Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
M
Assignment
Course
Coordinator: Dr.
M.D Omprakash
Submitted by:
Siddhant Das (1484)
Varun Rathi (1440)
Abhishek Das (1403)
Noopur Singh (1424)
Table of Contents
1
1.1.1
Bio-Alcohol...............................................................................................................2
1.1.2
Aviation Biofuel.........................................................................................................2
1.1.3
Biodiesel....................................................................................................................3
1.1.4
Bio-ether....................................................................................................................3
1.1.5
Biogas........................................................................................................................3
1.1.6
Syngas........................................................................................................................3
1.1.7
Solid Biofuel..............................................................................................................4
1.1.8
Advanced Biofuel......................................................................................................4
Advantages of biofuels......................................................................................................5
2.1.1
Safety.........................................................................................................................5
2.1.2
2.1.3
2.1.4
2.1.5
Cost Benefit...............................................................................................................5
2.1.6
Easy To Source..........................................................................................................6
2.2
Disadvantages of biofuels.................................................................................................6
2.2.1
2.2.2
Monoculture...............................................................................................................6
2.2.3
Use of Fertilizers........................................................................................................6
2.2.4
Shortage of Food........................................................................................................6
2.2.5
Industrial Pollution....................................................................................................7
2.2.6
Water Use...................................................................................................................7
2.2.7
2.3
3
Types of biofuels...............................................................................................................1
Economics of Bio-fuels....................................................................................................9
3.1.1
3.1.2
Energy Plantations.....................................................................................................9
3.1.3
Biofuel Blending........................................................................................................9
3.2
3.3
4.1.1
4.1.2
4.1.3
4.1.4
4.2
5
Results.............................................................................................................................14
Constraints......................................................................................................................17
References..........................................................................................................................18
List of Figures
Figure 1: Types of Biofuels.............................................................................................................1
Figure 2: Biodiesel Production across the world.............................................................................3
Figure 3: Net Energy Balance........................................................................................................14
Figure 4: Net Carbon Balance.......................................................................................................15
Figure 5: Net Carbon Ratio............................................................................................................15
Figure 6: % Carbon Reduction......................................................................................................16
List of Tables
Table 1: Average octane of various biofuels....................................................................................2
Table 2: Cost Benefit Matrix for Biodiesel....................................................................................11
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Figure 1: Types of Biofuels
1.1.1
Bio-Alcohol
Bio-Alcohol is an old concept. Henry Ford made an eco-friendly model-T car in 1940s which
used to run on ethanol and made up of hemp. "There's enough alcohol in one year's yield of an
acre of potatoes to drive the machinery necessary to cultivate the fields for one hundred years." Henry Ford
Methanol, ethanol, propanol, and butanol, are of greatest interest for fuel use as their chemical
properties make them useful in internal combustion engines. The below chart shows the energy
densities and octane vale of first four alcohols:
Table 1: Average octane of various biofuels
Octane value is the measure of the ignition quality of gas. Higher octane value indicates a fuel
that burns slowly and it shows how much susceptible is the fuel to 'knocking'.
1.1.2
Aviation Biofuel
As the Carbon foot print of the aviation industry is very high so by using these aviation bio-fuels
the carbon foot print of the Aviation industry can be reduced significantly. Aviation fuel has an
energy density of 42 to 50 MG/kg, which is much higher than the bio-alcohols. So we required a
fuel which has high quality, High freezing point, and Low risk of explosion, high octane value
and low contamination. There are two types of Aviation Bio-fuel present:
1. Avgas
2. Jet fuels
1.1.3
Biodiesel
Biodiesel produced from organic waste materials, including used cooking oils and biogas
produced from animal manure & organic household wastes can be categorized under 2nd
generation bio-fuels.
Above pie chart is showing the bio-diesel production in all over the world.
1.1.4
Bio-ether
Bioether is fuel which contains ether compound .Bioether can be made from wheat, waste
glycerol and sugar beet.. Bioether can be used as an additive to the current fossil fuels in the
place of petro-ether as an additive .But it has a low energy density.
Bio gas is produced from the anaerobic breakdown of organic matter. Organic matter can include
anything ranging from manure to sewage to plant material and even crops. As In IIFM we
produce bio-gas by the kitchen waste. And that waste slurry can be used as fertilizer.
1.1.5
Biogas
Biogas is produced through the use of bacteria or other microorganisms like acid forming
bacteria (Acetogens) and metane forming archaea (methanoges) .These bacteria digest and
degrade organic matter in oxygen-free (anaerobic) environments and participate in fermentation
reactions.
