SET-3

H$moS> Z.

Series SSO

Code No.

amob Z.

56/3/MT

narjmWu H$moS >H$mo Cma-nwpVH$m Ho$ _wI-n

>na Ad` {bIo &

Roll No.

Candidates must write the Code on the

title page of the answer-book.

H$n`m OmM H$a b| {H$ Bg Z-n _o _w{V n> 15 h &

Z-n _| Xm{hZo hmW H$s Amoa {XE JE H$moS >Z~a H$mo N>m Cma -nwpVH$m Ho$ _wI-n> na
{bI| &
H$n`m OmM H$a b| {H$ Bg Z-n _| >26 Z h &
H$n`m Z H$m Cma {bIZm ew$ H$aZo go nhbo, Z H$m H$_mH$ Ad` {bI| &
Bg Z-n H$mo nT>Zo Ho$ {bE 15 {_ZQ >H$m g_` {X`m J`m h & Z-n H$m {dVaU nydm
_| 10.15 ~Oo {H$`m OmEJm & 10.15 ~Oo go 10.30 ~Oo VH$ N>m Ho$db Z-n H$mo nT>|Jo
Ama Bg Ad{Y Ho$ XmamZ do Cma-nwpVH$m na H$moB Cma Zht {bI|Jo &
Please check that this question paper contains 15 printed pages.
Code number given on the right hand side of the question paper should be
written on the title page of the answer-book by the candidate.
Please check that this question paper contains 26 questions.
Please write down the Serial Number of the question before
attempting it.
15 minute time has been allotted to read this question paper. The question
paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the
students will read the question paper only and will not write any answer on
the answer-book during this period.

agm`Z {dkmZ (gmpVH$)

CHEMISTRY (Theory)

{ZYm[aV g_` : 3 KQ>o

A{YH$V_ AH$ : 70

Time allowed : 3 hours

56/3/MT

Maximum Marks : 70
1

P.T.O.

gm_m` {ZX}e :
(i)

g^r Z A{Zdm` h &

(ii)

Z g`m 1 go 5 VH$ A{V bKw-Cmar` Z h Ama `oH$ Z Ho$ {bE 1 AH$ h &

(iii)

Z g`m 6 go 10 VH$ bKw-Cmar` Z h Ama `oH$ Z Ho$ {bE 2 AH$ h &

(iv)

Z g`m 11 go 22 VH$ ^r bKw-Cmar` Z h Ama `oH$ Z Ho$ {bE 3 AH$ h &

(v)

Z g`m 23 _y`mYm[aV Z h Ama BgHo$ {bE 4 AH$ h &

(vi)

Z g`m 24 go 26 VH$ XrK-Cmar` Z h Ama `oH$ Z Ho$ {bE 5 AH$ h &

(vii)

`{X Amd`H$Vm hmo, Vmo bmJ Q>o~bm| H$m `moJ H$a| & H$Hw$boQ>am| Ho$ Cn`moJ H$s AZw_{V
Zht h &

General Instructions :
(i)

All questions are compulsory.

(ii)

Questions number 1 to 5 are very short answer questions and carry

1 mark each.

(iii)

Questions number 6 to 10 are short answer questions and carry 2 marks

each.

(iv)

Questions number 11 to 22 are also short answer questions and carry

3 marks each.

(v)

Question number 23 is a value based question and carry 4 marks.

(vi)

Questions number 24 to 26 are long answer questions and carry 5 marks

each.

(vii)

Use log tables, if necessary. Use of calculators is not allowed.

1.

1 _mob Al3+

Ho$

Al _|

AnM`Z H$aZo na {H$VZm Amdoe (MmO) (\$amS>o _|) bJoJm

How much charge in Faradays is required for the reduction of 1 mol of

Al3+ to Al ?
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2.

{ZZ{b{IV `w_ _| go H$mZ

SN2 A{^{H$`m

CH3 CH2 Br

Ama

A{YH$ VrdVm go H$aoJm

CH3
|
CH3 C CH3
|
Br

Which would undergo SN2 reaction faster in the following pair :

CH3
|
CH3 CH2 Br and CH3 C CH3
|
Br
3.

{XE JE `m{JH$ H$m AmB.`y.nr.E.gr. Zm_ {b{IE

CH3 O CH2 CH CH3

|
OH
Write the IUPAC name of the given compound :
CH3 O CH2 CH CH3
|
OH
4.

n|Q>m| H$s n[ajo{nV mdWm Ama n[ajonU _m`_ H$mo {b{IE &

Write the dispersed phase and dispersion medium of paints.

5.

