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(b Write an equation for the reaction of each of the following oxides with
) aqueous sodium hydroxide.
(i) sulfur dioxide
(ii) aluminium oxide
(a
)
Compound
melting point /
o
C
magnesium chloride
701
aluminium chloride
178
silicon chloride
70
Briefly relate these melting points to the structure of, and bonding in, [3
each of these chlorides.
]
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2
.
(b
)
(c
)
Using your answer in (b) and data from the Data Booklet, suggest the
pH of 1.0 mol dm3 solution of FeCl3. Explain your answer.
[2
]
[Total : 10]
3. (a Describe what you see when magnesium, phosphorus and sulfur are
)
separately burned in air or oxygen. Write an equation for the [4
reactions that occur.
]
(b) The oxides of magnesium, aluminium and phosphorus differ in their
reactions with water. Describe these reactions, relating them to the
structure and bonding in each oxide. Write equations where [5
appropriate.
]
(c) Describe the effect of the resulting solutions in (b) on Universal [1
Indicator solution.
]
(d) Write balanced equations, where applicable, to show how each oxide of
magnesium, aluminium and phosphorus reacts with
(i
)
NaOH(aq)
(ii HCl(aq)
)
[4
]
[Total : 14]
4. N2007/III/2(b)(c) Modified
The oxides MgO, Al2O3 and SiO2 are all used as refractory materials due to
their high melting points. The last two are major constituents of gemstones,
such as rubies, sapphires and amethysts.
(a) If a sample of one of the oxides was provided as a white powder,
describe the reactions you could carry out on the powder to
determine which of the three oxides it was.
[3
]
Compound
sodium
chloride
phosphorus
pentachloride
pH of resulting
solution upon
addition of
compound to water
[2
]
Page16
(b)
Explain the above observations, and why these two chlorides differ in
their reaction with water.
[Total : 5]
5. N2008/III/4(a)(b)(c)(d)
When dry chlorine is passed over heated aluminium foil in a hard glass tube,
a vapour is produced which condenses to a yellow-white solid in the cooler
parts of the tubes.
At low temperatures the vapour has the empirical formula AlCl3, and Mr of
267.
(a) Suggest the molecular formula of the vapour, and draw a dot-andcross diagram to describe its bonding.
[2
]
The yellow-white solid reacts with water in two separate ways.
When a few drops of water are added to the solid, steamy white fumes are
evolved and a white solid remains, which is insoluble in water.
When a large amount of water is added to the solid, a clear, weakly acidic
solution results.
(b) Write equations, including state symbols, for these two reactions and
explain the observations.
[4
]
(c) Describe and explain what you would see when a sample of Na 2O (s)
is added to a solution of litmus in water. Write an equation for the [2
reaction that occurs.
]
(d) When magnesium is burned in air, a mixture of the ionic solids
magnesium oxide and magnesium nitride, Mg3N2, is formed.
Adding water to Mg3N2 produces an alkaline gas and a white insoluble
solid.
(ii) Suggest an equation for the reaction between Mg 3N2 and water,
and use it to calculate the mass of white insoluble solid that
would be formed from 2.0 g of Mg3N2.
[6
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]
[Total : 12]
MCQ
6. N2006/I/13
The labels had become detached from four bottles in the laboratory. A
student realised that the contents of one of them could easily be identified
because, on addition of water it would not give fumes of hydrogen chloride.
Which did not give the acid fumes?
A
Al2Cl6
PCl5
MgCl2
SiCl4
7. N2007/I/15
What is not a trend from left to right across the elements of the third period
of the Periodic Table?
A
8. N2008/I/14
The chloride of an element R of the third period is a liquid which has a
boiling point of 76 C and fumes in air.
After mixing 0.010 mol of the chloride with water, the resulting solution
required
100
cm3
of
0.30 mol dm3 silver nitrate for complete precipitation of the chloride ion.
To which Group of the Periodic Table does R belong?
II
IV
III
V
Page16
9. N2010/I/14
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MgCl2
FeCl3
AlCl3
SiCl4
1 N2010/I/15
1.
Phosphorus is an
third period, Na
Periodic Table.
What is true for
none of the other
period?
element in the
to Ar, of the
phosphorus and
elements in this
Page16
10. N2006/I/14
Group II
1. J93/P1/6(a) modified
Fully describe the reactions, with appropriate equations, of the Group II
metals, calcium and barium, with
(a) oxygen and,
(b) cold water.
2. J98/P1/Q4 modified
(a) The melting points of Group II
oxides are given in the table
Oxide
Melting point /
MgO
285
CaO
261
SrO
243
BaO
191
C
2
4
0
8
on the right.
