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FE Thermodynamics Review
Outline of Thermodynamics topics
Suggestions for FE Exam preparation
Thermo context of exam & reference
handbook
Example test questions
morning session
afternoon session
Exam Pointers
Familiarize yourself with the reference handbook
Make educated guesses if you cant solve the
problem (or dont have the time)
cross out answers you know are incorrect
work problems backwards using the available
answers
FE pointers - Thermo
Know how to use ideal gas law & steam tables
to evaluate properties
Be able to apply 1st Law to open/closed systems
Know basic definitions/concepts (e.g., adiabatic,
isentropic, Carnot efficiency)
Know how to calculate u, h, and s for ideal
gases & liquids/solids
SAMPLE MORNING
QUESTIONS
enthalpy
internal energy
entropy
external energy
47%
56%
63%
74%
All real gases deviate to some extent from the ideal gas
law. For which of the following conditions are the
deviations smallest?
a)
b)
c)
d)
absolute temperature
saturation temperature
standard temperature
critical temperature
positive
negative
zero
Q
T
250
270
300
350
K
K
K
K
constant
doubled
quadrupled
halved
x
x
x
x
=0
= 0.0006
= 0.1
= 0.5
-0.35 kJ/kg-K
0.00 kJ/kg-K
0.26 kJ/kg-K
0.73 kJ/kg-K
320
390
450
550
kJ/kg
kJ/kg
kJ/kg
kJ/kg
350K
360K
620K
770K
0
(P2 P1)V
cpT
TS
SAMPLE AFTERNOON
QUESTIONS
78%
92%
97%
100%
2380 kJ/kg
b)
c)
d)
2420 kJ/kg
2560 kJ/kg
2600 kJ/kg
10 kg/s
110 kg/s
200 kg/s
270 kg/s
if
EIT EIJH
1.
0.37.3
2.
~pple
EVIE W
Problems on ~ermodyn&mics
(i)
(ii)
(A.)
!t3
(B) 9.3'15 .f't3
(C)
(D)
(E)
5.805 .f't3
9.222fi30.093f't3
(11.1)
(A)
0 Btu
(B) -800 Btu
(A)
(B)
(D)
(E)
0 Btu
8()Q Btu
~)teamente~ a turbine at 300 psia and 700or \lith a veloi:1ty of 200 !'t/sec.
The mass. .flow rate of steam is 10,,000 l'bm/hr" and the heat transfer rate
from the tUrbine is .30,,000Btu./hr. The stesm .flows steadily through the
turbine and leaves the tm-bine at 1; psia as a saturated vapor with -a
velocity of 600 rt/sec.
Detem.1ne: (i) the powr output of the turbine,
and (11) the irreversibility
for the process" if the SU!"rOtmd1ngtemperature
is ;37~.
(i)
(A) 890 hp
(B) ~8" 700 hp
(C) 209 hp
(D) 82.3 hp
(E) 6~ hp
3.
.(C)
J~reon-12 at 180 psia and lOOor enters an expansion valva in. a va.por-compre.ssion
refrigeration
system. The flow through the valve is adiabatic, steady", and
with negligible
changes in kinetic energy. Dete~e
the temperature of
the Freon (if in the suJ=erheatedvapor regime) or the quality of the Freon
(if in the two-phase region) leaving the expansion valve.
(1)
It.
(11)
(B)
B3or
o.hOB
(C)
0.350
(D)
(E)
-8.3or
0.650
(1)
(A)
..(B)
(0)
(D)
(E)
(11)
125.0
-22. 7
-500
+22.7
100.0
Btu/min.-~
Btu/min.-~
Btu/min.-~
Btu/min.-~
Btu/min. ~
(A) 53.5 hp
(B) 289.4 hp
(0) 235.8 hp
(D) 525.2 hp
(E) h2.4 hp
-2
s..
i)
-(ii)
(A)
(B)
(C)
(D)
(E)
6.
