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Cryogenics
journal homepage: www.elsevier.com/locate/cryogenics
Review
a r t i c l e
i n f o
Article history:
Received 10 November 2010
Received in revised form 3 April 2011
Accepted 12 April 2011
Available online 20 April 2011
Keywords:
Heat exchanger
Thermal hydraulic
Review
a b s t r a c t
Heat exchangers are the main components in cryogenic processes. Thermo-economic considerations set
the need for high-effectiveness equipment and accurate models. This situation is challenging due to the
complex operating conditions and the fact that some physical effects, such as changes in uid properties,
ow maldistribution, axial conduction and heat leakage, cannot be neglected.
In this work a systematic review of the state of art and challenges in modeling cryogenic heat exchangers is presented. They include lumped parameters, distributed parameters and stream-evolution models.
These formulations fail to take all relevant effects into account.
A general discussion on the performance of the reviewed models is presented. In general, more effects
are included in the framework of numerical solution of discretized energy balance equation. Two main
points stand out as not considered by the present models, namely the effects of pressure drop on heat
transfer and the existence of partial ow mixing. These two effects are highly relevant for two-phase ow
and multi-component applications, as in LNG processes.
2011 Elsevier Ltd. All rights reserved.
Contents
1.
2.
3.
4.
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Challenging features for modeling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.1.
Complex processes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.2.
Non-negligible effects . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.2.1.
Changes in fluid properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.2.2.
Flow maldistribution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.2.3.
Longitudinal thermal conduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.2.4.
Heat-in-leakage. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Cryogenic heat exchangers. Types and geometries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3.1.
Concentric tubes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3.2.
Coil wound. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3.3.
Plate-fin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3.4.
Perforated plate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3.5.
Regenerators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Heat exchanger models . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.1.
Lumped parameters models (LPM) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.1.1.
Mean temperature difference (MTD). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.1.2.
Other efficiencies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.2.
Distributed parameters models (DPM) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.2.1.
Zones . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.2.2.
Elements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.3.
Stream evolution models (SEM) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.3.1.
Aspen plate fin exchanger . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.3.2.
GENIUS, by Linde AG . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.4.
Summary. Features for cryogenic applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Corresponding author.
E-mail address: julio.pacio@ntnu.no (J.C. Pacio).
0011-2275/$ - see front matter 2011 Elsevier Ltd. All rights reserved.
doi:10.1016/j.cryogenics.2011.04.005
367
368
368
368
368
369
369
369
369
369
369
369
370
370
370
370
371
372
372
372
372
372
372
373
373
5.
6.
7.
367
373
373
373
374
375
375
376
376
376
377
377
Nomenclature
Abbreviations and Acronyms
CWHE
coil-wound heat exchanger
DPM
distributed parameters model
HE
heat exchanger
HTC
heat transfer coefcient
LHC
longitudinal heat conduction
LMTD
logarithmic mean temperature difference
LPM
lumped parameters models
MTD
mean temperature difference
NTU
number of thermal units []
PFHE
plate-n heat exchanger
PPHE
perforated-plate heat exchanger
SEM
stream evolution model
Greek symbols
DT
local temperature difference (K)
DTm
effective mean temperature difference (K)
DTlm
logarithmic mean temperature difference (K)
g
heat exchanger efciency ()
/
general scalar function of one or more variables
e
heat exchanger effectiveness ()
Physical variables
_
m
mass ow rate (kg s1)
1. Introduction
Heat exchangers (HEs) are the main components in cryogenic
processes. In air separation units and Liquefaction of Natural Gas
(LNG) plants, they represent 2030% of the investment costs [38].
In addition, their performance affects the sizing and design of other
major equipments, namely compressors and their power drivers.
Thermodynamic considerations make cryogenic processes very
sensitive to the HE performance. For example, Kanoglu et al. [53]
predicted a reduction of 22% in the production of liquid if the HE
effectiveness (e) departs from the ideal value of 100% to a more
practical one of 96.5%. In the case of liquefaction of helium, Atrey
[10] calculated that 12% less liquid is obtained if e is reduced from
97% to 95%, and Barron [13], Barron [15] stated that no liquid is
produced if e < 85%.
