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MoleculeWall Collisions:
Lets call Zw the rate of collisions of gas molecules with a section of wall of area A.
I.
II.
III.
The proportionality constant can be calculated from a complete analysis of the directions from which molecules
impinge on the wall; it turns out to have the value 1/4 . So the wall collision rate is
Diffusion
1
4
=
4
1
4
Diffusion is the process by which the molecules of different substances mingle with each other. The atoms of two
solids diffuse into each other when the two solids are in contact, but the process is very slow. The diffusion of a
solid through a liquid solvent is much faster but mixing normally needs to be encouraged by stirring or shaking
the solid in the liquid (the process is then no longer pure diffusion). Gaseous diffusion is much faster.
Effusion
Effusion is the process in which a gas escapes through a small hole into vacuum. This occurs if the diameter of
the hole is considerably smaller than the mean free path of the molecules.
Rate of Effusion
=
Ambedkar
Nagar
in 1 second. It will
An average molecule sweeps out a cylinder of volume d2
collide with any molecules whose centers lie within the cylinder. Using this
construction, we can calculate the rate of collisions with other molecules.
Length of collision tube in time =
The Volume Of Collision Tube = = =
If N/V is the number of molecules per unit volume in the gas (the number density of the gas), then the number of
collisions per second experienced by the moving molecule is
. =
( ) =
=
=
= so =
It can be proved that
Number of collision in Unit volume ( )
Now imagine that all of the gaseous molecules in the cylinder are moving . When you count all of the collisions
for every gaseous molecule moving within the cylinder in a sec, you get Zii. The relation was found to be:
Ambedkar Nagar
The mean free path is the average distance travelled by a moving gaseous molecule, between successive
impacts (collisions).
Z1 is the rate at which a particular molecule collides with other molecules. Its inverse, Z1-1 , therefore measures
the average time between collisions. During this interval, a molecule travels an average distance vavg /Z1which is
called the mean free path, .
=
=
=
Because 1/p, we see that the mean free path decreases as the pressure increases.
=