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Abstract
This paper studies several kinetic aspects of flotation of celestite and calcite in a mechanical cell with sodium dodecylsulphate
as the collector agent, using pure minerals ranging in average particle size between 137 and 74 mm, respectively, with a constant
pH 3 in the flotation bath in all experiments. The results obtained indicate that both minerals float rapidly and that the flotation
rate constant responds to a non-integral order equation. Likewise, a linear relationship exists between flotation rate and particle
diameter. 2001 Elsevier Science B.V. All rights reserved.
Keywords: Flotation kinetic; Froth flotation; Flotation rate; Particle
1. Introduction
In froth flotation, air bubbles are injected into a
moving stream of aqueous slurry containing a mixture
of particles, so that only hydrophobic ores are collected
on the bubble surface and exit the stream. Owing to its
simplicity, the process is widely used for separating a
great variety of solid particles. However, a number of
complex chemical and physical interaction aspects is
involved in the flotation process. An extensive work is
reported in the literature on the study of this process,
which has been studied from different angles. Of these,
kinetic approach has been highly instrumental in better
understanding leading to reasonably accurate
predictions.
The quantification of kinetic parameters is of increasing importance in industrial flotation to shed light on
the speed of the process. Numerous researchers have
studied the kinetic aspects of froth flotation paying
special attention to particle size, bubbles and their
complex interactions (Trahar and Warren [1]; Jameson
[2]; Radoev et al. [3]; Loewenberg and Davis [4]).
Arbiter and Harris [5] found that the flotation kinetics is the study of the variation in amount of froth
overflow product with flotation time, and the quantita-
2. Experimental
Celestite, SrSO4, and calcite, CaCO3, from two different mines were used for this research study.
0255-2701/01/$ - see front matter 2001 Elsevier Science B.V. All rights reserved.
PII: S 0 2 5 5 - 2 7 0 1 ( 0 0 ) 0 0 1 2 5 - 2
270
The celestite was taken from the Cerro de Montevives mine, located in Las Gabias, 12 km southwest of
the city of Granada (Spain). The mineral, fragmented
and selected again by hand to collect only the purest
samples, thus guaranteeing a concentration of 97%, as
shown by acid leach analysis. The calcite was taken
from a deposit near Torredonjimeno (province of Jaen,
Spain), with a concentration in CaCO3, over 99.6%.
271
percentage rises to 48%, while at 2.66 10 4 M, recovery percentage exceeds 80%. At this latter concentration, the values found for both sizes used are very
similar, indicating that this parameter (i.e. size) ceases
to be a limiting factor when there is an excessive
collector concentration as revealed by Taggart [11], and
Pereda and Hernainz [12].
Fig. 2 shows the results obtained for calcite using the
same sizes and SDS concentrations as those used for
celestite. For calcite size of 74 mm, the recovery percentage of the mineral rises as the SDS concentration is
increased up to a value of approximately 1.3310 4
M. From this point onwards, an increase in agent
concentration does not enhance the mineral recovery
percentage, which remains constant at around 70%.
Low recovery rates, between 15 and 17%, are obtained from calcite flotation for a size of 137 mm and
throughout the SDS concentration ranges studied.
These results suggest that size is clearly one of the
factors influencing recovery of this mineral, what coincides with that indicated by Trahar [3].
From a comparative study between celestite and calcite recovery (Figs. 1 and 2), it is seen that certain agent
concentrations allow kinetic constants to be determined, given that there is a noticeable separation between both sizes as well as good results in mineral
recovery. For example, at 1.33 10 4 M, for both
minerals, the difference in separation of the smallest
and the largest sizes is of importance (a difference of
over 40%) and at 2.2210 4 M the difference is
(1)
M
V
(2)
272
3.2.1. Celestite
Fig. 3 shows the recovery percentage plotted against
flotation time at pH 3 and 1.3310 4 M of SDS for
the following average particle sizes, 137, 115, 96.5, 81
and 74 mm.
The flotation rate is very fast for all sizes studied,
with the greatest part of the mineral having floated
within 3 min.
These experiments also reveal that a decrease in size
increases mineral recovery as pointed out by Trahar
[13] when using other minerals. An increase in flotation
rate is also seen to occur as size decreases, although for
81 and 74 mm, results are very similar as indeed occurs
for 115 and 96.5 mm.
Fig. 4 shows the results obtained using an SDS
concentration of 2.22 10 4 M. The recovery percentage is seen to increase considerably, reaching maximum
recovery within 3 min. It may also be seen that particle
size becomes less important than in the previous case
where SDS concentration was 1.33 10 4 M (Fig. 3).
The results for four of the five sizes used are very
similar in order to the recovery percentage.
The values obtained for the three assumptions under
consideration are shown in Table 1.
The correlation coefficient, r 2, obtained for kl indicates that the operation may not be assimilated in order
1 at either of the two SDS concentrations used.
For order 2, the correlation coefficients give acceptable values in some cases, mainly with the smaller sizes
used.
