2. Mixtures
CYCLOHEXYLAMINE 30-60%
CAS-No.: 108-91-8
Classification (EC 1272/2008)
Flam. Liq. 3 - H226
Acute Tox. 4 - H302
Acute Tox. 4 - H312
Skin Corr. 1B - H314

EC No.: 203-629-0
Classification (67/548/EEC)
Xn;R21/22.
Repr. Cat. 3;R62.
C;R34.
R10.

Repr. 2 - H361f
MORPHOLINE 10-30%
CAS-No.: 110-91-8
EC No.: 203-815-1
Classification (EC 1272/2008)
Classification (67/548/EEC)
Flam. Liq. 3 - H226
R10
Acute Tox. 4 - H302
C;R34
Acute Tox. 4 - H312
Xn;R20/21/22
Acute Tox. 4 - H332
Skin Corr. 1B - H314
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
Aqueous solution of Amines

4.

First Aid Measures

4.1. Description of first aid measures
Inhalation
Remove victim immediately from source of exposure. Provide fresh air, warmth and rest, preferably in a
comfortable upright sitting position. Get medical attention if any discomfort continues.
Ingestion
NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Do not induce vomiting. If vomiting
occurs, the head should be kept low so that stomach vomit doesn't enter the lungs. Rinse mouth thoroughly. Get
medical attention.
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Skin contact
Remove contaminated clothes and rinse skin thoroughly with water. Continue to rinse for at least 15 minutes.
Get medical attention if irritation persists after washing.
Eye contact
Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide
apart.
Important! Immediately rinse with water for at least 15 minutes. Get medical attention promptly if symptoms occur
after washing.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation.
No specific symptoms noted. Irritation of nose, throat and airway.
Ingestion
May cause chemical burns in mouth and throat. Nausea, vomiting.
Skin contact
Chemical burns.
Eye contact
May cause blurred vision and serious eye damage.
4.3. Indication of any immediate medical attention and special treatment needed
Probable mucosal damage may contraindicate the use of gastric lavage.

5.

Fire Fighting Measures

5.1. Extinguishing media
Extinguishing media
Fire can be extinguished using: Foam. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. Water spray,
fog or mist.
5.2. Special hazards arising from the substance or mixture
Unusual Fire & Explosion Hazards
If heated, volume and pressure increases strongly, resulting in explosion of container.
Specific hazards
Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of: Nitrogen.
5.3. Advice for firefighters
Special Fire Fighting Procedures
Move container from fire area if it can be done without risk. Cool containers exposed to flames with water until
well after the fire is out. Keep run-off water out of sewers and water sources. Dike for water control.
Protective equipment for fire-fighters
Leave danger zone immediately. Self contained breathing apparatus and full protective clothing must be worn in
case of fire.

6.

Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures
Follow precautions for safe handling described in this safety data sheet. For personal protection, see section 8.
6.2. Environmental precautions
Avoid release to the environment. To prevent release, place container with damaged side up.
6.3. Methods and material for containment and cleaning up
Absorb in vermiculite, dry sand or earth and place into containers. Containers with collected spillage must be
properly labelled with correct contents and hazard symbol.
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6.4. Reference to other sections

For waste disposal, see section 13.

7.

Handling and Storage

7.1. Precautions for safe handling
Avoid spilling, skin and eye contact. Avoid inhalation of vapours and spray mists. Keep away from heat, sparks
and open flame. Observe good chemical hygiene practices.
7.2. Conditions for safe storage, including any incompatibilities
Store in closed original container in a dry place. Do not store near heat sources or expose to high temperatures.
Store away from: Acids. Oxidising material.
Storage Class
Corrosive storage.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.

8.