(i) With reference to the given data, explain the trend in the melting
point of Group II oxides.
(ii) By stating one of these oxides clearly, suggest and explain a use
based on its melting point.
[3]
(b) Dolomite is a mineral with the formula CaMg(CO 3)2. A 1.000 g sample of
dolomite produced 0.450 g of carbon dioxide when treated with an
excess of hydrochloric acid.
(i) Construct a balanced equation for the reaction involved.
(ii) Calculate the percentage purity of the dolomite sample.
[3]
3. N01/P2/Q3(e) modified
Lime can be obtained by thermal decomposition of solid calcium carbonate.
(a) Write an equation for the thermal decomposition of calcium carbonate.
[1]
(b) Calcium carbonate decomposes at a lower temperature than barium
carbonate. Explain.
Explain why lime is used in agriculture
[2]
[1]
4. N00/P1/Q5 modified
(a) Describe and explain the variation, down the group, on the ease of
thermal decomposition of the Group II metal nitrates. Write an equation
for the reaction that takes place.
[3]
(b) When water is added to the solid residue, after barium nitrate has been
heated, an alkaline solution is produced. The addition of sulfuric acid to
this solution produces a white precipitate. Identify the products of these
two reactions, and write equations for the reactions that occur.
[4]
(c) When the procedure described in (b) is repeated using the solid [3]
remaining after magnesium nitrate has been heated, several differences
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(c)
[1]
Determine the empirical formula of Z.
)
[1]
(c) When water is added to the yellow solid Z, a white suspension forms and
ammonia is liberated. Identify the white suspension and write an
equation for the action of water on Z.
[2]
MCQ:
6. Which of the following decreases down Group II?
A
B
C
D
A
B
C
D
Page16
8. On strong heating, CaSO4 decomposes into CaO and SO3. Calcium carbonate,
CaCO3, decomposes at a lower temperature than calcium sulfate, CaSO4.
Which factor best explains the greater thermal stability of CaSO4?
1 N2001/P3/13
0. Two reaction routes for a Group II metal, M, is given below:
Group VII
1.
(a)
N93/P1/Q7
How do the chloride, bromide and iodide ions differ in their reactions with
(i)
(ii)
In each case, suggest the products of the reaction and write the equations, where appropriate.
(b)
[8]
[3]
J89/P1/Q5
State what you would observe in each of the following experiments. Explain these observations with the
aid of the Data Booklet where appropriate.
(a)
Solid iodine is shaken with aqueous potassium iodide; aqueous sodium thiosulfate is then added.
(b)
Aqueous iron(III) sulfate is added to aqueous potassium iodide and a few drops of starch indicator
are then added.
Page16
2.
What explanations can you offer for the differences in their reactions?
3.
(c)
Aqueous chlorine is added to aqueous iron( II) sulfate and aqueous sodium hydroxide is then
added.
(d)
Chlorine is passed into aqueous sodium hydroxide at room temperature and the mixture is then
heated.
[34]
N06/P3/Q5a
When sparked with hydrogen, chlorine reacts explosively and completely, while iodine reacts slowly and
reaches equilibrium.
(i) Write an equation for the reaction between chlorine and hydrogen.
(ii)
Describe and explain the trend observed in the reactions of the elements chlorine, bromine and
iodine with hydrogen.
(iii)
When sodium thiosulfate is reacted separately with chlorine and iodine, different products are
formed.
4Cl2 Na2 S2O3 5H2O 2NaHSO 4 8HCl
E O 0.51 V
SO24 4H 2e
SO2 2H2O
E O 0.17 V
N03/P3/Q5
(a) Describe and explain how the thermal stability of the hydrogen halides varies down Group
[5]
VII.
(b)
Describe, including an equation for the reaction, what you would see if chlorine water is added to
aqueous sodium bromide.
(c)
When chlorine is bubbled through an aqueous solution containing sodium hydroxide and sodium
bromide, bromide ions are oxidised to a bromide-containing oxyanion. Careful addition of aqueous
silver nitrate to the resulting solution precipitates 4.31 g of white solid. When this precipitate is filtered
off and more silver nitrate solution added, 1.18 g of cream solid is produced. The cream solid had the
following composition by mass :
Ag, 45.8% ; Br, 33.9% ; O, 20.3%
(i)
(ii)
Calculate the number of mole of cream solid and white solid formed.
(iii)
Hence, construct a balanced equation for the reaction between chlorine, sodium bromide and
sodium hydroxide.
[3]
[2]
[5]
Page16
4.
4SO2 4H 6e
MCQ:
1
.
J95/P4/Q15
Which of the following graphs correctly describes a trend found in the halogen
group?
N00/P3/Q15
Which product(s) is/are obtained
concentrated sodium hydroxide?
