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Zinc
Copper
Zink
Kuprum
Solution T/V
Larutan TN
Diagram 9 / Rajah 9
Solution
T
Deflection of voltmeter's
Yes
No
Table 9
needle
(i) Suggest suitable solutions for T and V. Explain the differences in observation for
solutions T and V.[4Mj
The question
Page
I 1
2015
Oktober 2015
Answer:
T: any soluble ionic compound
Example : Copper(II) nitrate
V : any covalent compound
Example : Benzene, methanol
Reject: alcohol - this is homologous series.
Explanation:
T solution contains free moving ion that can conduct electricity
V solution exist as molecule, no free moving ion present
in the solution.
(ii) Explain the rocess that occurs in the voltaic cell in Diagram 9
when solution Tis
ed.
ould include the half equations involved. [6M]
Refer to redox
At negative terminal
1. Zinc as negative terminal
2. Zinc will be oxidation because zinc lost electron
or oxidation number increases from Oto +2
3. Zn "7 zn2+ + 2e
At positive terminal
1. Copper as positive terminal
[T solution is Copper(II)nitrate
Copper(II)ion and H+ ion present in the solution.
Cu2+ ion was choose to discharge because lower in
Electrochemical series/ less electropositive.}
2. Copper(II) ion will be reduction because gain electron to form copper metal
or decreases oxidation number
from +2 to 0.
3. Cu-" + 2e "7 Cu
[lOM]
II
r
Page
Oktober 2015
Pipette
--------=--------- - - - - -- - -
2moldm-3
sodium hydroxide,
NaOH solution
---Sodium hydroxide,
NaOH solution
Distilled water
Calibration mark
Volumetric
flask
(d) Add water to bring the level of the solution
to the calibration mark. Shake well to
ensure thorough mixing.
Calculation involved
Used formula M1V1 = M2V2
Before/ original
after
Page
I 5
Oktober 2015
Procedure
Gunakan - Teknik ABC - untuk menulis laporan eksperimen
I Used - ABC Technique - to write the laboratory report
Simbol
Maksud
/Symbol
Contoh
/Mean
/Example
Arahan
Kepingan Magnesium/
Bahan
magnesium ribbon
Container
B Bah
an
Bersihkan
pita magnesium
Clean
magnesium ribbon
1.
Container
2.
Masukkan
Add
Timbang
Pita magnesium
Weights
magnesium ribbon
4.
Masukkan
Add
50 cm3 Larutan
ku prum(II) sulfat 1. 0
moldrrr-'
50 cm3 of 1. 0 moldm:" of
copper(II)sulphate
solution
3. Transfer the sodium hydroxide in the 2i2etl into 100 cm3 volumetric flask.
4. Add the distil wate
into the volumetric flask that was filled half full with water.
5. Drop aistil water wiselY.l by using the pipet until reach graduation/ calibration mark
4. Close the volumetric flask and shaking the volumetric flask.
Overall
List of materials and apparatus
1. Material
2.0 mol dm-3of sodium hydroxide, distil water
2. Apparatus
100 cm-' Volumetric flask, 25 cm-' pipet, 250 cm-' beaker,
Calculation involved
V1 = M2V2
M1
0.5 X 100
2.0
25 cm3
Procedure
1. Calculate the volume of sodium hydroxide need.
2. Prepare 25 cm-' of sodium hydroxide by using pipet.
3. Transfer the sodium hydroxide in the i etl into 100 cm-' volumetric flask.
4. Add the distil wate into the volumetric flask that was filled half full with water.
5. Drop aistil water wiselyj by using the pipet until reach graduation/ calibration mark
4. Close the volumetric flask and shaking the volumetric flask.
Switch
Suts
.-----1111-----,
""""'==~-
Carbon electrodes
Elek trod karbon
Crucible
Mangkuk pijar
plumbum bromide(II)
Panaskan
Diagram 4.1
Cathode/
Anode /Anod
1. Ion present
Ion hadir
Katod
2. Ion attract to
Ion bergerak ke
3. Ion choose
Ion dipilih
{Positive terminal}
{Negative terminal}
Bromide, Br-
leadll), Pb2+
Bromide, Br-
lead(II), Pb2+
4. Reason
Alas an
Position
Concentration
electrode
5. Observation
Pemerhatian
6. Comfirmatory test
Ujian Pengesahan
If gas/ jika gas
1. Method I Kaedah
2. Result I Keputusan
7. Product
Hasil
Page
I 6
none
none
Bromine gas
Lead
Oktober 2015
S'oivitch
Suis
~-------[--~
Diagram 4.2
Cathode/
Anode /Anod
1. Ion present
Ion hadir
2. Ion attract to
Ion bergerak ke
3. Ion choose
Ion dipilih
4. Reason
Alas an
Position
Concentration
electrode
5. Observation
Pemerhatian
6. Comfirmatory test
Ujian Pengesahan
If gas/ jika gas
1. Method I Kaedah
2. Result I Keputusan
7. Product
Hasil
Katod
{Negative terminal}
Less electronegative
{Position}
Less electropositive
{Position}
None
Oxygen gas
Copper
[SPM 14-04] Diagram 4.1 and Diagram 4.2 show the apparatus
cells with different electrolytes.
