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A B C D
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SECTION - I (Chemistry)
30 4 = 120
1.
In a hydrogen like sample two different types of photons A and B are produced by electronic transition. Photon
B has its wavelength in infrared (long) region. If photon A has more energy than B, then the photon A may
belong to the region :
I.
Ultraviolet
II.
Visible
III.
Infrared (short)
The correct option is :
(A)
I
(B)
II
(C)
I, II
(D)
I, II, III
2.
Two glass bulbs A and B are connected by a very small tube (of negligible volume) having stop cock. Bulb A
has a volume of 100 cm3 and contains gas while bulb B is empty. On opening the stop cock, the pressure in A
fell down by 60%. The volume of bulb B must be :
(A)
200 mL
(B)
150 mL
(C)
250 mL
(D)
100 mL
3.
The direct conversion of A to B is difficult, hence it is carried out by the following shown path :
C
D
B
S A
C 50
S C
D 30
S B
D 20
100
(D)
60
1
1
NO(g)
N 2 (g) O2 (g)
2
2
If pressure is increased by reducing the volume of the container then :
(A)
Total pressure at equilibrium will change
(B)
Concentration of all the components at equilibrium will change
(C)
Concentration of all the components at equilibrium will remain same
(D)
Equilibrium will shift in the toward direction
4.
5.
{X}
NaBH4
H2C
B2H6/H2O
HO
(A)
H2C
O (B)
OH, H2C
OH
OH, H2C
HC
OH
HO
(C)
6.
OH
(D)
Both are
OH
H2C
Cellobiose
(D)
Sucrose
7.
8.
How many times a solution of pH = 2 has higher acidic nature than the solution of pH = 6 ?
(A)
10000
(B)
12
(C)
1/10000
(D)
4
Vidyamandir Classes
9.
Which of the following electrolytes is least effective in causing of flocculation of ferric hydroxide sol ?
(A)
K 4 [Fe CN 6 ] (B)
K 2Cr2 O4
(C)
KBr
(D)
K 2SO 4
10.
11.
Which of the following compounds having highest and lowest melting point respectively ?
I.
CsF
II.
LiF
III.
HCl
IV.
HF
The correct option is :
(A)
II, III
(B)
I, IV
(C)
IV, III
(D)
II, I
12.
13.
Xe F2
(1 : 5 volume ratio)
673K, 56atm
XeF4
(D)
XeOF2
OF2
IV.
XeF4
(A)
14.
15.
XeF2
(B)
XeF6
(C)
(B)
II, III
(C)
Only I
(D)
All
Enzyme
(C)
Starch
(D)
Teflon
16.
An organic compound X on reduction gives compound Y which on reaction with chloroform and potassium
hydroxide forms Z. The compound Z on catalytic reduction gives N-methylaniline. The compound X is :
(A)
Nitrobenzene (B)
Nitromethane (C)
Methylamine (D)
Aniline
17.
Among the following compounds the decreasing order of reactivity towards electrophilic substitution is :
CH3
(A)
(C)
18.
19.
I
II > I > III > IV
IV > I > II > III
II
OCH3
CF3
III
(B)
(D)
IV
III > I > II > IV
I > II > III > IV
(B)
(C)
(D)
A compound formed by elements X and Y crystallizes in a cubic structure in which the X atoms are at the
corners of a cube and the Y atoms are at the face-centres. The formula of the compound is :
(A)
XY3
(B)
X3Y
(C)
XY
(D)
XY2
4
20.
Vidyamandir Classes
The radioactive isotope
60
27 Co
which is used in the treatment of cancer can be made by (n, p) reaction. For this
(A)
60
27 Co
(B)
60
28 Ni
(C)
(D)
60
27 Co
21.
A solid compound X on heating gives CO2 gas and a residue. The residue mixed with water from Y in water,
a clear solution, Z is obtained. On boiling Z compound X is reformed. The compound X is :
(A)
Ca(HCO3)2
(B)
CaCO3
(C)
Na2CO3
(D)
K2CO3
22.
NaNO2
HCl
CuCN
H2
Ni
(B)
(D)
HNO2
C6H5NH CH2CH3
C6H5CH2OH
(A)
ClCH2CH2OH (B)
OH
(C)
OH
(D)
H3 C
O2N
24.
The vapour pressure of two liquids P and Q are 80 and 60 torr, respectively. The total vapour pressure of
solution obtained by mixing 3 mole of P and 2 mol of Q would be :
(A)
140 torr
(B)
20 torr
(C)
68 torr
(D)
72 torr
CN
25.
