RATE OF REACTION 1 HOUR

SMK TUNKU AMPUAN NAJIHAH TEST

FORM 5 CHEMISTRY FORM 5 FORM 5
MONTHLY TEST 1-2010

Name :........................................................................................... Form : 5

Answer sheet Section A

1 A B C D 6 A B C D 11 A B C D 16 A B C D

2 A B C D 7 A B C D 12 A B C D 17 A B C D

3 A B C D 8 A B C D 13 A B C D 18 A B C D

4 A B C D 9 A B C D 14 A B C D 19 A B C D

5 A B C D 10 A B C D 15 A B C D 20 A B C D

Section A
Answer all question in space provided above.

1. Which of the following is clasified as slow 3. 6 g of calcium carbonate dissolves completely in

reaction? excess hydrochloric acid in 2 minutes. What is the
average rate of the reaction?
A. Fermentation process
B. Burning Magnesium in access oxygen A. 20.0 g s-1
C. Reaction between dilute hydrochloric acid B. 3.0 g s-1
and zinc granules C. 0.05 g s-1
D. Reaction between sodium thiosulphate and D. 0.33 g s-1
sulphuric acid.

2. Table below shows the total volume of carbon 4. The change of gas volume can be used to
dioxide liberated at regular time intervals for the measure the rate of reaction. Which of the
reaction between marble and acid at room following reactions involve the change of gas
temperature. volume?

Time 0 60 120 180 240 300 A. Reaction between sodium hydroxide and
Volume of hydrochloric acid
0 10.6 18.9 25.7 28.2 29.1
CO2 gas (cm3) B. Reaction between lead (II) nitrate with
sodium sulphate
What is the average rate of reaction in the third C. Reaction between silver (II) nitrate with
minute? pottasium chloride
D. Reaction between copper (II) oxide and
3 -1
A. 0.04 cm s sulphuric acid.
B. 0.11 cm3s-1
C. 0.14 cm3s-1
D. 0.43 cm3s-1

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5. The following chemical equation shows the 7. Which of the following factors does not affect the
reaction between two substances rate of reaction?

Na2S2O3 + 2HCl  2NaCl + H2O + SO2 + S A. The presence of catalyst

B. The mass of the reactant
Which of the following is suitable to determine C. The temperature of the reactant
the rate of the reaction above? D. The total surface area of the reactant

A. The concentration of the mixture

B. The decrease in mass of both substance 8. Diagram below shows a graph of volume of
C. The increase in volume of SO2 gas carbon dioxide gas collected against time when
D. The change of colour of mixture calcium carbonate react with hydrochloric acid.

3
Volume of CO2 / cm
6. Which of the following graphs shows the change
of the quantity of the reactant with time in a C D
* *
reaction? B
*
A
*
A.
Quantity of reactant

Time
Which of the points, A, B, C or D shows the
reaction occuring at the highest rate?

Time 9. Table below shows three experiments conducted

to investigate the initial rate of reaction between
B.
Quantity of reactant

zinc carbonate and nitric acid.

Initial rate
Exp. Substance
of reaction
2.0 g of zinc carbonate powder
1 and 25 cm3 1.0 mol dm-3 of X
Time nitric acid
2.0 g of zinc carbonate powder
C.
Quantity of reactant

2 and 25 cm3 2.0 mol dm-3 of Y

nitric acid
2.0 g of zinc carbonate chips
3 and 25 cm3 1.0 mol dm-3 of Z
nitric acid

Time Which of the following shows the ascending rate

D. of reaction for three reaction s above?
Quantity of reactant

A. X, Y, Z
B. Z, Y, X
C. Y, X, Z
D. Z, X, Y

Time

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10. The equation below shows a reaction to produce 14. What is the definition of activation energy
hydrogen gas.
A. The amount of energy possessed by the
2HCl + Zn  ZnCl2 + H2 reactant particles in a reaction.
B. The amount of energy that must be supplied
Which of the following would increase the rate to the reactant particles for a reaction to
of production of hydrogen gas? occur
C. The minimum amount energy that must be
A. Increase the time of reaction possessed by the reactant particles fo a
B. Increase the volume of acid reaction to occur
C. Increase the size of granulated zinc D. The energy change when the reactants react
D. Increase the temperature of the mixture to form the products.

11. The statements below relate to collision theory. 15. Diagram below shows the energy level diagram
for the reaction A + B  C + D

 The kinetic energy of particles increases

 The frequency of the collisions increase

Energy
150 J
Which of the factors below affects the rate of 580 J
reactions as described by the statements above? C+D