~---1111----,
Switch
Suis
Carbon electrod es
Elektrod karbon '"""='"--
romide
m(II)
Moltenlead(TI) b
Leburan plumbu
Panaskan
bromide
Crucible
Switch
Suis
1---------<III---~
Diagram 4.1
Diagram 4.2
[lM]
[lM]
[lM]
[lM]
[lM]
[lM]
(d) In Diagram 4.2, carbon anode is replaced with copper and electrolysis is carried out
for 20 minutes. State the observation at the anode. Give a reason.
Copper electrode became thinner.
Copper electrode dissolves/ I Copper electrode produce copper(II) ion
........................................................................................................................
[2M]
Carbon T
Carbon R
Karban T
Karban R
--
- -
Cathode/
Anode /Anod
1. Ion present
Ion hadir
2. Ion attract to
Ion bergerak ke
3. Ion choose
Ion dipilih
Katod
{Negative terminal}
Iodide, I- ion
Hydroxide, OH- ion
Potassium, K+ ion
Hydrogen, H+ ion
Iodide, I- ion
Hydrogen, H+ ion
4. Reason
Alas an
Position
Concentration
electrode
5. Observation
Pemerhatian
6. Comfirmatory test
Ujian Pengesahan
If gas/ jika gas
1. Method I Kaedah
2. Result I Keputusan
7. Product
Hasil
Concentration
of iodide ion
Iodine
Less electropositive
{position}
Hydrogen gas
Carbon T
Carbon R
Karban T
Karban R
[lM]
(c) (i) Name the ions attracted to anode.
Iodide and hydroxide
Reject formula sebab soalan nak nama
..........................................................................................................................
[lM]
(ii) Write the half equation for the ion discharged at the anode.
21- 7 h + 2e
Sebab kepekatan, ion halida terpilih
..........................................................................................................................
[lM]
[lM]
[2M]
(e) In another experiment, 1.0 mol dm-3potassium iodide solution is replaced with 0.001
mol dm-3potassium iodide solution.
(i) Name the gas released at the anode.
Oxygen gas
..........................................................................................................................
[lM]
(ii) The volume of gas collected at anode is 24.0 cm3 at room condition. Calculate the
number of molecules of gas collected.
[Avogadro's constant: 6.02 X 1023moli: 1 mol of gas occupies 24 dm3 at room condition]
Mol =volume/molar
volume
= 0.001
Mol = No of Molecules/Na
No of molecules=
0.001
mol X Na
[2M]
Carbon
Copper
Silver nitrate
Copper(II) sulphate
solution
solution
Cell 1
Cell 2
Anode /Anod
Cathode/ Katod
Anode /Anod
Cathode/ Katod
1. Ion present
Ion hadir
Silver, Ag+ ion, nitrate,
Copper(II),
Hydrogen,
2. Ion attract
Ion bergerak
{Positive
terminal}
{Negative
terminal}
{Positive
terminal}
{Negative
terminal}
nitrate,
Copper formed
Carbon
Copper
electrode
electrode
Silvernitrate
Copper(II) sulphate
solution
solution
in silver nitrate
solution. [lM]
[lM]
Magnesi
m---4---Copper
nn---+
Magnesium
Kuprum
r::t---
Magnesium nitrate----+-
solution
---
2. Reason
Alas an
Copper(II) sulphate
solution
Larutan kuprum(II) su/fat
Cathode/ Katod
Positive Terminal
Anode /Anod
Negative Terminal
1. Determine Terminal
Kenalpasti terminal
Porous pot
Pasu berliang
Magnesium
Copper
More electropositive
Less electropositive
more electropositive
less electropositive
3. The direction of
movement of electron
Arah pergerakan
elektron
4. Ion present
Ion hadir
Magnesium to copper
Mg2+, N03H+, OH-
5. Ion choose
Ion dipilih
6. Half Equation
Persamaan setengah
7. Observation
Pemerhatian
Cu2+,S042H+, OHCu-"
Mg 7 Mg2+ + 2e
Cu-" + 2e "'7 Cu
-----!