+ CH3 MgBr
OCH3
H3O+
OH
CH
CO CH3
COCH3
COOH
CH3
CH3
(A)
(B)
OH
(C)
OCH3
(D)
26.
4.5 g of aluminium (atomic mass = 27 gm/mol) is deposited at cathode from Al3+ solution by a certain quantity
of electric charge. The volume of hydrogen produced at STP from H+ ions in solution by the same quantity of
electric charge will be :
(A)
22.4 L
(B)
44.8 L
(C)
5.6 L
(D)
11.2 L
27.
I, II, III, IV
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28.
Given that :
I2 2e
2I ; E 0 0.54V
Br2 2e
2Br ; E 0 1.09 V
29.
(A)
(B)
(C)
(D)
Potassium salt of succinic acid on electrolysis gives (X). (X) on reaction with :
(A)
PhH in presence of HF BF3 gives styrene
(B)
(C)
(D)
30.
Which of the following complex will show geometrical as well as optical isomerism ?
(A)
[Pt(NH3)2Cl2] (B)
[Pt(NH3)2Cl4] (C)
[Pt(en)3]4+
(D)
[Pt(en)2Cl2]
SECTION - II (Physics)
31.
32.
In the figure a block of mass M is at rest on the floor. The acceleration with which should a
boy of mass m climb along the rope of negligible mass, so as to jut lift the block from the
floor is :
(A)
m 1 g
(B)
m 1 g
(C)
M
m
(D)
m
M
B
a
m
A particle is moving along a path of radius 3 m such a way that the distance traversed along the circumference
is given by s
(A)
33.
30 4 = 120
t 2 t3
2
3 . The acceleration of the particle when t = 2 sec. is :
1.3 m/s2
(B)
13 m/s2
(C)
5 m/s2
12 m/s2
(D)
3t 2
2 watt. Here t is in second and velocity of
(B)
4 m/s
(C)
2 m/s
(D)
2 2 m/s
A steel ring of radius r and cross-sectional area A is fitted onto a wooden disc of radius R(R > r). If the Youngs
modulus of steel is Y, then the force with which the steel ring is expanded is:
(A)
35.
1 m/s
R
AY
r
(B)
AY
R r
r
(C)
Y R r
(D)
A r
10 V
(B)
(C)
2 20 V
(D)
20 V
20 V
Yr
AR
a
R1 50
R2 100
R3 100
6
36.
Vidyamandir Classes
Four equal charges Q are placed at the four corners of a square of side a. The work done in removing a charge
Q from the centre of the square to infinity is :
(A)
37.
(B)
2 Q2
4 0 a
2 Q2
0 a
(C)
Q2
2 0 a
(D)
Two large parallel plates having equal and opposite charge Q are placed very close to each other
and distance between the plates is d. Find the work done by external agent to increase the
separation between plates by d (area of plates is A)
(A)
38.
zero
Q2d
2 A 0
(B)
Q2d
2 A 0
(C)
3Q 2 d
2 A 0
(D)
Q2 d
A 0
A bar magnet has a magnetic moment 2.5 JT 1 is placed in a magnetic field of 0.2 T. The work done in turning
the magnet from parallel to antiparallel position relative to the field direction is :
(A)
39.
0.5 J
(B)
1J
(C)
1.5 J
(D)
0J
A particle moves on the X-axis according to the equation x A B sin t . The motion is simple harmonic with
amplitude :
(A)
40.
(B)
(C)
A+B
A2 B 2
(D)
A ray of light passes from vacuum into a medium of refractive index , the angle of incidence is found to be
twice the angle of refraction. Then the angle of incidence is :
(A)
41.
cos 1 / 2
(B)
2 cos 1 / 2
(C)
2 sin1
2 sin1 / 2
(D)
-particle has a binding energy 7 MeV per nucleon and binding energy of deuteron 1H2 is 1.2 MeV per nucleon.
In the reaction 1 H 2 1H 2
2 He 4 Q energy released Q is :
(A)
42.
4.6 MeV
(B)
18.4 MeV
(C)
20.6 MeV
(D)
23.2 MeV
An object is cooled from 75 C to 65 C in 2 minutes in a room at 30 C . The time taken to cool the same object
from 55 C to 45 C in the same room in minutes is :
(A)
43.
(B)
(C)
(D)
A rod length l slides down along an inclined plane and the ground as shown in the figure. At any instant the
velocity of end B is v, then the velocity of end A at the same instant will be :
(A)
(C)
V sin
sin
(B)
V cos (D)
V cos
cos
V cos
44.
