IIT JEE 2014

TIME: 1HR

TW TEST
TOPICS:CHEMICAL EQUILIBRIUM

MARKS: 65

SECTION-I
This section contains 10multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONLY ONE is correct.
(+3, - 1)
1.

The graph below shows the variation of concentration with time for the reaction
3A(aq) B(aq) + 2C(aq) at 25oC.

C
A
B

What is the value of the equilibrium constant?

(a) 1.18
(b) 0.845
(c) 0.567

(d) 0.222

2.

Consider the reaction: 2CO(g) + O2(g) 2CO2(g). If the equilibrium concentrations of CO(g) is 1.6
10-2 m/L, O2 is 9.0 10-2 m/L and CO2 is 6.4 10-2 m/L, what was the initial O2 concentration
before the reaction started to form any CO2(g)?
(a) 1.2 M
(b) 12 M
(c) 0.12 M
(d) 0.012 M

3.

Calculate the equilibrium concentration of H2 in a 1.0 L container initially containing 0.118 mole of
HBr at 1400 K. Kc = 1.5 10-5 at 1400 K for the reaction
2HBr(g) H2(g) + Br2(g)
(a) 1.8 10-6 M
(b) 0.118 M
(c) 1.5 10-5 M
(d) 4.5 10-4 M

4.

X, Y and Z react in the 1:1:1 stoichiometric ratio. The

concentration of X, Y and Z where found to vary with time as
shown in the figure below.
Which of the following equilibrium reacting may represent the
correct variation of concentration with time
(a) X(g) + Y(g)
Z(g)
(b) X(g) + Y(s)
Z(g)
(c)Z(g) + Y(g)
X(g)
(d)Z(g) + X(g)
Y(g)

5.

10

Conc. (M)

8
6

Z
Y

Time (Minutes)

The equilibrium constant for a reaction.

A B C D is 1.0 102 at 298 and is 2.0 at 373 K. The chemical process resulting in the
formation of C and D is
(a) Exothermic
(b) Endothermic
(c) Unpredictable
(d) None

6.

1 mol of N 2 is mixed with 3 mol of H 2 in a litre container. If 50% of N 2 is converted into ammonia
by thereaction N 2 g 3H 2 g 2NH3 g , then the number of moles of gas at the equilibrium are
(a) 1.5
(b) 4.5
(c) 3.0
(d) 6.0

7.

Consider the reaction

A g Bg C g D g
Which occurs in one step. The specific rate constant are 0.25 and 5000 for the forward and reverse
reaction, respectively. The equilibrium constant is
(a) 2.0 10 4
(b) 4.0 102
(c) 5.0 105
(d) 2.5 106

8.

For the equilibrium system

2HX g H 2 g X 2 g
the equilibrium constant is 1.0 105 . What is the concentration of HX if the equilibrium
concentration of H 2 and X 2 are 1.2 103 M, and 1.2 104 M respectively?
(a) 12 104 M

9.

(b) 12 103 M

(c) 12 102 M

(d) 12 101 M

8 mol of gas AB3 are introduced into a 1.0dm3 vessel. It dissociates as 2AB3 g A 2 g 3B2 g
At equilibrium , 2 mol of A 2 is found to be present. The equilibrium constant for the reaction is
(a) 2mol 2 L2

10.

(b) 3mol2 L2

(c) 27mol 2 L2

(d) 36mol 2 L2

What concentration of CO2 be in equilibrium with 0.025 M CO at 120o C reaction

FeO s CO g Fe s CO2 g
If the value of K c 5.0 ?
(a) 0.125M
(b) 0.0125M

(c) 1.25M

(d) 12.5M

SECTION-II
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONE OR MORE is/are correct.
(+3, 0)
11.

Consider the following reversible systems

N2 + O2
1
1
N 2 O2
2
2

K1

2NO;
K2

NO

K3

2NO
N2 + O2,
1
1
K4

NO
N 2 O2
2
2
Correct relation between K1, K2, K3 and K4 is

(a) K1 K3 = 1

(b)

K1 K 4 1

(c)

K3 K 2 1

(d) none of these

Dd
is correctly matched for : ( is the degree of dissociation, D and d are the
(n 1)d
vapour densities before and after dissociation)
n
n
n
2n
(a) A B C
(b) A B C
2
3
3
3
n
n
n
(c) A B C
(d) A B C
2
4
2

12.

The equation

13.

Variation of equilibrium constant K for the reaction

2A(s) + B(g) C(g) + 2D(g)
is plotted against absolute temperature T in figure as: ln K Vs (1/T)
(a) the forward reaction is exothermic
(b) the forward reaction is endothermic
(c) the slope of line is proportional to H
(d) adding A favours forward reaction

14.

For the reaction H2 g I2 g 2HI g , the equilibrium can be shifted in favour of product by

15.

(a) Increasing the H2

(b) Increasing the catalyst

(c) Increasing the I2

(d) By using the pressure

In a reaction A 2 g 4B2 g 2AB4 g , H 0 . The formation of AB4 is favoured by

(a) Low temperature and high pressure
(c) Low temperature and low pressure

16.

17.

(b) High temperature and low pressure

(d) High temperature and high pressure

For which of the following reactions at equilibrium at constant temperature, doubling the volume
will cause a shift to the right?
(a) N 2O4 g 2NO2 g

(b) CaCO3 s CaO s CO2 g

(c) 2CO g O 2 g 2CO2 g

(d) N 2 g O2 g 2NO g

Which of the following statements is/are wrong?

(a) At equilibrium, concentrations of reactants and products become constant because the reaction
stops.
(b) Addition of catalyst speeds up the forward reaction more than the backward reaction.
(c) Equilibrium constant of an exothermic reaction decreases with increase intemperature.
(d) K p is always greater than Kc .

SECTION-III

(Paragraph Type)

This section contains 2 groups of questions. Each question has 4 choices (A), (B), (C) and (D)
for its answer, out of which ONLY ONE is correct.
(+3, -1)

N 2 g 3H 2 g 2NH3 g ; H 22.4kJ
The pressure inside the chamber is 100 atm and temperature at 300K.

18.

If K p for the given reaction is 1.44 105 , then the value of Kc will be:
(a)

1.44 105

0.082 500

mol L1

(b)

1.44 105

8.314 200

mol L1

(c)
19.

1.44 10
mol L1
2
0.082 700 s

(d) none of these

The preparation of ammonia by Habers process is an exothermic reaction. If the preparation follows
the following temperature-pressure relationship for its % yield. Then for temperature T1 ,T2 , and T3
the correct option is:

(a) T3 T2 T1

(b) T1 T2 T3

SECTION-IV

(c) T3 T2 T1 (d) T1 T2 T3

(Integer Answer Type)

This section contains 2 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9. The correct digit below the question number in the ORS is be bubbled.
(+4, 0)
20.

For the reaction A B C , the rate constants for the forward and the reverse reactions are 4 102
and 2 102 respectively. The value of equilibrium constant K for the reaction would be

21.

One mole of ethanol is treated with one mole of ethanoic acid at 25o C . Half of the acid changes into
ester at equilibrium. The equilibrium constant for the reaction will be.

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

a, b, c

12.

13.

a, c

14.

a, c

15.

16.

a, b

17.

a, b, d

18.

19.

20.

2.

21.