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lolathsby Sl.JHAu
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10. Section1 contains8 questions.
The answerto eachquestionis a singledigitintegerranging
from 0 to 9 (bothinclusive).
Marking scheme:+4 for correctanswerand 0 in all othercases.
11. Section2 contains10 multiplechoicequestionswithone or morethanone correctoption.
Marking scheme:+4 tor correctanswer,0 if not attemptedand-2 in all othercases.
12. Section3 contains2 "matchthe following"type questionsand you will have to matchentries
in ColumnI withthe entriesin Columnll.
Marking scheme: for each entry in Columnl, +2 tor correctanswer,0 if not attemptedand
-1 in all othercases.
OPTICALRESPONSESHEET:
13. The ORS consistsof an original(topsheet)and its carbon-lesscopy (bottomsheet).
14. Darkenthe appropriate
bubbleson the originalby applyingsufficient
pressure.Thiswillleave
an impressionat the corresponding
placeon the carbon-lesscopy.
15. The originalis machine-gradable
and will be collectedby the invigilator
at the end of the
examination.
16. You will be allowedto take awaythe carbon-less
copy at the end of the examination.
17. Do not tamperwithor mutilatethe ORS.
18. Writeyour name,roll numberand the name of the examination
centerand sign with pen in
the space providedfor this purposeon the original.Do not write any of these details
anywhereelse. Darkenthe appropriate
bubbleundereachdigitof your rollnumber.
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Q.1
Two identical uniforrn discs roll without slipping on two different surfacesAB and CD (see
figure) starting at A and C with linear speedsu, and u2,respectively,and always remain in
contact with the surfaces.If they reach B and D with the same linear speedand u, = 3 m/s,
then u2rn m/s is ( g = 10 m/s2t
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PHYSICS
material of
A nuclear power plant supplying electrical power to a village uses a radioactive
total porn'er
half tife ? years u, th" fuel. The amount of fuel at the beginning is such that the
plant
at that
the
from
requirement of the village is l2.b% of the electrical power available
period
time. If the plant is able to meet the total power needs of the village for a mffium
\j2i
of nT years, th*tt the value of n is
rence arrangement with slits Sr and S, is immersed in water
A Young'sdouble LIt ]1n].terfer
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(refractive index
,),
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,.L' - d' where 2 is the wavelength of light in air (refractive
,
Dy x,- =p'm
water are given by
rration between the slits and nt.is an integer. The value of p is
3pD a
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index = 1), 2d rs the
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PHYSICS
An infinitely long uniforrn line charge distribution of charge per unit length 2 lies parallel to
the y-axis in the y-z plane at z =
J 5 , o(see
. figure).
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L/
field through the rectangular surface ABCD lying in the r-v plane with its centre at the
trL
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Q.7
Consider a hydrogen atom rvith its electron in the nth orbital. An electromagnetic radiation of
wavelength 90 nm is used to ionize the atom. If the kinetic energy of the ejected electron is
10.4 eV, then the value of z is (hc = 1242eV nm) A
e)
Q.8
A bullet is fired vertically upwards with velocity u from the surface of a spherica-lplanet.
When it reachesits maximum height, its acceleration due to the planet's gravity is 1/4thofits
value at the surface of the planet. If the escapevelocity from the planet is u"""= uJF, then
the value oflfis (ignore energy loss due to atmosphere)
F
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PHYSICS
Q . e Two independent harmonic oscillators of equal mass are oscillating about the origin with
angular frequencies or and co,.and have total energies Er and Er, respectively. The
g
variations of their momenta p with positioris r are shown in the fisures. If b = n2 anc
I - ru,then the correctequation(s)is(are)
R
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Q.10 A ring of mass M and radius .R is rotating with angular speed a about a fixed vertical axis
passing through its centre O with two point masses each of mass 4 at rest at O. These
8
masses can rnove radially outwards along two massless rods fixed on the ring as shown in
the figure. At someinstant the angular speedofthe system is 9,
at a distance of ].R from O. At this instant the distance ofthe other mass from O is
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PHYSICS
Q . 1 1 The figures below depict two situat ions in which two infinitely long static line charges of
constant positive line charge densit y ), are kept parallel to each oth er. In their resulting
electric field, point charges q and -g are kept in equilibrium betw een them. The point
charges are confined to move in the r direction only. If they are given a small displacement
about their equilibrium positions, thr:n the correct statement(s) is(are)
lr
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Charge *q executes sipple harmonic motion while charge -q continues moving in the
Charge -q executes simple harmonic motion while charge *q continues moving in the
direction of its displacement.
