Chemistry form 5

Answer Scheme of First Term Test

Part A
1 A/D
11 C

2D
12 C

3D
13 D

4C
14 B

5D 6D
15 D

7A

8A

9C

10 A

Part B
1
Answer
(a) P: Tin , Q: Manganese , R: Zinc
(b) A: to make decorative ornaments/ souvenirs
B: to make body of aeroplane
C: to make taps/ decorative ornaments/ three-pin plugs
(c)
(i) 2 NH3 + H2SO4 ( NH4 ) 2 SO4
(d)

(ii) % of nitrogen by mass of urea = 46.67%

% of nitrogen by mass of ammonium sulphate = 21.21%
Urea is a better fertiliser

(e)

(i)
Hard/ brittle/ electrical insulator/ resistant to chemical corrosion
(ii)
Glass : silicon dioxide / silica / SiO2
Ceramic: kaolinite/ aluminosilicate/ Al2Si2O5

2
(a)

Answer
S2O3 2- + 2H+ S + SO2 + H2O

(b)
(c)

Yellow precipitate form // Pungent smell

(s-1)

(d)

0.020

0.042

Mark
1
1
1
0.063

(e)

Able to
1. Draw x axis and y axis with the label and the unit.
2. Mark the scale correctly
3. Mark all the point correctly and draw a straight line
Rate of reaction

(f)

The higher the temperature, the higher the rate of reaction.

(g)

Mark
1+1+1
1
1
1
1
1
1
1
1
1
1
1
JUMLAH 14

0.083

0.100

1. Show on graph
2. 1/0.05 = 20s

Part c
1
Answer
(a)
- Industries emit (acidic gases)/(sulphur dioxide).
- These gases dissolve in rainwater forming acid rain.
- The rain water has a higher concentration of acid.
- more collisions between (reacting particles)/(metal and acid) to occur.
(b) (i
Zn + 2HCl
ZnCl2 + H2
)
Number of mole of HCl = 0.4 x 50/1000 // 0.02 mol
Mole ration HCl : H2 = 2 : 1
Volume of H2 = 0.01 * 24 // 0.24dm3 // 240cm3
(ii) Axes are labels with units
Curves I, II and curve III are leveling started at 10 and 5 minutes respectively.

1
3

1
1
1
1
JUMLAH 11

Mark
1
1
1
1
1
1
1
1
1
1
1
1


(iii)
(iv)

The gradient of curves II and III are more steep than curve I
3
3
Volume of graph level off in Exp. II is 0.24 dm and 0.12 dm in Exp. I and III.
I:
rate = 0.12 x 1000/10 x 60 // 0.2
II:
rate = 0.24 x 1000/10 x 60 //0.4
Experiment I and Experiment II:
- The initial rate of reaction in experiment II is higher.
- The concentration of hydrochloric acid in experiment II is higher.
- The number of hydrogen ion per unit volume in experiment is higher.
- The frequency of collision between zinc atoms and hydrogen ions is higher.
- The frequency of effective collision also increases.

1
1
1
1
1
1
1

Experiment I and Experiment III:

- The initial rate of reaction in experiment III is higher.
- Size of zinc in experiment III is smaller
- The powdered zinc has a larger total surface area.
- The frequency of collision between zinc atoms and hydrogen ions is higher.
- The frequency of effective collision also increases.
JUMLAH
2
(a) (i)

(ii)

(iii)

(b) (i)

(ii
)

Answer
P1. Sulphur dioxide burnt/react with excess oxygen to produce sulphur trioxide.
P2. Passed over vanadium(V) oxide catalyst at 450C, 1 atm
P3. Chemical equation : 2SO2 + O2 2SO3
P1. Step 1: Sulphur trioxide is dissolved in concentrated sulphuric acid to form oleum.
P2. SO3 + H2SO4 H2S2O7
P3. Step 2: Oleum is diluted with water to produce sulphuric acid.
P4. H2S2O7 + H2O 2H2SO4
P1. Moles of S = 48 / 32 =1.5 mol
P2. Mole ratio S : SO2 = 1 : 1
P3.Volume of SO2 = 1.5 / 24 dm3 = 36 dm3
P

Bronze

Borosilicate glass

hard and Strong // Shiny surface // Withstand

temperature// Does not corrode easily//
Resistant to chemicals // low thermal expansion

1
1
1
1
1
25
Mark
1
1
1
1
1
1
1
1
1
1
1+1
1+1

Tin
Copper

P1 Arrangement of atoms
P2 Label
P3. Alloy P/bronze is harder than pure copper
P4. Atomic size in pure copper is the same , atomic size in alloy P/bronze is different.
P5. Atoms in pure copper are orderly arranged while atoms in alloy P/bronze are not orderly
arranged.

1
1
1
1
1