COMPLETE PARING 1-7 CHAPTER WITH SHORT AND LONG

Part 1:
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2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.

Why actual yield is usually less than the theoretical yield?

One mole of CO2 and NO2 have same number of molecules. Why?
Define actual yield, write formula for the calculation of percentage yield.
Define limiting reactants. How they can be identified?
No individual neon atom in the sample of the element has a mass of 20.18 a. m. u. Discuss.
Define adsorption and partition chromatography.
Rf Value is always less than I. O. comment on it.
Differentiate between stationary and mobile phase. Also write an example of each phase.
Naphthalene can best be purified by sublimation. Why?
Give the four uses of paper chromatography.
Mention the major steps involved in crystallization.
Explain the process of sublimation.

Part 2:
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13.
Part 3:
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4.
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11.

Why pressure correction is done by van der Waals?

Differentiate between diffusion and effusion of the gases.
What do you mean by Absolute zero?
Give mathematical expression for mean square velocity and root mean square velocity.
Joule Thomson effect is operative in the Lindens Method of liquefaction of air. How?
State what is natural and artificial plasma?
Water freezes from surface to the downward direction in Ponds and Lakes. Explain why?
Why do we feel uncomfortable breathing at higher altitude?
How in very cold winter fish in garden ponds owe their lives to hydrogen bonding?
One feels sense of cooling under the fan after bath. Why?
Justify that HF is a weak acid than HCl.
How liquid crystals are used as a locator of tumors?
How in very cold winter fish in garden ponds owe their lives to hydrogen bonding?
Define Heisenberg uncertainty principle.
Positive rays are also called canal rays. Give reason.
Why e/m value of the cathode rays is just equal to that of electron?
What are defects in Rutherfords atomic model?
What is importance of Moseley law?
How you can compare orbit and orbital?
Differentiate between Stark effect and Zeeman Effect.
State Pauli Exclusion Principle and Hunds rule.
Give two postulates of Plancks Theory.
Make difference between line spectrum and continuous spectrum.
State Auf bau principle and Paulis exclusion principle.
12.
Define dipole moment. Give its various units..
13.

Why Pi ( ) bonds are diffused than sigma ( ) bonds?

14.
No bond in chemistry is 100% ionic. Justify it.
15.
Why the dipole moment of CO2 is zero and that of H2O is 1.85D?
16.
Why nitrogen molecule is diamagnetic?
17.
Write two points of Valence Bond Theory.
18.
The bond angels of H2O and NH3 are not 109.5o like that of CH4, although oxygen and nitrogen atoms are sp3
hybridized. Why?
19.
Write down two postulates of VSEPR theory.
20.

Helium is diamagnetic in nature, Justify.

Part 4:
1. Temperature is a state function but heat is not. Why?
2. Define system and surrounding with one example each.
3. Define enthalpy of formation (

Hof) and enthalpy of atomization (

Hoat)

4. Define first law of thermodynamics. How it is represented?

5. Differentiate between internal energy and enthalpy.
6. Explain that burning of a candle is spontaneous process.
7. What is the physical significance of equation,

H = qp?

8. Draw labeled diagram of bomb calorimeter.

9. Define Hesss law of constant heat summation with one example.
10. Spontaneous reaction always proceeds in the forward direction. Give reason.
Lec.Rana Muhammad Hassan Tariq

COMPLETE PARING 1-7 CHAPTER WITH SHORT AND LONG

Chapter 1:
1.

2.

3.

Glucose C6 H12 O6 is the most important nutrient in the cell for generating chemical
potential energy. Calculate the mass% of each element in glucose and determine the
number of C,H and O atoms in 10.5g go the sample.
A mixture of two liquids, hydrazine N2H4 and N2 O4 are used as a fuel in rockets. They
produce N2 and water vapors. How many grams of N2 gas will be formed by reacting 100g of
N2 O4 and 200g g of N2 O4.
Calculate the number of grams of A1 2 S3 which can be prepared by the reaction of 20 g of
A1 and 30 g of sulphur. How much the non-limiting reaction is in excess?

4. Mg metal react with HC l

solution (27% by weight) required to produce 12. 1g of H2. The density of HC l

solution 1.14g/cm3.

Mg(s) + 2HC l

(aq)

Mg C2 l

(aq)

+H2(g)

Chapter 4:
1.
2.
3.
4.

Define and explain London dispersion forces. What are the factors which affect London forces? Discuss briefly.
What are covalent solids? Discuss the structure of Diamond.
Define Vapour pressure. Describe manometric method for the measurement of vapour pressure.
Define metallic bond. Justify the electrical conductivity, thermal conductivity and shining surfaces of metals.

Chapter 3:
1. State Grahams law. Explain Grahams law of diffusion according to kinetic equation.
2. Describe postulates of kinetic molecular theory of gases.
3. Describe Daltons law of partial pressure. Write its all applications.
4. State and explain Grahams law of diffusion of gases.
Chapter 5:
1. Explain Millikans oil drop experiment to determine charge of the electron.
2. Derive radius of revolving electron in nth orbit of an atom.
3. (i) Write three points of Plancks quantum theory.
(ii)
Define frequency and wavelength.
4. Write down the defects in Bohrs atomic mode.
5. Derive the formula of calculating the energy of an electron in nth orbit of H atom using Bohrs model.
Chapter 6
1. What is dipole moment? Give its units. Explain the structure of CO2 FB3 and H2O on the basis of dipole moment.
2. Define hybridization. Explain the Sp2,Sp3,Sp with their examples
3. How will you describe the paramagnetic character of oxygen on the basis of MOT?
4. Write the postulate of VSEPR theory and discuss the structure of NH3 with reference to this theory.
Chapter 7
1. State first law of thermodynamics. How does it explain that q p =
2. Discuss first law of thermodynamic and prove that

E = qv

3. How does Born Haber cycle help to calculate lattice energy of NaCl?
4. Define the following giving one example in each:
a. (i)
enthalpy of solution
(ii)
Enthalpy of atomization
b. (iii)
System
(iv)
Surroundings
5. Write a note on construction and working of bomb calorimeter.
6. Define the following:
(i)
Standard Enthalpy of neutralization with example.
(ii)
Standard enthalpy of combustion with example.

Lec.Rana Muhammad Hassan Tariq