1.1.6
Syngas
Syngas is the mixture of carbon monoxide, hydrogen, and carbon dioxide. Syngas is produced by
gasification process. Gasification process is a thermo chemical process that converts organic
material into the mixture of hydrogen, carbon monoxide and carbon dioxide. The syngas is used
in the production of other fuels, namely methanol, and diesel fuel produced.
1.1.7
Solid Biofuel
Solid Biofuel is nothing but Fuel like wood, animal dung, municipal waste ,crop residue etc.
1.1.8
Advanced Biofuel
Advanced fuels are the fuel generated from Lignocelluloses ,Jatropha , Camelina and algae.
1.1.8.1 Lignocelluloses
Lignocelluloses are a derivative of plant biomass that contains cellulose and lignin.
Lignocellulosic biomass has an advantage over other agriculturally important biofuels feedstock
such as corn starch, soya beans and sugar cane because it can be produced quickly ,at very low
cost. It is an important component of the major crops. It is the non edible portion of the plant,
which is currently underutilized.
Jatropha: Jatropha is a flowering plant and with the help of the jatropha seeds we can
generate biofuel. The oil from Jatropha can be refined into biodiesel and the leftover can
be used as a solid biofuel or as a feedstock for producing syngas
Camelina: This is also a flowering plant that produces seeds rich in oil. Like Jatropha, its
seeds can contain up to 40% oil that is easily converted into biodiesel and even jet fuel.
Algae: Algae produce lipid, which is oil that can be converted into a number of different
fuels including biodiesel, ethanol, methanol, butanol, jet fuel, and others. Algae-derived
biofuels cannot be used in standard engines because they can erode and damage the seals,
gaskets, and lines made of rubber. Specialized rubber is needed if algae-based biofuels
are to be used in an internal combustion engine.
Safety
Biofuels are safe to handle and transport because they are biodegradable, much less toxic than
even table salt, and have high flashpoints of about 300F compared to gasoline and petroleum
diesel fuel. Because of its safety, the number of incidence of severe vehicle fires can be reduced,
and its safety making it to be one of the safest of all alternative fuels. Also, biofuels produce
fewer by-products than conventional hydrocarbon based fuels after combustion or burning. The
conventional hydrocarbon-based fuels will produced a greater output of some noxious byproduct, for example, carbon monoxide. That means, biofuels could lead to less localized smog
in urban centers (Michael & oloruntoba, 2007)
2.1.2
2.1.3
2.1.4
2.1.5
Cost Benefit
Biofuels almost costs the same in the market as gasoline does. However, the overall cost benefit
of using them is much higher. They are cleaner fuels, which mean they produce fewer emissions
on burning. Biofuels are adaptable to current engine designs and perform very well in most
conditions. This keeps the engine running for longer, requires less maintenance and brings down
overall pollution check costs. With the increased demand of biofuels, they have a potential of
becoming cheaper in future as well. So, the use of biofuels will be less of a drain of the national
capital.
2.1.6
Easy To Source
Gasoline is refined from crude oil, which happens to be a non-renewable resource. Although
current reservoirs of gas will sustain for many years, they will end sometime in near future.
Biofuels are made from many different sources such as manure, waste from crops and plants
grown specifically for the fuel.
2.2.2
Monoculture
Monoculture refers to practice of producing same crops year after year, rather than producing
various crops through a farmers fields over time. While, this might be economically attractive
for farmers but growing same crop every year may deprive the soil of nutrients that are put back
into the soil through crop rotation.
2.2.3
Use of Fertilizers
Biofuels are produced from crops and these crops need fertilizers to grow better. The downside
of using fertilizers is that they can have harmful effects on surrounding environment and may
cause water pollution. Fertilizers contain nitrogen and phosphorus. They can be washed away
from soil to nearby lake, river or pond thus resulting in Eutrophication.
2.2.4
Shortage of Food
Biofuels are extracted from plants and crops that have high levels of sugar in them. However,
most of these crops are also used as food crops. Even though waste material from plants can be
used as raw material, the requirement for such food crops will still exist. It will take up
agricultural space from other crops, which can create a number of problems. Even if it does not
cause an acute shortage of food, it will definitely put pressure on the current growth of crops.
One major worry being faced by people is that the growing use of biofuels may just mean a rise
in food prices as well.
2.2.5
Industrial Pollution
The carbon footprint of biofuels is less than the traditional forms of fuel when burnt. However,
the process with which they are produced makes up for that. Production is largely dependent on
lots of water and oil. Large scale industries meant for churning out biofuel are known to emit
large amounts of emissions and cause small scale water pollution as well. Unless more efficient
means of production are put into place, the overall carbon emission does not get a very big dent
in it.