Q.12 Two identical glass rods S, and S, (refractive index = 1.5) have one convex end of radius of
curvature 10 cm- They are placed with the curved surfaces at a distance d as shown in the
figure, with their axes (shown by the dashed line) aligned. When a point source of Iight P is
placed inside rod S, on its axis at a distance of 50 cm from the curved face, the light rays
emanating from it are found to be parallel to the axis inside Sr. The distance d is
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PHYSICS
Q.13 A conductor (shown in the figure) carrying constant current 1is kept in the r-y plane in a
uniform magnetic field .d. If F is the magnitude of the total magnetic force acting on the
conductor, then the conect statement(s) is(are)
J
l--
(A)
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l*--
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Q. 14 A container of fixed volume has a mixture of one mole of hydrogen and one mole of helium in
equilibrium at temperature ?. Assuming the gasesare ideal, the correct statement(s) is(are)
...
The average energy per mole of the gas mixture is 2.8?.
Sf
(B) The ratio of speedof soundin the gas mixture to that in helium gas ;s ./e/f .
(C)
1pr'tt
The ratio of the rms speedof helium atoms to that of hydrogen moleculesis 1/2 .
"
ratio of the rms speedof helium atoms to that of hydrogen moleculesis tlJi
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PHYSICS
Q.15 In an aluminum (Al) bar of square cross section, a square hole is drilled and is frlled with
iron (Fe) as shown in the figure. The electrical resistivities of Al and Fe are 2.?xl0-8 f) m
and 1.0x10-7 C)m, respectively. The electrical resistance between the two faces P and Q of
the compositebar is
-a?
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4a q,s
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Q.16 For photo-electric effect with incident photon wavelength )", the stopping potential is Vo
Identifi'the correct variation(s) of Vowith ,L and Ll ). .
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PHYSICS
Q.17 Consider a Vernier callipers in which each I cm on the main scale is divided into
8 equal divisions and a screw gauge with 100 divisions on its circular scale. In the Vernier
callipers, 5 divisions of the Vernier scale coincide with 4 divisions on the main scale and in
the screw gauge, one complete rotation of the circular scale moves it by two divisions on the
linear scaie.Then:
(A) If the pitch of the screw gaugeis twice the least count of the Vernier callipers, the least
count of the screwgaugeis 0.01 mm.
=: j;l {S -=
g
i"i
r,.
(B) If the pitch of the screw gaugeis twice the least count of the Vernier callipers, the least
' ' . . - ' t " : l'l
;'i =
count of the screw gaugeis 0.005mm.
(C) If the least count of the linear scaleof the screw gaugeis twice bheleast count of the
*Yqo
Vernier callipers,the least count of ihe screw gaugeis 0.01 mm.
(D) If the least count of the linear scaleof the screw gaugeis twice the least count of the
Vernier callipers,the least count of the screw gaugeis 0.005mm.
#en+l
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Q.18 Planck's constant h, speed of light c and gravitational constant G are used to form a unit of
IengthrL and a unit of mass M. Then the correct option(s)is(are)
,1*/ru*f.*
(B) *;&
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the bubbles of all the matching entries' For
F'or each entry in colurnn r, darken
three
these
entries (Q), G) and (T), then darken
if entry (A) in column I matches with
bubblesirrtheoRs.Similarly,forentries(B),(C)and(D).
Marking scheme:
For each entrv in Column I'
the correct match(es)is(are) darkened
+2 If only the bubble(s)correspondingto all
0 If none of the bubbles is darkened
-1 In aII other cases
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e.20
A particle of unit mass is moving along the r-axis under the influence of a force and its total
energy is conserved.Four possible forms of the potential energy of the particle are given in
column I (o ancl Uo are constants). Match the potential energies in column I to the
corresponding statement(s) in column II.