H$mna na_mUw _| _yb AdWm _|

Vd h & `m| ?

d-Am{~Q>b|

nyar Vah go ^ar hB h {\$a ^r `h EH$ gH$_U

1

Copper atom has completely filled d-orbitals in its ground state but it is a
transition element. Why ?
6.

{ZZ{b{IV H$mo `dpWV H$s{OE :

(i)
jmar` gm_` Ho$ ~T>Vo hE H$_ _|

C6H5 NH2, CH3 CH2 NH2, C6H5 NH CH3

(ii)

dWZmH$ Ho$ ~T>Vo hE H$_ _|

C2H5 OH, CH3 CH2 NH2, CH3 NH CH3

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Arrange the following :

(i)

in increasing order of basic strength

C6H5 NH2, CH3 CH2 NH2, C6H5 NH CH3

(ii)

in increasing order of boiling point

C2H5 OH, CH3 CH2 NH2, CH3 NH CH3

7.

Xa pWamH$ (k) H$mo n[a^m{fV H$s{OE & {ZZ{b{IV Ho$ {bE Xa pWamH$ Ho$ _mH$
{b{IE :
(i)
W_ H$mo{Q> A{^{H$`m
(ii)
{Vr` H$mo{Q> A{^{H$`m

Define rate constant (k). Write the unit of rate constant for the following :

8.

(i)

First order reaction

(ii)

Second order reaction

{ZZ{b{IV H$s gaMZmE Amao{IV H$s{OE

(i)

H2S2O7

(ii)

XeO3

Write the structures of the following :

9.

(i)

H2S2O7

(ii)

XeO3

dmn Xm~ Ho$ Amno{jH$ AdZ_Z Ama {dbo` Ho$ _moba `_mZ Ho$ ~rM g~Y H$mo `wn
H$s{OE &
Derive the relationship between relative lowering of vapour pressure and
molar mass of the solute.

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10.

H$mbog [Co(NH3)5(CO3)]Cl H$m AmB.`y.nr.E.gr. Zm_ {b{IE & Bg H$mbog mam

{H$g H$ma H$s g_md`dVm XemB OmVr h ?

AWdm
AmB.`y.nr.E.gr. n{V H$m Cn`moJ H$aVo hE {ZZ{b{IV Cnghg`moOZ `m{JH$m| Ho$ gy
{b{IE :

(i)

Q>oQ>mbmoamBS>mo`yoQ>(II)

(ii)

nmoQ>{e`_ Q>oQ>mhmBS>mgmoqOHo$Q>(II)

Write down the IUPAC name of the complex [Co(NH3)5(CO3)]Cl. What

type of isomerism is shown by this complex ?
OR
Using IUPAC norms write the formulae for the following coordination
compounds :

11.

(i)

Tetrachloridocuprate(II)

(ii)

Potassium tetrahydroxozincate(II)

{ZZ{b{IV Ho$ {bE H$maU Xr{OE

(a)

p-ZmBQ>mo\$sZmb

AnojmH$V o-ZmBQ>mo\$sZmb go A{YH$ Abr` h &

(b)

BWam| _| C O C Am~Y H$moU MVw\$bH$s` H$moU

hmoVm h &

(c)

(CH3)3C Br

O~

NaOCH3

(10928)

go WmoS>m ~S>m

go A{^{H$`m H$aVm h V~ EH$ EoH$sZ XoVm h Z

{H$ EH$ BWa &

Give reasons for the following :
(a)

p-nitrophenol is more acidic than o-nitrophenol.

(b)

Bond angle C O C in ethers is slightly higher than the

tetrahedral angle (10928).

(c)

(CH3)3C Br on reaction with NaOCH3 gives an alkene instead of

an ether.

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P.T.O.

12.

{ZZ{b{IV $nmVaU Amn H$go H$a|Jo

(i)

Eo{ZbrZ H$m ~oOrZ _|

(ii)

EWoZo_mBS> H$m _oWZEo_rZ _|

(iii)

ZmBQ>mo~oOrZ H$m Eo{ZbrZ _|

AWdm
{ZZ{b{IV A{^H$maH$m| Ho$ gmW O~
amgm`{ZH$ g_rH$aUm| H$mo {b{IE
(i)

CH3COCl/{n[aS>rZ

(ii)

C6H5SO2Cl

(iii)

CHCl3 + KOH

C2H5NH2

H$mo CnMm[aV {H$`m OmVm h V~ g~

How do you convert the following :

(i)

Aniline to benzene

(ii)

Ethanamide to methanamine

(iii)

Nitrobenzene to aniline
OR

Write the chemical equations involved when C2H5NH2 is treated with

the following reagents :
(i)

CH3COCl/pyridine

(ii)

C6H5SO2Cl

(iii)

CHCl3 + KOH

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13.