Magnesiun---H
Magnesium
v,
----1--Copper
Kuprum
...,,..
Magnesiumnitrate-+'" solution
Porouspot
Pasu ber/iang
---
Copper(II)sulphate
solution
Larutan kuprum(II) sulfat
[lM]
[lM]
Series
[lM]
[lM]
(b) Diagram 3.2 shows an incomplete cell Q to electroplate an iron ring with silver.
Cell Q
sa
Iron
Mag:111:t">imrr-Fm1--11--=--c1
1
Afag1n1:1irm1
~----
ring
solution
..-. --
f.'<troJ,an
wgcnlum nilNU
~
Magne.siwn mitrate
.oolution
Ltmit(II!
Copper
Kfipn,m
nlfl'SJleSilll'l:I
C0pper(fil) sulphate
K~m(II)lulfat
mfnlt-~
[lM]
(iii) Write the half equation for the reaction occurred at the iron ring
Ag++ e 7 Ag
Sebab ion Ag+yang terendah dan dipilih untuk dinyahcas
........................................................................................................................
(iv) What happens to the concentration
[lM]
iagne mm
....,,.....
Magne tum
C
opper
Kuprum
CelJ I
ell
C HH
Se/II
[lM]
[lM]
: Mg 7 Mg2+ + 2e
Copper electrode
: cu2+ + 2e 7 Cu [2M]
(d) State the change in colour of copper(II) sulphate solution in cell I and cell II.
Cell I : Blue CuS04 turn to colourless
[lM]
[lM]
------11+Impure Z
i,-----
Pure Z
----Z .soJutio.D
Lukis dan berfungsi - 1 Markah
Label
- 1 Markah
[3M]
Chapter
12 - RedOX - Reduction
and Oxidation
ChemQuest 2015
[SPM03-05] Diagram 5 shows the setup of apparatus to investigate the reactions that
Conversion of
iron(II) to iron(III)
~
Magnesium
Dissolve/ thinner
Mg7 Mg2+ + 2e
Oxidation
Reducing agent
Oto+ 2
Copperf Il)
__
sulphate ---.-,,,
solution
Magnesium
ribbon
Bromine Bromine
water
--=t-----i-">lr.
Test tube Q
Test tube P
Copper(II)
sulphate
Ferumtl l)
sulphate
solution
Diagram 5
water
Br2 +2e7 2Br
O to -1
Reduction
Oxidising agent
Ferum(II) sulphate
Fe2+ "'7 Fe3+ + e
Oxidation
Redcuting agent
Green "'7 brown
Cu 2+
--+
Mg2+
Cu
(c) State what is meant by oxidizing agent in terms of electron transfer. [lM]
www.cikguadura.wordpress.com
I Since
2007
rbon electrode L
ktrod karbon L
Carbon electrode
Elektrod karbon M
Iron(II) sulphate
solution
Lannan ferum(II) sulfat
--~
Bromine
water
Airbromin
Bromine water
Br2 +2e "'7 2Br
O to -1
Reduction
Oxidising agent
___.,.._
[lM]
[ 1 M]
[lM]
(f) Without using U Tube, draw another apparatus set up to investigate the transfer of
electron at a distance, using the same materials as in Diagram 6. Mark in the diagram
the positive and negative terminal of the cell.
l-i-oiiiiiiiiiiiapiiiiiiiiiiiiiiiiiiii
suis
c
arbon electrode
orol!l.s po
Bromine wafer
Carbon
Functional apparatus
Label apparatus and material
Label positive and negative terminal
[3M]
[MRSM09-06] ( a) Diagram 6.1 shows the apparatus set up to investigate the transfer of
electrons at a distance between potassium iodide solution and acidified potassium
manganate(VII) solution. After a few minutes, colourless solution turns brown at electrode R.
----r
Potassium iodide
Or---"'"
Potassium icdide
KMn04
Kali1.1m iodida
Sulphuric add
A std suifank
(i) Name the product formed at electrode R. [lM]
Iodine (solution)
(ii) Complete the half equation for the reaction at electrode S. [lM]
...... H+ + ..... e --+ Mn2+ +
H20
.. 8... H+ + .. 5.. e ----+ Mn2+ + .4 .. H20
(iii) State the change in oxidation number of manganese
S. [2M]
Change in oxidation number
: +7 to +2
Name of process
: reduction
that occurs at
(iv) Suggest a substance that can replace potassium iodide solution in order to
obtain the same reaction. [lM]
sodium iodide
(b) Diagram 6.2 shows the setup of the apparatus to investigate the reactivity of metals J, K
and L. The different metals are heated consecutively.
