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Chapter 1 : MATTER
1.1 Atoms and Molecules
1.2 Mole Concept
1.3 Stoichiometry
Learning Outcomes
At the end of the lesson, you should be ABLE to:
(a) Describe proton, electron and
neutron in terms of mass and charge
(b) Define proton no, nucleon no
and isotope
MATTER
Mixtures
Solutions
What is matter?
Anything that occupies space/has volume and
has mass.
Example:
Air, gases, liquid, solid.
..
3 Types of Particles
ATOMS
MOLECULES
IONS
An atom is the
smallest unit of a
chemical
element/compound.
A molecule consist of a
small number of atoms
joined together by bonds
An atom or molecule
with a net electric
charge due to the
loss or gain of one or
more electrons.
Examples:
Na, Cu, Ne
Example: Cu
Examples:
O2, CO2, H2O
Examples:
Na+, NH4+,
O2-, NO3atom
6
Atoms
Diatomic Molecules
Atomic Structure
(n)
(e)
An atom consist of 3
subatomic particles:
Proton (p)
Neutron (n)
Electron (e)
(p)
9
Subatomic Particles
Subatomic
particle
Electron
(e)
Proton
(p)
Mass
(gram)
9.1 x
10-28
Charge
(coulomb)
Relative
charge
-1.6 x 10-19
-1
Neutron
1.67 x 10-24
(n)
+1
0
10
11
Nucleon
number
(p + n)
Proton
number
(p only)
Element
symbol
(can be an
atom or an
ion!!!)
12
Isotope Notation
13
Nucleon number of
mercury, A = 202
Total charge
on the ion
The number of
neutrons
=AZ
= 202 80
= 122
proton number of
mercury,
Z = 80
* No of e = 80 -2 = 78
14
Isotopes
An atom that has the same proton number but different in the number
..............................................................................................
of the neutron in the nucleus of an atom.
..............................................................................................
............................................................................................
Examples:
2
1
3
1
202
80
200
80
Hg
Hg
235
92
238
92
U
15
Atom
loses e
NaNa+ + e
Z = 11
e = 11
Z = 11
e = 10
Atom
(neutral)
Atom
accepts e
Anion
(- ion)
Cl + e ClZ = 17
e = 17
Z = 17
e = 18
16
Exercise 1
Give the number of protons, neutrons, electrons
and charge in each of the following species:
Symbol
Number of :
Charge
Proton
Neutron
Electron
Hg
80
200-80=120
80
63
29
Cu
29
34
29
17
8
O2
10
-2
27
32
24
+3
200
80
59
27
Co
17
Exercise 2
Write the appropriate notation for each of the
following nuclide :
Number of :
Species
Notation
for nuclide
Proton
Neutron
Electron
10
2A
+
1B
1C
14 D37
18
Learning Outcomes
At the end of the lesson, you should be ABLE to:
NEXT.
19
Relative Mass
Relative Atomic
Mass (Ar)
Relative Molecular
Mass (Mr)
atom of an element
of a compound compared
compared to 1/12
atom
of 12C with the mass
12 g.
Amu =
atomic mass unit
Relative Mass
Relative Atomic
Mass (Ar)
Relative Molecular
Mass (Mr)
Example 1
Determine the relative atomic mass of an element Y if the
ratio of the atomic mass of Y to carbon-12 atom is 0.45.
ANSWER :
Ar
= 12 x 0.45
1
= 5.4
EXAMPLE 2:
NaOH
Ar of Na = 23.0
Ar of O = 16.0
Ar of H = 1.0
Mr of NaOH= 23.0 + 16.0 + 1.0
= 40
23
Example 3 :
Calculate the relative molecular mass (Mr) of C5H5N
Answer :
Mr
= 5 X 12 + 5 X 1 + 14
= 79
24
Learning Outcomes
At the end of the lesson, you should be ABLE to:
25
Mass Spectrum
63
8.1
24
% or
Ratio or
Fraction
9.1
25 26
m/e
(mass, amu)
m/e =
mass/charge
Average
atomic =
mass
Total of Q
Amu =
atomic mass unit
Q=
m=
Example 1
Copper, Cu consists of two isotopes which is 69%
63Cu
65Cu
Relative
abundance
(%)
69
31
62.9
64.9
m/e (amu)
SOLUTION:
Average
atomic mass =
Qi mi
Qi
Example 2
Relative
abundance
18
7
85
87
m/e
(amu)
Relative
abundance
SOLUTION
18
7
85
87
m/e
(amu)
CONTINUE SOLUTION
C.
Qi M i
Average mass of Rb
Qi
(18x85) (7 x87)
25
85.56 amu
85.56 amu
A r of Rb
1 x12.00 amu
12
85.56
Example 3
The ratio of relative abundance of naturally occurring of chlorine
isotopes is as follow :
35
Cl
3.127
37
Cl
Based on the carbon-12 scale, the relative isotopic mass of
35Cl
chlorine.
SOLUTION
Ar = 34.9689 X 3.127 + 36.9659 X 1
3.127 + 1
= 35.4528 amu
CONTINUE SOLUTION
Example 4
6
The relative atomic mass of 3 Li and
7 Li
3
SOLUTION
CONTINUE SOLUTION
Recap
What have you learnt today?
41