{ZZ{b{IV nXm| H$mo n[a^m{fV H$s{OE

(i)
F-g|Q>a
(ii)
p-Q>mBn AYMmbH$
(iii) \o$arMw~H$d

Define the following terms :

14.

(i)

F-centre

(ii)

p-type semiconductor

(iii)

Ferrimagnetism

O~ Vmn_mZ
pWamH$

300 K

2 102

go

320 K

go ~T>H$a

n[ad{VV hmoVm h Vmo W_ H$mo{Q> H$s A{^{H$`m H$m Xa

8 102

hmo OmVm h & g{H$`U D$Om

(Ea)

H$m n[aH$bZ

H$s{OE &

3
(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)

The rate constant of a first order reaction increases from 2 102 to

8 102 when the temperature changes from 300 K to 320 K. Calculate
the energy of activation (Ea).
(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)

15.

{ZZ{b{IV nXm| H$mo n[a^m{fV H$s{OE

(i)

g_mJr CoaU

(ii)

H$XZ

(iii)

_H$mo-AmpdH$ H$mobmBS>|

Define the following terms :

(i)

Homogeneous catalysis

(ii)

Coagulation

(iii)

Macromolecular colloids

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P.T.O.

16.

{ZZ{b{IV _| `oH$ A{^{H$`m Ho$ _w` CnmX H$s gaMZmE {b{IE

Write the structure of the major product in each of the following

reactions :

17.

(i)

YmVwAm| Ho$ OmoZ n[aH$aU Ho$ nrN>o Omo {gmV h, CgH$m CoI H$s{OE &

(ii)

dU (JmoS>) Ho$ {ZH$fU _| VZw

(iii)

Am`aZ H$m H$mZ-gm $n (\$m_) `mnm[aH$ Am`aZ H$m ewV_ $n h

(i)

Mention the principle behind the zone refining of metals.

(ii)

What is the role of dilute NaCN in the extraction of gold ?

(iii)

Which form of iron is the purest form of commercial iron ?

56/3/MT

NaCN H$s

`m ^y{_H$m h

?
?

18.

90 g

~oOrZ _| O~ EH$ Admnerb {dbo` H$m

dWZmH$

353.23 K

go ~T>H$a

353.93 K

1.5 g

Kwbm`m OmVm h, V~ ~oOrZ H$m

hmo OmVm h & {dbo` H$m _moba `_mZ

n[aH${bV H$s{OE &

(~oOrZ

H$m

Kb = 2.52 K kg mol1)

When 1.5 g of a non-volatile solute was dissolved in 90 g of benzene, the

boiling point of benzene raised from 353.23 K to 353.93 K. Calculate the
molar mass of the solute.
(Kb for benzene = 2.52 K kg mol1)

19.

20.

(i)

O~ D-byH$mog

(ii)

moQ>rZm| _| {H$g H$ma H$m qbHo$O CnpWV hmoVm h

(iii)

DNA Ama RNA Ho$

(i)

Write the product obtained when D-glucose reacts with Br2 water.

(ii)

What type of linkage is present in proteins ?

(iii)

Write one difference between DNA and RNA.

(a)

{ZZ{b{IV H$mbogm| _| gH$aU Ama CZH$m AmH$ma {b{IE

56/3/MT

go A{^{H$`m H$aVm h Vmo mV CnmX H$mo {b{IE &

?

~rM EH$ AVa H$mo {b{IE &

(i)

[Co(NH3)6]3+

(ii)

[NiCl4]2

(na_mUw H$_mH$
(b)

Br2 Ob

: Co = 27, Ni = 28)

Ama en _| H$mZ-gm {bJS> YmVw Ho$ gmW A{YH$ Wm`r H$mbog ~ZmVm
h Ama `m| ?
NH3

P.T.O.

(a)

Write the hybridization and shape of the following complexes :

(i)

[Co(NH3)6]3+

(ii)

[NiCl4]2

(Atomic number : Co = 27, Ni = 28)

(b)

Out of NH3 and en, which ligand forms more stable complex with
metal and why ?

21.

{ZZ{b{IV ~hbH$m| Ho$ EH$bH$m| Ho$ Zm_ Ama CZH$s gaMZmE {b{IE
(i)

~wZm-N

(ii)

~oHo$bmBQ>

(iii)

Q>obmZ

Write the names and structures of the monomers of the following

polymers :

22.