A NaClO only
B NaClO3 only
C NaCl and NaClO
D NaCl and NaClO3
3
.
when
chlorine
is
bubbled
into
hot
N07/P1/Q16
The ash from burnt seaweed contains chlorides and iodides of some Group I
and Group II elements. Some seaweed ash was treated with concentrated
sulfuric acid and the resulting fumes passed first through a cold tube and lastly
bubbled through aqueous silver nitrate.
What would be observed during the experiment?
A
B
With aqueous
silver nitrate
White precipitate
Yellow precipitate
Page16
2
.
C
D
4.
No deposit
No deposit
N03/P1/Q17
The table shows the results of
experiments in which the halogens X2,
Y2 and Z2 were added to separate
aqueous solutions containing X, Y
and Z ions.
White precipitate
Yellow precipitate
Halog
en
X2
Y2
Strongest
X
Y
X
Z
Y
Z
Z
X
Z2
X(aq)
Y(aq)
Z(aq)
No
reactio
n
X2
formed
X2
formed
No
reaction
No
reactio
n
Z2
formed
No
reactio
n
No
reaction
No
reaction
Weakest
Z
Y
X
Y
N11/P1/Q15
HCl is stable to heat, but HI decomposes into its elements when heated. What
is responsible for this difference?
A HI is a stronger reducing agent than HCl.
B HI is more volatile than HCl.
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6
.
B
1 and 2
only are correct
C
2 and 3
only are correct
D
1 only
is correct
N98/P3/Q36
Which statement(s) about the trends in the properties of the halogens is/are
correct?
1 The electronegativity decreases on descending the group.
2 The volatility decreases on descending the group.
3 Their reactivity as oxidising agents decreases on descending the group.
8.
J04/P1/Q36
When a hot glass rod is inserted into a gas jar of hydrogen iodide, an
immediate reaction takes place as the hydrogen iodide decomposes.
Which of the following is/are correct statement(s) about this reaction?
1
2
3
9.
N01/P3/Q36
The chemical behaviour of the cyanide ion, CN, closely resembles that of Cl .
Which of the following properties can be expected of compounds containing
cyanide?
1
2
3
Page16
Transition Metals
2.
(a)
(b)
(c)
(i)
*(ii
)
The spectra show that the peak in the curve for [Cu(H2O)6]2+
complex is at a longer wavelength than is the peak in the
curve for [Cu(NH3)4(H2O)2]2+ complex.
Page16
1.
What deduction can be made from this fact about the size of
the d-orbital splitting in the two complexes?
[3]
[M(H2O)6nLn]
(mn)+
+ nH2O
(i)
(ii)
(iii)
M m+
Kstab value
Fe3+
SCN
9 x 102
Fe3+
CN
1 x 1031
Co3+
CN
1 x 1064
4.
[7]
[3]
(b)
[4]
Page16
3.
(ii
)
(iii
)
(iv
)
4.
5.
(b)
(a)
[8]
[3]
(i)
(i)
[3]
N01/P4/Q22 modified
This question is about copper and its compounds.
(a) Briefly explain why complexes of Cu(II) are coloured whereas
complexes of Cu(I) are colourless, despite the fact that the dorbitals are split into two energy levels in both series of
complexes.
(b)
[2]
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[2]
Page16
6.
[3]
CuCl2(aq)
CuCl2(a)
B
pale blue ppt
C
deep blue solution
concentrated
HCl
A
yellow green
solution
[8]
[1]
MCQ:
A
B
2.
A
B
C
D
3.
N93/P4/Q20
Iron has a proton (atomic) number of 26.
What is the electronic configuration of the iron cation which can form the
complex ion
[Fe(CN)6]4?
[[Ar] 1s2 2s2 2p6 3s2 3p6]
[Ar] 3d34s2
[Ar] 3d44s2
C
D
[Ar] 3d64s0
[Ar] 3d64s2
N04/P1/Q19
Which species does not act as a ligand in the formation of complexes?
CH3NH2
Cl
NH4+
OH
J97/P3/Q16
Which of the following ions contains five unpaired d-electrons?
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1.
A
B
C
D
4.
A
B
C
D
Cr3+
Fe3+
Mn3+
Ni2+
N01/P3/Q17
Which statement concerning the transition metals is correct?
They are the only metals of which the anhydrous chlorides have
covalent bonds.
They are the only metals which give coloured ions in aqueous
solution.
They are the only metals which have more than one valency
(oxidation state).
They are the only metals with a complete 4s orbital in their atoms.
A
1, 2 and 3 are
correct
5.
B
1 and 2 only are
correct
C
2 and 3 only are
correct
D
1 only are correct
Page16
6.