2.2.6
Water Use
Large quantities of water are required to irrigate the biofuel crops and it may impose strain on
local and regional water resources, if not managed wisely. In order to produce corn based ethanol
to meet local demand for biofuels, massive quantities of water are used that could put
unsustainable pressure on local water resources.
2.2.7
example when carbon stored in forests or grasslands is released from the soil during land
conversion to crop production. For example, while maize produced for ethanol can generate
greenhouse gas savings of about 1.8 tons of carbon dioxide per hectare per year, and switch-grass
a possible second-generation crop can generate savings of 8.6 tons per hectare per year, the
conversion of grassland to produce those crops can release 300 tons per hectare, and conversion
of forest land can release 6001000 tons per hectare. (Fargione, 2008)
The conversion of rainforests, peat-lands, savannahs or grasslands to produce ethanol and
biodiesel in Brazil, Indonesia, Malaysia or the United States of America releases at least 17 times
as much carbon dioxide as those biofuels save annually by replacing fossil fuels. They find that
this carbon debt would take 48 years to repay in the case of Conservation Reserve Program
land returned to maize ethanol production in the United States of America, over 300 years to
repay if Amazonian rainforest is converted for soybean biodiesel production, and over 400 years
to repay if tropical peat land rainforest is converted for palm-oil biodiesel production in
Indonesia or Malaysia. (Fargione, 2008)
Among the options for reducing greenhouse gas emissions that are currently being discussed,
biofuels are one important alternative but in many cases improving energy efficiency and
conservation, increasing carbon sequestration through reforestation or changes in agricultural
practices, or using other forms of renewable energy can be more cost-effective. For example, in
the United States of America, improving average vehicle-fuel efficiency by one mile per gallon
may reduce greenhouse gas emissions as much as all current United States ethanol production
from maize. Also, the processing of biofuel feed stocks can affect local air quality with carbon
monoxide, particulates, nitrogen oxide, sulphates and volatile organic compounds released by
industrial processes. (Tollefson, 2008)
Biofuels reduces carbon emissions on two fronts: first, at the generation stage, where plantations
qualify for carbon credits under the land use, land use change, and forestry (LULUCF) segment
of accounting for GHG emissions; and second, at the consumption level, when it replaces diesel
and emits less carbon. Hence, it was anticipated that there would be a large potential for
biodiesel projects to receive Clean Development Mechanism (CDM) or similar benefits.
There are two broad categories under which biofuels can be eligible for CDM benefits:
Energy plantations
Biofuel blending
3.1.2
Energy Plantations
Energy plantation is the practice of planting oil-bearing trees, which sequester carbon dioxide
(CO2) and help reduce GHG emissions into the atmosphere. Energy plantations are therefore
eligible as CDM payments.
A typical forestry or reforestation project on barren or degraded land or wasteland will have an
average certified emission reduction (CER) generation of 7 tons per hectare per year for 30 years
of crediting period. The actual CER potential of a given plantation is site specific and is based on
soil conditions, type of tree species, tree canopy, and agronomic practices. One CER is 1 ton of
carbon equivalent avoided or sequestered, and it is generated in a project activity that is verified
by a third party and certified by the United Nations Framework Convention for Climate Change
(UNFCCC). To calculate the total CER generation potential of a biodiesel development activity,
one needs to know the total area of the plantation, the species planted (jatropha, pongamia, etc.),
the baseline condition (soil type), and the package of practices followed. Indias projected
cultivation area of about 32 million hectares, conservatively assumed to generate 5 CERs per
hectare per year, could generate up to 160 million CERs per year. At an estimated price of $5 per
ton of CER, revenue generation across India could be as high as Rs36,000 million per year.
3.1.3
Biofuel Blending
Although biofuel combustion emits co2, this emission is defined as carbon neutral under the
Intergovernmental Panel on Climate Change (IPCC) guidelines. Because this co 2 is deemed to
have been absorbed and sequestered by plants during its growth, the net co 2 emission can be
counted as zero when it is burned in the atmosphere. Indias Department of Biotechnology has
estimated the extent of carbon emissions avoided through the blending of ethanol and biodiesel.