Table 1
Celestite
SDS (M)
1.33104
2.22104
137
115
96.5
81
74
137
115
96.5
81
74
n=1
n=2
n-non-integral
k1 (min1)
r2
k2 (g1 min1)
r2
kq (min1)
r2
0.1313
0.2954
0.3418
0.3617
0.3741
0.2880
0.4378
0.4518
0.4812
0.5006
0.76
0.82
0.88
0.82
0.79
0.76
0.85
0.89
0.85
0.89
0.00237
0.00820
0.01060
0.01463
0.01688
0.00829
0.01875
0.02204
0.02766
0.03415
0.78
0.88
0.94
0.93
0.91
0.85
0.94
0.96
0.98
0.99
47
73
79.8
87
90.1
77
88
90
94
96
0.8506
1.1542
0.8325
0.7010
0.6240
0.7794
1.0561
0.8777
0.7021
0.6589
0.92
0.98
0.97
0.94
0.93
0.91
0.99
0.96
0.93
0.98
273
Table 2
Calcite
SDS (M)
1.33104
2.22104
137
115
96.5
81
74
137
115
96.5
81
74
n= 1
n =2
n-non-integral
k1 (min1)
r2
k2 (g1 min1)
r2
kq (min1)
r2
0.0061
0.0173
0.0197
0.0354
0.1434
0.0226
0.0230
0.0544
0.0716
0.2018
0.67
0.72
0.73
0.75
0.75
0.71
0.81
0.85
0.78
0.82
8.2564105
2.4962104
2.8397104
5.3479104
0.00345
3.1278104
3.3492104
7.4449104
0.001194
0.005357
0.67
0.73
0.74
0.76
0.82
0.71
0.82
0.82
0.80
0.89
9.2
14.9
16.6
22.9
62
13.6
15.4
25.5
35
68
1.4274
1.4816
1.2141
1.0991
0.8290
1.6855
1.2361
1.0968
0.9800
0.7450
0.87
0.94
0.97
0.98
0.98
0.97
0.98
0.98
0.98
0.94
274
and Ratcliff [16]). However, the form of the relationship between flotation rate and particle size is not yet
clear. The most recent theoretical analyses suggest that,
k8d
(3)
4. Conclusions
1. The flotation rate is very fast for both minerals and
for all sizes studied, with the greater part of the
mineral having floated within 3 min.
2. The results obtained on flotation of celestite and
calcite indicate that the representative kinetics of the
process correspond to a non-integral order although
the correlation coefficient gives the best results
(r 2 \ 0.93 in the most cases), and, therefore, kq may
be taken as representative of the process. The value
for kq lessens with a decrease in the mineral size, for
the two SDS concentrations used. The values of kq
are between 1.1542 and 0.624 min 1 for celestite,
and 1.6855 and 0.745 min 1 for calcite.
3. Likewise, the correlation coefficient, r 2, obtained of
the kq plotted against average particle size indicates
that a linear relationship exists between flotation
rate and particle diameter (r 2 \ 0.98 for celestite and
r 2 \ 0.91 for calcite).
Appendix A. Nomenclature
n
R
C
d
k
k1
k2
kq
References
Table 3
Celestite
Calcite
SDS (M)
r2
1.33104
2.22104
1.33104
2.22104
1.35
1.10
1.18
1.15
0.98
0.99
0.91
0.94
[1] W.J. Trahar, L.J. Warren, The floatability of very fine particles
a review, Int. J. Miner. Sci. 3 (1976) 103 131.
[2] G.L. Jameson, Physical factors affecting recovery rates in flotation, Miner. Sci. Eng. 9 (1977) 103 118.
[3] B.P. Radoev, L.B. Alexandrova, S.D. Tchaljovska, On the kinetics of froth flotation, Int. J. Miner. Process. 28 (1989) 127138.
[4] M. Loewenberg, R.H. Davis, Flotation rate of fine spherical
particles and droplets, Chem. Eng. Sci. 49 (1994) 39233941.
[5] N. Arbiter, C.C. Harris, in: D.W. Fuerstenau (Ed.), Froth
Flotation, AIME, Ann Arbor, MI, 1962, p. 215 Fiftieth anniversary volume.
[6] S.P. Mehrotra, N.P.H. Padmanabhan, Flotation kinetics a
review, Trans. Indian Inst. Met. 43 (1990) 9 21.
[7] F. Hernainz, M. Calero, Flotation rate of celestite and calcite,
Chem. Eng. Sci. 51 (1996) 119 125.
[8] M. Cabrerizo, Propiedades Electrocineticas y de Adsorcion de
Tensioactivos Ionicos sobre Celestina y su Aplicacion a la Flitacion, Ph.D. thesis, University of Granada, Spain, 1986.
275
[14] A.R. Laplante, J.M. Toguri, H.W. Smith, The effect of air flow
rate on the kinetics of flotation. Part. I: the transfer of material
from the slurry to the froth, Int. J. Miner. Process. 11 (1983)
203 220.
[15] A.R. Laplante, J.M. Toguri, H.W. Smith, The effect of air flow
rate on the kinetics of flotation. Part. II: the transfer of material
from the froth over the cell lip, Int. J. Miner. Process. 11 (1983)
221 234.
[16] D. Ready, G.A. Ratcliff, Removal of fines particles from water
by dispersed air flotation: effects to bubble size and particle size
on flotation efficiency, Can. J. Chem. Eng. 51 (1973) 178185.