Metal powder
Glass wool
Panaskan kuat
Heat
Panaskan
K
L
Name
Metal
Zinc
Copper
Mg
Observations
Burns brightly - 2
Glows dimly -3
Burns with a very bright flame -1
Table 6.1
Colour of residue
Hot
Cold
Yellow
White
Black
Black
White
White
Zinc
(ii) Write a chemical equation for the reaction between metal J and oxygen. [lM]
2 Zn + 02 ~ 2 ZnO
metals J, Kand
K,J,L
No changes.
Because Metal Lis more reactive with oxygen than metal J
[SPM 14-05] Table 3 shows the information for four sets of experiment to construct the
reactivity series of metals.
Set
I
II
III
IV
Reactants
Carbon + Iron(III) oxide
Carbon + Oxide of X
Carbon + Magnesium
oxide
X + Iron(III) oxide
Observation
Grey solid is formed
Brown solid is formed
No change
Reaction Happen
yes
yes
No
No change
Table 3
position
C> fe
C>X
C< Mg
X< Fe
[lM]
[2M]
[lM]
[lM]
(b) Based on set II and set III, explain the difference in the observations.
In set II, carbon is more reactive than metal X
In set III, carbon is less reactive than Magnesium
........................................................................................................................
[2M]
(c) (i) Arrange X, carbon, magnesium and iron in descending order of reactivity.
Mg, C, Fe, X
........................................................................................................................
[lM]
(ii) Suggest X.
Copper
........................................................................................................................
[lM]
Carbon powder+
oxide of motal x
serbuk karbon +logam
oksida X
farapor,uinig
di I,
mangkuk pijar
[2M]
[MRSMlO-OSc] (c) Diagram 5.3 shows the set-up of apparatus for an experiment to compare
the reactivity of reactions between metal oxides and hydrogen gas.
Result
Metal oxide powder glows
brightly.
Black powder turned brown.
No reaction. Powder turns
yellow when hot and white
when cold.
No reaction.
White powder remained.
Metal
Copper
Zinc
Magnesium
Zinc
(ii) Arrange the reactivity of J, T, Magnesium and Hydrogen in ascending order. [lM]
J, H, T, Mg
in (c)(ii).[3M]
1. Metal J lowest in arrangement because metal J can displace from it Metal Oxide by
hydrogen
2. Metal T and Metal Mg is higher than Hydrogen, because Hydrogen cannot react
with their metal oxide.
3. Mg is higher because, metal Tis Zn, it less reactive than Mg.
of iron. [lM]
Water
Anode:
Cathode:
(b)(i)Describe the reactions that take place at the edge of water droplet (positive terminal)
during the rusting of iron after the Fe2+ and OH- ions are formed. [3M]
Iron ship
--------------------------
K.apal' besi
Zinc plete
K.epmgcm zi1;1t
Diagram 6
(i) Explain how the zinc plates protect the iron ship from rusting. [2 M]
(ii) Write the half equation for the reaction in 6(c)(i). [lM]
Zn -----+ Zn2+ + 2e
- Kimia
[SBPTrial14-06] Experiments I, II and III are carried out to investigate the factors
affecting the rate of reaction. Table 6.1 shows the reactants and temperature used in
each experiment.
Eksperimeri I, II dan III dijalankan untuk mengkajifaktor-faktor yang mempengaruhi
kadar tindak balas. Jadual 6.1 menunjukkan bahan tindak balas dan suhu yang
digunakan dalam setiap eksperimen. Experiment
Experiment
Eksperimeri
I
II
III
Reactants
Bahan tindak balas
Excess zinc powder + 25 cm-' of 0.1 mol
dm-3hydrochloric acid
Serbuk zink berlebihan + 25 ems asid hidroklorik:
0.1 mol dm=
Excess zinc powder + 25 cm., of 0.1 mol
dm-3hydrochloric acid
Serbuk zink berlebihan + 25 ems asid hidroklorik: 0.1
mol dm=
Temperature
Suhu (0C)
(0C)
30
40
30
Zn
penuh
2HC1
Zn
2H+
Zn Cb
zn2+
b) Based on the experiments, state two factors that affect the rate of reaction. [2M]
Merujuk kepada eksperimen, nyatakan dua faktor yang mempengaruhi kadar tindak
balas.
