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THERMOFORMING
INDEX
Thermoforming principles
-History of thermoforming industry
-Products manufactured by thermoforming
Heating plastics
-Heat transfer: conductivity, convection
and radiation
-Thermal properties of plastics
-Heat transmission media
-Temperatures and forming cycles
-Establishing the right temperature
for the material
11
Thermoforming equipments
-Gas furnaces with pressured air circulation
-Infrared heating furnace
-Lineal heating electric resistors
17
Thermoforming
25
31
Thermoforming techniques
-Bi-dimensional thermoforming
-Tri-dimensional thermoforming (with molds)
-Molding techniques in infrared heating
furnace
46
51
53
Thermoforming variables
-Material variables
-Mold variables
-Pre-stretching variables
-Mechanical support variables
58
62
Appendix
68
-Glossary
-Glass fiber reinforced plastic
-Unit conversion table
Thermoforming
Thermoforming principles
History of
thermoforming
industry
Since the beginning of the XX century some techniques to form sheets, with materials
such as metal, glass and natural fibers, have been known. The true thermoforming
principles emerged as thermoplastic materials were developed, which happened during the second world war. The post-war period brought about mass commercialization
and rapid development of equipment and machinery capable to adapt to the manufacturing modern methods, to make more useful and income yielding products.
In the 50s, the volume of thermoplastic material production and the products made
with it reached impressive figures. In the 60s, by developing the thermoforming industry, the foundations for the future were established. Then huge consumers and product competitiveness, in the 70s, required high speed productive machinery. Equipment
manufacturers met those needs by making machinery capable to produce about one
hundred thousand thermoformed individual containers per hour. Sophisticated controls
were also required.
Since the 80s up to the present, thermoformers have so much relied on their process
that they have gone beyond their expectations and have established production lines
that can produce finished thermoformed products, not only from sheets but also from
resin pellets; besides, they recycle the scrap with minimum control. Equipments have
been computerized and at present, they can perform auto-monitoring and diagnostic
functions. Nowadays, very complex equipment does not require more than one worker to handle and control it thanks to electronic advances. Thus, it is believed that the
thermoforming industrial labor market will undergo a shortage of technically trained
and experienced personnel, since traditional knowledge will no longer be enough.
Therefore, lectures, seminars, courses, etc., would be useful to increase thermoformers general knowledge, and would further advance this well established industry.
Manufacturing
thermoformed
products
Thermoforming
At present, most of the packaging equipments (blister) are high speed automatically
sustained. These equipments are called "form-fill-seal" and are used to pack cosmetics, cold cuts, sodas, candies, stationery, etc.
Take away food industry
In the growing "take away food" industry, a great deal of thermoformed products are
used, ranging from a complete meal container (divided containers), to hamburgers and
sandwich packages, sodas, etc.
Usually, that industry requires printed thermoformed packages. This printing can be
made before or after thermoforming. Some examples of this are trays, cups, sandwich,
hamburger, hot-dog packages, etc.
Food packaging industry
Supermarkets are the great consumers of thermoformed containers. The materials
used are low-cost thermoplastics. These are designed to be piled or placed in different forms. Examples: meat, fruit, eggs and vegetables containers.
Transport
Public and private transport such as bus, train subway, plane, car, etc., has within its
equipment many thermoformed plastic parts. Most of these are used for inside finishing or non-structural exterior parts. In others, they are used for seats, backs and arms
of seats, fronts of doors, service tables, wind-shields, instrument protectors, guards,
spoilers, etc.
Signaling and advertisements
These are usually made of acrylic and can consist of only one piece and can be very
large. Transparent (clear) acrylic is generally used and it is painted on the inside using
acrylic based paint.
The use of acrylics for exteriors makes advertisements weather resistant and they virtually need no maintenance; furthermore, they can stand extreme cold or hot weather
conditions. Exterior lighted bill-boards, interior advertisements, signaling in public
places, offices, etc., are some examples.
Household products
There is a great deal of products that have thermoformed parts; actually, they are produced in great quantities. They can be found in cabinet, washing machines, dish
washers, dryers, refrigerators, air conditioning outlets, humidifiers, T.V. and radio cabinets, etc.
Food industry
One of the oldest and greatest thermoformed product consumers is the food industry.
The use of trays and other accessories has a greater potential use, besides the great
5
Thermoforming
users like hospitals, nurseries, schools fairs and others, there are the military sector
and international aid organizations. Some examples of products are: trays, cups and
plates.
Medical industry
The medical industry requires a great variety of products and sterilized packaging for
hospitals, clinics and doctors offices. The specifications for these products are usually very strict and recycling materials is unacceptable.
The use of acrylic , since it is physiologically harmless, is growing every day. Some
examples are: chirurgical equipment, syringes and needles, chirurgical tables, cabinets, incubators, dentists seats and exercise platforms.
Agriculture and horticulture
Commercialization of decoration plants in supermarkets and specialized shops has
generated, for some time, the need to make flower pots and small containers, including with multiple divisions for exhibiting and selling. This kind of containers are made
of recycled plastic at low cost. Flower pots, different size and divided containers, small
green houses, trays for growing seeds, planting containers, etc., are some examples.
Constructin and housing
For some years, construction industry has used thermoformed products, which have
become quickly popular. Thermoformed parts have easily replaced a lot of products.
Actually, there are products that cannot be manufactured any other way, such as skylights or cannon arches. In this sector, acrylic is used a lot because of its weather
resistant properties and its thermoforming quality.
Examples of these are: skylights, cannon arches, hydro-massage tubs, bath modules,
wash basins, bathroom screens and cabinets, tables, chairs, lamp stands, kitchen
items, stairs, frontages, partings, windows, aquariums, etc.
Luggage
Some luggage manufacturers are deciding in favor of using the thermoforming
process, since it has advantages over the injection products. Because it is molded
effortlessly, the possibility of thermoformed products fracturing is reduced. Examples:
all kinds of suitcases, briefcases, etc.
Photography equipment
One of the oldest thermoformed products is the tray used for developing photos, also
flash bulbs (metallic reflector) and the magazine for standing cameras, even though its
manufacturing requires a precision thermoforming technique.
Thermoforming
HEATING DEFLECTION
TEMPERATURE
POLYMERS
Extruded acrylic
Cell-cast acrylic
Cellulose acetobutyrate
High density polyethylene
Polypropylene
Polystyrene
High impact polystyrene
SAN
ABS
Polyvinyl chloride (RV.C.)
Polycarbonate
Thermal
properties
AT 264
PSI
(F)
AT 66
PSI
(F)
201.2
204.8
149-167
208.4
230
167-176
140-176
230-239
158-212
194-203
221
176-248
167
248
131-149
158-203
185-203
212
167-239
158
266
WITHOUT
CHARGE
(F)
THERMOFORMING
TEMPERATURE
SHEET
TEMP.
(F)
275-347
320-356
248-302 284-320
212
293-374
293-392
284
284-338
212
338-356
248
428-446
248-356
203
275-347
230
356-446
320
MOLD
TEMP.
(F)
AID
TEMP
(F)
149-167
149-167
203
338
113-149
113-149
194
194
158-185
113
203-248
194
176
284
One of the least considered aspects in thermoforming practice, is that of the thermal properties of polymers which is one of the most relevant and critical aspects of
the process. Wholly understanding these factors will reduce the risk of long pre-production run or bad adjusting of the product to the outline.
When we talk about thermal properties, it is indispensable to establish the concepts
related to this topic. First, it must be remembered that energy often dissipates
through friction and then it appears as heat or the inner thermal energy of a body.
Of course, some times, heat in a substance is increased deliberately to change its
temperature or its form.
Thermoforming
Specific heat and thermal conductivity are two of the physical properties of polymers
that are extensively used in thermoforming.
Temperature
In the thermal phenomenon debate some terms and concepts must be included. The
first thermal property is temperature. Temperature is the measurement of the degree of
"heat" or "cold" in an object. A temperature scale must be established, water properties
have been taken as a parameter, specially the degree of ice fusion and water boiling.
There are three scales to measure the temperature of a substance: the scale in centigrade
degrees (C), Fahrenheit (F), and Kelvin (K), the first two are the most commonly used.
Heat
measurement
Heat is simply a form of energy, therefore, the suitable physics unit to measure heat is
the same as the one for mechanical energy and it is the joule (J). As in the case of temperature, water is used as parameter of substance to define the heat unit. The amount
of heat needed to raise the temperature of 2.2 pounds of water by one degree [at present it is taken as 58.1F to 59.9 F (14.5 C to 15.5 C) is defined as 1 calorie (cal)].