Four spheres, each of mass m and radius r are placed with their centres on the four corners of a square of side
b. The moment of inertia of the system about any side of the square is :
(A)
(C)
4
5
8
5
mr 2 mb 2
(B)
mr 2 4mb 2
(D)
8
5
4
5
mr 2 2mb 2
mr 2 2mb 2
Vidyamandir Classes
45.
A large open tank has two holes in the wall. One is a square hole of side L at a depth y from the top and the
other is a circular hole of radius R at a depth 4y from the top. When the tank is completely filled with water, the
quantities of water flowing out per second from both the holes are the same. Then, R is equal to :
(A)
46.
47.
49.
51.
(C)
(D)
40 mg
h
(B)
mg
h
(C)
mg
2h
(D)
20 mg
h
L
2
m
h
The radii of two soap bubbles are R1 and R2 respectively. The ratio of masses of air in them will be :
(atmospheric pressure is P0 and surface tension is s)
R13
R23
(B)
R23
R13
(C)
4S
P R R3
1 1
P 4S R23
R2
(D)
The potentiometer wire shown in figure has length 100 cm and resistance
500 . Balanced length for a cell having emf 12V is found to be 40 cm.
Then R is :
(A)
4000
(B)
3000
(C)
(D)
1000
1500
4S
P R R3
2 2
P 4S R13
R1
EP = 120V
In LC circuit the maximum charge on the capacitor is Q0. Find the maximum value of current in the circuit.
(Capacitance = C, and inductance = L)
Q0
2 LC
(B)
Q0
LC
(C)
2Q0
LC
(D)
3Q0
2 LC
3
is :
(A)
a
(B)
2a
(C)
3a
(D)
2a
If one mole monatomic gas is mixed with one mole of a diatomic gas, the value of for the mixture is :
(A)
52.
2 L
(A)
(A)
50.
(B)
A block of mass m initially at rest is dropped from a height h on a massless pan attached to
a massless spring of force constant k. The maximum compression in the spring is h/4, then
spring constant k is (Assume the block stick with pan after collision)
(A)
48.
1.40
(B)
1.50
(C)
1.53
(D)
3.07
There are two pipes each of length 2 m, one is closed at one end and other is open at both ends. The speed of
sound in air is 340 m/s. The frequency at which both can resonate is :
(A)
340 Hz
(B)
510 Hz
(C)
42.5 Hz
(D)
None of these
A 2m 2 1m
1m
4m 2
8
53.
54.
55.
Vidyamandir Classes
The downwards force exerted by the water on the top surface of the object is :
(A)
2.0 105 N
(B)
2.1 105 N
(C)
2.2 105 N
(D)
2.3 105 N
0.4 105 N
0.2 105 N
(C)
0.3 105 N
(D)
A metallic wire bent into a right abc moves with a uniform velocity v as shown in the figure. B is the strength
of uniform magnetic field perpendicular outward the plane of triangle. The net emf is and emf along ab is :
(A)
zero, zero
b
B
(B)
zero, Bv (bc) with b positive
(C)
zero, Bv (bc) with a positive
v
(D)
Bv (bc) with b positive, zero
a
56.
In a Youngs double slit experiment, light consisting of two wavelengths 7000 and 6000 is used to obtain
interference fringes. If the distance between the two slits is 1 mm and the distance between the plane of slits and
screen is 100 cm, what is the minimum distance from central maximum where bright fringes due to both the
wavelength coincide ?
(A)
0.54 cm
(B)
0.62 cm
(C)
0.42 cm
(D)
0.28 cm
57.
A resistance and inductance are connected in series across a voltage, V 400 2 sin 240 t volt and current is
found to be 4 sin 240t / 4 amp . Then the values of inductance and resistance are :
(A)
58.
(B)
0.5 H , 60
(C)
Gm 2 2 1
r
Gm
r
(B)
2 1
(D)
5
12
H , 100
(D)
None of these
Gm
r
2 2Gm
r
A radioactive material decays by simultaneous emission of two particles with respective half-lives 1620 years
and 810 years. The time (in years) after which
(A)
60.
(C)
Four particles each of mass m, are placed at the vertices of square and are moving along a circle of radius r
under the influence of mutual gravitational attraction. The speed of each particle will be :
(A)
59.
0.25 H , 80
1080
(B)
2430
1
4
3420
0.75 mA
(B)
1.25 mA
(C)
4 mA
(D)
0.5 mA
(D)
+15V
4860
12k
D1
10 k
5k
10 k
D2
5k
3k
Vidyamandir Classes
30 4 = 120
10
Vidyamandir Classes
Vidyamandir Classes
11