A. Size of particle A+B

B. Presence of catalyst
C. Concentration factor
What is the activation energy for this reaction?
D. Temperature factor
A. 150 J
B. 430 J
12. Which of the following solution will dissolve a 5g
C. 580 J
of calcium carbonate in the shortest time?
D. 730 J
A. 25 cm3 0.3 mol dm-3 of nitric acid
B. 25 cm3 0.5 mol dm-3 of sulphuric acid
16. Student carry out an experiment as stated in the
C. 25 cm3 0.5 mol dm-3 of hydrochloric acid
table below
D. 25 cm3 0.3 mol dm-3 of ethanoic acid acid
Exp 5 g of zinc powder is added to 100 cm3 of 1 mol
1 dm-3 sulphuric acid.
13. The following statements are related to the
collision theory of a chemical reaction.
What is the effect on the initial rate of reaction
and the total volume of hydrogen collected if the
I The kinetic energy of the reactant particles
experiment is repeated by adding a few drops of
increases.
copper (II) sulphate solution to the reacting
II The frequency of effective collisions between
mixture?
the reactant increases.
III The sizeof the reactant of particles increases
Initial Rate Total Volume of Hydrogen
IV The activation energy of the reaction is
A. Increase Increase
lowered
B. Increase No change
A. I and II only C. No change Increase
B. I and III only D. No change No change
C. II and IV only
D. I, II and IV only
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17. Which of the following are characteristics of a 20. Table below shows the decomposition process
catalyst? of hydrogen peroxide with presence of catalyst.

I A catalyst increases the yield of a reaction Set Reacting conditions

II A catalyst is spesific in its reaction I 0.1 g of manganese (IV) oxide powder +
III A small quantity of catalyst can influence the 50 cm3 0.1 mol dm-3 of hydrogen peroxide
rate of a reaction solution at room temperature and
IV The chemical property of a catalyst remains pressure
unchanged after the reaction. II 0.1 g of manganese (IV) oxide powder +
25 cm3 0.1 mol dm-3 of hydrogen peroxide
A. I, II and III solution at a temperature of 65 oC.
B. I, II and IV
C. II, III and IV Which of the following shows the volume of
D. I, II, III and IV oxygen gas liberated against time for the both
sets of the experiments?

18. The table below shows the mass of ammonia

A.

3
formed at different temperature during Haber

Volume of O2 / cm
II
Process.
I
Mass of ammonia
Temp. oC Time taken
produced / kg
300 360 3 hours
400 210 2 hours Time
500 70 10 minutes
B.
3

600 105 25 minutes

Volume of O2 / cm

II
At what temperature is the rate of production of
ammonia the highest? I

A. 300 oC
B. 400 oC Time
C. 500 oC
D. 600 oC C.
3
Volume of O2 / cm

I
19. Which of the following methods will cook 2 kg of
potatoes in the shortest time?
II
A. Fry the potatoes in a wok Time
B. Boil the potatoes in boiling water
D.
3

C. Boil the potatoes in pressure cooker

Volume of O2 / cm

D. Steam the potatoes in a steamer. I

II

Time

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Section B
Answer all question

1. Three experiments were conducted to study the rate of reaction between hydrochloric acid and zinc. Table 1.1
shows the mixture of the substances used and time taken to collect 25 cm3 of gas released in each experiment.

Experiments Reaction Mixture Time Taken /s

I 20.0 cm3 1.0 mol dm-3 of hydrochloric acid + excess of zinc powder 50.0

20.0 cm3 1.0 mol dm-3 of hydrochloric acid + excess of zinc powder
II 35.0
+ 5 drops of copper sulphate solution

III 20.0 cm3 1.0 mol dm-3 of sulphuric acid + excess of zinc powder 25.0

a. Draw a labeled set up of apparatus for these experiments.

[2 marks]

b. Write the balanced chemical equation for experiment II

…………………………………………………………………………………………………………………………………………………………………….
[1 mark]

c. Calculate average rate of reaction for

i. Experiment I

ii. Experiment III

[2 marks]

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 d. Base on collision theory, explain the difference in rate of reaction between Experiment I and Experiment
III

…………………………………………………………………………………………………………………………………………………………………….

…………………………………………………………………………………………………………………………………………………………………….

…………………………………………………………………………………………………………………………………………………………………….
[3 marks]

e. What is the function of copper (II) sulphate solution in experiment II?

…………………………………………………………………………………………………………………………………………………………………….
[1 mark]

f. Sketch the graph of volume of gas against time for Experiment I and II

[1 mark]

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2. An experiment was conducted to study the effect of temperature on the rate of reaction between 50 cm3 0.2
mol dm-3 of sodium thiosulphate and 5 cm3 1.0 mol dm-3 of hydrochloric acid. The time taken for the reaction
complete is recorded. The experiment was repeated five times using different temperatures of sodium
thiosulphate.
Table below shows the temperature and time taken for mark X to disappear from view.

Experiment 1 2 3 4 5

Temperature of sodium thiosulphate / oC 30.0 40.0 60.0 80.0 90.0

Time taken 55.0 35.0 20.0 14.0 12.0

(s-1) 0.026 0.035 0.053 0.071 0.080

a. Complete the table above.

[1 mark]
b. i. Plot a graph of temperature against (s-1)
[3 marks]

ii. Referring to the graph in (b) (i), state how the temperature affects the rate of reaction.

………………………………………………………………………………………………………………………………………………………………
[1mark]

c. Write the balanced chemical equation for the reaction above.

…………………………………………………………………………………………………………………………………………………………………….
[1 mark]

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 d. Calculate the maximum mass of sulphur that produced in the experiment.
[Relative atomic mass of S=32]

[3 marks]

e. State one other factor that needs to be constant in the experiments.

…………………………………………………………………………………………………………………………………………………………………….
[1 mark]

END OF QUESTION PAPER

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