-0.1)0
-101.1
+0.221
-0.039
+0.039
Btu/lbm-~
Btu/lbm~~
E~~~-~
Btu/l~-~
Btu/lbm-~
(iii)
(A)
(B)
(C)
(D)
(E)
+62.0
-70.9
-88.6
+70.9
+hU.3
Btu/lbm
Btu/lbm
Btu/lbm
Btu/lbm
Btu/lbm
(A.) -8.9
(B) -26.6
(C) -44.3
(D) -+62.0
(E) +44.3
Btu/l.bm,
Btu/lbm
Btu/lbm
Btu/lbm
Btu/lbm
(i)
(A) 1)10 it/sec.
(B) 342 it/sec.
:C) 2.5.50
it/sec.
,D) 1.547rt/st.;~.
E) 43,100 it/sec.
(ii)
(A) 2.9l
(B) u9.l
(C) 0.39
(D; 1.49
(E: 1.76
.)
'jI')
.
:)
)
J)
13,100
19,500
Uh7
7570
17,600
kW
kW
kW
kW
kW
0..516
0..345
0.484
0.199
0.250
.r"
(:
(.
(:(
(I
65.2$
10.5%
89.5%
46.8%
53.2$
:11):A)
39 psi
,B)
14.7 psi
,C),D):E)
331 psi
197 psi
173 psi
iii)
10.
-3 -
9.
bas1s~ "is
as folloW's
; 0
.7.7$
; N
-84.8%
The products of' combustion are at 1, psia. Determine: I(i) the air-fuel
ratio on a mass basis, (1.1) the percent theoretical
air, and (ill)
the dew
point temperature or the products or combustion.
(
(1) 1:..":'1
(11)
(A.) 11.3l1bm, air/lbm fuel
(J. lS~
( A) 213~
( B 12S~
(B) 9.,2 lbm, air/lbm, 1'u21 (B loot
( C) h2or
(c) 7.93 lbm air/lbm .fuel
(C
S~
( D,) 63~
(D) 17.2 lbm, air/lbm, .fuel
(D
83%
84~
( E)
(E) 2,.9 lbm, air/lbm ruel
(E
27zt
S:tesmis condensed in & surface condenser at 0.50 psia.
Cooling vater
at a mass .flow rate or 26 x 105 J.bm/hr is supplied at an inlet tetlperature
of 68r.
The steaM enters the condenser at a quality or 0.900 and & mass
low rate of 8O,000 J.bm/hr. No sub-cooling of the condensate occurs.
The overall coefficient
of heat transfer is U -490 Btu/br-fta_~.
Determine the square feet of condenser surface required. .
(A)
(B)
(C)
(D)
(E)
J.8,900 fi2
53,000 .t't2.
16,200 .ft2
J.U,OOO.ft2,
32,400 ft2. .
-4 .ANSWERS
to Sample Problems on 'l'hermod3'namics
.-
1..
The system and the process on the T-s plane are shownbelow. Property
vaJ.ues are taken .tram. the CO!nbustionEngineering Steam Tables.
lLOOOY
'The initial
v
J,
specific
-v
gJ,
volume is:
-1.8630
ft3/lbm
at 400O:r
3.
-my
ms. (B)
3.
Fc)r a reversible
8
2
isothermal
.(.5.0)(860~)(1.7134
-+
-W
The internal
1.
-h
-U
].2
c (.5.0)(860)(0.1860)
ARS.(c)
-U
].
.m(u
-u
].
-pv
1 1
.1201.0
u -1201.0 -85.3
2.
-1..5274)
799.8 Btu
ThE~nJ
].2
-(247.259)(144
.1115.7 Btu/lbm
1n~/ft2)(1.8630)/(778
ft-1bf/BtU)
-s -
(No.-l, cont'd)
~ 2
W
~ 2.
2.
-799.8
~rhe sy-stem is
-($.0)(2,.0)
shown below.
Engineering
$teamTables.
.799.8
Propen,.
-12$.0
values
-+674.8
are taken
.
= ---[~.
J.
-1368.9
h2 -1150.9
s
.sat.vap.)
J.
-1.6758
s , -1.