Specific
heat
When a calorie is added to 2.2 pounds of water, the water temperature increases 33.8
degree, for example: if the same amount of heat is added to the same amount of methylalcohol, the temperature rises about 35.06 degrees, or if 1 cal. is added to 2.2 pounds
of aluminum, the temperature of the metal rises about 41 degrees. In fact, each substance will respond differently when exposed to heat. The amount of heat needed to
raise 33.8 degree in 2.2 pounds substance is called specific heat of that substance.
Water works as a parameter and it has been determined as 1 cal./pounds, and it is taken
as a basis to compare every material. Excepting water, most materials have a specific
heat, lower than plastics.
Thermal
conductivity
Thermal conductivity is one of the three ways by which heat energy can be transferred
from one place to another; it results from the molecular movement and therefore, it
needs the presence of matter. Heat energy is transferred by collisions where the rapid
movement of atoms and molecules of the hotter object transfers part of the energy to
the colder object or the one with a slower movement of atoms and molecules. When a
substance is heated, it expands, heat increases the volume of a substance and diminishes its density. The thermal conductivity of acrylic is 0.0005 cal./seg. cm2
Thermal
expansion
Thermoforming
a piece to get hot as to get cool. It must be taken into consideration that there might
be problems when the thermoformed parts have to be within a very close dimensional
tolerance. There might be other kinds of problems when there is shrinkage in a male
mold, making it difficult to remove the part from the mold. The thermal expansion coefficient of acrylic is 0.00009 cm./cm./C.
Thermoforming
Heating plastics
Heat transfer:
conduction,
convection
and radiation
In the thermoforming process, the heating operation is one of the longest stages in
which there might be present the most difficulties and material and human resources
waste. That is why this chapter is devoted to heat transfer, aiming at trying to clarify
phenomena that might occur in plastics heating operation.
Although scientists have divided heat transfer into three different phenomena: conduction, convection and radiation, in practice, the three phenomena are concurrent.
Conduction
This is heat transfer from one part of a body to another part of the same body, or from
one body to another which is in physical contact with it, without a substantial displacement of the particles of the body.
Convection
This is heat transfer from one point to another, in a fluid, gas or liquid (by mixing one
part of the fluid with another). In natural convection, the movement of the fluid totally
derives from the difference in density as a result of different temperatures. In the forced
convection, which is the one we are interested in, the movement is produced by
mechanical means. When velocity is relatively low, it must be noted that free convection factors, such as different temperature and density, may have an important influence.
Radiation
This is heat transfer from one body to another that is not in contact with it, by means
of a wavy movement through space.
For the purposes of thermoforming process, three media for heat transfer are considered:
A) Contact with a solid, liquid or hot gas.
B) Infrared radiation.
C) Internal excitation or by microwaves.
The first two ones are very much used in plastic thermoforming and for several of them
the scope of temperature is between 120C and 205C (250F and 400F).
10
Thermoforming
Thermal
properties
of plastics
Plastics are poor heat conductors; therefore, thick sheets need a considerably long
time to heat. In table 8, there are some thermal properties of some materials to be compared. In plastic thermoforming the method and size of the heating equipment must be
taken into consideration.
Heating a sheet on both sides (sandwich-like heating) helps to reduce the time taken
in this operation. In some cases, heating time can be reduced if the sheet is pre-heated and kept at a medium temperature; however, this is rarely done with less than 6mm.
thick materials.
In addition, the amount of heat required to raise the temperature of plastics is high,
compared with any other material; except water. To estimate the needed heat for a
sheet, the following formula can be used.
Required heat = Length X width X thickness X density of material X (specific heat X different temperature + fusion heat)
Table 8: Thermal properties of some materials.
MATERIALS
Air
Water
Ice
Soft wood
Hard wood
Phenol R.
Epoxy R.
Polyethylene
Acrylic
Polycarbonate
Graphite
Glass
Quartz
Aluminum
Steel
Copper
11
Thermoforming
SPECIFIC
GRAVITY
g/cm3
SPECIFIC
HEAT
Btu/ Ib 0F
0.0012
1
0.92
0.5
0.7
1.5
1.6-2.1
0.96
1.19
1.2
1.5
2.5
2.8
2.7
7.8
8.8
0.24
1
0.5
0.4
0.4
0.3
0.3
0.37
0.35
0.30
0.20
0.20
0.20
0.23
0.10
0.092
FUSION
HEAT
Btu/lb
144
144
55
171
171
88
THERMAL
CONDUCTIVITY
Btu ft/sq ft hr 0F
0.014
0.343
1.26
0.052
0.094
0.2
0.1-0.8
0.28
0.108
0.112
87
0.59
4y8
90
27
227
THERMAL
COEFFICIENT
of LINEAL
in/in 0F10-5
2.8
1.5
1.5
3-5
1.5-2.8
7
3.5
3.7
0.44
0.5
0.4 y 0.7
1.35
0.84
0.92
Heat
transfer
media
For practical purposes we will divide the media for heat transfer into 4 types:
Heating by contact
The fastest heating method is placing a plastic sheet directly in contact with a hot
metal sheet. It is specially used in mass production of small and thin items.
Heating by immersion
With this method, a plastic sheet is immersed in some liquid that transmits heat as
evenly and quickly as possible, but its use is restricted to molding parts out of huge or
very thick sheets, since handling and cleaning of the piece are very difficult
Heating by convection
Furnaces with air convection are widely used, because they provide even heating and
can, to a certain degree, dry some materials that contain some degree of moisture.
These furnaces provide a huge safety margin as for time variations in thermoforming
cycles.
Important note:
All the above mentioned heating media require a considerable amount of time to preheat the equipment.
Infrared heating:
This method can supply instant heating and therefore, its exposition cycles are very
short, and sometimes it takes only a few seconds. The main sources of this kind of
energy are:
-Quartz lamps that emit in the visible and near infrared.
-Ceramic or metal resistors that emit more energy in the far infrared.
The surface of these radiation heaters can be between 599 F and 1301 (315C and
705C). It must be noticed that at the highest temperatures, the mass of radiation
occurs at shorter wave lengths. On the other hand, at lower temperatures, radiation
expands on longer wave lengths; and this is extremely important, since each plastic
absorbs infrared radiation in different areas. Only the radiation absorbed is used to heat
plastic directly.
Internal heating
This method has not had enough application in thermoforming because the equipment
used is very expensive. Besides, it is not suitable for every plastic, and cooling time is
very long. It is useful in forming processes where localized heating is required on a specific area of the material. For example, when forming edges of material which has a
high loss factor, such as P.V.C.
12
Thermoforming
In certain applications, thermoformed products show uneven parts, even when a sheet
has been uniformly heated. Heterogeneous shrinkage of a sheet is due to the very
design of that part. In those special cases, controlling heat by section will give more
uniform wall areas. This procedure is called shading or screening and it consists in
placing a non-flammable filter to regulate heat (a wire net, asbestos, etc.) between the
sheet and the source of heat, this will reduce the flow of heat to certain areas of the
material, and will prevent excessive stretching on that area.
In more sophisticated equipments, at present, there are electronic controls and ceramic parabolic elements that allow variability when heating different areas of the sheet.
Temperatures
and forming
cycles
Before we start with temperatures and forming cycles, we will establish some terminology:
a) Temperature to remove items off a mold
b) Operation: bottom limit
c) Normal temperature to form
d) Operation: top limit
Temperature to remove item off a mold
It is the temperature at which an item can be removed off the mold without distortion.
Some times an item can be removed at higher temperature if cooling devices are used.
Operation bottom limit
This represents the lowest temperature at which the material can be formed without
internal effort. This means that the plastic sheet must touch each corner of the mold
before it reaches its bottom limit. The material processed under this limit will show
internal effort that later will cause distortions, glow loss, cracking and other physical
changes in the finished product.
Normal temperature to form
This is the temperature at which a sheet must be formed in a normal operation. It must
cover the whole sheet. Shallow thermoformed items with the aid of air or vacuum will
allow a bit lower temperatures, and this translates into shorter cycles. On the other
hand, deep forming requires high temperatures, as well as for pre-stretching operations, details or intricate radiuses.
Operation top limit
Under this temperature a thermoplastic sheet begins to degrade, and it also turns too
fluid and cannot be handled. These temperatures can be exceeded, but only with modified formulations that improve the physical conditions of the sheet. Injection and extrusion molding, actually use much higher temperatures, but only for very short periods of
time.
13
Thermoforming
General recommendations
a) The characteristics of a finished product are determined by the kind of thermoforming technique used.
b) The material must be heated evenly at the annealing and forming point, before it
cools below its molding temperature.
c) Acrylic must cool slowly and evenly while it is in the mold.
d) The formed piece must be cool before any finishing is done, like spraying paint or
serigraphy.
e) In the design of a piece, a 2% shrinkage in both directions and a 4% increase in
thickness must be taken into consideration, as well as a 0.6% contraction at 1%
when cooling
Temperatures and forming cycles
As it was previously mentioned, one of the most important steps of the thermoforming
process is determining the right temperature of the material. For acrylic, the right selection of annealing or normal temperature will prevent:
At a low temperature:
Internal effort concentrates in the thermoformed piece which later, under sudden environmental temperature changes, will emerge as fissures or cracking.
