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BABU MEDICAL ACADEMY

Umashanker Nagar, Kanuru, Vijayawada.

WEEKEND 3
CHEMISTRY

Sub : CHEMISTRY
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Dt : 12 -07 - 2015

An electron has magnetic quantum number as 2 . Its principal quantum number is


A) 3
B) 2
C) 1
D) 4.

The velocity of electron in hydrogen atom is 1.09 x 108 cm/sec. The potenial energy of electron is
A) - 27.2 ev
B) -13.6 ev
C) -6.8 ev
D) -3.4 ev.
[

The number of d electrons in Fe3+ is


A) 6
B) 3

C) 4

D) 5.

Hydride ion is iso electronic with


A) He+
B) H+

C) He

D) Be+

Which of the following has maximum number of unpaired electrons ?


A) Fe3+
B) Fe2+
C) Co2+

D) Co3+

Which one has the lowest number of electrons in the valence shell
A) O2B) O
C) N3-

D) Cl-

The number of electrons in n = 3 shell of an element with atomic number 24 is


A) 24
B) 13
C) 12

D) 8

The number of unpaired electrons present in the 2nd excited state of chlorine atom is
A) 1
B) 3
C) 5
D) 7

2S has nodes
A) 0

B) 1

Maximum number of electrons with + spin in n = 2 is


A) 4
B) 8

C) 2

D) 3

C) 2

D) 6

For which one of the following sets of quantum numbers an electron will have the highest energy ?
A) 3, 2, 1,
B) 5, 1, +1, +
C) 4, 1, 0,
D) 4, 2, +2, + [

132.

If velocity of an electron in the electron in the 3rd orbit of hydrogen atom is X, The velocity in 4th orbit of
Hydrogen
A) 3x/4
B) 1/3x
C) 9x/16
D) 16x/9
[
]

133.

The number of waves made by an electron moving in an orbit having a maximum quantum number of +2
A) 2
B) 3
C) 1
D) 4
[
]

134.

As the value of n increases, the energy difference between two successive shells
A) decreases
B) Increases
C) Remains the same
D) Cannot be predicted[

Which atom has as many s electrons as p electrons


A) H
B) N
C) Na

135.
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How many d electrons present in Ni2+ ion ?

D) Mg

A) 2
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B) 8

C) 6

D) 4

D) 16

Wavelength of an electron is 5AO. Velocity of the electron is


A) 1.45 x 108 cm/sec
B) 1.6 x 10-8 cm/sec
C) 3.2 x 10-27 cm/sec D) None

The probability of finding electron in YZ plane for Px orbital is


A) 100%
B) 99%
C) 95%

D) 0%

There is no difference between a 2p and a 3p orbital regarding


A) value of n
B) size
C) shape

D) energy

The number of unpaired electron in [Ar]3d84s2 is


A) 8
B) 2

C) 4

D) 5

Number of valence electrons in sulphur is


A) 8
B) 6

C) 2

D) 3

Which of the following pair of ions have same number of d electrons


A) Cr3+, Fe2+
B) Fe2+, Fe3+
C) Cu2+, Ni2+

D) Fe3+, Mn2+ [

The (n+l) value for 4s subshell


A) 4
B) 0

C) 5

D) 6

n, l and m values of 3s orbital are


A) 3, 0, 0
B) 3, 1, 0

C) 3, 0, 1

D) 3, 1, 1

Value of m for valence electron in Lithium atom is


A) 1
B) 2

C) 3

D) 0

The radius of hydrogen atom in the ground state is 0.53Ao, the radius of Li2+ in the similar state is
A) 1.06.06Ao
B) 0.265Ao
C) 0.175
D) 0.53Ao
[

If n = 4; the total possible values for magnetic quantum number will be


A) 4
B) 8
C) 12

148.

In hydrogen atom the kinetic energy of electron is 3.4 ev.The distance of that electron from the nucleus
A) 2.116Ao
B) 0.529Ao
C) 1.587Ao
D) 21.16Ao [
]

149.

Which of the following transitions in hydrogen atom will require the highest amount energy
A) n = 1 to n = 2
B) n = 1 to n = 3
C) n = 2 to n = 1
D) n = 3 to n = 4 [

150.

The energy of an electron in the first Bohrs orbit of a hydrogen atom is 2.18 x 10-18J. Its energy in the
second orbit would be
A) 1.09 x 10-18J
B) .436 x 10-18J
C) 5.45 x 10-19J
D) 8.72 x 10-18J[ ]

151.

What is the wavelength (in m) of a particle of mass 6.62 x 10-29g moving with a velocity of 103 m.s-1 ?
A) 6.62 x 10-4
B) 6.62 x 10-3
C) 10-5
D) 105
[
]

152.

For an electron to have the same de Broglie wavelength as that of a Deuteron, its velocity should be -----times that of Deuteron
A)1836
B)1/1836
C)3772
D)1/3672
[
]

153.

Which of the pair of orbits have electronic density along the axis

B) dx2 y2, dz2

A) dxz, dyz
154.

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C) dxy, dyz

D) dxz, dz2

Which of the following pairs of atoms / ions have identical ground state configurations ?
A) Li+ and He+
B) Cl- and Ar
C) Na and K
D) F+ and Ne [

Which of the following sets of quantum numbers represents the highest energy of an atom ?
A)n = 3, l = 2, m = 1,s = +
B) n = 4, l = 0, m = 0,s = +
C) n = 3, l = 0, m = 0,s = +
D) n = 3, l = 1, m = 1,s = +

Which one of the following ions has same number of unpaired electrons as that of V3+ ion ?
A) Cr+
B) Mn2+
C) Ni2+
D) Fe3+ [
In which of the following Aufbau principle is violated ?
A)

2S

B)
2P

2s

2p
C)
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159.

160.

D)


2s
2p
2s
2p
The number of electrons in the ground state of atom (z=24) with the quantum numbers l = 1 and l = 2 are,
respectively
A)12, 4
B) 12, 5
C) 16, 4
D) 16, 5
[
]
The total number of electrons present in all the s orbitals,all the p orbitals and all the d orbtals of
cesium ion are respectively
A)8,26,10
B)10,24,20
C)8,22,24
D)12,20,22
[

Which atom has a many s electrons as p-electrons


A)H
B)N
C)Na

D)Mg

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