2
Btu/lbm
(300 psia,
Btu/lbm
(15 psia,
.700Cj-)
Btu/lb
.m
ANS.CD)
-30,000Btu/hr
1m
Btu
:;t; I
I
-~
7552 Btu/J.bm-~
IJ
!@
+ m(h
+ ~/2g
1
v.
..~ .q.
W/m
-h
V .(-30,000/10,000)
The powr
-h
C
.(y-
-~/2g
2
) .o
-V';;'2)/2g
+ (1368.9
c.
-1150.9)
.(2002
-6002)/(2)(32.2)(778)
output is:
ms. CD)
For stesq
...0
.R
I .426,,360
-S
) -Q
is given by:
.(10,,000)(537
+ 30,,000 .456,,360
Btu/hr
)(1.7552
-1.6756)
-(-30,,000)
ms. (A)
<!>,---, @
180
psia
'- --20
psia
---J..
@
h
Applying
the
First
Law
of
'!'hemodynamics
.f'or
stead3-."f1ow"
on
unit
mass
basis"
q -w'"
(h -h ) ...(~V2)/2g
...(gig
)Ez -z
) .0
.12
12
C
.c
1
2
T]le system. is adiabatic (q .0)"
there is no mechanism .f'c:r doing work (w .0)"
C11ange
s in Jdnetic and potential
ene rgies are negligible;
therefore..
the
FjLrst Law reduces to:
h
.- -h
ANS. (C)
-7
h.
r TH .80~
ROOM
the roan is
.,40~
.rooQ,
Qg
-6,Sroom
'l'g
CJPJlO'l'
REF.
~ .10,,000Btu/min.
.
OOLDSPACE
TL .-20or
.hhO~
QL
(-)
~
L
~ -J.2,270 Btu/min.
-T
-(540)(
.+ 22.7 Btu/min.-~
Note that the entropy of the room incre ases. because hea't is ~
'I'he power requirement .for the Carnot re.frigerator
-~
w -(2270
w -53..5
Jon alternate
-12,270
Btu/min.)(60
-10,000
.2270
to the room.
is .round !'ran:
Btu/min.
min./br.)/(2545
Btu!bp-hr.)
ANS. (A)
is as follows.
a Carnot refrigerator
- -~
TH -TL
'lben,
ANS. (D)
hp
solution
4400
12,270
Then,
.6,Sroom
5400
~Sroom
w -~
10,000
5hO -b4o
w .10,000/4.40
.2270
Btu/min.
.53.5
hp
is:
-B
-T
J.
(n-1)/n
(-!).
P
100 (
-(5600,&)( -)
15
J..2~-J.)IJ..215 -(560)(6.667).2.00
1
T
-s
-(';-60)(1.161)
-8
J.
-s
-R1A_),~
--
ANS. CD)
~2
V dp -
n(p v
2
n R(T
.a
-n
(1.25)(53.34)(818.4 -560)
(778)(1
-T
(-a.)
(k-l)/k
J. .
ANS. (0)
-1.25)
-(S40~)( ~
100
pJ.
T
2
)
].
1 -n
-T
-(540)(0.631)
.340.9~
or
)(~.~o-l)/~.~O
., (5hOO)(O.20)O.286
-9
(No.6, cont'd)
ANS. (D)
~~e specific
2.
--=.- (20)(lh4)
RT
is
of stete,
(S.3..3u)(.3hO.90)
P2
~['he required
area. is
fo1md from:
.-
m .J.
V Iv
2
(3.0)(6.314)
mv
--2-
.0.01224
ft2
(1547)
ANS. (E)
7.
TJle system and the cycle on the temperature-entropy plane are sho n below.
.Ul property. values are taken from the Canbustion Engineering S~am. Tables.
T
@
700~
m .100,,000
lbm/hr
~~
~
--
@
-.~~
]:1
1.
.
-h
]~
2.
'4
~~
"
.~~
69.73 Btu/1~ ; V
+ v (p
~
~ 2-
- P1 ) .69.73
-70.92 Btu/l~
]:1
3
POMP
+ (0.016136)(400 -1)(144)/(778)
.69.73
+ 1.19
12.925
~
"
-h
+x
r"
h
".fg"
-69.73++
therefore,
.is:
(O.8l7l)(lO36~)
-69.73.