At high temperature:
Bubbles and mold marks, due to extreme heating.
Table 9 shows the ranging temperatures for Plastiglas acrylic sheet, for general use,
and Sensacryl FP, deep molding sheet.
Table 9
TEMPERATURE RANGE
KIND OF MATERIAL
14
BOTTOM LIMIT
(OF)
TOP LIMIT
(OF)
320
356
356
392
Thermoforming
In Mexico, due to the high cost of electricity, it is more common to use a convection
furnace with pressured air re-circulation by means of gas, for which a very practical formula is very useful to determine the permanence time for an acrylic sheet, taking into
consideration the annealing temperature range previously adjusted.
Formula: 53.3 X E (inches) = T (min.)
Where : 53.3 = Factor, E = Thickness of material, T = time.
This formula can be used for thin (0.04 to 0.24 inches) Chemcast sheets. For thicker
sheets, the factor has to be changed as follows:
Formula: 3 X E (inches) = T (min). Ex: 53.3 X 0.118 = 6.30 min.
As it has already been mentioned, there are variables that may modify these formulas,
such as: environmental temperature of the place where the furnace is located, cure
(especially in extreme weather conditions), material thickness fluctuation and the conditions of the equipment among other things.
Forming temperature
Every thermoplastic material has a process specific temperature. These ranges apply
without taking into consideration the way the material will be processed. The most
used materials compared with acrylic are mentioned in table 10:
Table 10, Ranges of forming temperature
MATERIAL
Acrylic CHEMCAST
Sensacryl FP
ABS
Polycarbonate
AD Polyethylene
EstablishIng
the right
temperature
of the material
SHEET
TEMP.
(0F )
320- 356
356-392
257-356
392-482
320-428
BOTTOM NORMAL
(0F )
LIMIT
0
(F)
320
356
257
392
320
338
374
329
455
374
TOP
LIMIT
(0F )
REMOVAL
TEMP.
(0F )
MOLD
TEMP.
(0F )
MECHANICAL
SUPPORT
TEMP
. (F)
356
392
356
482
428
248
266
185
284
185
149-167
158-176
158-185
194-248
194-212
210
248
338
Another important factor in the thermoforming process, is establishing the right temperature for plastic material. You must bear in mind that apart from the heat transmission medium, a sheet must be heated at the recommended range of temperature
(annealing range), besides, a sheet has to be heated in an evenly way.
In practice, it is not easy to accurately establish the temperature of the sheet, even
when using contact thermometers; therefore, this determination is based on the performance of a sheet. The gradual change in which a sheet yields during the heating
15
Thermoforming
process (annealing point), is one of the cues to establish the right temperature. Some
controls for infrared radiation thermoforming equipment have been developed, where
a sheet is fastened horizontally, and the "yielding" or "bending" phenomenon is used,
and photo-electric cells control heating time and/or temperature.
Clamp
Frame
Vacuum box
Photo-electric cells
Solenoid valve controlled by
photoelectric cells.
However, this criterion cannot be applied indiscriminately to every plastic, since some
materials may over-heat before they begin to yield or bend. Although a range of temperature is established, the expected temperature of a sheet may not be achieved; this
may be caused by:
a) Fluctuations in the thickness of the material
b) Temperature changes in the equipment and/or environment
c) Minimum fluctuations in the line voltage (in infrared equipment).
d) The regulator of the pressured air circulation gas equipment may not be the right
one, there is not enough gas pressure, the burner is not the right one or it may be
blocked with soot, etc.
There are cone formed pyrometers, infrared radiation or gas (hot air) heating tablets,
that can render a more accurate measurement. Although probably, the best way to
measure the temperature of a sheet is by means of an infrared pistol, which measures
by zones; though the equipment is expensive, it is the only one that measures the temperature of a sheet accurately and reliably.
16
Thermoforming
Thermoforming equipments
Originally, convection furnaces were the first equipments to heat plastic sheets that
were going to be thermoformed, and up to now, that kind of heating is still preferred
for sheets of different thickness, and for temperature even distribution.
Heat can be applied with gas or electric resistor units. To produce air circulation from
4,500 to 6,100 cm3/min. (150 to 200 feet3/min), pressured air re-circulation and deflectors are crucial to get homogeneous temperatures. The furnace temperature must be
adjusted to the plastic forming temperature.
Infrared radiation heating, compared with oil immersion or contact heating (the two latter very limited in practice), is extremely rapid. For example, a 3.0 mm sheet heating
time by infrared radiation can be achieved in one min. at about 10 watts/inch2.
Because infrared radiation heating takes very little time, heat energy absorbed by a
sheet may cause over-heating, that may even affect the degrading of the material
(bubbles or burning) if it is not controlled. It is important to consider that in long runs,
the furnace temperature has to be gradually reduced.
In some cases, when the product has intricate or very deep sections, there is the risk
of the thickness of the material considerably thinning; in this case screens must be
used (they may be made of perforated plate or metallic display) to prevent over-heating.
The elements of infrared radiation can be obtained in a very wide range of designs,
according to their importance they are:
1.- Tungsten filaments in quartz tubes or lamps, temperature 3992 F (2,200 C).
2.- Spring- like nichrome resistor on refractory ceramic bases.
3.- Nichrome resistors protected by plate or stainless steel tubes.
There are manufacturers who make infrared radiation thermoforming machines in a
wide variety of sizes, capacity, degree of automation and versatility.
The specifications to acquire a thermoforming machine vary depending on the finished
product that you want to get and therefore, it is necessary to consider:
Voltage, wattage, amperage, useful area of forming, number of heaters (lower and
upper), controls to regulate temperatures by zones, degree of automation, capacity to
17
Thermoforming
This kind of furnace supplies uniform heat and constant temperature, with a minimum
risk of over-heating an acrylic sheet. Electric ventilators must be used to force hot air
circulation on the acrylic sheet at a speed about 4,500 to 6,100 cm3/min., and
devices to distribute the air in every zone of the furnace.
Gas furnaces need heat inter-changers to prevent accumulation of soot due to the
gas flow, as well as controls to interrupt the gas flow, when necessary.
Electric furnaces can be heated, using sets of 1000 watts resistors. When using a furnace with a 10 m3 capacity, about 25,000 power watts will be consumed and half of
this will be used to compensate heat loss due to leakage, insulating transmission and
the use of doors. A minimum 2" thick insulation is advised and the doors of the furnace should be as narrow as possible, to reduce most of the temperature loss.
Automatic devices must be used to strictly control temperature between 32 F and
482 F (0 C and 250 C). To get a more uniform sheet heating, it is important to hang
it vertically, and this can be done with a system that fastens the material all along with
clamps or canals with springs which move on wheels that slide on rails, like the ones
used for closets.
Basic criteria to construct a gas furnace with pressured air circulation.
The best advice in this case, is asking any industrial furnace manufacturer to build
one with the mentioned characteristics, since the construction of one, specially the
heating and operation systems, is very risky for anybody who has only little knowledge on the subject.
This kind of equipment must be approved by specialists in gas installations, it also
has to be registered before the corresponding authorities.
It is also relevant to point out that the information provided here, is only related to the
metallic structure and fastening system for acrylic sheets. A furnace construction can
be divided into the following sub-systems:
A) Structure
B) Fastening acrylic sheet
C) Electric system
D) Gas installation
E) Controls
18
Thermoforming
19
Thermoforming
Iron hinge
Spring
1/4 crossbar
handle
Washer
Nut
Acrylic sheet
1/2
20
Thermoforming
LATERAL VIEW AND DETAIL OF THE FURNACE DOOR AND RAILING SYSTEM
Steel cable to fix it to the
ceiling of the place
1 1/2 x 1
iron angle
1/2
No. 50 wheel
2 1/2 x 2 1/2
iron angle
Furnace door
Infrared
heating
furnace
21
Thermoforming
Infrared energy is absorbed by the acrylic surface exposed, rapidly reaching temperatures over 356 F (180 C), that later on, is transmitted to the center of the material due
to temperature conduction.
Infrared radiation heating can be obtained using tubular metal elements, spring electric resistors, or by grouping infrared light lamps. To get a more uniform heating distribution, a net or metallic mesh can be placed among the heating elements and the
material which can work to expand the temperature. It is also convenient to place an
infrared heating plate, about 12from the material and 20 from the bottom plate.
To regulate energy input into the equipment, we recommend using devices such
as different transformers or percentage
meters that will help to control temperature. Planning electric energy charges and
great capacity equipment is also advisable, an electric sub-station will also be
needed.
