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Formal Report
Date Performed: 25
August 2015
Date Submitted: 17
September 2015
Institution/Department:
Department of
Chemical Engineering
College: Engineering
Instructor: Cris Angelo
Pagtalunan
Gravimetric
Determinatio
Coo, 2015| 1
Formal Report
Introduction
Fertilizers are commonly used in
plants and crops to provide nutrients. They
contain compounds of potassium and
phosphorous which are needed by plants to
grow, which may be lacking in the soil where
they are planted. For quality purposes, the
contents of these compounds must be
closely observed and determined to ensure
proper nutrient content. Among other
methods, gravimetry is used because of its
accuracy and low-cost.
Gravimetry is a method in analytical
chemistry used to obtain masses, percent
composition, and other unknown quantities
through the use of an analytical balance, a
device that accurately measures weight.
There are two types of gravimetry, mainly
precipitation gravimetry and
volatilization gravimetry. In precipitation
gravimetry, the analyte is precipitated as a
known compound, filtered, dried, and
weighed to obtain percent compositions of
the constituent elements and compounds in
the analyte. Ideally, the precipitate should
be 1) Easily filterable, 2) of known chemical
composition, and 3) of low solubility to
minimize loss of analyte during filtering and
washing.
In this experiment, a sample of
commercial fertilizer, more specifically the
phosphorous (P2O5) in it, is precipitated as
magnesium ammonium phosphate
hexahydrate (MgNH4PO46H2O) according to
the following reaction:
MgN H 4 P O4 6 H 2 O(s)
2++O H
++ M g
2+ N H 4
5 H 2 O+ HP O4
Eq.1
Formal Report
weight of
obtained.
the
crucible
and
sample
is
B. PREPARATION OF SOLUTIONS
500mL of 10%(w/v) MgSO47H2O:
50g of MgSO47H2O crystals (See
Appendix) was dissolved inside a 400mL
beaker. After complete dissolution, it was
quantitatively transferred into a 500mL
volumetric flask, filled to mark, and mixed
thoroughly by inverting the volumetric flask.
The solution was stored inside a clean
reagent bottle and labeled properly.
(3) 500mL solutions of 2M NH3:
67.58mL of 14.8M NH3 (See
Appendix) was pipetted out into a 500mL
volumetric flask already containing about
200mL distilled water. The solution was
diluted to mark and mixed thoroughly by
inverting the volumetric flask. It was then
transferred into a clean reagent bottle and
labeled properly. This was done thrice to
obtain a total of 1500mL of 2M NH3.
C. PRECIPITATION OF MgNH4PO46H2O
A filter paper that was to be used in
the latter part of the experiment was pre
weighed using an analytical balance and
placed inside the dessicator while not in use.
The sample inside the crucible in part A was
quantitatively transferred inside a 250 ml
beaker. 40 ml of distilled water was
measured in a graduated cylinder and added
to the 250 ml beaker to dissolve the sample.
The sample was then filtered in a beaker
using a funnel and a filter paper that was
not pre weighed to remove the impurities
and a clear colored filtrate was obtained. 45
ml of 10% MgSO47H2O was pipetted from
the 500 ml solution in B and this was added
to the filtrate. After the addition of
MgSO47H2O 150 ml of 2M NH3 was
added slowly to prevent nucleation and a
white precipitate was observed. Then, the
mixture was left for 15 minutes to allow it to
cool and precipitate completely at room
temperature. After 15 minutes, the
precipitate was filtered by using the pre
Chem 31.1 Section, Room No., Time
Formal Report
hour. After cooling for 15 minutes inside a
glass desiccator, it was then weighed using
an analytical balance.
%P=
Formal Report
precipitate to form; both affect the weights
References
recorded.
[1] Hage, David S. and Carr, James D. 2011.