Page
I 24
Oktober 2015
(c) Compare the rate of reaction between Experiment I and II. Explain the difference by
using collision theory. [4M]
Bandingkan kadar tindak: balas antara Eksperimen I dan II. Terangkan perbezaan itu
dengan menggunakan teori perlanggaran.
Faktor
Apa factor tu buat
FOC di antara apa dengan apa bertambah/meningkat
FOEC di antara apa dengan apa bertambah/meningkat
Kesimpulan - ROR bertambah
1.
2.
3.
4.
5.
1.
2.
3.
4.
5.
(d) Diagram 6.2 shows the curve of the graph of total volume against time for Experiment
I. Sketch the curve obtained for Experiment III on the same axes.
Rajah 6.2 menunjukkan garis lengkung bagi graf jumlah isi padu gas melawan masa bagi
Eksperimen I. Lakarkan garis lengkung yang diperolehi bagi Eksperimen IIIpada paksi
yang sama.
Volume of
gas ( crn3)
III
Time (s)
[lM]
e) During a master chef competition, an apprentice found that a piece of meat is still not
tender after cooking for one hour.
Semasa satu pertandingan 'master chef', seorang pelatih mendapati ketulan daging yang
dimasak masih tidak lembut selepas satu jam.
State one method that should be taken to make the meat become tender in a shorter
time. Explain you answer. [2M]
Nyatakan satu kaedah yang boleh diambil supaya daging itu menjadi lembut dalam masa
lebih singkat. Terangkan jawapan anda.
1. Cut the meat into smaller size I I potong daging kepada ketulan kecil
2. Larger total surface area of meat will absorb more heat
OR
1. Cook in pressure cooker
2. High pressure in pressure cooker increase the temperature
[SPM 14-06] Diagram 5.1 shows the graph of the mass of zinc against time for the
reaction between zinc and hydrochloric acid. In this experiment, 5.00 g of zinc is added
to 100 cm-' of 1.0 mol dm-3hydrochloric acid to study the rate of reaction at the
temperature of 30 C.
Rajah 5.1 menunjukkan graf jisim zink melawan masa bagi tindak: balas antara zink dan
asidhidroklorik: Dalam eksperimeri ini, 5. 00 g zink ditambahkan kepada 1 00 ems asid
hidroklorik: 1. 0 mol dm= untuk mengkaji kadar tindak: balas pada suhu 30 C.
The
L~l"\'C
t,
Dia.g1M.115. I
Rtyah -.1
'firne(s)
M"asa(s)
Zn
HCl
Zn Ch
Zn
= 0.077
Atau
Daripada graf,
---
Diagram:5.1
imc(
Masa(s)
Ro.juh 5.1
1.75
(c) In this experiment, the rate of reaction can also be determined by measuring the
volume of hydrogen gas produced at regular intervals of time. Draw the apparatus set-up
for the experiment.
Dalam eksperimeri ini, kadar tindak: balas boleh ditentukan dengan mengukur isi padn
gas hidrogen yang dihasilkan pada sela masa yang tetap. Lukis rajah susunan radas
untuk eksperimeri ini.
h drochlori - id
Zinc powder
[2M]
(d) The experiment is repeated at the temperature of 40 C with other factors remain
unchanged.
Eksperimeri diulangi pada suhn 40 C dengan semua faktor lain kekal tidak berubah.
(i) Sketch the curve obtained for this experiment on the same axis in Diagram 5.2.
Lakarkan lengkungyang diperoleh dalam eksperimen pada paksiyang sama dalam
500
l 7
---\
The ur
c e at the temperature of 30
Lengkung' pada uhu 30 C
'-.. "-
ime()
Ma a()
Diagram 5.2
Rajah 5.2
[lM]
(ii) Based on your answer in 6(d)(i),explain how temperature affects the rate of reaction
by using collision theory. [3M]
Berdasarkan jawapan anda di 6(d)(i),terangkan bagaimana suhu mempengaruhi kadar
tindak balas dengan menggunakan teori perlanggaran.
1.
2.
3.
4.
The
the
The
rate
1.
2.
3.
4.
(e) Apart from temperature, state one other factor that will also affect the rate of reaction
in this experiment. [lM]
Selain daripada suhu, nyatakan satu faktor lain yang juga boleh mempengaruhi kadar
tindak balas dalam eksperimeri ini.
Adura
= 28.0 C
= 29.0 C
= 33.0 C
(c) Calculate the number of mol of lead(II) ions and sulphate ions that exist in every
solution. [2M]
(i) Lead(II) ions
1
Page I 73
Oktober 2015
Polystyrene cup
Cmvan polistirena
O cm3 of 0.2 mol chu-3copper (II) sulphate
50 cm'kuprunull) sulfat 0.2 mo/ dm"
Diagram 4 Rajah 4
Based on the experiment,
Berdasarkan eksperimen di atas,
(a) State the meaning of heat of displacement.