Lineal heating
electric
resistors
An electric resistor can only be used to make bends in a straight line; to achieve this,
you also need a spring type electric resistor (20) or armored type (about 1KW X 1.2 m.).
Lineal resistors are made of wire, inside Pyrex ceramic tubes. The material must not be
in contact with the tube to avoid marks on the surface. A distance of 6 mm. from the
tube to the material is recommended to get uniform heating on thin material.
When more than 3.0 mm thick material is going to be heated with this procedure, the
resistors should be placed on both sides of it. In the next picture, it is shown how an
asbestos plate bender at the beginning of production will provide a suitable bend, but
as production advances, the heating area expands making a bigger radius bend, that
is why a resistor with water re-circulation is much better for acrylic bending.
22
Thermoforming
Acrylic Sheet
Heating zone
Asbestos
plate
Electric resistor
Acrylic Sheet
Heating zone
Asbesto
s plate
Electric resistor
23
Thermoforming
24
Thermoforming
The oldest method to form a plastic sheet into a utilitarian piece is vacuum forming. The
original description of the thermoforming process was precisely "vacuum-forming".
The basic principle of the vacuum-forming process is having a softened thermoplastic
sheet in a mold perfectly sealed and where the air inside is evacuated by the vacuum
force or suction. As the air is evacuated from the mold, it creates a negative pressure
on the surface of the sheet and therefore,
natural atmospheric pressure yields, forcing the hot sheet to take the place of the
empty spaces, as it can be seen in the
picture.
Acrylic
sheet
25
Thermoforming
Vacuum equipment
There is a great variety of vacuum pumps: reciprocal piston, diaphragm, blades, eccentric rotor, etc. All these provide a good vacuum but cannot evacuate great volumes of
air at high speed; that is why a stock tank has to be connected to be used as "vacuum accumulator". On the other hand, there are compressors that can evacuate a great
volume of air but are limited for vacuum force.
A suitable vacuum system needs a pump that can displace from 28 to 29" Hg or from
0.5 to absolute 1 Psi (710 to 735 mm of Hg.) in the stock tank before the forming cycle.
The line, duct or pipe between the stock tank and the mold should be as short as possible with a minimum of angles. It is important to eliminate air leaking due to damaged
piping, perforated hoses, loose couples or nipples, as well as unnecessary valves.
Rapid action or globe valves should be used. Vacuum pumps are available in one or
two steps. A two step vacuum pump can evacuate pressures below 10 Psi; displacement capacity or evacuation for a one step pump is reduced by half. Table 11 shows
vacuum pumps typical capacities
DIAMETER
(inches)
3.04
3.04
4.08
5.08
5.6
5.6
---0.280
0.498
0.935
1.54
3.08
SPEED
POWER
DIAMETER
(RPM)
NEEDED
OF PIPING
(Kw)
OUTLET
0.56
0.74
1.48
2.2/3.7
3.7
5.6
19
25
32
38
52
52
800
800
800
750
900
900
Vacuum tanks
Excepting some vacuum equipments, most have a stock tank. Bearing in mind that
work pressure is about 10 Psi (about 21 inches Hg/530 mm. Hg) vacuum, then the volume of the tank should be 2.5 times bigger than the volume between the molds, the
vacuum box and the piping. Doubling the volume of the stock tank (along with other
similar conditions) pressure can be increased 15% (11.5 Psi), according to what is
established, the theoretical limit for the vacuum forming process is only 14.5 Psi.
26
Thermoforming
In many cases, a rapid displacement of vacuum is very important. This can only be
made by placing the vacuum tank as near the mold as possible and reducing the piping friction as much as possible, which can be done by:
a) A bigger piping diameter.
b) Piping with wide curves, avoiding 90 angles.
c) Changes in the transversal section of the piping (diameter changes).
Many equipments in the market do not meet these requirements. In general, the piping
must be 1" diameter to displace 1 ft3 of air, for big pieces a 2" or 3" diameter is suitable. There should also be a flexible plastic hose internally reinforced with wire or a
similar material that prevents it form collapsing; it should be connected between the
mold and the piping, as shown in the picture.
Bearings
globe valve
Solenoid valve
Air deflector
Thermoforming
Pressured air
forming.
Acrylic
Mold
Pressured air
Vacuum orifices
Acrylic
Mold
Air exhaust
28
Thermoforming
When needed, the mold should have orifices to eliminate the air caught inside
and avoid wrinkles or deficient forming.
Pressured air forming has become popular, specially for small pieces. The advantages of this method are: improvement
on dimensional tolerance, forming speed
can be considerably increased and fine
details are better defined.
Mechanical
forming
29
Thermoforming
Combined
techniques
Mechanically forming with matrix-male molds does not only depend on the forces
used, usually, this kind of forming can be combined with vacuum, pressured air or both
at the same time. Therefore, the matrix-male mold does not have to coincide accurately, the male mold may be relatively inferior in dimensions and have a substantially
different form from the matrix.
When male molds are made like this, they can act as "pushers" of a plastic sheet. This
kind of support is called mechanical support, because it presses the softened material into the matrix. The purpose of this support is to stretch the material so that the final
form is accomplished in combination of vacuum and/or pressured air.
Using mechanical support in the process has the advantage of a better distribution of
the thickness of a product, than using any other process. Many variations in the
process can be obtained combining these techniques. Those variations can be vacuum pressure changes, vacuum or pressure application time, mold closing speed time
or forming cycles.
Mechanical
support
design
Usually, mechanical supports are made of wood. Hard or tropical wood is the most
used to make supports. In some cases, pieces of other plastic material such as: nylon,
rigid polyurethane, acrylic, aluminum or steel, which are easily machine finished, can
be incorporated.
If production volume requires it, a cooling and/or heating system can be incorporated.
The decision to heat or cool the support, must be made from the beginning of the
design, since later on it will be harder if not impossible to try to adapt a heating element, that is why required machine finishing should be made to incorporate the system.
When a support is very cold, a sheet will surely get cold on it. Cooling usually takes
place between the points of a support and a sheet and the sheet and the mold. In
extreme cases, the sheet may shrink on the support during the forming.
The form of a support has a determining
influence on the wall or thickness of a finished piece. In the next picture, there are
three different kinds of support.
30
Thermoforming
31
Thermoforming
Tin-like support
Sphere-like support
Thermoforming molds
Choosing
the type of
thermoforming
technique
Criteria to
design
thermoformed
products
It must be mentioned that: products made using thermoforming technique, though this
technique is versatile and flexible, regarding aspect and characteristics, differ from
products manufactured using injection molding. In the following comparative table the
basic differences can be analyzed. To conclude, to design thermoformed pieces the
following criteria must be established:
1. - Thinning of material should be considered, this mostly depends on form, size and
technique used (chapter 8). Generally, thinning of material is directly proportional
to the height of a piece.
2.- A 3 and 5 exit angle of the mold should be considered.
3. - It must be taken into consideration that a piece will contract 0.6 to 1% when it cools.
4. - In general, the surface of a thermoformed piece will be smooth, though some textures can be obtained.
5.- In designing a piece, big radiuses should be included; there may be edges but they
can tear the material.
32
Thermoforming
VARIABLES
Thickness
Mold exit angles
Molding temperature
Dimensional tolerance
Inserts
Surface finishing
Production
Mold
33
Thermoforming
PROCESO
INJECTIN
TERMOFORMING
Constant
0.5 to 1
392F-464F (200C 240C)
Excellent
Possible insertion of elements in
other materials.
Smooth surfaces or any other
texture can be obtained.
High production, hundreds or
thousands of pieces a day.
Steel with alloys or expensive
treatment, complex design,
matrix-male mold.
Yes.
Variable
3 - 5
320F-356F (160C 180C)
Relatively good, not for accuracy.
Mold surface can be prepared
for inserts
Only smooth surfaces, some
shallow textures
Medium, some dozens a day.
From 3 to 6 months.
Criteria to
design
thermoforming
molds
The following criteria are key factors to successfully produce thermoformed pieces.
They are the core of any development, but it is also vital to thoroughly analyze these
concepts and later we will see in detail each consideration in the design of molds.
Then, these basic criteria and considerations will be the fundamental parameters to
manufacture thermoforming molds, regardless of their complexity. It should be noted
that when these molds are manufactured, the following concepts must be assessed.
1. - Form and dimensions of the piece.
2.- Aspect of the piece.
3.- Estimated production volume.
Probably the most important of these concepts is the estimated production volume,
since it will depend on the definition of the kind of mold, material, finishing, thermoforming technique, etc. Next, the model designs are shown:
1. - A male mold is easier to use, less
expensive and more suitable to form
deep pieces. In general, a matrix should
not be used to form pieces deeper than
half the width of the piece. The matrix is
used when the concave face of the finished piece must not be in contact with
the mold.