(i)

Buna-N

(ii)

Bakelite

(iii)

Teflon

{ZZ{b{IV Ho$ {bE H$maU Xr{OE :

(i)
S>mBZmBQ>moOZ EH$ Jg h naVw \$m\$moag EH$ R>mog h &
(ii)
H2O go H2Te VH$ Am~Y H$moU KQ>Vm h &
(iii) hbmoOZm| H$s A{YH$V_ G$Um_H$ BboQ>mZ mpV EWnr hmoVr h &
Give reasons for the following :
(i)

Dinitrogen is a gas but phosphorus is a solid.

(ii)

Bond angle decreases from H2O to H2Te.

(iii)

Halogens have the maximum negative electron gain enthalpy.

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10

23.

OdmZ ~m| _| _Yw_oh Ama AdgmX (CXmgr) H$s ~T>Vr g`m H$mo XoIH$a, EH$ {g
Hy$b Ho$ q{gnb lr MmonS>m Zo EH$ go{_Zma H$m Am`moOZ {H$`m {Og_| A` q{gnbm| Ama
~m| Ho$ _mVm-{nVmAm| H$mo Am_{V {H$`m & `h {ZU` {b`m J`m {H$ Hy$bm| _| gS>o hE
ImZo H$s dVwE ~X H$s OmE Ama dm`dYH$ dVwE Ogo gyn, bgr, XY, Am{X CnbY
H$amB OmE & Chm|Zo `h ^r {ZU` {b`m {H$ Hy$bm| _| amoO mVH$mb H$s Eogo~br Ho$ g_`
~m| H$mo AmYm KQ>o H$m emar[aH$ `m`m_ A{Zdm` $n go H$am`m OmE & N> _mh Ho$
nMmV, lr MmonS>m Zo A{YH$Va Hy$bm| _| {\$a dm` narjU H$am`m Ama ~m| Ho$
dm` _| AZwn_ gwYma nm`m J`m &
Cn`w$ {ddaU H$mo nT>H$a {ZZ{b{IV Zm| Ho$ Cma Xr{OE :
(i)
lr MmonS>m mam {H$Z _y`m| (H$_-go-H$_ Xmo) H$mo X{eV {H$`m J`m

(ii)

EH$ {dmWu Ho$ $n _|, Amn Bg {df` _| H$go OmJ$H$Vm \$bmEJo

(iii)

{~Zm S>mQ>a H$s gbmh {V-AdgmXH$ S>g H$m godZ `m| Zht H$aZm Mm{hE
H${_ _YwH$mar nXmWm] Ho$ Xmo CXmhaU Xr{OE &

(iv)

Seeing the growing cases of diabetes and depression among young

children, Mr. Chopra, the principal of one reputed school organized a
seminar in which he invited parents and principals. They all resolved
this issue by strictly banning junk food in schools and introducing
healthy snacks and drinks like soup, lassi, milk, etc. in school canteens.
They also decided to make compulsory half an hour of daily physical
activities for the students in the morning assembly. After six months,
Mr. Chopra conducted the health survey in most of the schools and
discovered a tremendous improvement in the health of the students.
After reading the above passage, answer the following questions :
(i)

What are the values (at least two) displayed by Mr. Chopra ?

(ii)

As a student, how can you spread awareness about this issue ?

(iii)

Why should antidepressant drugs not be taken without consulting

a doctor ?

(iv)

Give two examples of artificial sweeteners.

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P.T.O.

24.

(a)

{ZZ{b{IV A{^{H$`mAm| _|

(b)

{ZZ{b{IV Ho$ ~rM AVa H$s{OE

(c)

A, B, C Ama D H$s

C6H5 COCH3

(ii)

~oOmoBH$ Ab Ama \$sZmb _|

2-hmBS>mgr~oOpS>hmBS>

(i)

Ama

gaMZmE {b{IE

C6H5 CO CH2CH3

_|

H$s gaMZm {b{IE &

AWdm
(a)

O~ EWoZob

(CH3 CHO)

{ZZ{b{IV A{^H$maH$m| Ho$ gmW A{^{H$`m H$aVm h,

Vmo mV _w` CnmXm| H$s gaMZmAm| H$mo {b{IE

(b)

(i)

HCN

(ii)

H2N NH2/H+

(iii)

LiAlH4

Zm{^H$Zohr gH$bZ A{^{H$`m Ho$ {V CZH$s ~T>Vr hB A{^{H$`merbVm Ho$ H$_

_| {ZZ{b{IV H$mo `dpWV H$s{OE :
C6H5COCH3, CH3 CHO, CH3 CO CH3

(c)

{ZZ{b{IV `m{JH$ `w_ Ho$ ~rM AVa H$aZo Ho$ {bE EH$ gm_m` amgm`{ZH$ OmM
Xr{OE :
CH3CH2CHO

56/3/MT

Ama

CH3CHO
12

(a)

Write the structures of A, B, C and D in the following reactions :

(b)

Distinguish between the following :

(c)

(i)

C6H5 COCH3 and C6H5 CO CH2CH3

(ii)

Benzoic acid and Phenol

Write the structure of 2-hydroxybenzaldehyde.

