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1.
In which of the following first resonating structure is more stable than the second ?
(1)
(2)
(3) CH2=CHNH2
2.
(2)
C=CH2
(3) CH2 = CH N
(4)
4.
(4)
RESONANCE
PAGE # 1
6.
(1)
8.
(2)
(3)
(4)
(1) 5,8,9-Triethyl-4,7-Bis(1,1-Dimethylpropyl)-2,3-dimethylundecane
(2) 4,7-Bis(1,1-Dimethylpropyl)-5,8,9-triethyl-2,3-dimethylundecane
(3) 7-(1,1Dimethylpropyl)-4-(1,2dimethylpropyl)-5,8,9-triethyl-3,3-dimethylundecane
(4) 5-(1,1-Dimethylpropyl)8-(1,2-dimethylpropyl)-3,4,-7-triethyl-9-,9-dimethylundecone
10.
How many acyclic esters have molecular formula C4H6O2 (only structural isomers considered)
(1) 2
(2) 3
(3) 4
(4) 5
11.
(1) 4
RESONANCE
(2) 3
(3) 2
(4) 5
PAGE # 2
12.
(1)
13.
15.
16.
(3)
(4)
(1) 13
14.
(2)
(2) 12
(3) 15
(4) 14
4-Amino-2-methylbut-3-en-2-ol
(1) NaNO2 / HCl
4Amino2,2-dimethylbut- 3-yn-1-ol.
(2) Br2 / H2O
O
O
O
||
||
||
O / Zn, H2O
H C CH2 C CH2 C H + HCHO
X 3
The structure of X will be :
(1)
17.
(2)
(3)
(4)
(3) 22
(4) 24
(1) 18
RESONANCE
(2) 20
PAGE # 3
18.
Among these groups, which of the following orders is correct for the magnitude of their + effect ?
(1) > >
(2) > >
(3) > >
(4) > >
19.
(1) 1,2-Dibromo-3-chlorocycloprop-1-ene
(3) 1,2 Dibromo-3-chlorocycloprop-2-ene
20.
(2) 1,3-Dibromo-2-chlorocycloprop-1-ene
(4) 2,3-Dibromo-1-chlorocycloprop-1-ene
(1) 4-Bromo-3-cyanophenol
(3) 2-Cyano-4-hydroxybromobenzene
22.
(4) Metamers
(2) 2-Bromo-5-hydroxybenzenecarbonitrile
(4) 6-Bromo-3-hydroxybenzonitrile
H / Ni
2
Cl2 / h
X
C8H16
3 mono chloro structural product
Structure of X will be :
(1)
RESONANCE
(2)
(3)
(4)
PAGE # 4
23.
(1)
and
(2)
and
(3)
and
(4)
24.
and
O
||
C
(b) CH3
CH
|
OH
(1) a, b, c & d
(3) a & b
25.
O
||
(c) CH 3 O CH 2 C H
O
||
(d) CH2 C CH3
|
OH
(2) a, b & c
(4) a only
Cl
26.
27.
The smallest unsaturated Acyclic aldehyde and its next homologue are reacted with NH2OH to form oximes.
(1) Two different oxime are formed
(2) Four different oxime are formed
(3) Three different oxime are formed
(4) Only one oxime is formed
28.
(1)
RESONANCE
(2)
(3)
(4)
PAGE # 5
29.
and
(2)
(3) Homologs
(4) Identicle
(3)
(4)
(1)
32.
(2) Enantiomers
(1)
31.
are :
(2)
(3)
(4)
(3) 6
(4) 8
CH CH CH CH CH
|
Cl
(1) 2
33.
(2) 4
(functional isomers)
(Metamers)
(Chain isomer)
(Metamers)
|
CHO
34.
is
(1)
RESONANCE
(2)
(3)
(4)
PAGE # 6
36.
(1)
37.
(2)
(3)
(4)
(4) None
(3) 4
(4) 5
(4) 5
41.*
(3)
&
&
(2)
&
HC C C CH
(4)
&
42.*
43.*
44.*
(2)
(4)
(1) CH2=CHCl
45.*
(3)
(2)
(4)
(1)
RESONANCE
; (4)
(2)
; (6)
(3)
; (3)
(4)
; (6)
PAGE # 7
46.
Column-I
Column-II
(Stability order)
(Responsible effect)
(1)
>
(2)
>
(q) Resonance
(r) Hyperconjugation
(4)
> CH3CH2
47.
48.
49.
Find the number of total structurally isomeric cyclic ethers with molecular formula C4H8O.
50.
ANSWER KEY
1.
(3)
2.
(4)
3.
(2)
4.
(3)
5.
(4)
6.
(1)
7.
(3)
8.
(2)
9.
(2)
10.
(4)
11.
(1)
12.
(2)
13.
(1)
14.
(3)
15.
(2)
16.
(2)
17.
(3)
18.
(4)
19.
(2)
20.
(4)
21.
(2)
22.
(4)
23.
(1)
24.
(1)
25.
(4)
26.
(2)
27.
(3)
28.
(1)
29.
(4)
30.
(3)
31.
(3)
32.
(2)
33.
(4)
34.
(3)
35.
(4)
36.
(1)
37.
(2)
38.
(1)
39.
(1)
40.*
(1, 2, 3, 4)
41.*
(1, 2, 3, 4)
42.*
(1, 2, 3, 4)
43.*
(2, 3, 4)
44.*
(1, 2, 4) 45.*
(1, 2, 3, 4)
46.
47.
8e
48.
49.
RESONANCE
50. 6
PAGE # 8