Column II
Colurnn I
(A)
u,(*)=+['
(;)')'p
(B)
u,(*)=+[;)'
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C)
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The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 toY
inclusive
For each question, darken the bubble corresponding to the correct integer in the ORS
Marking scheme:
+4 If the bubble correspoqding
to the answer is darkened
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Q.2 1
For the octahedral complexes of Fe3* in SCN- (thiocyanato-S) and in CN- ligand
environments, the difference between the spin-only magnetic monlents in Bohr magnetons
el
(when approximated to the nearest integer) is
O
tr'e- 26]
26]
numberof tr'e
[Atomic number
[Atomic
Os
(4)
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\ o
o/
v..
x
x
^1 x ,.
Or, lgtr,ICI;, I; and XeF", the
total number of linear molecule(s)/ion(s)where the hybridization of the central atom does not
have contribution from the d-orbital(s) is
fn)
\|/
=
=
53 and Xe - 54]
[Atomic number : S 16, Cl I7 ,I
Q.23 Not considering the electronic spin, the degeneracy of the second excited state (n = 3) of
H atom is 9, while the degeneracyof the secondexcited state of H- is
All the energy released from the reaction X + Y, A.GO = -193 kJ rnol-1
is used for oxidizing M* as M* -> M3* + 2e-, E0 = -0.25V .
q.24
Under standard conditions, the number of moles of M* oxidized when one mole of X is
converted to Y is
,,h
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9
6
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CHEMISTRY
Q.25
that canexistfor M is
Q . 2 6 The total numberof stereoisomers
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CHEMISTRY
SECTION 2 (Maximum Marks: 40)
.
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Q.29
w
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9Hg
Ufr
1 equivalent
HBr
urc,)\"cH'
L-....--c\acAL
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(A)
?ru
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Br
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Q.30 The structure of D-(+)-glucose
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H
HO
H
H
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OH
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I OH
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HO
H
C HzoH
CHO
Ho-l-H
H-f oH
(A) HofH
t-t-
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C Ho
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H
HO I H
(c)
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OH
H
C H2 0 H
o
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CH
H
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H
H:[
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I
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Q.31
tr.J-1-c02H
H3C--,.^-..-,
t..y^yco2H
NH2
cHs oH
cHs oH
H3C-,-ar^t._.,.
(D)II
cHs oH
NH2
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N a N O 2a, q u e o u sH C I
CHEMISTRY
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L7t32
CHEMISTRY
Q.34 tr'e'*is reducedto tr'e'*by using
(A) HrO, in presenceof NaOH
(C) HrO, in presenceof H2SO1
Q.35
(B)
NarO, in water
. )r ylru .t\oq
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at (P, 4) is givenbeiow.
_2\
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time
If this reaction is conducted at (P, Tr) , with T2 > f , the %yield of ammonia as a function of
time is represented by
(A)
E
';c,
-o
.;(u
>R
rtE
#ffi3#
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time
time
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18132
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CHEMISTRY
(B)
*{;,*
Q.37
1,I
(c)
(D)
22
compound(s)is(are)
t...tt
(A) H3c'VcH3
(c)
H ,.Br
-"Y'^at,
/a
\.'
cHg
Q.38
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CHs ii. H+,heat
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d"
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(D)
cHs
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15
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19132
CHEMISTRY
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For each entry in Colurnn I, darken the bubbles of ail the matching entries. For example,
if entry (A) in Colurnn I matches with entries (Q), (R) and (T), then darken these three
bubbles in the ORS. Similarly, for entries (B), (C) and (D).
Marking scheme:
tr'or each entrv in Colurnn I+2 If only the bubble(s) corresponding to all the correct match(es) is(are) darkene,C
0 If none of the bubbles is darkened
-1
In all other cases
Q.39 Match the anionic species given in column I that are present in the ore(s) given in
Column II.
Column I
Column II
tDi- [g ,t]
(A) Carbonatu
(P)
Siderite s\or-
(B) Surphide
+'lf
(Q)
(R)
Malachite cutol'tvtoil)r
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(S)
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(T)
Argentite
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CHEMISTRY
(].10
Match the thermodynamic processesgiven under Column I with the expressions given under
Column lI.