Nyatakan maksud haba penyesaran.
Heat change when 1 mol of copper was displace from
opper(II) sulphate by zinc that more electropositive metal
[lM]
(b) Give one reason why polystyrene cup is used in the experiment.
Berikari satu sebab mengapa cawan polistirena digunakan dalam eksperimeri ini.
Polystyrene is a heat insulator I I to reduce heat loss to surroundings
[lM]
(c) The thermochemical equation below represents the displacement reaction.
Persamaan termokimia di bawah mewakili tindak balas penyesaran itu.
Zn + CuS04
ZnS04
Cu ; 11H
= -
210 kJ mol-!
Calculate / Hitung:
(i) the number of moles of copper(II) ion.
bilangan mol ion kuprum.
No of moles of Copper(II) ion=
0.2 x 50
1000
I I 0.01 mol
[lM]
2100 J
210 kJ heat
the experiment.
4.2 J g-1"C:"; Density of solution=
ini.
1 gcm-"]
Q =mcO
0 = Q/mc = 2100/[50 x 4.2] = 10 C
2100 J =
so x
4.2 x
11
e=
10
c
[lM]
(d) The experiment is repeated using magnesium powder to replace zinc powder. The
volume and concentration of copper (II) sulphate used is remained the same.
Eksperimeri diulang dengan menggunakan serbuk magnesium menggantikan serbuk zink.
Isi padu dan larutan kuprum(II) sulfat yang digunakan adalah sama.
(i) Predict the heat of displacement for the reaction.
Ramalkan haba penyesaran bagi tindak balas itu.
More than -210 kJ mol-1 I Higher I Increases
[lM]
(ii) Give a reason for your answer in 4(d)(i).
Ben sebab bagi jawapan di 4(d(i).
Magnesium is more electropositive than zinc I I magnesium is higher than zinc in
electrochemical series I I distance between Mg - Cu is further than Zn-Cu in
electrochemical series
[lM]
(e) Draw the energy level diagram for the reaction.
Lukis gambar rajah aras tenaga bagi tindak balas ini.
Energy
Zn + CuS04 I
Zn-Cu2+
Aff
= -
10 kJ mor1
ZnSO .. + Cu/
Zn2+ + Cu
6 menunjukkan
haba pembakaran
(a) The combustion of the fuels is an exothermic reaction. What is meant by exothermic
reaction?
Pembakaran bahan api adalah tindak balas eksotermik. Apakah yang dimaksudkan dengan
tindak balas eksotermik? [ 1 M]
Reaction that gives out I released heat to the surroundings.
(b) Diagram 6 shows the energy profile for the combustion of ethanol.
Rajah 6 menunjukkan profil tenaga bagi pembakaran etanol.
Diagram 6 / Rajah 6
Mark i::1H for the reaction in Diagram 6.
Tandakan LJH bagi tindak balas itu dalam Rajah 6. [IM}
(e) During a football game, a player found that his knee was swollen after being hit by the
opponent player.
Semasa perlawanan bola sepak, seorang pemain
dengan pemain lawan.
A physiotherapy put ice cubes on his knee to relieve the pain. As a chemistry student,
suggest another method to help the player. Explain how the method you choose will help
the player. [3M]
Seorang ahli fisioterapi meletakkan ketulan ais pada lutut pemain itu untuk
mengurangkan kesakitan. Sebagai seorang pelajar kimia, cadangkan kaedah lain untuk
membantu pemain itu. Terangkan bagaimana kaedah yang dipilih dapat membantu
pemain itu.
1.
2.
3.
in
- Kimia
Rajah 1 menunjukkanperubahan
keadaan tiqa jirim, X, Y dan Z bagi air.
Diagram 1 shows the inter-conversion of the three states of matter, X, Y and Z of water.
SPMl0-01
00
x
Freezing
Solid
Pepejal
condesation
liquid
gas
gas
cecair
Melting
boiling
Iaitu
Molekul/ I molecule
........................................................................................................................
[lM]
(b) Di bawah suhu bilik; pada suhu berapakah ais berubah kepada
air?
Under the room temperature, at what temperature does ice change to water?
0 C
........................................................................................................................
Page
I 14
[lM]
Oktober 2015
Keadaan fizikal
Adalah
gas
........................................................................................................................
[lM]
keadaan Y.