646.6
h -.916.11 Btu/lbm
4
Jlpplying the First
c:hanges in kinetic
...
Wt .m
(h
-h
) -(lOO,OOO)(l363.h
steady now
-9l6JL)
.(4.47)(10?)/(34l3
with negligible
.(100,000)
(4h7.0).
Btu/kW-hr)
ANS. (A)
1.
-h
) .(100,000)(-1.19)
Wnet .(U47.0
--119,000
-1..19)(105)
.4.4S8
'?
Btu/hr
kW
4.4,8 x .10
0.34, -34.$%
X 10"
ANS. (B)
8.
-11
Tbe cy-cle 'on the p-v and T-s planes is sho\o'nbelow. Properties or air are:
'~ .'O.2hO Pt.u/lbm-~ ; Cv .O.l71lL Btu/lbm-Op. ; R .53.34 rt-lbr/l~-Op.
:k .J..400
4500Dr
@)
@
---@
lh.7
(;)
ps:1a
v
The temperature
isentropic
J.
end of the
compression
process
is
found
from
relationship,
The speci1'ic
v
at the
vol1me at point
1 is:
The pres~
The specific
RT
V
3
(S3.3U)(4960)
-~-
(591.h)(~)
P3
The temperature
at point
.3.107
4 is fO'1nd frm
.ft3/J.bm
the isentropic
relationship,
k-l
The heat added during the constant-pressure
qH .h
-h
the
~
7.1
4a.
AHS. (E)
net work
mep-
pi~on
-v
displacement
Wnet
1
-v
(442.9)(778)
CO + 0.4 co + 7.,7 0
-~
2
+ 84.8
N
2.
a -7.1
(1 + 3.76)
2.
+ 0.4 -7.50
2c , or
AFR.-~
+ CH 0
c .2a.
(2)(7.50) -15.00
--
(7.50)
..ANS.
"
-~
co
(E)
10.
~
1.3 -
(No. 9, c~t'd)
AFR
The theoretical
-(2
theo.
+ 7.52)/(1)
.9.52
air is:
14.31
AFR
%TA.
.
AFRtheo.
The mole fraction
air-fuel
ratio is:
lbmole
-1..50
-1.50
air/lbmOle
fuel
% theoretical
ANS. (A)
air
9.$2
y(H 0) .(1,.00)/(100.0
+ 1,.00)
.0~304
2;
The partial
p v .P
pressure
m
,.(H2 0) .(1,
psia.)(O.l304) -1.9,6,
of c~bustion
is:
psia
ANS. (B)
:From the Combustion" Engine:ring
T -79.586F
the .following
at 0.50 psia
propertie~:
Ste am
0.50 psis.
h -
47.62 Btu/l~
:r
1.
.68r
f + x h ) -h f .x
fg
~h .(O.900)(lOh8.6)
The heat transfer
The exit
T
Condensate
fg
.991.36 Btu/lbm
+ (7.93)(107)/(26)(108)(1.0)
The log~ean
IRTD.
temperature difference
+ 3.0So.
7l.0S~
(79.586 -68)
is:
-(79.586 -71.05)
lnCn.586/8.536)
'T'\,.ft"
.660
I -DIU
tKTD -(7.93)(lO?)/(490)(9.9BO)
3.050
-9.9SoF
0.3055
-16,200
!t2
ANS. (c)
T -.~-'
k""'"
~
;':(s::'. ~ne...,
~~
-~-V O:.J--'.:_.2.
T':"{'" '\'- C "' ~
-~r--=-"_.
:> ,;>~
C...
~:.~n
1270 gpD
76,196
gpn
81,775 gpm
(D).
1825 gpIt
(E)
1959 ~
.,
!s~
fu~
.30
in.
indetenninate
(C)
(D)
(E)
307or
h11of
IlO2or
of
1s:
!!E~
~~
A Carnot refrigerator
operates between -32or and +96F. The energy
absorbed from the low-temperature space is JOOBtu/lbm.