Exposure Controls
8.1. Control parameters
Name
STD
TWA - 8 Hrs
CYCLOHEXYLAMINE
WEL 10 ppm - 41 mg/m3
MORPHOLINE
WEL 10 ppm - 36 mg/m
WEL = Workplace Exposure Limit.
Sk = Can be absorbed through skin.
Ingredient Comments
WEL = Workplace Exposure Limits
8.2. Exposure controls
Protective equipment

STEL - 15 Min

Notes

320 ppm72 mg/m3

Sk

Process conditions
Provide eyewash station.
Engineering measures
Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of
vapours.
Respiratory equipment
No specific recommendation made, but respiratory protection must be used if the general level exceeds the
recommended occupational exposure limit.
Hand protection
Wear protective gloves. Breakthrough time is dependent on the characteristics of the brand of glove used,
consult your supplier. It has been found that gloves made from rubber, neoprene or PVC provide short-term
splash protection.
Eye protection
Wear approved safety goggles.
Use face shield in case of splash risk.
Other Protection
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Wear suitable protective clothing as protection against splashing or contamination.

Hygiene measures
Promptly remove any clothing that becomes contaminated. Remove contaminated clothing and wash the skin
thoroughly with soap and water after work. Wash hands at the end of each work shift and before eating, smoking
and using the toilet.
Skin protection
Wear apron or protective clothing in case of splashes.

9.

Physical and Chemical Properties

Appearance:
Colour:
Odour:
Solubility:
Initial boiling point & boiling range:
Melting point (C):
Relative density:
Vapour density (air=1):
Vapour pressure:
Evaporation rate:
pH, Conc. Solution:
Viscosity:
Decomposition temperature (C):
Odour Threshold, Lower:
Odour Threshold, Upper:
Flash point:
Auto Ignition Temperature (C):
Flammability Limit - Lower(%):
Flammability Limit - Upper(%):
Partition Coefficient
(N-Octanol/Water):
Explosive properties:
Oxidising properties:

Clear liquid.
Colourless to pale yellow.
Amine.
Miscible with water
Not available.
Not available.
0.97 - 1.00 @ 20 C
Not available.
Not available.
Not available.
12.5 - 13.5
Not available.
Not available.
Not available.
Not available.
80 PM Closed cup.
Not available.
Not available.
Not available.
Not available.
Scientifically unjustified.
Does not meet the criteria for oxidising.

10. Stability and Reactivity

10.1. Reactivity
Exothermic reaction with: Acids.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Hazardous Polymerisation
Will not polymerise.
10.4. Conditions to avoid
Avoid heat, flames and other sources of ignition. Avoid excessive heat for prolonged periods of time.
10.5. Incompatible materials
Materials To Avoid
Strong acids. Strong oxidising substances.
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10.6. Hazardous decomposition products

Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of: Nitrogen.

11. Toxicological Information

11.1. Information on toxicological effects
Inhalation
May cause irritation to the respiratory system.
Ingestion
Harmful if swallowed.
Skin contact
Harmful in contact with skin. Causes burns.
Eye contact
Risk of serious damage to eyes. Causes burns.
Health Warnings
This chemical may cause skin/eye irritation and burns (corrosive).
Route of entry
Skin and/or eye contact. Ingestion. Inhalation.
Toxicological information on ingredients.
MORPHOLINE (CAS: 110-91-8)
Aspiration hazard:
Inhalation
Irritating to respiratory system. High concentrations of vapours may irritate respiratory system and lead to
headache, fatigue, nausea and vomiting.
Ingestion
Harmful if swallowed. Liquid irritates mucous membranes and may cause abdominal pain if swallowed. May
cause nausea, headache, dizziness and intoxication.
Skin contact
Prolonged contact may cause redness and irritation. Product has a defatting effect on skin.
Eye contact
Irritating and may cause redness and pain. Risk of corneal damage.
CYCLOHEXYLAMINE (CAS: 108-91-8)
Other Health Effects
Toxic to Reproductive Health Category 3.
Aspiration hazard:
Inhalation
Harmful by inhalation. Vapours irritate the respiratory system, and may cause coughing and difficulties in
breathing.
Ingestion
Causes burns. Harmful if swallowed. Ingestion may cause severe irritation of the mouth, the oesophagus and the
gastrointestinal tract. Nausea, vomiting.
Skin contact
Causes burns. Harmful in contact with skin.
Causes severe burns. May cause blurred vision and serious eye damage. Irritation, burning, lachrymation,
blurred vision after liquid splash.

