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i)
ii)
(b)When the gas is Argon with molar mass of 40 kg/ k mol and Cp of 0.52 KJ/ kg k..
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(i) Derive Clausius inequality and mention the criteria for reversibility of a cycle.
(ii) A reversible heat engine operates between two reservoirs at 820C and 27C. Engine
drives a reversible refrigerator which operates between reservoirs at temperatures of
27C and -15C. The heat transfer to the engine is 2000 kJ and network available for the
combined cycle is 300 kJ. (1) How much heat is transferred to the refrigerant and also
determine the total heat rejected to the reservoir at 27 C. (2) If the efficiency of the heat
engine and COP of the refrigerator are each 40% of their maximum values, determine
heat transfer to the refrigerator and also heat rejected to the reservoir at 27C.
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(i)State Carnot theorem and the various types of irreversibilities associated with it .
(ii) An inventor claims to have developed an engine which receives 1000 kJ at a
temperature of 160C. It rejects heat at a temperature of 5C and delivers 0.12 kWh of
mechanical work. Is this a valid claim? Justify your answer through Classius inequality.
(iii) A refrigerator operating between two identical bodies cools one of the bodies to a
temperature T2. Initially both the bodies are at temperature T1. Deduce the expression
for the minimum specific work input, taking their specific heat as c.
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Find the specific volume and enthalpy of steam at 9 bar when the condition of steam is
a)Wet with dryness fraction 0.95
Steam initially at 400 K Pa and 0.6 dry is heated in a rigid vessel of 0.1m3 volume. The
final condition is 600 K Pa. Find the amount of heat added and mass of steam.
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2 kg of steam initially at 5 bar and 0.6 dry is heated at constant pressure until the
temperature becomes 350 C.find the change in entropy and internal energy.
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A steam plant working on a simple rankine cycle operated between the temperature of
260c and 95C .the steam is dry and saturated when it enters the turbine and
expanded isentropic ally. Find rankine efficiency.
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2.5 kg of steam is heated at constant pressure of 250 kpa and 100c, until temperature
is 250C.Find the amount of heat added and change in entropy. (Use mollier chart)
A ir at 1.02 bar, 22C, initially occupying a cylinder volume of 0.015 m3, is
compressed reversibly and adiabatically by a piston to a pressure of 6.8 bar. Calculate:
( i) The final temperature ( ii) The final volume
( iii) The work done on the mass of air in the cylinder.
0.05 kg of carbon dioxide (molecular weight 44), occupying a volume of 0.03 m3 at
1.025 bar, is compressed reversibly until the pressure is 6.15 bar. Calculate final
temperature, the work done on the CO2, the heat flow to or from the cylinder walls,
( i) When the process is according to law pv1.4 = constant,
( ii) When the process is isothermal,
( iii) When the process takes place in a perfectly thermally insulated cylinder.
A ssume CO2 to be a perfect gas, and take = 1.3.
A system receives 42 kJ of heat while expanding with volume change of 0.123 m3
against an atmosphere of 12 N/cm2. A mass of 80 kg in the surroundings is also lifted
through a distance of 6 metres.
( i) Find the change in energy of the system.
( ii) The system is returned to its initial volume by an adiabatic process which requires
100 kJ of work. Find
the change in energy of system.
( iii) Determine the total change in energy of the system.
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