The net work done
on the working sub3tance is:
(A)
69.1 Btu/lbn
(B) 1003.1 Btu/lbm
(C) 230.9 Btu/lbn
(D)
(E)
89.7 Btu/lbm
389.7 Btu/lbn
.
~~
-2 'nle nOW'through
.(.1)
0.0 Btu/lbm
(B)
( C)
(D)
(E)
indetenrlnate
0.042 Btu/lbn
3.23 Btu.lJ.bm
22.,;' Btu/lbm
No. 7'~ In a basic ideal RanJd.necycle using s't.eemas the worldng fi'Cid, the
pressure and temperat1n'e at the inlet of the turbine are .500 psis. and SOODr.
The e:xhs.ustpressure .fran the turbine is 1.0 psis.. The themal ef'ficiency
0.1"the q-cle is:
(1) 25.5%
(B) .31.~
(0) 19.(#
(D)
3S.JL
(E) 34.JL
No.8.
.(A)
11.00
(B)
(C)
11.70
3.S8
"
(D) 10.00
(E) S.70
}foe 9. .An ideal Ot.to cycle uses sir as the wor1dng fluid.
The compression
rai~o is 7.00 J and tJ1e max:1Jn\Z
temperature of the cycJ.e is 1400&. The
thermal efficiency for the cycle is:
(A) 16.7%
(B) 43.3
(0) 6l.~
CD) lh.Jt
(E)
51.1.1$
No. 10. An ideal simple BrQ"ton cy-cle uses air as the wor]d.ng fluid.
The maximum
and JrlniDttml.temperatures in the cy-cle are 1 aX>Dr and 6Oor, respectively.
The
pressure ratio across the compressor and the turbine is 6.00 The thermal
efficiencY' for the cy-cle is:
(J..)
(B)
(C)
(D)
51 %
49 %
indeterminate
60 %
(E)
110%
~
(1181.76)
-3 .~utions
..
to The~o~cs'
Probl~s
40,000 lbm/hr
steam at
0
0
water
vater at
10l.74Dr
at 6OOp
condenss.te
saturated liquid
101.74 Op'
-9.15
X 105 1bm/hr
The volmuetric
.v.
now rate
of cooling
water 192
gal./!t3)
:m h
+ m h
2.2
111
Substituting
'values,
.In
Site mn at
C8
23
the numerical
.m
'water
at
.(mw
..
BOOF
1.00 psia
and lOOODr
@
.steam
at
60 Rsia and
100 F sprht.
-~
I
'
+ 48.04 =w
+ 100)(1229.8)
(100)(1$32.0
-1229.8)
:m
e>
+ D'o) h
W
(100)(1$32.0)
1.00 lbm/min.
(1229.8
-lIB.oll)
. (100)(312.2) -25.57
lbm/min.
.ANs. (c)
-h~l,.
chart,
it is .found that
the entering
state o! the ate- is in the
." 't1>-phase region; there!ore J the steam
..t.aperature
is the saturatim1 temperature
" at a preSBm"e o! 280 psia.
t .4U~
~
ANS.(D)
.!.9.~L
or an incanpressible
!"luid
in an isentropic
process,
."
.W
..
.V
(p
2;
-p
) .(20
gil./min.)(O.l3368
rt3/g8l.)(80
-20)(144)/{33,OOO)
JNS. (E)
!.Q~
The coefficient
COP
..
TH
h28~
TL
No.6.
.3.311--~
-TL
300/3.3lL
is:
is:
89.7 Btu/lbm
AN5. (D)
I. 1351.8 Btu/l~
-=-r-.~<1-~._.~.
.h
--13;1..8
2
Btu/lbm
Temp..
6~OF
hCiJpsia" h-1335.9
:B]' i].'lterpolation,
s-1.6163
s
700~
Pressure
1351.8
s
1363.4
1.6uO6
The irreversibill
ty is I
:l -22.S Btu!J.bm
ANS.(E)
,0/
~
-s ~Z.!.
.~ts
.8 h.
sat 8 liq.
