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This article is about the metallic element. For the place, metals become denser with increasing atomic mass.
see Calcium, New York.
Calcium has two allotropes.[7]
Calcium has a higher electrical resistivity than copper or
aluminium, yet weight-for-weight, due to its much lower
density, it is a better conductor than either. Its use as
such in terrestrial applications is usually limited by its
high reactivity with air; however, it has potential for use
as wiring in o-world applications.[8]
Notable characteristics
3 ISOTOPES
2 Compounds
See also: Category:Calcium compounds.
Calcium,
combined with phosphate,
forming
hydroxylapatite, is the mineral portion of human
and animal bones and teeth. The mineral portion of
some corals can also be transformed into hydroxylapatite.
Calcium forms a family of ionic compounds known
as lime; they are all alkaline white powders (at STP).
Calcium carbonate (CaCO3 ) is one of the common compounds of calcium and occurs naturally as limestone and
chalk. When heated at high temperature (above 825 C),
it forms calcium oxide (CaO), also known as quicklime.
When added to water (H2 O), quicklime vigorously reacts
(hence its name) to form calcium hydroxide (Ca(OH)2 ).
Also known as slaked lime, this substance is an inexpensive base material used throughout the chemical industry. When mixed with sand, it hardens into a mortar and
is turned into plaster by carbon dioxide uptake. Mixed
with other compounds, lime forms an important part of
Portland cement.
When water percolates through limestone or other soluble carbonate-containing rocks, it partially dissolves the
rock and causes cave formation with their characteristic stalactites and stalagmites, and also forms hard water. Other important calcium compounds are calcium nitrate, calcium sulde, calcium chloride, calcium carbide,
calcium cyanamide and calcium hypochlorite.
A few calcium compounds where calcium is in the oxidation state +1 have also been investigated recently.[2]
Charlotte Froese Fischer predicted that a Ca ion would
be stable; this ion was discovered experimentally in
1987.[11]
3 Isotopes
Main article: Isotopes of calcium
3
Ninety-seven percent of naturally occurring calcium is in
the form of 40 Ca. 40 Ca is one of the daughter products of
40
K decay, along with 40 Ar. While KAr dating has been
used extensively in the geological sciences, the prevalence
of 40 Ca in nature has impeded its use in dating. Techniques using mass spectrometry and a double spike isotope dilution have been used for K-Ca age dating.
The most abundant isotope, 40 Ca, has a nucleus of 20
protons and 20 neutrons. This is the heaviest stable isotope of any element that has equal numbers of protons
and neutrons. In supernova explosions, calcium is formed
from the reaction of carbon with various numbers of alpha particles (helium nuclei), until the most common calcium isotope (containing 10 helium nuclei) has been synthesized.
3.1
Isotope fractionation
As with the isotopes of other elements, a variety of processes fractionate, or alter the relative abundance of, calcium isotopes.[12] The best studied of these processes
is the mass-dependent fractionation of calcium isotopes
that accompanies the precipitation of calcium minerals,
such as calcite, aragonite and apatite, from solution. Isotopically light calcium is preferentially incorporated into
minerals, leaving the solution from which the mineral
precipitated enriched in isotopically heavy calcium. At
room temperature the magnitude of this fractionation is
roughly 0.25 (0.025%) per atomic mass unit (AMU).
Mass-dependent dierences in calcium isotope composition conventionally are expressed the ratio of two isotopes
(usually 44 Ca/40 Ca) in a sample compared to the same ratio in a standard reference material. 44 Ca/40 Ca varies by
about 1% among common earth materials.[13]
Calcium isotope fractionation during mineral formation
has led to several applications of calcium isotopes. In particular, the 1997 observation by Skulan and DePaolo[14]
that calcium minerals are isotopically lighter than the solutions from which the minerals precipitate is the basis of
analogous applications in medicine and in paleooceanography. In animals with skeletons mineralized with calcium the calcium isotopic composition of soft tissues reects the relative rate of formation and dissolution of
skeletal mineral. In humans changes in the calcium isotopic composition of urine have been shown to be related
to changes in bone mineral balance. When the rate of
bone formation exceeds the rate of bone resorption, soft
tissue 44 Ca/40 Ca rises. Soft tissue 44 Ca/40 Ca falls when
bone resorption exceeds bone formation. Because of this
relationship, calcium isotopic measurements of urine or
blood may be useful in the early detection of metabolic
bone diseases like osteoporosis.[15]
input exceeds mineral precipitation. It follows that rising 44 Ca/40 Ca corresponds to falling seawater Ca2+ concentration, and falling 44 Ca/40 Ca corresponds to rising
seawater Ca2+ concentration. In 1997 Skulan and DePaolo presented the rst evidence of change in seawater
44
Ca/40 Ca over geologic time, along with a theoretical
explanation of these changes. More recent papers have
conrmed this observation, demonstrating that seawater
Ca2+ concentration is not constant, and that the ocean
probably never is in steady state with respect to its calcium input and output.[16][17] This has important climatological implications, as the marine calcium cycle is closely
tied to the carbon cycle (see below).