A quick, back-of-the-envelope calculation of the potential CERs, based on these figures, shows
that if the targeted 20% blend of biodiesel is achieved by 2017, the GHG emissions avoided will
amount to 83.87 million tons of co 2 equivalent (t co2e) per year. If all these potential reductions
are carried forward for CDM registration at an estimated rate of $5 per t co 2e, the projected
revenue-earning potential per year from biodiesel is Rs18,870.75 million
production figure from 2015. Biodiesel crops are long-term crops; therefore, a 25-year project
period was considered in the analysis
Different scenarios have been considered in the calculation of various outcomes and these are
presented in the table below.
Table 2: Cost Benefit Matrix for Biodiesel
Scenario
Base Case
Base Case + CDM
20% Cost Increase
20% cost increase + 10%
productivity increase
15% diesel price increase
25% diesel price increase
40% diesel price increase
Internal Rate
of Return
(%)
14.85 %
26.48 %
7.59 %
12.21 %
151,297.19
550,279.29
241,116.59
1,487.34
6,177.20
322,670.22
30,9311.40
128,172.15
20.10 %
23.04 %
27.17 %
841,567.00
1,137,035.56
1,580,238.39
468,302.11
679,638.72
996,643.64
220,246.86
220,246.86
597,620.31
The results show that the biodiesel project, which proposes to meet the 20% blending target by
2017, is economically feasible with an EIRR of 15%. The NPV for the base case is negative at a
15% discount rate, indicating that the results are sensitive to the discount rate. With the inclusion
of afforestation, CDM benefits (at a very conservative CER price of $5 per ton) increase the
economic attractiveness of the project and the NPV turns positive even at a 15% discount rate.
The project becomes economically unattractive in the unlikely circumstance of a 20% increase in
costs.
However, even then, a productivity increase of about 12% is enough to bring the project EIRR to
12%. To address concerns about the yield of the two oilseed species, particularly jatropha, yield
is assumed to be 25% lower than in the base case. Even at such low yield biodiesel is
economically feasible if CDM benefits are realized, as the results show. The economic feasibility
of biodiesel at current diesel prices is clearly demonstrated. As diesel prices increase, economic
benefits also increase. Given the very high likelihood of oil price increases in the future, the
results warrant a proactive promotional program for biodiesel in India.
some other wild species may serve the purpose in place of jatropha. Whatever the species
selected out of over 400 wild oil-bearing-seed producers, a proper scientific investigation has to
be carried out first.
However, more than scientific uncertainty, policy uncertainty has prevented the development of
the biodiesel industry in India. There are many reasons why the biodiesel sector in India has not
taken off.
First and foremost, to show interest in biodiesel, private oilseed producers must know
that they can make a reasonable profit.
Second, information and coordination failures prevent the development of biodiesel
markets. Without a dedicated institute that will successfully correct these information and
coordination failures, new sectors like biodiesel sector will not take off.
Third, adequate financial incentives should be complemented with an enabling policy and
regulatory framework. Simply put, there is no demand for biodiesel. Demand has to be
created through a regulatory measure (such as compulsory blending). The policy
environment should be stable over a period that is long enough, as the experience of the
Brazilian biofuel sector demonstrates.
Fourth, in view of the market failures in Indias land markets, proper government
interventions must be introduced to make wasteland available for biodiesel production.
Premature attempts to develop this sector together with ambitious targets are bound to fail
ethanol production from Molasses, Sweet Sorghum and Cellulosic Biomass and Biodiesel from
Jatropha.
The life cycle stages were divided into four parts namely: feedstock development, conversion
processes, blending and end use to establish a common framework to estimate energy and
carbon balance for the selected biofuels with best feasible technologies. The study then analyzed
previously mentioned feedstock on the following four key parameters:
A. Net energy balance
The energy supplied by the biofuel and associated co-products at the end use minus the
energy required during various manufacturing stages of biofuel
B. Net carbon balance
The net quantity of Greenhouse Gases emitted / avoided to the atmosphere during the
various stages of manufacture, distribution and end use of fuel.
C. Net energy ratio
The ratio of energy output obtained from the end use of biofuel and energy input used for
the production of biofuel.
D. Percentage reduction in carbon emissions
The net quantity of Greenhouse Gas emissions avoided compared to the use of the petro
fuel substituted by the biofuel.
4.1 Results
4.1.1
The figure below shows that bio ethanol produced using Sweet Sorghum gives the highest net
energy ratio (7.06), i.e., energy produced from Sweet Sorghum based bio ethanol per unit of
energy input is the highest.
The reason behind being that the energy needed during the processing is supplied by bagasse,
hence the energy input and carbon emission are considered nil for most of the processing steps.
The biodiesel from jatropha gives a lower ratio of 3.41 due to the use of pesticides, fertilizers,
irrigation and methanol during processing stage.