T
2.
(!){I
.69.73 + 1.49 .71.22
Btu/lbm
(7---
(1 -.x) .
1.9781 -1.11921
-S
g4~
-~
..0.2633
1.8455
4,
Big"
h
-h
g4
-(1
-x
)h.r
4 ..g"
Vnet
wnet
turbine
-W
P1Jmp .(h
I. A- ft -g~~.~~J
o..~ r\r'\ .~~~~.~
.
"}-~b
-h
-(h
1.119 .398.25
-h)
].
-1.49
-.396.76 Bt.u/lbm
is:
396.76
ANS.(E)
.O.JaJ .34.3t
U;9.98
..2
1.
h
h
h
The heat
-h
1
"
-h
absorbed
-78.335
"
in
qg
the
-.33.531
0,..' ~'-~'-
% .U4.oUU D't.W.1.~
The work input to the compressor is:
w
net
.h
-h
Wnet .12.;'18
The coefficient
.90.853
-78.335
Btu/lbm
of performance is:
.hl1.80h./12.Sl8
1:J2. 9~
The thermal
efficiency
for
ANS.(c)
.3.58
--
the ideal
Otto
cycle
is
given by:
1.11-1
k-l
-1
-0.459
ms. (E)
No.10.
(k-l)/k
rp
"r? .O.lJOO
.40
--
-l-{-)
1 (1.4-1)/1.4
6
.1
-0.600
ANS.
r-,
1.
4.
The state
2.
3.
of a thermodynamic
A)
absolute
B)
process
on Thermodvnsmics
S7S'tem is
a1.wqs
defined
b:r its
temperat1Ir8
c) properties
D)
E)
avaUabilit,-
KathematicalJ.'1', a thermodynaDic
(A.) a point tmction
(B) a. path .t\mction
(C)
an inexact differential
(D)
discontinuous
(E)
an exact di.!'ferential
propert,.
point of l1qmd
Equations
tor
of "tate
the foUoidng,
What is this
oxy-genis 90 K.
~pera.ture
a single-canponent
~x~'Pt:
the material
5.
In the pressure-temperature
of
point
labeled -P?
(A) thepour
point
(B)
(C)
(D)
(E)
isentropic point
cri tic;l
point
triple
point
nomal boiling point
~
~ ~
~
C/]
C7)
C/)
VAPOR
m-iPERAI'URE
6.
524.1 Btu/lbm
1029.7 Btu/lbm
.9.
10.
-2 -
7.
8.
-3.29
(B)
(C)
-2.60 Btu
+6.71 Btu
Btu
(D)
(E)
+7.40 Btu
none of these
processes
The ma:x:im-um
thermal efficiency
that can be obtained in an ide al reversible
heat engine operating between lS40~ and 340~ is cJ,osest to:
(A.).
(B)
(0)
(D)
(E)
u.
'
6\Yp
7~
hot
2~
A re.frigerator with a ~r
input of 3 hp operates between Oar and lOOar.
The ma'T"'tmum
theoretical
heat transfer rate .from. the cold reservoir is
ne&rest to:
(.1.) t. 7~800 Btu/hr
(B)
(c)
12.
lO~
13,000 Btu/hr
23,000 Btu/hr
(D)
(E)
35,000 Btu/hr
43,000 Btu/hr
valve
The rate of heat transfer through a given section of' a un1.form ve1.l for a
gi Ten temperature di.f"ference is:
(A.) directly proportimlal
to the coe;fficient of' thermal conduct! vi t7 and
'to the thickness ot the vall
.
(B)
(C)
(D)
(E)
inversely
proportional
dire ctly proportional
directly
proportional
iDversely
proportional
to the c~tficient
of thermal conductivity
to the thickness of' the vall
to the c~tticient
of' therm&1. coMuctivit,to the thickness ot the vill
of thermal conductivit.v
and
and
and
Given a vall ha'rlng an inner surface temperature of BOor and the outer
S"ar.tace is exposed. to abient .wind and surraandings at .$O~. The. ~nvecti va
heat trmsfer
coefficient
for a 1.$ mph wind is about 7 Bt"1J/hr-ft2_~.