X (Pepejal)kepada Y (cecair)
Takat lebur/melting
point
SAL AH
Sebab soalan tanya proses
Peleburan/ /Melting
........................................................................................................................
(e) Apabila air berubah daripada keadaan Y kepada keadaan Z,
nyatakan perubahan bagi:
When water changes from state Y to state Z, state the changes in:
Y (cecair) kepada
Z (Gas)
[lM]
Perubahan
High
Reject:
perubahan
[lM]
Soalan menyatakan
air,
Sebatian kovalen
Daya tarikan
molekul dengan
molekul
Strong
perubahan
Berkurang I weaker
........................................................................................................................
[lM]
Kemudian terangkan.
Rajah 1 menunjukkan
of the apparatus
an experiment to study
Solid agar
Agar-agar peja 1
olid potassium
S anganate(VII)
m
Pepejal kalium
mangana t(VII)
~--
-Whole agar
turns purple.
Seluruh agar
menjadi ungu
Resapan/ I diffusion
[lM]
sebatian
[lM]
ion
(iii) Explain the observation in this experiment based on the kinetic theory of matter.
Terangkan pemerhatian dalam eksperimeri ini berdasarkan teori kinetik jirim.
Berdasarkan
moving/vibrate
dan berputar
and rotate
SPM14-03 (a) Diagram 3 shows standard representation for three isotopes of carbon
which are carbon-12, carbon-13 and carbon-14.
Rajah 3 menunjukkan peruiakilari piawai bagi tiqa isotop karbon iaitu karbon-12, karbon13 dan karbon-14
12
6
13
6
14
6
Reject:
number of nucleon//
neutron number
[lM]
Nucleon number=
Neutron
proton+
=n
eon number - proton
= 13 - 6
7
[lM]
(iii) State one use of carbon-14 in daily life.
Nyatakan satu kegunaan karbon-14 dalam kehidupan harian
[lM]
(iv) Draw the atomic structure of carbon-12 and label the subatomic particles.
Lukis struktur atom karbon-12 dan label zarah subatomnya.
Susunan
electron
Atomic structure
Mesti melukis adanya
[2M]
Melting point ( C)
Takat lebur ( C)
0
Boiling point ( C)
Takat didih ( C)
0
-23
77
801
1413
Electrical conductivity
Kekonduksian elektrik
Solid /Pepejal
Molten / Leburan
Cannot
Cannot/
Tidak boleh
Tidak boleh
Cannot
Can
Tidak boleh
Boleh
Based on Table 2,
Berdasarkan Jadual 2,
solid
Solid + liquid
liquid
Melting point
(0C) Takat
lebur ( C)
Substance
Bahan
Liquid+ gas
Boiling point
(OC)
Takat didih (
oC}
gas
-23
801
(i) what are the physical states of substance X and substance Y at room temperature?
apakah keadaan fizik bagi bahan X dan bahan Y pada suhu bilik?
X: liquid/ I cecair
Y: pepejal/ /solid
[2M]
Substance
Bahan
x
y
Electrical conductivity
Kekonduksian elektrik
Solid /Pepejal
Molten / Leburan
Cannot
Cannot/
Tidak boleh
Tidak boleh
Cannot
Can
Tidak boleh
Boleh
Compound
Sebatian
kovalen
ionik
Maka,
molecule
[lM]
SPM2013-01
Jadual
Substance /Bahan
Argon / Argon
Bromine / Bromin
Napthalene /Naftalena
Sodium chloride /Natrium klorida
Based on table 1:
Berdasarkanjadual
1:
Substance /Bahan
Argon / Argon
Bromine / Bromin
Napthalene /Naftalena
Sodium chloride /Natrium
klorida
Kimia
Zarahnya
atom
Molekul
Molekul
10n
[lM]
Argon
Sebatian ion
[lM]
Cecair
[lM]
(iv) Sodium chloride cannot conduct electricity in solid state but can conduct electricity
in aqueous solution. Explain why.
Natrium klorida tidak boleh mengkonduksi elektrik dalam keadaan pepejal tetapi boleh
mengkonduksi elektrik dalam larutan akues. Terangkan mengapa.
1. Sodium chloride in solid, its ion not free to move. Hold by strong electrostatic
force.
Natrium klorida di dalam pepejal, tiada ion-ion yang bebas bergerak. Di tarik oleh daya
elektrostatik yang kuat
2. in liquid, its ions is free to move
Di dalam cecair, ion-ionnya bebas bergerak.
[2M]
Group 18
[lM]
(b) Diagram 1 shows the graph of temperature againts time when liquid naphthalene is
cooled.
