Kips Unit 4, UHS Topic 4(A), 2 MCQs

Chemical Bonding

Contents

VSEPR Theory
VBT
Hybridization
Bond energy, Bond
length
Bond Polarity

Muhammad Farooq Mukhtar

KIPS UNIT 4, UHS TOPIC

4(A), 2 MCQs

Valence Shell Electron Pair

Repulsion Theory
Features
Only applicable for AB2 and
above systems.
Molecular geometry depends
on both lp and bp of es.
Maximum
separation
between electron pairs to
minimize repulsions.

l p > bp
l p - l p > l p - b p > bp - b p
Space occupied:

In ABx type molecule

B represents
A. Bond pairs
B. Lone pairs
C. Electron pairs
D. Bonded atoms

KIPS UNIT 4, UHS TOPIC

4(A), 2 MCQs

Valence Shell Electron Pair

Repulsion Theory
Type

Total e
pairs

Bond
pairs

Lone
pairs

AB2

3
AB3

3
2

Electro Molecul
nic
ar
Exam
Angle
geome geomet
ple
try
ry
Linear

Linear

Triangul
ar
Triangul planner
ar
planner
Bent

180o

120o
Less
than
120o

KIPS UNIT 4, UHS TOPIC

4(A), 2 MCQs

Valence Shell Electron Pair

Repulsion Theory
Type

AB4

Total e
pairs

Electro Molecul
nic
ar
Exam
Angle
geome geomet
ple
try
ry

Bond
pairs

Lone
pairs

Tetrahedr
109.5o
al

Trigonal Less
Tetrahed pyramid than
ral
al
109.5o

Less
than
109.5o

Bent

KIPS UNIT 4, UHS TOPIC

4(A), 2 MCQs

Valence Shell Electron Pair

Repulsion Theory

KIPS UNIT 4, UHS TOPIC

4(A), 2 MCQs

Valence Shell Electron Pair

Repulsion Theory
Pick the one with bent
shape
A. CO2
B. SnCl2
C. CS2
D. HgCl2

The H-O-H bond angle in

H2O(s) is
A. 104.5o
B. 107.5o
C. 109.5o
D. Less than 104.5o

All are incorrect statements

about bond angle in NH3 & NF3
excepts
A. Both have 104.5o
B. Both have 107.5o
C. NF3 has greater bond angle
D. NH3 has greater bond angle
H2S & H2O has same hybridization
and no of lone pairs. Select the
correct option about bond angle
A. Both have same bond angle
B. H2S has greater bond angle
C. H2O has greater bond angle
D. Difficult to predict

KIPS UNIT 4, UHS TOPIC

4(A), 2 MCQs

Valence Bond
Theory
Which one

will result
stronger covalent bond
A. s-s overlap
B. s-p overlap
C. p-p overlap
D. All have same strength

in

All statements are correct

about VBT except
A. No
idea
about
paramagnetism
B. Justifies valencies of all
elements
C. Colour of complexes is not
explained
D. Maximum sigma bonds b/w

KIPS UNIT 4, UHS TOPIC

4(A), 2 MCQs

Valence Bond
Theory

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4(A), 2 MCQs

Valence Bond
Theory

Formation of bond

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4(A), 2 MCQs

bond

Sidewise
overlapping

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4(A), 2 MCQs

Sidewise
overlapping

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4(A), 2 MCQs

Sidewise
overlapping

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4(A), 2 MCQs

Planar molecule with

cloud above and below
the plane

Formation of Bond

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4(A), 2 MCQs

Hybridization
Features
Intermixing of atomic orbitals
of slightly different energy
and shapes to form hybrid
orbitals of same energy and
shape.
No of hybrid orbitals = No of
atomic orbitals intermixed
Occupied by lp and bp of
sigma bond
It decreases reactivity of
molecules.

KIPS UNIT 4, UHS TOPIC

4(A), 2 MCQs

Hybridization
Property

sp3

sp2

sp

s-orbitals
p-orbitals
Hybrid
orbitals
% s character
% p character
Unhybrid
orbitals
Sigma bonds
Pi bonds

1
3

1
2

1
1

25 %
75 %

33 %
66 %

50 %
50 %

4
0

2
2

Geometry

Tetrahedral

Bond angle
Example

109.5o
CH4, CCl4

3
1
Triangular
planner
120o
BF3, AlCl3

Linear
180o
BeCl2, CO2

KIPS UNIT 4, UHS TOPIC

4(A), 2 MCQs

sp3 Hybridization

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4(A), 2 MCQs

sp3 Hybridization

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4(A), 2 MCQs

sp2 Hybridization

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4(A), 2 MCQs

sp Hybridization

Overlap of Be and Cl orbitals to form

BeCl

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4(A), 2 MCQs

Hybridization
Which one the following
has only sigma bonds
A. Acetic acid
B. Ethyl alcohol
C. Propene
D. Benzene

Which hybridized carbon is

more electronegative
A. sp3 hybridized
B. sp2 hybridized
C. sp hybridized
D. Electron attracting power
of C-atom is always same

The hybrid state of S in SO3

is similar to C atom in
A. C2H2
B. C2H6
C. CO2
D. C2H4

The pair having similar

geometry is
A. BF3 , NH3
B. BeF2 , H2O
C. BF3 , AlCl3
D. BF3 , PCl3

KIPS UNIT 4, UHS TOPIC

4(A), 2 MCQs

Bond Energy & Bond

Length

KIPS UNIT 4, UHS TOPIC

4(A), 2 MCQs

Bond Energy & Bond

Length

KIPS UNIT 4, UHS TOPIC

4(A), 2 MCQs

Bond Energy & Bond

Length
Minimum
observed
following
A. HF
B. HCl
C. HBr
D. HI

bond energy is
in which of the
A- 566 Kjmol-1
B- 431 Kjmol-1
C- 366 Kjmol-1
D- 299 Kjmol-1

Which of the following

overlap
will
result
in
minimum bond length
A. sp3 s overlap
B. sp2 s overlap
C. sp s overlap
D. p-p overlap

Maximum bond energy

is in the case of
No lone pair in
A. C-C
C
B. N-N
A- 348 Kjmol-1
B- 163 Kjmol-1
C. O-O
C- 146 Kjmol-1
D. F-F
D- 139 Kjmol-1

KIPS UNIT 4, UHS TOPIC

4(A), 2 MCQs

Dipole Moment
Features
Mathematical determination of polarity of bond.
=qr
Units: (SI Unit = Cm) (Derived Unit = Debye)
1D = 3.336 10-30 Cm
%age ionic character = observed ionic 100
Geometry of molecule

Atomicity

=0

AB2

Linear

AB3

Triangular Planner

Bent

AB4

Tetrahedral

Pyramidal, Bent

KIPS UNIT 4, UHS TOPIC

4(A), 2 MCQs

Dipole Moment
Which of the following isomer
of xylene posses maximum
polarity
A.

B.

C.

D. All same

Which of the following is

non-polar but contains polar
bonds
A. H2O
B. SO2
C. CS2
D. All are polar

Which one has zero

dipole moment
A.
B.
C. D. All same

QUESTIONS