Neglecting 8%]j"'
radiatian losses.. cal~ate
the overall heat tranSfer
coefficient
for the Cmlduction and convection heat transfer.
The heat nux
t.hrough the wall'is 2h Bt1J/hr-fta..
(A)
(B)
(c)
(D)
(E)
0.14 BtWhr-ft 2- or
0.80 Btu/hr-ft2_~
J..2.$Btu/hr-ft2_or
7.J.0 Btu/hr-ft2_or
8.20 Btu/br-ft2-or
"
u.
1.
3.
6.
10.
13.
15.
-4-
2.
(c)
4.
CD)
5.
7.
(A.)
B.
(C)
".Q -w.
9.
u
~. (...+6. 7l Btu
(D)
is
energy
also
can
called
be
the
neither
created
Conservation
(B)
engine)
60%.is The
given
thermal
by: efficien~
nor
of
Energy
destrqyed.
The
First
Law
of
Thermo~acics
Principle.
of an ideal
reversible
BOo~
22.
(B)
(C)
~.
(C)
(B)
u .(2h)/(BOO
-50)
.0.80 ~~~
hr-!t
-F
.-a;e.d.........
Section
~"J."U
JJI 0UTLDl.E
1.
Conce'Ct,sand Definitions
a.
b.
c.
Thermodynamic
Specific
vol~e
Pressure;
Zeroth
(v .VIm)
TO1mu.e
and densit,-
( p .l/v
6P .p
(g/g-)~z
...
!.
(~)
.(1.8)(OX)
(~)
.(1.8)(0)
+ 32
(Oa) .(~)
+ 459.70
(K ) .(OC)
+ ~~13.2
body',
2 .Prope~,ies
of Pure Substances
a.
S~b-cooled Uquid,
n~ssure-temperature
Pr~ssure-volu.'!1e
Temperature-entrow diagram.
Hollier
chart (enthalw-entrow
saturated,liquid
(r),
saturated
vapor (g),
and
S'Up3rheated vapor
g
h,
Steam Tables
Tw'o-ph~e region:
Ideal
The First
V'
diagrmn)
v 1" + oXv r
gas
J R -R~
c.
General
First
+
systeD1:
;".
Ru -1.54.5 tt-lb1"/lbm- ~
J. 2
process:
J. 2
Law equation:
inl~Smi(hi
Closed
h.f' + x Ar
g
b.
d.
h.
Law of ThemOdynamics
Evaluation
Q -W
;
g
pv-RT
3.
-diagrm
diagram
outle2:ts me (h~!
sf ...oX Sf 0'
0
e.
b.
d.
t.
-2 Ste ady'-!'low
.t.
.--
m -!._V/v
g.
h.
Throt tUng
.!
Vp
pro c e s s :
hi -he
Thermal etf.icienc,.
"7 .Wnet/~
OOp. ~ /Wnet
.,
TH -TL
7]carnot.
c.
Clausius
T
H
roP carnot
.T
TL
-T
and Ielvi!1-Planck
(Clausius)
It is impossible to construct a heat engine that produces
no effect other than the transfer 0: heat from a coOler body to a
hotter body'.
(Kelvin-Planck)
It is impo-,sible to construct a heat engine which
produces no effect other than doing worlc on the surroundings and
exchang"...ngheat with a single the~al reservoir.
A lO~ efficient
heat engine is impossible.
Corollaries
n.
III.
IV.
e.
I.
It is impossiOle
to
temperature
scale.
achieve
thml a reversible
a negative
temperat".Jre
Entropy- production,
Ps .0
for
a reversibl~
Ps > 0
for
an irreversible
Ps ..(. 0
for
an i.!Ilpossible
process
process
process
heat engine
on the
absolute
h.
1.
a.b.
3-
g.
-dQ
Closed system:
-+P
T
-(s
-S1,)
stored
Stsad3'-flow sys'tem:
dq
-+p'S
"T
-s
GE!neralirreversibi1i
I .TASstored
oj.
ty equation:
L meTose
outlets
Stead:'1-i'lowsystem:
RS"Hne cy-cle
&aheat cy-cle
e.