2.- The molds must have enough vacuum
orifices so that an annealed sheet can
conform to the critical parts of the mold,
the vacuum orifices have to be made in
the deepest parts and areas where air is
caught, and must be small enough not to
leave marks (1/32" to 1/8" diameter).
Vacuum can be more effective if the hole
is enlarged from the inside.
3.- There must be ducts that allow water
or oil circulation through the mold when
temperature control in it is needed.
34
Thermoforming
8.- The thin or weak parts can be reinforced with reinforcement ribs, which will
also reinforce big flat areas.
35
Thermoforming
30
9.- If it is necessary to mold using a permanent incrustation, you should consider: the difference between the expansion
coefficient and the various materials, otherwise, there can be a failure due to a
forced insert, because of different expansions and contractions of the materials in
contact.
10.- The surface of the molds can be lined
with cotton flannel, felt, velvet, suede, etc,
to diminish mold marks. The most common is cotton flannel.
Considerations
in the design of
thermoforming
molds
One of the advantages of the thermoforming process is the diversity and kinds of
molds that can be made at a very low cost and relatively fast, being highly accepted
for other applications, over other processes.
Usually and unlike injection molds, only half the mold is needed and it depends on the
form of the product, desired aspect and chosen technique (may be male mold or
matrix).
Choosing the right one is much more important when the part to be thermoformed is
very deep. When the pieces are shallow, profiles are small or when thinning is irrelevant, choosing will depend on the aspect of the piece. If details of the mold are important, then the side of a plastic sheet in contact with the mold surface should be the
front of the piece.
Some times, a bigger radius or smooth aspect is desirable if a sheet of material shows
a nice surface, then the surface which does not touch the mold will be the front of the
piece, besides, a dimensional control closer to the surface of the mold can be
obtained.
Thinning of the material
Under every condition of thermoforming when pieces are formed of a plastic sheet, the
area of the surface will get bigger, there will be some stretching and the material will
get thinner.
One of the decisive factors of this thinning is the ratio, generally defined as maximum
depth or height ratio with a minimum space through the opening. To estimate this thinning, the area of the available sheet to be thermoformed must be determined and divided into the area of the finished piece, including waste. It is always desirable that the
36
Thermoforming
molds and thermoformed pieces have generous curving radiuses. Theoretically, there
is a formula to determine the thinning percentage of the material, considering that the
material is uniformly annealed and stretched.
Thinning % =
AXB
A X B X E (2C + 2D)
A=3
B=4
C=2
D=1
E=1
A=3
B=4
C=2
D=1
E=1
In practice, with a micrometer or calibrator you can determine thickness directly on the
thermoformed piece, cutting small pieces on different sections. Other methods use
translucent sheets and correlate color intensity vs. thinning of the sheet. Thickness can
also be determined making squares with an oil marker on the sheet before thermoforming it and observing stretching of the material.
One should consider the possibility of
wrinkling on some critical areas or on the
bottom of a male mold or matrix. If an
annealed sheet cannot contract from the
dimension A to E, excess material will create wrinkles.
37
Thermoforming
When low molding temperature is used, a sheet will keep a greater tenacity and elasticity. For big pieces, molding time and temperature should be increased on difficult
zones to be thermoformed, minimizing this kind of defect. For deep molding sheets,
because of their partially cross-linked structure, they tend to minimize wrinkling. When
there are many molds, there should be enough room to prevent wrinkling, a distance
1.75 times the height of a piece, is suitable.
Dimensional shrinking and tolerance.
Dimensional shrinkage and tolerance in thermoforming vary for pieces formed on
matrix or male mold. On a male mold, shrinkage can be reduced if the piece cools most
of the time on the mold. If cooling reaches environmental temperature on the mold,
shrinkage will be minimum. Thus, the internal dimension of the piece will be very close
to the one of the mold, but then a production cycle will not be productive.
However, the fact is that a piece must be removed from the male mold when it is still
hot, otherwise removal will be difficult. This is exactly thermal shrinkage, which is the
proportional difference between the environmental temperature and the one at the time
of removal. Thus, to keep the specified dimension of a piece, the model must be slightly bigger.
On the other hand, a piece formed in a matrix will begin shrinking as soon as the temperature of the material is below the one of forming. To keep a close continuous tolerance, the mold dimension must be considerably increased and vacuum pressure kept
during the whole operation.
38
Thermoforming
NO
39
Thermoforming
YES
If you want a sheet to copy details of a mold, like non-skid textures or similar ones,
those detail should be at least three times bigger than the thickness of the material.
Actually, it is better to have a not so smooth molding surface, this way, the piece will
not copy the mistakes of the mold. It may even be sand-blasted with glass fiber micro
spheres or an abrasive material. This way you can eliminate the air caught between the
mold and the piece. Some times it is a good idea to sand the surface using rough
sandpaper, this helps at the time of removal, to break the vacuum between the mold
and the piece.
Superficie spera
Vacuum bores
When using thermoforming techniques with vacuum or pressured air, it is very important to eliminate most of the air between a mold and a sheet in a minimum of time.
Depending on the kind of mold, 1/2" or 1" orifices can be used, as in the case of thermoformed skylights, up to homogenous distribution in all the vertexes of the mold.
Metallic frame
Acrylic
Base
1/2 or 1 piping
Thermoforming
great volume of air, 1/8" or _" diameter holes can be drilled. Depending on the manufacture of the mold, the bores can be widened on the inside of the mold, as shown in
the picture. To reduce the time to eliminate the volume of air round a softened sheet
and a vacuum box, the space can be refilled with polystyrene foam balls or
polyurethane pieces.
Widened bores on
the inside
Increased diameter
bore
Another function of a mold is to contribute along with a frame to stabilize the position
of a sheet and provide good sealing all around the mold. In some cases, a canal
around the piece is helpful, exactly on the external zone of the cutting line.
Mold cooling
Some times when production runs are very long, the mold should have a cooling system, generally copper piping is used. It should be placed adequately and have enough
capacity to carry a considerable volume of water or refrigerant. A relationship between
the temperature of the sheet and the mold should be established so that the material
does not get too cold and it does not thermoform below the bottom limit of the molding temperature.
There are different methods to cool a mold, for example, when there are critical molding zones, plastic or poly-tetra-fluorine-ethylene inserts can be incorporated. In some
cases, a plastic covering can be applied to reduce thermal conductivity, or even after
thermoforming, pressured air can be injected through the bores or holes. Three cooling systems are shown in the next picture: First an undulated cooling system, the second is a branch system and the third is an external multiple alternative flow branch
system with 2 inputs and 2 outputs.
Branch system
Undulated
system
41
Thermoforming
External multiple
alternative flow
branch
Mold supports
As it has been mentioned before, when thermoforming a piece the material always gets
thinner. Molding supports are used to get a better distribution of material in a thermoformed piece. Their purpose is to stretch a softened sheet, as a pre-forming. This technique is very important, specially with very deep pieces. In general terms, the molding
supports can be made of the same material as molds. There are three categories of
mold supports:
Metallic supports
Usually they are made of iron or aluminum, must be very smooth, with radius on the
edges. The range of temperature is 10 to 15C (10F) below the temperature of the
material, if their temperature is too high the sheet will stick to them.
Thermal material supports
These are made of wood, plastic or metal and they are built under the principle of a
good thermal insulator. The surface may be of soft wood, plastics like nylon, or another thermofixed, synthetic foam or any other material including soft flannel.
Skeleton type support
Skeleton or frame type supports are only rounded bars welded forming intersections,
which should be totally rounded to avoid tearing the material.
Support dimensions are related to the size of a piece, since they have a great influence on the thickness distribution of the material. It must be noted that in some
cases, by only changing the depth penetration of a support (75% depth of the piece),
the thickness of the material between the faces and the surface can be controlled.
Therefore, the equipment must have the required depth adjustment capacity, penetration power and speed.
Materials used
to manufacture
thermoforming
molds
Materials used.
Unlike other plastic molding processes, such as injection or compression, thermoforming has the advantage of using relatively low pressure and temperature. That is
why a great variety of materials can be used. Usually, wooden molds can be used, they
are ideal for low production and as wood has a low thermal conductivity, it helps the
annealed sheet not to cool quickly at first contact, but these molds are not good for
medium or high production. Manufacturing molds with phenol laminates are better
because they are not seriously affected by heat or humidity.
There are also molds made of mineral or metallic charges and polyester or epoxy or
rigid polyurethane resins. These are easy to remove off a mold and may even have a
mold with multiple cavities. The thermal properties of epoxy and polyester resins make
them suitable for medium production. Copper piping can be used as cooling system to
better control the mold temperature, but even then, it is not enough for high production.