4 Geochemical cycling
Calcium provides an important link between tectonics,
climate and the carbon cycle. In the simplest terms, uplift of mountains exposes Ca-bearing rocks to chemical
weathering and releases Ca2+ into surface water. This
Ca2+ eventually is transported to the ocean where it reacts with dissolved CO2 to form limestone. Some of this
limestone settles to the sea oor where it is incorporated
into new rocks. Dissolved CO2 , along with carbonate and
bicarbonate ions, are referred to as dissolved inorganic
carbon (DIC).
7 APPLICATIONS
History
Occurrence
Applications
Calcium is used[26]
5
construction.
in the making of cheese, where calcium ions inuence the activity of rennin in bringing about the
coagulation of milk.
7.1
Calcium compounds
8 Nutrition
8 NUTRITION
Dairy products, such as milk and cheese, are a wellknown source of calcium. Some individuals are allergic to dairy products and even more people, in
particular those of non Indo-European descent, are
lactose-intolerant, leaving them unable to consume nonfermented dairy products in quantities larger than about
half a liter per serving. Others, such as vegans, avoid
dairy products for ethical and health reasons.
Many good vegetable sources of calcium exist, including
seaweeds such as kelp, wakame and hijiki; nuts and seeds
like almonds, hazelnuts, sesame, and pistachio; blackstrap molasses; beans (especially soy beans); gs; quinoa;
okra; rutabaga; broccoli; dandelion leaves; and kale. In
addition, several foods and drinks, such as orange juice,
soy milk, tofu, breakfast cereals, and breads are often
fortied with calcium.[37]
Numerous vegetables, notably spinach, chard and rhubarb
have a high calcium content, but they may also contain
varying amounts of oxalic acid that binds calcium and reduces its absorption. The same problem may to a degree
aect the absorption of calcium from amaranth, collard
greens, and chicory greens. This process may also be related to the generation of calcium oxalate.
An overlooked source of calcium is eggshell, which can
be ground into a powder and mixed into food or a glass
of water.[38][39][40]
The calcium content of most foods can be found in the
USDA National Nutrient Database.[41]
8.1
Dietary supplements
Calcium supplements are used to prevent and to treat calcium deciencies. Oce of Dietary Supplements (National Institutes of Health) recommends that no more
than 600 mg of supplement should be taken at a time
because the percent of calcium absorbed decreases as
the amount of calcium in the supplement increases.[28]
It is therefore recommended to spread doses throughout
the day.[42] Recommended daily calcium intake for adults
ranges from 1000 to 1300 mg.[42] Calcium supplements
8.2
Bone health
8.3
Cardiovascular impact
8.4
Cancer
Overall, there is no strong evidence calcium supplementation helps prevent cancer in people: some studies suggest it might decrease the risk, but others suggest it might
increase the risk. The National Cancer Institute, part of
the National Institutes of Health, does not recommend the
use of calcium supplements to prevent any type of cancer, due to the lack of evidence supporting its use for this
purpose.[53]
There is weak evidence calcium supplementation might
have a preventative eect against developing colorectal
adenomatous polyps, but the evidence is insucient
to recommend such supplementation as a benecial
practice.[54]
period of weeks or months can cause milk-alkali syndrome, with symptoms ranging from hypercalcemia to
potentially fatal renal failure. What constitutes excessive consumption is not well known and, it is presumed,
varies a great deal from person to person. Persons
consuming more than 10 grams/day of CaCO3 (=4 g Ca)
are at risk of developing milk-alkali syndrome,[58] but
the condition has been reported in at least one person
consuming only 2.5 grams/day of CaCO3 (=1 g Ca), an
amount usually considered moderate and safe.[59]
Oral calcium supplements diminish the absorption of
thyroxine when taken within four to six hours of each
other.[60] Thus, people taking both calcium and thyroxine
run the risk of inadequate thyroid hormone replacement
and thence hypothyroidism if they take them simultaneously or near-simultaneously.[61]
Excessive calcium supplementation can be detrimental to
cardiovascular health, especially in men.[62][63]
10 See also
11 References
[1] Standard Atomic Weights 2013. Commission on Isotopic
Abundances and Atomic Weights
[2] Krieck, Sven; Grls, Helmar; Westerhausen, Matthias
(2010). Mechanistic Elucidation of the Formation of
the Inverse Ca(I) Sandwich Complex [(thf)3Ca(-C6H31,3,5-Ph3)Ca(thf)3] and Stability of Aryl-Substituted
Phenylcalcium Complexes.