4.1.2
The net energy balance as shown in the Figure above, is highest for Jatropha-SVO followed by
transesterified biodiesel, therefore the net carbon balance is also highest for Jatropha SVO
followed by transesterified biodiesel.
4.1.3
Since the net energy balance is highest for Jatropha-SVO followed by transesterified biodiesel,
therefore the net carbon balance is also highest for Jatropha SVO.
4.1.4
With the highest net energy ratio, the % carbon emission reduction will be highest. Therefore, the
Sweet Sorghum based ethanol is having highest net energy ratio, which will result in highest %
carbon emission reduction.
Jatropha biodiesel appears to be a good alternative in terms of delivering net energy per unit of
biodiesel produced, though energy and carbon balance of Jatropha biodiesel is dependent on the
utilization of co-products obtained during the production of biodiesel.
Production of bio ethanol from cellulosic biomass using bagasse and rice straw also yields a
good energy and carbon balance result. In future, with further developments in the technology,
the energy and carbon balance of producing bio ethanol from cellulosic biomass may further
improve.
Reducing the energy input and carbon input during feedstock development and processing stage
can further improve the energy and carbon balance for the biofuels. This can be achieved by:
Further advancement of technology, particularly for the more recent technologies, like bio
ethanol from cellulosic biomass, which gives a higher yield of biofuel per ton of the feedstock
would improve the energy and carbon balance.
4.2 Constraints
The present production capacity of biodiesel is constrained by the production of feedstock. The
Integrated Energy Policy of India has estimated that the potential for plantation for biodiesel is
20 m ha and that will result in production of biodiesel equivalent to 20 million tons of oil
equivalent. This set target will only be a reality only when the constraints in biodiesel production
and promotion are identified and addressed properly. Some of these are discussed below:
There is lack of Nodal Agency dealing with biodiesel and also there is lack of
coordination among the agencies involved. The State Governments need to take interest
in the program in a sustained manner and designate a nodal ministry or a high-powered
body for this program.
However, technological advances have made it possible to utilize both low and high FFA
oils for conversion to biodiesel but still there is need to look for successful and
commercial transesterfication technology such that it is flexible to undertake some
variations in the feed stock quality and should be in a modular form. All the
transesterfication standardization has been on edible oils, extension to non-edible oils
required additional work
Adequate production capacity had not been established to supply biodiesel to the oil
Companies. The automobile and engine companies were hesitant to promote biofuels
because of frequent fluctuations in international price of crude petroleum products.
One of the major barriers of high cost of production is the small unviable plant size,
which does not lead to economies of scale. In order to achieve this, availability of
feedstock has to be ensured and would require both consumption and production volumes
to grow substantially.
Financial support from Banks and other financial institutions like NABARD is also
needed to encourage plantations of biofuel crops.
Prolonged price negations between the biodiesel companies and oil companies were
another factor.
Variation in price of seed: Most states have not announced minimum prices of seed that
will encourage farmers to take up plantation that will give commercial yield in 3 to 6
years. If the prices of seed fall or the farmer is not able to sell seed he may remove the
plantation.
Government needs to announce certain tax incentives and, if required, subsidies for
making Biodiesel more attractive.
The cost of biodiesel is at present significantly higher as compared to petro-based diesel.
The price of biodiesel is reported to be Rs. 40.00-110.00/litre as against the present retail
price of diesel of Rs 40.00/litre. Since large-scale plantation is taking place in the country
the price of Jatropha based biodiesel was reported to be even higher at Rs. 80.00110.00/litre.
Public awareness needs to be created throughout the country regarding the hazards of
using non-edible seeds and oils for edible purposes. 4 Regulatory and Institutional
Aspects. The Regulatory and Institutional Issues are important because they can either
facilitate in removing barriers or can become barriers themselves. All regulations and
rules should be devised in a way so that they encourage and promote biofuels rather than
becomes a major hindrance.
5 References
Fargione. (2008). Biofuels and its Feasibility in the Current Scenario. The Royal Society .
Gunnatilake, H. (2013). Financial and Economic Assessment of Biodiesel Production and Use in
India. New Delhi: Asian Development Bank.
Jason Hill, E. N. (2013). Environmental, economic, and energetic costs and benefits of biodiesel
and ethanol biofuels. Minnesotta: Departments of Ecology, Evolution, and Behavior and Applied
Economics.
Michael, R. R., & oloruntoba, R. (2007). Public policy and biofuels: The way forward? pp. 231255.
S S Raju, S. P. (2013). Biofuels in India: Potential, Policy and Emerging Paradigms. Mumbai.