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Kristianne Samantha G. Gonzales, Camille Louisse R. Lee, Danielle Sabrina E. Lim, Kenneth H. Lim,
Ieoh Kenzo T. Macatiag, Miguel Antonio L. Mendoza
Group 6
2D Medical Technology
Organic Chemistry Laboratory
Abstract
Distillation is the process of separating different components in a liquid substance by means of
evaporation and condensation. After which, collecting the distillate in another container. The objectives of
the experiment were to differentiate simple distillation from fractional distillation, separate the
components of an alcoholic beverage, specifically, vodka and to calculate the percentage of ethanol in a
beverage. A certain volume of vodka (20 ml) was placed in the quick-fitting distilling flask that contained
boiling stones on a fractional distillation set-up and was heated with an alcohol lamp constantly being
rotated under the flask. In every test tube, a certain volume (0.5 mL) of distillate was collected and
recorded until it reached 100C. The first distillate and the last distillate were kept to test its flammability.
The first distillate was flammable meaning it contained ethanol while the last distillate was not flammable,
meaning it only contains water. The volume of distillate collected by the end of the distillation was 6.5 ml
at 100 C, giving a percent ethanol of 12.5%
Introduction
Distillation is a commonly used method for
more efficient in terms of decontamination
or
separation of substances. A fractional distillation
apparatus includes a fractionating column placed
between the pot and the distilling head, as
shown in Figure 1. The objective of this
experiment is to (a) Differentiate simple and
fractional
distillation,
(b)
Separate
the
components purifying liquids and separating
mixtures
of
liquids
into
their
individual
components.
Familiar examples include the
distillation of crude fermentation broths into
alcoholic spirits such as gin and vodka, and the
fractionation of crude oil into useful products
such as gasoline and heating oil. In the organic
lab, distillation is used for purifying solvents and
liquid reaction products. There are four methods
of distillation: simple distillation, fractional
distillation, vacuum distillation, and steam
distillation. In this experiment we used the simple
and fractional method. If one compound is much
more volatile than the other, the compounds can
be separated in one evaporation step. Such a
step is called simple distillation which is a set-up
where a solution or mixture of substances with
different volatility is separated through exposure
to heat. Evaporation takes place, changing liquid
to gas. Vapors form and pass through a
condenser wherein it changes its form from gas
to liquid. The collected vapor is the distillate of
the experiment. Residue is the remains in the
set-up that didnt pass through the process of
evaporation and condensation. It uses an
apparatus that consists of only a pot, a
distillation head, a condenser, an adapter, and a
receiver.
Experimental
A. Compounds tested (or Samples used)
The sample used was clear unflavored
vodka. (Cossack Blue Vodka)
B. Procedure
The set-up used was a fractional distillation setup (See Figure 1). The apparatus used were the
following: iron stand, iron rings, iron clamps,
alcohol lamp, quick-fit distilling flask, still head
thermometer, fractioning column (with boiling
stones), condenser, rubber tubing, adapter and
test tubes. The instruments were tightly secured,
assembled and sturdy. The quick-fit distilling flask
contained few pieces of boiling stones and 20 mL
of the sample beverage which is vodka. After
which, the flask was heated with an alcohol lamp
constantly being rotated under the flask. In every
test tube, a certain volume (0.5 mL) of distillate
was collected and recorded until it reached
100C. The first distillate and the last distillate
were kept to test its flammability. The first and
the last distillate were tested for flammability test
in a watch glass. The set-up was cooled and the
volume of the residue was recorded. The
temperature readings versus the volume of the
distillate collected were plotted in a graph. The
percentage
of ethanol
percentage loss (%
(%
v
v )
and
the
v
v ) were also computed.
Volume of Ethanol
100
Volume of Sample
2.5 mL
100
20 mL
= 12.5%
= 0% loss
%Loss
32.512.5
100
32.5
20
100
32.5
= 27.5% loss
100
True value
error =
32.520
100
32.5
12.5
100
32.5
= 61.5%
Calculations for simple distillation:
%Ethanol =
Volume of Ethanol
100
Volume of Sample
6.0 mL
100
3 o mL
= 20%
%Loss
= 38.5%
References
10.5
11.0
11.5
12.0
12.5
13.0
13.5
14.0
14.5
15.0
15.5
16.0
http://www.scribd.com/doc/36247410/Distillation
-of-Alcohol-inFlammability
Temperature
Vodka 9/20/15
Test
Simple
78
79
84
84
84
84
84
86
87
87
87
87
87
88
88
88
88
89
90
90
92
94
94
94
94
96
96
98
98
98
99
100
[4]Laforteza,
B.P.,
Lazatin, M.J., Lee, G.M.,
Leoncio,
Mt.T.
and
Magdamit, D. Simple
and
Fractional
Distillation.
http://www.scribd.com/doc/105189778/Simpleand-Fractional-Distillation-formal-Report#scribd 9
/20/15
60
50
40
30
Volume (mL)
100.00
90.00
80.00
70.00
Temperature
60.00
50.00
40.00
30.00
Volume