Journal of the American Chemical Society 132 (35):
1249212501.
doi:10.1021/ja105534w. PMID 20718434.
[3] Dickson, A. G. & Goyet, C. (1994). Chapter 5.
Handbook of method for the analysis of the various parameters of the carbon dioxide system in sea water, version
2 (PDF). ORNL/CDIAC-74.
[4] Pauling, Linus (1970). General Chemistry. Dover Publications. p. 627. ISBN 0-7167-0149-9.
[5] Theodore Gray. The Elements. Page 55
[6] http://education.jlab.org/itselemental/ele020.html
[7] Bale, C. W.; Pelton, A. D. (1987). The CaLi (CalciumLithium) system. Journal of Phase Equilibria 8 (2): 125.
doi:10.1007/BF02873196.
[8] Georey Landis (2014). Resource Production on the
Moon (PDF). NASA. Retrieved 2015-05-20.
11
REFERENCES
[9] Tordo, M. G. (2001). Calcium: Taste, Intake, and Appetite (PDF). Physiological Reviews 81 (4): 156797.
PMID 11581497.
[23] Oates, J. A. H (2008-07-01). Lime and Limestone: Chemistry and Technology, Production and Uses. ISBN 978-3527-61201-7.
[24] calx. Charlton T. Lewis and Charles Short. A Latin Dictionary on Perseus Project.
[52] Downing L; Islam MA (July 2013). Inuence of calcium supplements on the occurrence of cardiovascular
events. Am J Health Syst Pharm (Review) 70 (13): 1132
9. doi:10.2146/ajhp120421. PMID 23784160.
[53] Calcium and Cancer Prevention: Strengths and Limits
of the Evidence. National Cancer Institute. 4 May 2009.
Retrieved November 2014.
[54] Weingarten MA; Zalmanovici A; Yaphe J (2008).
Dietary calcium supplementation for preventing colorectal cancer and adenomatous polyps.
Cochrane Database Syst Rev (Review) (1): CD003548.
doi:10.1002/14651858.CD003548.pub4.
PMID
18254022.
[55] Lewis, R. J. (1996). Saxs Dangerous Properties of Industrial Materials (9th ed.). New York, NY: Van Nostrand
Reinhold. p. 635. ISBN 0-471-37858-5.
[56] ITII. Toxic and Hazardous Industrial Chemicals Safety
Manual. Tokyo, Japan: The International Technical Information Institute. 1988. p. 101.
[57] Rumack BH. POISINDEX. Information System Micromedex, Inc., Englewood, CO, 2010; CCIS Volume
143. Hall AH and Rumack BH (Eds)
[58] Beall DP; Henslee HB; Webb HR; Scoeld RH (2006).
Milk-alkali syndrome: a historical review and description of the modern version of the syndrome. Am. J.
Med. Sci. 331 (5): 23342. doi:10.1097/00000441200605000-00001. PMID 16702792.
[59] Picolos MK & Orlander PR (2005). Calcium carbonate toxicity: The updated milk-alkali syndrome; report
of 3 cases and review of the literature. Endocrine Practice 4 (11): 27280. doi:10.4158/EP.11.4.272. PMID
16006300.
[60] Singh, N.; Singh, P.; Hershman, J. (2000). Eect of
calcium carbonate on the absorption of levothyroxine.
JAMA: the Journal of the American Medical Association
283 (21): 28222825. doi:10.1001/jama.283.21.2822.
PMID 10838651.
[61] Harding, Anne. Calcium May Help With Weight Loss.
Retrieved 2007-07-10.
[62] Michalsson K; Melhus H; Warensj Lemming E; Wolk
A; Byberg L (2013). Long term calcium intake and rates
of all cause and cardiovascular mortality: community
based prospective longitudinal cohort study. BMJ 346:
f228. doi:10.1136/bmj.f228. PMC 3571949. PMID
23403980.
[63] Xiao Q; Murphy RA; Houston DK; Harris TB; Chow
WH; Park Y (2013). Dietary and supplemental calcium intake and cardiovascular disease mortality: the
National Institutes of Health-AARP diet and health
study. JAMA Internal Medicine 173 (8): 639646.
doi:10.1001/jamainternmed.2013.3283. PMC 3756477.
PMID 23381719.
10
12
13
Further reading
13
External links
WebElements.com Calcium
Calcium at The Periodic Table of Videos (University
of Nottingham)
UK Food Standards Agency: Calcium
Nutrition fact sheet from the National Institutes of
Health
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