42
Thermoforming
Aluminum molds are the best for high production, but because of the thermal conductivity of aluminum, the mold has to be pre-heated by means of circulating hot water
through the cooling/heating system or radiating heat with electric resistors, or even
heating the mold with the same material to be thermoformed. For long runs, a thermostat has to be incorporated, to ensure there is the least temperature fluctuation on the
surface of the mold, thus, preventing over cooling. Applying poly-tetra-fluorine-ethylene to aluminum can improve its properties.
Summarizing, there are 4 groups to manufacture thermoforming molds:
1)
2)
3)
4)
Wood.
Minerals.
Plastic resins.
Metals.
GROUP
Woods
43
Thermoforming
MATERIALS
USED
PRODUCTION
VOLUME
Pine
Mahogany
Cedar
Maple
Triply
Agglomerated
Low
MATERIALS
USED
PRODUCTION
VOLUME
Cast
(Calcium
Carbonate)
Sodium
Fluoric-silicate
Low
Medium
Plastic resins
Polyester
Epoxy
Phenol
Plastic
laminated
Nylon
Medium
Metallic
Aluminum
Berylliumcopper
Iron
High
GROUP
Minerals
44
Thermoforming
45
Thermoforming
Thermoforming techniques
Thermoforming is the simplest and most used process to form an acrylic sheet. Being
a thermoplastic material it softens and it is easy to handle and can take any form when
heated at suitable temperature and time.
As it cools it recovers its rigidity and keeps the form it was exposed to. The cost of
equipment and molds is relatively low and bi or tri-dimensional forms can be obtained
by means of a great variety of processes.
Bi-dimensional
thermoforming
Acrylic
YES
No
46
Thermoforming
Top
Support with
adjustable hinge
at any angle
Butts
Electric resistor
Acrylic
Use fixed or
adjustable templates
to keep the piece at
the desired angle
Cold forming
Chemcast acrylics sheet can be cold formed on curved frames, as long as the radius
of the curve is 180 times bigger than the thickness of the material used.
Formula: R (radius) = 180 X T (Thickness of material in inches.)
R=180 X E
Threedimensional
thermoforming
(with molds).
The procedures for tri-dimensional forming in general, require using vacuum, pressured
air, mechanical equipment, or a combination of these to mold Chemcast acrylic sheets
to a desired form. These techniques are described next:
Acrylic
Mold
Male mold
Frame
Matrix
47
Thermoforming
48
Thermoforming
Presin de aire
Vaco
Vaco
Vaco
49
Thermoforming
Infrared
heating furnace
molding
techniques
50
In this section we will try to expand the techniques mentioned before. Although these
examples are designed for infrared heating equipments, it is possible to apply them to
the conventional molding systems.
Thermoforming
51
Thermoforming
Conduction and convection are practically the only methods to dissipate heat, since
thermal conductivity is low, pieces over 0.08 thick require long cooling. The most
common is using electric ventilators to cool the piece; this method has the advantage
of allowing cooling the piece on the mold. The disadvantage is that the air draft is not
enough to cool the mold in each cycle, and the mold will be too hot, interfering with
the normal heating cycle.
Cooling a piece in contact with a mold is very efficient if it is a metallic mold and has
cooling ducts with water re-circulation. In these cases, enough volume of refrigerant
liquid should be used to keep a constant temperature on the mold. If the cooling water
is kept at a certain temperature, marks on the piece (usually known as undulations on
its surface) due to a cold mold, can be minimized. Aluminum or epoxy resin and/or
polyester molds are very suitable if you want to include a refrigeration system. Wooden
molds are not convenient for long runs because they do not dissipate heat quickly.
Non
conventional
cooling
methods
52
There are faster cooling methods that use a spray or a very thin de-ionized water curtain or liquid carbon dioxide, which rapidly cools a thermoformed piece. This method
is not common because of its cost, but both methods can be justified, specially if they
are applied locally to prevent thermal tearing of very deep pieces. Irregular fast cooling
of a formed piece causes great efforts that affect durability.
Thermoforming
SHEET
Thickness inches
DIAMETERS (inches)
Thickness (inches)
0.06-0.12
0.12-0.16
0.2-0.4
0.48-0.6
0.72-0.84
1-2.08
8
10
10
12
12
12-14
1/16-1/32
3/32-1/8
1/8
1/8
1/8
1/8-5/32
96
82-96
82-96
82-96
48-52
48-52
*Teeth with tungsten carbide bit, teeth with straight surface at the center, combined or alternated
53
Thermoforming
Band saw
A band saw is the right one to make curves in flat sheets and rethread formed pieces.
A band saw with variable speed up to 5000 feet/min. and minimum 10" deep groove is
recommended . It is convenient to use the special bands to cut metal or plastic; the
guide must be adjusted as close as possible to the material to avoid chipping on the
cutting line and to reduce the vibration of the saw to a minimum. Next, cutting specifications with a band saw are listed:
Table 15, cutting specifications with a band saw.
SHEET
Thickness (inches)
0.06-0.12
0.16-0.24
0.32-0.48
0.6-1
1-2.08
ENGINE
BAND
WIDTH MIN
(inches)
TEETH X
(inch)
HP
RPM
3/16
3/16
1/4
3/8
3/8
18
14
10
8
8
1
1.5
1.5
1 .5-2
2
DE
2500
A
3500
WIDTH OF
BAND (inches)
TICKNESS OF
BAND (inches)
TEETH X
INCHES
0.48
0.52-0.76
0.8-1.52
1.56-2.28
2.32-3.04
3.08-4.56
4.6-8.12
8.16-12.2
12.24-20
3/16
1/4
3/8
1/2
5/8
3/4
1
1 1/4
1 1/2
.028
.028
.028
.032
.032
.032
.035
.035
.035
7
7
6
5
5
4
4
3
3
BAND
Router
Chemcasts acrylic sheets can be cut with a portable or fixed router (electric or pneumatic). A 1.5 HP and 20,000 to 30,000 RPM electric router is recommended, and bits
or cutters with tungsten carbide bits with 1/4 or 3/8" diameter and ideally 1/2" to avoid
that vibrations break the bit.
54
Thermoforming
This method provides very uniform cut and is good to form as well as to make big
diameter holes. The router can be fixed to a table and a copying guide can be used for
intricate designs.
The cutting tool of a circular saw or router can be changed for an abrasive normal disk
or even a diamond one; this kind of disk should not be used when an acrylic formed
piece is reinforced with glass fiber, as in the case of tubs, wash basins, phone booths,
etc.
Automatic equipment.
This kind of cutting equipment is used when a high automatic level is required; generally, this equipment has a computing system and specialized software, like CAD-CAMCAE, which is used to design the cutting pattern, and later send the information to a
peripheral one, that in this case may be 1 or 5 head routers, pressured water system
or laser. Cutting capacity is not limited to a direction or plane, it can perform any kind
of cut or perforation.
Pressured water cutting
The abrasive system with pressured water eliminates many of the problems related to
the machinery and cutting operations of conventional cutting. A very fine jet of pressured water 50.000 Psi, is concentrated, at a speed of about 3.3 yd./min and a pressure of +/- 0.04.
Using a combination of highly pressured water and abrasive materials, such as silica
powder, the water jet can cut every material without heating and provide an exceptional
finishing on the cutting surface.
The advantages of this cutting system on acrylic are: eliminating heating distortions,
any cutting angle can be performed because of its multi-directional type integrated to
computing systems, it eliminates secondary operations like sanding, and reduces
material waste since the cutting area is very reduced.
Cutting with laser
Cutting with laser is a technique that has already been used in other industrial sectors
for several years and its main characteristics are:
High pressure cutting
Manufacturing flexibility
Reduced cost
An advantage of the laser cutting is its application versatility, since apart from its direct
use to cut acrylic sheets, it offers the possibility of processing many other materials.
55
Thermoforming
With a laser device you can cut, weld and hew surfaces up to 1.2 thick, because laser
energy is concentrated on one spot and heat generation can be limited to a minimum
zone, which avoids any heat deformation or structural changes in the material. Very fine
cuts with accurate edges can be obtained which is good for acrylic pieces with intricate forms. You can make 0.004 diameter bores at a speed up to 150,000 holes per
hour. A laser equipment can cut 1/2" of acrylic at a speed of 12./min.
Swaging
This technique is not much used because of its limitations; it may be used on thermoformed pieces when they are still hot and are not over 0.08 thick, the blades should
be at a temperature between 104F and 140F (40C and 60 C). Even then cutting
quality is not very good. This kind of cutting is better for plastics-like acetate polystyrene and foamed P.V.C.
Cutting
techniques
Although there are non conventional cutting techniques and highly automatic ones,
their practical application is far from popular, because of their high investment and
maintenance cost compared with traditional techniques like router or circular saw cutting.