An important consequence of HE under-performance is the
need for modications in the process to achieve the desired liquid
production rate. The refrigeration capacity has to be increased,
with the corresponding increase in power input, which is a major
concern in cryogenics. The minimum ideal power input per unit
of removed heat in a refrigeration circuit, given by the inverse
W
A
C
C
cp
dA
dQ
dT
En
F
P
Q
R
T
U
W
Subscripts
c
refers to the lower temperature level (hot)
h
refers to the higher temperature level (cold)
max
maximum value
min
minimum value
Carnot cycle [20, ch. 10] can be computed according to (1). Given
the usually low values of Tc, the mechanical-to-thermal power ratio W/Q given by (1) is relatively high. For this reason, the refrigeration capacity should be kept at a minimum, emphasizing the
requirements for high HE performance.
W Th Tc
Q
Tc
368
369
370
Table 1
Summary of HE geometries. HTC = heat transfer coefcient. LHC = longitudinal heat conduction. Sources: [1,8,15,60].
Advantage(s)
Disadvantage(s)
Scale
Heating surface density (m2/m3)
Cost per unit duty
Modeling challenges
CWHE
PFHE
PPHE
Regenerators
High HTC
Limited in size
Small
up to 6000
High
HTC and LHC
C c dT c U dAT h T c
C h dT h U dAT h T c
3.5. Regenerators
Regenerators present a design that is conceptually different to
the above mentioned geometries. In a regenerator both uids occupy the same space alternately and the transfered heat is temporarily stored in a packing material, called the matrix. Therefore they
run in a cyclic operation, storing and releasing energy from the matrix. A review on the historical development of regenerators and
applications in cryogenics can be found in the book by Ackermann
[1]. They are widely used for small-scale single-phase gas
purposes.
The main advantage of regenerators is their extremely high area
density, reaching up to 6500 m2/m3 [1]. The periodic ow reversal
371
LPM
DPM
Zones
Elements
ASPEN
GENIUS
Single-phase ow
Two-phase ow
Flow mixing (partial)
Flow mixing (complete)
Changes in uid properties
Multiple streams
Multi-component mixture
Flow injection/removal
Heat-in-leakage
Axial thermal conduction
Flow maldistribution
Effect of pressure drop on heat transfer
_
where the heat capacity rate (C), dened as the mass ow rate m
times the specic heat (cp) is used.
_ p
C mc
DT m
Q
UA
In the case of co-current or counter-current ow, the integration results in a logarithmic mean temperature difference DTlm, dened as:
DT lm
DT m
! Q UAF DT lm
DT lm
dq U DT dA
SEM
Q
Q max
NTU
C
UA
C min
10
C min
C max
11
12
13
NTU h
UA
;
Ch
NTU c
UA
Cc
14
The second parameter is a heat capacity rate ratio (R) for each
stream:
Rh
Ch
;
Cc
Rc
Cc
Ch
15
Pc
Q
;
C c DT max
Ph
Q
C h DT max
16
372
Pc e
C min
;
Cc
Ph e
C min
Ch
17
18
19
DT m
DT max
20
e
NTU
Pc
Ph
NTU c NTU h
4.2.2. Elements
The heat exchanger is divided in elements of some given physical length, in a geometry-oriented approach. This approach is useful for complex geometries like air conditioning and heat pump
systems with multiple tube passes in several directions [33,59].
Since this model is not ow-oriented, the transition between single- and two-phase is not intrinsically considered, which may lead
to some numerical problems. These issues can be solved by reducing the element size to a tube-segment, as proposed by several
authors [80,112], therefore reducing the size of the transition element, although this scenario is only conditionally stable. Iu et al.
[48] further divided the transition elements into two zones, in a
mixed geometric- and ow-oriented approach.
21
373
The following subsections cover the state-of-the-art on these effects. Section 5.5 describes the literature on combination of these
four effects. Finally, the review described in this section is summarized in Tables 38.
5.1. Changes in uid properties
Distributed parameters and stream-evolution models, discussed in Sections 4.2 and 4.3, deal with this effect in a discretized
approach. Some other approaches have been reported in literature,
for example the use of averaged or effective values, and are reviewed in this section.