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12. Ecological Information

Ecotoxicity
Ecotoxicity information based on the individual components properties.
12.1. Toxicity
12.2. Persistence and degradability
Ecological information on ingredients.
MORPHOLINE (CAS: 110-91-8)
Degradability
The product is easily biodegradable.
CYCLOHEXYLAMINE (CAS: 108-91-8)
Degradability
The product is easily biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential
The product does not contain any substances expected to be bioaccumulating.
Partition coefficient
Not available.
Ecological information on ingredients.
MORPHOLINE (CAS: 110-91-8)
Bioaccumulative potential
The product does not contain any substances expected to be bioaccumulating.
12.4. Mobility in soil
Ecological information on ingredients.
MORPHOLINE (CAS: 110-91-8)
Mobility:
The product is soluble in water.
CYCLOHEXYLAMINE (CAS: 108-91-8)
Mobility:
The product is soluble in water.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
Not available.

13. Disposal Considerations

General information
When handling waste, consideration should be made to the safety precautions applying to handling of the
product.
13.1. Waste treatment methods
Dispose of waste and residues in accordance with local authority requirements.

14. Transportation Information

14.1. UN number

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UN No. (ADR/RID/ADN)
UN No. (IMDG)
UN No. (ICAO)
14.2. UN proper shipping name
Proper Shipping Name

3267
3267
3267
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S., (contains
cyclohexylamine)

14.3. Transport hazard class(es)

ADR/RID/ADN Class
Class 8: Corrosive substances.
IMDG Class
8
ICAO Class/Division
8
Transport Labels

14.4. Packing group

ADR/RID/ADN Packing
III
group
IMDG Packing group
III
ICAO Packing group
III
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
EMS
F-A, S-B.
Emergency Action Code
2X
Hazard No. (ADR)
80 Corrosive or slightly Corrosive substance.
Tunnel Restriction Code
(E)
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Classification Code (Adr)
C7

15. Regulatory Information

15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning
the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European
Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and
Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives
91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of
the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of
substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006 with amendments.
15.2. Chemical Safety Assessment

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16. Other Information

General information
For advice on chemical emergencies, spillages, fires or first aid in relation to this product please contact the
relevant emergency number.
Risk Phrases In Full
R34
Causes burns.
R10
Flammable.
R20/21/22
Harmful by inhalation, in contact with skin and if swallowed.
R21/22
Harmful in contact with skin and if swallowed.
R62
Possible risk of impaired fertility.
Hazard Statements In Full
H226
Flammable liquid and vapour.
H302
Harmful if swallowed.
H312
Harmful in contact with skin.
H314
Causes severe skin burns and eye damage.
H332
Harmful if inhaled.
H361f
Suspected of damaging fertility.
Disclaimer
For safety reasons it is IMPERATIVE that customers:1. Ensure that all those within their control who use the products are supplied with all relevant information
contained within the Safety Data Sheet and Technical Bulletin concerning the applications for which the product
is designed and any instructions and warnings contained therein.
2. Consult us before using or supplying the product for any other applications.
The information contained herein is based on the present state of our knowledge and is intended to describe our
products from the point of view of safety requirements. It should not therefore be construed as guaranteeing
specific properties.
3. This information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process. Such information is, to the best of the company's
knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or
representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself
as to the suitability of such information for his own particular use.
IMPORTANT NOTICE
The information contained in this Safety Data Sheet is to be used in conjunction with the additional information,
precautions and instructions for use. It is the responsibility of the employer to ensure that all persons who use or
handle this product should have access to, and be aware of, the information contained herein.
Revision Date: August 2013
Doc. Ref. 08-13.

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