Some cutting alternatives of thermoformed pieces are shown next. As long as it is possible, you should build a cutting template as support for the thermoformed piece, this
way you will avoid variations on a piece and production will be standardized.
56
Thermoforming
57
Thermoforming
Thermoforming variables
In the thermoforming process there are variables that can affect aspect, quality, dimensions and distribution of the material of a formed piece. Knowing these variables can
help to solve difficult production problems in the thermoforming process. Following, the
most frequent variables as deviations in the thermoforming process are shown.
Material
variables
Thickness of a sheet
When electric resistors or infrared radiation is used to heat, changes on caliber of the
thickness of the material can cause an uneven heating, creating variations in the
formed part. In pre-stretching or deep forming, close dimensional tolerance is needed
to avoid breaking the material in very thin areas, because of the force exerted by vacuum or pressured air. In very deep pieces there is a variation in the thickness of the
material which depends on the thickness used, the area and maximum depth of a
piece. When there is a thickness variation between each sheet, the heating temperature must be reduced to prevent material from over softening. If the temperature of a
sheet is homogeneous, even a piece with thin areas can be well made.
Sheet pigmentation
In the case of radiation heating (electric resistors) the different colors of the same material can cause temperature changes and heating cycle changes. In a convection furnace (hot air re-circulation) this variable does not apply.
.
Size of a sheet.
To get a better distribution of the material of a very deep piece, it is more economic to
increase the size of a sheet instead of its thickness.
Temperature uniformity of a sheet
When the temperature of any material is increased, tension force is reduced and therefore the sheet becomes malleable. Simple or deep forming made at a lower range than
annealing temperature provides the best results.
For high quality pieces, it is important that a sheet heats evenly at annealing point
length-wise and width-wise. The sheets that are not evenly heated will be deficiently
formed: there will be more stretching in the normal temperature zones than in the ones
that were not softened.
58
Thermoforming
Mold variables
Pre-stretching
variables
Vacuum box
In vacuum with return and free forming it is very effective to use a vacuum box of 3.2
to 4.8 longer than the total depth of the formed bubble to prevent cooling on the
perimeter of the sheet in contact with the mold. Before forming the bubble, the sheet
must be strongly sealed on the mold. In a vacuum with return operation, maximum
thinning will occur at the bottom of the formed bubble. To get thicker walls, there must
be a two step edge in the vacuum box which will cool the top area making it thicker.
Air temperature
Sometimes the air of the system should be pre-heated. When air at room temperature
gets into the system, it may cool the sheet, affecting its size and form. With thin materials, the cooling problem is more serious. With pre-heated air, the temperature should
be about 10% below the temperature of the sheet. An air deflector or an air diffuser
should be used at the intake of the mold since they can prevent a sudden cooling in
some areas of the material.
59
Thermoforming
Mechanical
support
variables
60
Thermoforming
61
Thermoforming
POSIBLE CAUSE
Excessive moisture
Irregular heating.
Insufficient vacuum
Excessive heating
Low mold temperature.
62
Thermoforming
SUGGESTED SOLUTION
Pre-dry sheet.
Dry both sides of sheet at
140F (60C)
Reduce furnace temperature.
Increase distance between
sheet and heater.
Check and fix the furnace.
Check heating elements.
Eliminate obstructions in vacuum system
Increase number of holes
Increase their diameter
More tank and vacuum pump
capacity.
Leakage.
Check vacuum system for
possible leaks.
Use vacuum canals in possible areas.
Increase temperature or heating time.
Reduce heating time.
Reduce furnace temperature.
Heat mold.
DEFECT
Color change of a sheet.
POSIBLE CAUSE
Low temperature of mechanical
support
Too much thinning of a sheet.
Sheet cooling before its formiing is completed.
Inadequate material
Excessive warping or bending of a sheet
Thermoforming
Insufficient temperature of
support.
63
SUGGESTED SOLUTION
DEFECT
Small wrinkles or circular
marks..
POSIBLE CAUSE
Sheet too hot
64
SUGGESTED SOLUTION
Thermoforming
DEFECT
Piece surface bad aspect
POSIBLE CAUSE
SUGGESTED SOLUTION
Excessive distortion or
shrinking after removing a
piece off a mold.
Use different forming technique: vacuum with return, pressured air and mechanical support, pressured air and return
with vacuum.
Check material meets quality
norms and /or complain.
Check furnace operation.
Reduce furnace temperature.
65
Thermoforming
DEFECT
Pieces twist
POSIBLE CAUSE
SUGGESTED SOLUTION
Thin sheet
Sheet unevenly heated
66
Thermoforming
DEFECT
Piece sticks to mechanical
support.
POSIBLE CAUSE
Mechanical support (wood).
Mechanical support (metal).
67
Thermoforming
SUGGESTED SOLUTION
Redesign piece.
Increase mold curve radius.
Increase thermoforming temperature.
Make sure piece is wholly
formed before it cools below
forming temperature.
APPENDIX
Glossary
ABSORBENCY
Fraction of radiant energy taken by a sheet.
CAVITY
Depression of a vacuum made mold, machine finished or a combination of both,.
depending on the number of depressions, it may have one or several cavities.
CONDUCTION
Energy transferred by directly touching a solid.
CONVECTION
Energy transferred by the movement of a fluid current.
COOLING MARKS
Marks caused by using wrong temperature on a plastic sheet, derived from inadequate
heating.
CO-POLYMER
Polymer composed of tow different kinds of monomers.
CYCLE
Complete repetitive sequence in the thermoforming process, which consist in: heating,
forming, cooling and removal.
DIMENSIONAL STABILITY
Capacity of a piece to keep the accurate shape and dimension of the mold used.
ENTHALPY
Inner energy of a system.
HEAT TRANSFER COEFFICIENT
Effectiveness measure of energy transported between a fluid current and a solid surface.
HOMO-POLYMER
Polymer made of only one monomer
INFRARED
Part of electro-magnetic spectrum, between the range of visible light and the range of
radio waves. Radiant heating is the range at which infrared heaters are used to heat a
sheet. Wave length is 0.08 to 0.4
68
Thermoforming
MELTING TEMPERATURE
Range of temperature at which a crystalline polymer turns from a solid rubber-like state
into a viscous-elastic liquid.
MOLDING TEMPERATURE
A piece temperature at which it can be removed without deforming.
PRESSURED AIR SHAPING
Difference of pressure exceeding two atmospheres (30 Psi.).
RADIATION
It is the transfer or exchange of electromagnetic energy.
REFLECTIVITY
Fraction of radiant energy reflected on a sheet surface.
RESIN
Another name to call a polymer or plastic material.
SCRAP
Material waste that is not part of the final piece.
TENSION
External charge exerted on a defined area.
THERMAL DIFFUSIVENESS
Transmission index of calorific energy in a material.
TRANSMITTANCE
Fraction of energy that is transmitted through a sheet.
TRI-POLYMER
Polymer composed of three different kinds of monomers.
VACUUM TANK
Tank between the vacuum pump and the mold, that allows you to apply pressure evenly during forming.
69
Thermoforming
70
Thermoforming
tive covering, decorative objects, buttons, etc. Reinforced plastic industry is the one
that has the most polyester consumption.
Increasing demand and application of plastic reinforced items are basically due to their
properties and features, among which, the following can be mentioned:
1) Composites are easy to handle (polyester resin is applied in liquid form).
2) Easy curing and using.
3) Excellent dimensional stability in the final product.
4) Good dielectric properties.
5) Excellent physical and mechanical properties. A reinforced plastic sheet, equivalent
to three times steel thickness, has mechanical resistance to tension, weighs about half
and is more resilient.
6) Rust resistant and also to a great amount of chemical agents.
7) Easy finishing (coloring, painting, machine finishing, etc.).
To obtain optimal reinforced plastic features, the reinforcing material must have the
best mechanical and chemical properties. Next, reinforcements most used are mentioned.
Reinforcing materials
The most important reinforcing material are:
1.- Cellulose fibers.
Cellulose alpha.
Cotton.
Jute.
Salwort.
Rayon.
2.- Synthetic fibers.
Polyamides (nylon).
Polyester (Dacron).
Polyacrylonitrile.
Polyvinyl alcohol fibers.
3.- Asbestos fibers.
4.- Special fibers.
Carbonate and graphite fibers.
Boron and tungsten fibers.
Ceramic fibers.
71
Thermoforming
72
Thermoforming
Glass fiber
In reinforced plastic industry, the material most used is glass fiber because of its features:
1.- Tension high resistant.
2.- Incombustible.
3.- Biologically inactive.
4.- Excellent weather resistant as well as to a great deal of chemical agents.
5.- Excellent dimensional stability.
6.- Low thermal conductivity.
The main uses of glass fiber reinforcements are:
Roving.
Mat.
Woven roving.
Surfacing mat.