For single-phase ow HE design, the most relevant effects are
given by the specic heat capacity and the overall heat transfer
coefcient (HTC). Most research has been focused on their separate
effect. The combination of both effects has been studied by Roetzel
[90]. He recommended the use of suitable averaged values based
on the calculation at two points. Following this work, Peters [77]
included the variation of HTC in length due to laminar ow development. However, this author recognized that no reasonably simple procedure is successful when large variations are present.
While most published works were limited to co-current and counter-current ow arrangements, Roetzel [91] extended this study to
crossow HE, considering both length and temperature effects.
5.1.1. Specic heat capacity
Kays and London [55] suggested the use of constant values for
the uid properties in a recuperator, evaluated at the mean temperature. This approach is valid when the variation is limited to a
factor of 2. However, this is usually not the case in cryogenic systems. Chowdhury and Sarangi [24] studied the case of supercritical
hydrogen in the temperature range 30080 K and 30040 K, where
the specic heat varies by a factor 4. They observed that the use of
a harmonic mean specic heat gives good results for balanced ow
HE, but present some deviations for unbalanced, high NTU cases.
The same approach (harmonic mean) was proposed by Sahoo
and Sarangi [94] for the analyisis of regenerators. They observed
that the overall effectiveness is correctly calculated, however this
method does not satisfactorily predict the temperature proles.
Kumar and Sarangi [57] noted that the use of averaged constant
properties fails to predict the location of points with minimum
temperature difference (pinch points). This pinch points occur
when the heat capacity ow ratio Ch/Cc varies from a value of less
than unity to one larger than unity, or vice versa. This situation is
likely to occur in cryogenic systems with a close-to-balanced design. In this case, the authors recommend a nite-difference solution. The considered working uids were both normal- and parahydrogen.
Soyars [101] studied a cryogenic helium HE using discretized
e NTU and LMTD models. The author noticed that the e NTU approach relies on the estimation of the heat capacity ow. In closeto-balanced design condition, a poor estimation of the heat capacity may lead to sections of the HE with a value of e larger than
unity. This situation is not physical, and leads to an erroneous sizing of the HE. For this reason, the author recomended the use of a
discretized LMTD method.
374
Table 3
Summary of available literature on the effects of variations in specic heat capacity.
Method
Observations
Reference(s)
Up to a factor 2 variation
Up to a factor 4 variation. Misleading results for unbalanced, high NTU cases
Predicts well e, but the temperature proles are incorrect
LMTD preferred over e NTU
Identies pinch points
[55]
[26]
[94]
[101]
[57]
Table 4
Summary of available literature on the effects of variations in heat transfer coefcient.
Method
Observations
Reference(s)
Review (1977)
Logarithmic mean of U DT
Arithmetic mean of U DT
Four-points integration
Non-linear energy equations
[41]
[28]
[18,40,110]
[100]
[54]
Table 5
Summary of available literature on the effects of ow maldistribution.
Method
Observations
Reference(s)
[36]
[82]
[92,95]
[8487]
[51]
[76]
Table 6
Summary of available literature on the effects of longitudinal heat conduction.
Method
Observations
Reference(s)
Review (1994)
Pioneer work, non-dimensional
Conduction in outer wall
Regenerators (conduction in uid)
Regenerators (conduction in matrix)
[98]
[56]
[115]
[96]
[32]
Table 7
Summary of available literature on the effect of heat exchange to the surroundings.
Method
Observations
Reference(s)
Some graphical results. For cryogenics, heat exchange to the cold uid is more severe
Counter-current ow arrangement is less affected
Analytical solution, useful as a guideline
If Cc < Ch, an optimum NTU exists
[12,24,78,97]
[6,5]
[72,3]
[6264]
Table 8
Summary of available literature on combined effects.
Method
Observations
Reference(s)
Tend to eliminate each other for high NTU, and augment each other for low NTU
An optimum value for NTU is found to exist
Computing their effect simultaneously or separated gives similar results, within
10%
[21,81]
[44,71]
[43,72]
constant. This approach uses a logarithmic mean combined function of HTC and temperature difference. This means that the average HTC is calculated on the basis of the extreme values.