Rajah 1 menunjukkan graf suhu melawan masa apabila cecair naftalene disejukkan.
Temperature (C)
Suhu (0C)
Q
p
Time(s)
Masa (s)
Berdasarkan
graf diatas,
Based on diagram 1
Berdasarkan Rajah 1:
(i) State the freezing point of napthalene.
Nyatakan takat beku bagi naftalena. [lM]
[lM]
(ii) Why there is no change in temperature from R to Q?
Mengapakah tidak terdapat perubahan suhu dari R ke Q? [lM]
Heat released
Haba di bebaskan
Was balance by heat released during the formation of bond between the particles
Diseimbangkan oleh haba yang dibebaskan semasa pembentukkan ikatan di antara
zarah-zarah
........................................................................................................................
[lM]
(iii) What are the states of matter from R to Q?
Apakah keadaanjirim dari R ke Q? [lM]
[SBPTrial14-02] (a) (i) One mole of a substance is defined as the quantity of a substance
that contains the same number of particles as in n g of element A.
What are n and A?
Satu mol bahan ditakrifkari sebagai kuantiti bahan yang mengandungi bilangan zarah
yang sama seperti yang terdapat dalam n g unsur A.
Apakah n dan A?
A = carbon-12/ I karbon-12
n = 12
(ii) What is the number of atoms in 0.5 mole of methane gas, CH4? [2M]
Berapakah bilangan atom dalam 0.5 mol gas methane, CH4?
[Avogadro constant= 6.02 x 1023moli] [Pemalar Avogadro= 6.02 x 102s mol:i]
Telah diberikan:
0.5 mol
Maka
Maka ada 5~
=
=
membentuk
CH,
Page
I 20
Oktober 2015
2M]
111ng11
i11111
Diagram 2 / Rajah 2
(i) When carrying out the experiment, why does the crucible lid need to be opened once a
while? [lM]
Semasa menjalankan eksperimeri itu, mengapakah penutup mangkuk pijar perlu dibuka
sekali sekala?
dengan
oksigen
Reject
magnesium
: plumbum(II) oksida
(c) Copper(II)carbonate, CuC03 is heated strongly to produce copper(II) oxide and carbon
dioxide gas. The reaction is given by chemical equation below;
Kuprum(II) karbonat, CuC03 dipanaskan dengan kuat menghasilkan kuprum(II) oksida
dan gas karbon dioksida. Tindakbalas ditunjukkan oleh persamaan kimia di bawah;
6.2 g copper(II) carbonate, CuC03 is heated during an experiment. Calculate the volume
of gas released. [3M]
6.2 g kuprum(II) karbonat, CuCOs di panaskan dalam suatu eksperimen.
Hitungkan isipadu gas yang dibebaskan.
[Relative atomic mass: Cu=64; C=12, 0=16; 1 mole of gas occupies 24 dm3 at room
conditions]
[Jisim. atom relatif: Cu=64; C=12, 0=16; 1 mol gas menempati 24 dm3 pada keadaan bilikj
0.05
CuCOa =
6.2
64 + 12 + 16(3)
6.2 =
124
an oxide of copper.
Rajah 2 menunjukkan
oksida kuprum.
Oblda htprum
Hidrogen gas
Gas hidrogen
Heat
Pana ka
.A. nhydrou ealei am chloride
logam dengan
Zinc/magnesium/aluminium
Zink/magnesium/aluminium
asid kuat
I I hydrochloric
acid/nitric
acid/ sulphuric
/ / asid hidroklorik/asid nitrik/ asid sulfurik
acid
Based on Table 1, calculate the empirical formula for the oxide of copper.
Berdasarkan Jadual 1, hitung formula empirik bagi oksida kuprum.
[Relative atomic mass: Cu= 64; 0 = 16]
[Jisim.atom relatif: Cu = 64; 0 = 16]
Buatjadual
Element/unsur
Mass/ jisim (g)
Mol
Cu
0
26.52 - 24.60 = 1.92
27.00 - 26.52 = 0.48
1.92 = 0.03
0.48 = 0.03
64
16
Ratio
0.03= 1
0.03= 1
0.03
0.03
Simplest ratio
1
1
Empirical formula/ formula empiric= CuO
[3M]
kuprum?
[lM]
(e)(i)Can the empirical formula for magnesium oxide be determined by using this
method?
Bolehkah formula empirik bagi magnesium oksida ditentukan dengan menggunakan
kaedah ini?
NO
[lM]
(ii) Give one reason for your answer in 2(e)(i).
Berikan satu alasan bagi jawapan anda di 2(e)(i).
[lM]