Chopped strand.
Following, processes to obtain these and their features are mentioned.
Roving
Roving is one of the most used glass fiber products, and it is indispensable when reinforced plastic items are made by sprinkling, directed filament and hot forming (preform manufacturing). Roving comes wound on bobbins, and it usually has 60 threads.
73
Thermoforming
Mat
This is the most popular and known glass fiber product in reinforced plastic industry
and it is made of fiber mono-filaments about 2, long.
Woven roving
This is roving strings woven at 90 angles as to their longitudinal axes. Combined with
mat, it is used as secondary reinforcement, to manufacture boats and big structures.
Surfacing mat
This material is made of glass fiber sections like the mat, though with less weight/unit
area. It is mainly used to improve the finishing of reinforced plastic products and to
increase their weather resistance features; since when it is put on the reinforcement
material, usually a mat, it does not allow the fiber to crop up and as it absorbs resin,
finishing gets smoother.
Chopped strand
This glass fiber presentation is not much used, it is made by the machine that makes
mat. Its size varies from 2/2" to 2" long (1.25 to 5.0 cm). It is mainly used to make items
by methods of pre-mixing.
According to reinforcing materials classification, there is another type of products used
in the manufacture of reinforced plastics, the most important are:
Asbestos.
Salwort, henequen, jute.
Synthetic fibers.
Ceramic fibers.
Polyvinyl alcohol fibers.
Special reinforcements.
To improve reinforced plastic efficiency and application, several reinforcing elements
have been developed. Their main characteristic is a high elasticity module, which considerably increases mechanical resistance of laminated products. This is specially
important in specialized fields like aero-spatial vehicles, submarines, etc. Among these
reinforcements are:
Boron tungsten filaments.
Carbonate and graphite fibers.
Metallic filaments.
Whiskers
Adhesion promoting agents.
Hybrid reinforcements.
Metalized reinforcements.
74
Thermoforming
Mechanical resistance of a plastic/reinforcing composite derives from joining, generally mechanically a system composites. This joint, satisfactory in most cases, may
reduce composite or product aging as well as moisture, when glass fiber systems are
used to reinforce, since the fiber is hydrophilic and tends to absorb water which weakens or destroys plastic joints.
To prevent this, chemical composites hydrogen siliceous type are added to the inorganic charge, resin or reinforcing material. They provide a chemical consolidation in the
interface of the joint, improving and keeping the mechanical properties of composites,
apart from improving dielectric characteristics of the system.
Manufacturing reinforced plastic molds.
To make a mold, a model or original of the piece to be made is required. When there
are only specifications and blue prints, the model can be made of cast, wood, or epoxy
paste, depending on how difficult the piece is and how skilled the operators are. Some
times, the model can be made by combining polyurethane foam or polystyrene plates
covered with a thin coat of cast or epoxy.
When the model is finished, roughness can be smoothed with emery cloth and then
applying a sealer to eliminate porosity. In most of the cases it can be a nitro-cellulose
lacquer, which is spayed, or shellac dissolved in alcohol. To polish the model, a removing agent is applied, its specific function is avoiding adherence of the resin to the mold.
Removing agents can be classified in three groups:
Solutions.
Generally aqueous polyvinyl-alcohol, methyl-cellulose, etc. This kind of removers must
be applied in each molding operation.
Waxes and wax emulsions
This agent is applied with a flannel or felt, and polished manually.
Internal removers
These agents are mixed with gel-coat. When they mix with the tooling gel-coat, removing characteristics improve, making molding easy.
Once the removing agent has been chosen, the mold is coated with a resin preparation known as gel-coat or finishing coat.
Gel-coat
It is made of a resin that provides a film whose characteristics are:
1.-Uniform surface.
2.-Avoiding that reinforcing material crops up.
3.-Improving weather resistant properties.
75
Thermoforming
Some times, a glass fiber mat should be put to reinforce gel-coat, getting a resin rich
coat and avoiding that the reinforcing material crops up. Gel-coat is usually sprayed,
but it can also be applied with hair brushes. In that case, accelerator/catalyst quantities should be less than for immersion. Finishing film thickness depends on the use and
characteristics of the piece to be made and it can be measured with a calibrator of
humid film.
Manual finishing process
It is often used since it does not require any special equipment. Its process is:
A mold prepared with removing agents (wax, removing film or both) is coated with a
finishing product using a soft brush or spraying equipment, thickness varies depending on the use of the piece and the suppliers specifications. Once the gel-coat thickness is determined and it has been cured, the glass fiber mat is placed. Next, using a
brush and with vertical movements, a resin of styrene monomers or methyl methacrylate, or both, is applied to the mold, as well as the accelerator, whiskers and/or toxitropic agents, heat concentrator, catalyst, etc.
Later, and before the resin jells rolling is done, with a plastic or metal 0.36 to 1 (9.0
to 25mm.) diameter and 2 to 8 (5 to 20 cm.) long roller generally grooved, depending
on the case.
Rolling the roller in several directions pressing evenly helps to eliminate air caught in
the resin and reinforcing material, as well as to obtain good adhesion with the gel-coat.
Finishing and rolling should be done by sections no bigger than 1m2 when a piece is big.
76
Thermoforming
Often, commercial measurements of mat and woven roving (which are always applied
with this procedure) are not enough to cover the whole mold; therefore, they have to
be joined by sections. Overlapping them 5cm is suggested. The resin to join them
should have the least accelerator and catalyst to avoid problems created by material
contractions which derived from a bigger amount of resin, that reduces curing time and
increases exo-thermal temperature.
Some times, one or more woven roving layers have to be used as reinforcement. They
must be put between the 2 mat sections, or even better, as a final layer and never
directly with the gel-coat, because if the finishing coat is not properly applied, the
woven roving will be visible, which will give the product a bad aspect.
The brushes and rollers have to be washed intermittently with a solvent like acetone,
ethyl acetone, methyl ethyl acetone, etc., since as the resin cures it hardens and they
may get damaged. Most of the time it is enough to put them in a container with a solvent or a monomer mixture.
Reinforced plastic machine finishing.
Reinforced plastic product manufacturing, often includes machine finishing or adjusting, operations that are not highly specialized, but must be done carefully to get good
results. Among machine finishing operations are: cutting, perforating, joining, etc. The
most important are detailed next
Cutting on the mold.
It is also known as trimming and it is cutting the material (glass fiber and resin) that surpasses the mold or piece made. This is done with steel blades along the edge of the mold
when the resin is jelled and has not been totally cured. In the case of products manufactured with pressure or temperature, cutting must be done immediately after removing the
piece; otherwise, it becomes harder to do so.
Cutting with equipment.
It is performed on totally finished products. Abrasive products are recommended, since
metallic disks are not as fast, accurate, and ergonomic as the ones suggested. Water
should be used as cutting takes place; since water acts as refrigerant and lubricant
helping to eliminate reinforced plastic dust and the cut is cleaner.
Reinforced plastic joints
Often, 2 or more sections have to be joined to get a final piece; The systems commonly
used are
77
Thermoforming
78
Thermoforming
Specific gravit: 1
g
lb
= 62.4
cm3
cu ft
Heat fusion: 1
Btu in
Btu ft
cal cm
=12
= 0.00413
= 0.0173
sq ft hr F
sq hr F
cm2 sec C
Thermal conductivity: 1
79
Thermoforming
in = 1.80 cm
ln F
cm C
W cm
cm2 C
C
10
12.8
15.6
18.3
21.1
23.9
26.7
29.4
32.2
35.0
37.8
40.6
43.3
46.1
48.9
51.7
54.4
57.2
60.0
62.8
65.6
68.3
71.1
73.9
76.7
79.4
82.2
85.0
87.8
90.6
93.3
96.1
98.9
101.7
104.4
107.2
110.0
112.8
115.6
118.3
121.1
123.9
126.7
129.4
132.2
Thermoforming
F
275
280
285
290
295
300
305
310
315
320
325
330
335
340
345
350
355
360
365
370
375
380
385
390
395
400
405
410
415
420
425
430
435
440
445
450
455
460
465
470
475
480
485
490
495
500
C
135
137.8
140.6
143.3
146.1
148.9
151.7
154.4
157.2
160.0
162.8
165.6
168.3
171.1
173.9
176.7
179.4
182.2
185.0
187.8
190.6
193.3
196.1
198.9
201.7
204.4
207.2
210.0
212.8
215.6
218.3
221.1
223.9
226.7
229.4
232.2
235.0
237.8
240.6
243.3
246.1
248.9
251.7
254.4
257.2
260.0
IMPORTANT: CHEMCAST is not legally liable for the recommendations or information given in this manual,
which are based on information we consider to be true, we offer it bona fide, but we do not guarantee it, since
transformation conditions and use of products are beyond our control.
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Thermoforming