Gardner and Taborek [41] presented an up-to-date review of HE
models with variable HTC. For counter-current ow, the model
375
Jung and Jeong [51] studied the effect of transverse heat conduction in single-body HE for counter-current single-phase ow.
This condition provides some extent of thermal coupling between
the different channels. The consequence is similar to that of ow
mixing, that is, provides a more homogeneous temperature prole,
thus reducing the effect of ow maldistribution in performance.
This situation is interesting for the design of anisotropic equipment, such as perforated-plate HE.
Recently, Pacio and Dorao [76] presented a numerical analysis
including the momentum equation for two-phase ow. They
concluded that the pressure-drop coupling between channels is
expected to produce a secondary maldistribution that further
reduces the HE performance.
376
variation in uid properties and heat transfer coefcients. In addition, more effects can be included with the consideration of energy
balances in the wall. Following the same trend as in Table 2, more
effects can be considered within this framework. The computational costs, however, are more demanding and for this reason advanced numerical methods, more efcient than the traditional
nite-differences, will be needed. Examples of advanced methods
used by some authors for the solution of HE include: rst-order nite-element [81,83,88,97], spectral Galerkin [7,50], and collocation schemes [107,108]. In addition, the least-squares spectral
elements method presents some potential advantages for its application to this problem.
Some general comments on the performance of available models for HE design were presented in Section 4.4 and Table 2, concluding that they fail to take into account all relevant effects.
This situation is improved with the advanced models presented
in Section 5. However, two points are not considered: rst, the effects of pressure drop on heat transfer and second, partial ow
mixing. Some remarks on these two points are presented next.
Changes in the working pressure affect the uid physical properties and consequently, the heat transfer performance. While singlephase uid properties are mainly dependent on the temperature,
that is not always the case for two-phase ow. Of special interest
for boiling and condensation applications are the variations in the
saturation temperature. This situation can bring the temperature
curves closer, thus reducing the total heat duty.
Flow mixing is neglected by some authors, while others assume
a complete and continuous mixing. The practical case is an intermediate situation, producing temperature non-uniformities. The
reason why this condition was not considered is because it cannot
be successfully modeled by a one-dimensional formulation. Nevertheless, this effect is interesting for large shell-type HE, given that
it affects the performance. In the case of multicomponent mixtures,
partial mixing can also produce non-uniformities in the mass concentration proles.
7. Summary
1. HE are key equipment in cryogenic systems. Thermodynamic
and economic considerations set high-efciency requirements
which result in the need for accurate models. The state of the
art on HE modeling for cryogenic applications is reviewed in
this article.
2. Cryogenic systems involve two main challenges for the modeling of HE: complex processes and non-negligible physical
effects. The complexity of the processes include large temperature ranges, multiple streams, two-phase ow and the use of
multicomponent mixtures. The required accuracy is such that
physical effects like changes in uid properties, axial conduction, ow maldistribution and heat-in-leakage cannot be
neglected.
3. The geometries used in cryogenic applications are summarized
in Fig. 2 and Table 1. The selection of the HE type depends on
the particular application. In this work, they were presented
from a design-challenges perspective.
4. Present HE models used for design were reviewed. In general,
they can be divided in three categories: lumped-parameters,
distributed-parameters and stream-evolution. Their ability to
consider relevant effect is summarized in Table 2. While the
stream-evolution models are the most advanced, they are proprietary and, nevertheless, do not take all physical effects into
account.
5. Extensive research covering the four above mentioned non-negligible effects is available in the open literature, resulting in
state-of-the-art advanced models. In general, they can be
377
divided into two categories: non-dimensional analysis and discretized energy equations. While most works were focused in
only one of these effects, there are some published reports on
their combination, indicating that no signicant error is introduced by considering them separately.
6. The advanced models include more effects than those used for
design. Nevertheless, two points are not considered: the effects
of pressure drop on heat transfer and partial ow mixing. The
variation on operating pressure is particularly important for
two-phase ow, since it affects the saturation temperature.
Flow mixing is neglected by some authors, while others assume
a complete a continuous mixing. The practical case is an intermediate situation, producing temperature non-uniformities.
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