Colurnn I
tr'reezing of water at 273K and 1 atm (,f-lgiD
(P)
e=0
(B)
(Q)
w=0
(c)
(R)
4,S",,,< 0
(D)
(S)
A[/ = 0
(A)
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END OF PART II : CHEMISTRY
*2
2T132
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DIGIT
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5 boys and 5 girls can stand in a queue in such a way that exactly four girls
stand
consecutively in the queue. Then the valu of L
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! lb=y{ t : l ' ; , i ,
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A cvlindrical container is ftii0RAirn[ffF. hdtr certain solid material with the following
constraints: It has a fixed inner volume of V mm3 , has a 2 mm thick solid waII and is open
at
the top. The bottom ofthe container is a solid circular disc of thickness 2 mm and is ofradius
equal to the outer radius of the container.
If the volume of the material used to make the container is minimum when the
inner radius
V
of the container is 10 mm, then the valu" of
i.
250 n
Lto_)
4)L
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, I
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in theintervall0,2nlts
q.47
f Lq\*l-
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3559
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Let the curve C be the mirror image of the parabola y' - 4x with respect to the line
x+y+4-0.If
A a n d B a r e t h e p o i n t s o f i n t e r s e c t i o no f C w i t h the line J : -5, then the
distance betweenA and B is ril-'
l?
^ F.. . Q.48 The minimum number of times a fair coin needsto be tossed,so that the probabilitv of
gettingat leasttwo hea-ds
is at least0.96,is
r< ,.rrrrtr )
= ; S
B
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MATHEMATICS
SECTION 2 (Maximum Marks: 40)
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I
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Q . 4 e I n I R " ,c o n s i d e r t h e p l a n e s 1 , y : 0
f Fgt'
nE
and Pr:x*z=L.
P, and Pr, which passes through the intersection of I and P2. If the distance of the point
(0, 1,0) from PB is 1 and the distance of a point (a, f , y) from PB LS2, then which of the
2a+f+2r+2-0
(C)
2a+f-2y-10:0
(D) 2a - f + 2y-8 = 0
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In IR",Iet L be a straight line passing through the origin. Suppose that all the points on I are
a t a c o n s t a n t d i s t a n c ef r o m t h e t w o p l a n e s 1 , * + 2 y - z + 1 = 0 a n d P r : 2 x - y + z - 1 - 0 . L e t
M be the locus of the feet of the perpendiculars drawn from the points on L to the plane 4.
Which of the following points lie(s) on M ?
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24t32
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MATHEMATICS
Q.51 lt P and Q be distinct points on the parabola y2 =2x sudn that a circle with pe as
diameter passesthrough the vertex O of the parabola. If P lies in the first quadrant and the
area of the triangle AOP@ is 3J2, then which of the following is (are) the coordinates of p?
/
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(A) \+,z^lz)
/-\
(D)b,a)
tcl l 1
(B) le,3J2/
t-.
r-
[4', 42
Q.52 Let y(.r) be a soiution ofthe differential equation (l+e")y'+ye" =1. If y(0) =2, then which
#sgr
3a*fi
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(B)
(C)
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k
e{+ lc
{YY(-4)=o
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+l
3.
x+4:l
L'I =
,z:)
,,
J* _,ti
,,Jt=*r.
Q . 5 3 Consider the family of all circles whose centers lie on the straight line y - 5. If this family of
circles is represented by the differential equation
of x, y and.y' (heire y' =
E_
d-J
" d2 Y '
, y" =W ), then which of the following statements is (are) true?
d,x,
(A)
P-y+x
(B)
P:J-x
(C)
P +Q -1- x+ y -Fy'+(y')'
(D)
P-Q=x+y-y'-(y')'
i+I
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L
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MATHEMATICS
Q . 5 4 l,etg: IR-+ IR be a differentiablefunction with g(0)=0, g'(0)=0 and g'(t)+0. Let
I\x)=1trl
I 0.
frE
ts $8*,
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(c) /.h isdifferentiable
at r =0
(B) hisdifferentiableat
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at =o *r"JoflnTfi;
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MATHEMATICS
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27132
MATHEMATICS
SECTION 3 (Maximurn Marks: 16)
a
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For each entry in Column I, darken the bubbles of all the matching entries. For example,
if entry (A) in Column I matches with entries (Q), G) and. (T), then darken these three
bubbles in the ORS. Similarly, for entries (B), (C) and (D).
Marking scheme:
For each entry in Column I.
+2 If only the bubble(s) corresponding to all the correct match(es) is(are) darkened
0 If none of the bubbles is darkened
-1
In all other cases
x2
28t32
MATHEMATICS
Q.5e
Column I
(A)
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