..
feedwater hea~rs)
..
!
c
to)
Co)
0 .
Q,
g.
~ c~
2
e...
c
~ ~
H
t)
re
~
~
is ~
~
~
~
~
H
rJ]
~
~ ~
~
e
5
&{
~
~
fo4
~
~
0
tJ
ft
7c
c~-~1
g.
.""--'"
C P4 .
ct
~
g.P4 E-t_
(-4
E-4
r4
m
ori
r4
...
>..
~
..
~ct
ft
.I
>NI ~
.('I
E-t,
E-4
~
~
~ ~
~
~
~
Po
CJ'
CI
io4P4
.
...
E-t~1 E-t
.
E-cftlE-c
rf
g,
I
~rf
I
rof
ft
..ft
g,
.of
~
~
I
.of
~cw r-4
g.
ft
~ft
=
I
f"'f
~
I
~CI
>~I p
CI
~"1 ~
- - -
c:
rf
Prf
c..
...
r-I
P4
~P4
r4
to-
D-
oc
~
~
p
cq
Po
r4
cw
to-
t'a
...
Eo4
-..
E-t
I
Eo4
()
->
.
e...
f'f
...
fot
I
fot
C)
-Q.
CW
-rt
Eo4
I
Eo4
-0c
Eo4
-..
.
-"
I
E-o
.c
I
~
I
.::
-..
~
~
-~
r-.
(II
"
g.
,
m
-4-
"
l3(!)
~
-.5
SrE.AK PO'Q. CYa.ES
~eic'l~~
_c-
TURBnlE
,.-
rom;R
~c1_~
~Wt
@CONIENSER
@~~~;~.
~
s
Wp"""'"
QH -h
,.w t
-h
.h
3 .'
h"
-h
~hee.t_C1'c1e
s
-h
) + (h
2
c.-h
~.L.
&
-h)
.h
-I
.{h
-h
~~!rati
-p
2
-h)
3
ve Cy-~
--~-
@)
""1..~-
Wt
~-
-J@~;~~-~ ~
~
~
WPJ.
p2
~.h
-h
-h
"
2.
)/(h
e.
-6 JIR-ST.A!fDARDPO~
CYCLES
Otto Cycle
~e~l
Qzc_l~
~tirling
Cycle
Pa.
D1&X
CYCLES
p~
compression ratio
rv
~p
.-.presS'tlre
Vmin
rT
Cycle
v Iv
2.2.
tr
k-l
.T
.T
-V Iv:.
r", -T
k-l
.v
-thermal e.t'.t'iciency
qH
"'J -1-(-)
r
~ -~
-temperatureratio
TJdn
Otto
Pmin
v
---~
ratio
43
1.
..
])
2.
k-l
rirv
) .
'4
1.
J.
k
V
r Ir
1"
k-l
V
J.
Diese1 Q:9'cle
T
; r
~
r
-v
Iv
2.
.2.
T
-T
.T
.T
"
2.
J.
1.
k
Pa -p1,ry
r
r
k-l
P3 .P2.
k
P4.
1. C
-P1,
k
P1, rC
Cycle
rv
rT
ratio
k-J.
~t~lin~
.cut-off
.T
.T
1.
.T
.T
..3
.r
P2, ry
L
H
D P /p
1.
rV
I/i-;:
-8 -
~j--~~;~-i~2
caiP.
@TURBnlE
C~BUS1'ER
@~4~
-w:c~
..-~
(k-l)/k
"'J -1-(-)
Vnet
-T
2.
-T
"
,QH
3.
(k-l)/k
p
rir~k-l)/k
@
CQ!PP.E
S5OR
-~~I~~~;:;;;:.."'-l
,-
VAI.VE~
!}= -.-w
I
.-0
EVAPORATOR
--
w
c
COP-qt
W
c
.h
-h
1.
-h
~-h
~
-h
"
-h
2
.h
B
-h
3
-h-h
1