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AND LABRADOR
Department of Environment and Conservation
LI = pH pH s
where pH = measured pH of the tap water
pHs= calculated saturation pH of the tap water
b. Determine m , the activity coefficient of monovalent ions (ions that are able to form only one covalent
or ionic bond having only one valence) using the Davies relationship:
If I < 0.5M ,
If
I
0.2 I
log m = AZ 2
1+ I
I
0.5M < I < 1.0 M , log m = AZ 2
1+ I
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A = 1.82 10 6 (DT ) 2
D = 78.3 , the dialectric constant for water and T = temperature in Kelvins (K). To convert
temperature (t) in degrees centigrade (C) to Kelvins (K):
[T = t(C)+273]
and
Z = the oxidation number of the chemical species in question, which for monovalent ions = 1
1
+
I
c. Calculate pK 2 :
pK 2 =
2902.39
+ 0.02379(T ) 6.498
T
K 2 = 10 pK 2
d. Calculate D , the activity coefficient of divalent ions (ions having two valences):
I
log D = AZ 2
1 + I
where as defined earlier;
3
A = 1.82 10 6 (DT ) 2
D = 78.3 , the dialectric constant for water, and T = temperature in Kelvins (K). To convert
temperature (t) in degrees centigrade (C) to Kelvins (K):
[T = t(C)+273]
and
Z = the oxidation number of the chemical species in question, which for divalent ions = 2
Then calculate D :
D = 10 log
e. Calculate K 2 :
K 2 =
K2
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pK 2 = log
1
K 2
a.
First compute pK s :
pK s = 0.01183t + 8.03
where t = temperature in degrees Centigrade (C)
K s = 10 pK s
c. Using the value of D calculated earlier, calculate K s :
K s =
Ks
( D )2
pK s = log
1
K s
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3. To compute pCa 2+ :
a. Convert the concentration of Ca2+ (mg/litre) to moles per liter:
Ca 2+ (moles / litre) =
c. Calculate pCa 2+ :
pCa 2+ = log
4.
1
[Ca (moles / litre)]
2+
Alkalinity (Alk) is reported as mg/litre CaCO3. It is necessary to convert the given alkalinity concentration to
moles/litre:
Reference:
Benefield, L., Judkins, J. & Weand, B. 1982. Process Chemistry for Water and Wastewater Treatment. PrenticeHall, Inc. Englewood Cliffs, New Jersey.
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