OR

(a)

(b)

Write the structures of the main products when ethanal

(CH3 CHO) reacts with the following reagents :
(i)

HCN

(ii)

H2N NH2/H+

(iii)

LiAlH4

Arrange the following in the increasing order of their reactivity

towards nucleophilic addition reaction :
C6H5COCH3, CH3 CHO, CH3 CO CH3

(c)

Give a simple chemical test to distinguish between the following

pair of compounds :
CH3CH2CHO and CH3CHO

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P.T.O.

25.

{ZZ{b{IV gob Ho$ {bE {dwV-dmhH$ ~b (B.E_.E\$.) Ama

G H$m

n[aH$bZ H$s{OE

Ni (s) | Ni2+ (0.01 M) | | Ag+ (0.001 M) | Ag (s)

{X`m J`m h

: E0(Ni2+ / Ni) = 0.25 V, E0(Ag+ /Ag) = + 0.80 V

AWdm
Ho$ 0.1 mol L1 {db`Z H$s MmbH$Vm 1.06 102 S cm1 h & BgH$s
_moba MmbH$Vm Ama {d`moOZ-_mm () H$mo n[aH${bV H$s{OE & {X`m J`m h
0(Na+) = 50.1 S cm2 mol1 Ama 0(Cl) = 76.5 S cm2 mol1.

(a)

NaCl

(b)

mW{_H$ Ama {Vr`H$ ~Q>ar Ho$ ~rM `m AVa hmoVm h

EH$-EH$ CXmhaU Xr{OE &

`oH$ H$ma H$m

5

Calculate e.m.f. and G for the following cell :

Ni (s) | Ni2+ (0.01 M) | | Ag+ (0.001 M) | Ag (s)
Given : E0(Ni2+ / Ni) = 0.25 V, E0(Ag+ /Ag) = + 0.80 V
OR
(a)

The conductivity of 0.1 mol L1 solution of NaCl is

1.06 102 S cm1. Calculate its molar conductivity and degree
of dissociation (). Given 0(Na+) = 50.1 S cm2 mol1 and
0(Cl) = 76.5 S cm2 mol1.

26.

(b)

What is the difference between primary battery and secondary

battery ? Give one example of each type.

(a)

{ZZ{b{IV H$mo H$maU XoVo hE n> H$s{OE :

(i)
Ce4+ Obr` {db`Z _| EH$ ~b CnMm`H$ h &
(ii) gH$_U YmVwAm| H$s na_mpdH$aU H$s EWnr C hmoVr h &
(iii) 3d loUr _| _JZrO (Mn) gdm{YH$ CnM`Z AdWmE XemVm h &

(b)

{ZZ{b{IV g_rH$aUm| H$mo nyU H$s{OE

(i)

2 Mn O 4 + 6 H+

(ii)

Cr2 O7

+ 5 NO2

+ 14 H+ + 6 Fe2+

AWdm
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14

(a)

(b)

{ZZ{b{IV H$mo H$maU g{hV g_PmBE

(i)

gH$_U YmVwE aJrZ `m{JH$ ~ZmVr h &

(ii)

Cr2+ EH$

(iii)

EopQ>Zm`S>| AnZo BboQ>m{ZH$ {d`mg _| A{Z`{_VVmE XemVo h &

~b AnMm`H$ h &

bWZm`S> gHw$MZ H$mo n[a^m{fV H$s{OE & bWZm`S>m| H$s gm_m` CnM`Z AdWm
{b{IE &

(a)

(b)

Account for the following :

(i)

Ce4+ is a strong oxidizing agent in aqueous solution.

(ii)

Transition metals have high enthalpy of atomization.

(iii)

Mn shows maximum number of oxidation states in 3d series.

Complete the following equations :

(i)

2 Mn O 4 + 6 H+

(ii)

Cr2 O7

+ 5 NO2

+ 14 H+ + 6 Fe2+
OR

(a)

(b)

Account for the following :

(i)

Transition metals form coloured compounds.

(ii)

Cr2+ is a strong reducing agent.

(iii)

Actinoids
show
configurations.

irregularities

in

their

electronic

Define lanthanoid contraction. Write the common oxidation state

of lanthanoids.

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P.T.O.