Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
The first part of the experiment was done to determine the effect of
concentration on the rate of reaction. A beaker, with an X mark at the outer-bottom
side, was filled with the required volumes of Sodium Thiosulfate and water. Enough
HCl was then added to the solution and the time it took for the X mark to be
covered by a cloud of precipitate was recorded. This was done for 3 Runs (runs 13; refer to table 1). For the next 3 runs (runs 4-6), required amounts of HCl was
added into the water (Refer to table 1). Required volumes of Sodium Thiosulfate
were then added to the solutions and the time it took for a cloud of precipitate to
cover the X mark was recorded. Take note that only 1 beaker must be used
throughout the experiment and that there should be only one (1) observer.
Table 1.1 Determination of the Effect of Concentration on the Rate of
Reaction
Run
Vol. of 0.15 M
Vol. of water,
Vol. of 3M HCl ,
Na2S2o3 , mL
mL
mL
1
10.0
3.0
2.0
2
5.0
8.0
2.0
3
2.5
10.5
2.0
4
5.0
1.0
1.5
5
5.0
1.5
1.0
6
5.0
2.0
0.5
Next was the determination of the effect of temperature on the rate of
reaction. Specified volumes from Run 3 (Table 1) were used to conduct this part of
the experiment. Sodium Thiosulfate and water were mixed together in a 50-mL
beaker with X mark while HCl was put in a test tube. Both solutions were put
inside a water bath of desired temperature (cold, ambient, hot). It took about 5 to
10 minutes for the temperature to remain constant and this temperature was
recorded. After this, HCl was added to the thiosulfate solution. Keep in mind that
the 50-mL beaker was still submerged in water bath. The time it took for the
cloudy precipitate to cover the X mark was recorded. Waste from the first part and
this part was filtered. Precipitate was collected ad submitted in a vial while the
filtrate was disposed of in the Inorganic Waste bin.
The last two parts of the experiment dealt with Catalysis. For the first, a hot
bath was prepared and its temperature was kept at around 65 0C. Two 6-inch test
tubes were then prepared. Both test tubes contained 5mL of 0.3M sodium tartrate
and 2mL of 6% Hydrogen peroxide. An additional 8 drops of 0.3 M CoCl 2 was
added to test tube 2. After that, both test tubes were placed in the hot water bath
and the time it took for the solutions color to change was recorded. Keep in mind
that the temperature must be kept around 65 0C since the reaction mixture may
overflow at higher temperatures. Waste from this part was disposed of in the
Peroxide Waste container.
For the last part, 1 mL of saturated Na 2C2O4, 5 drops of water and 1 mL of
3.0 M H2SO4 were mixed in a 4-inch test tube. This mixture was then split into two,
leaving us with Test Tube 1 and Test Tube 2. A drop of 0.01 M KMnO 4 was added to
test tube 1 and the time it took for permanganate to decolorize was recorded.
Another drop of 0.01 M KMnO4 was added to test tube 1 and again, the time it took
323.15
277.65
0.00309
0.00360
23.43
595.24
0.04268
0.00168
Appendix:
1. Plot of ln k vs 1/T
2.
References:
[1] Bissonnette, C.; Herring, G.; Madura, J.; Petrucci, R. General Chemistry:
Principles And Modern Applications; 10th ed.; Toronto, 2011.
[2] Padolina, M.; Simon-Antero, E.; Alumaga, M. Conceptual And Functional
Chemistry; 2nd ed.; Vibal Publishing House: Manila, 2010; pp. 268-269.
[3]People.duke.edu,.
Introduction
to
linear
regression
analysis
http://people.duke.edu/~rnau/regintro.htm (accessed Jun 24, 2015).
[4]Chemeddl.org,.
ChemEd
DL
Image
Collection
http://www.chemeddl.org/alfresco/service/org/chemeddl/video/video_images?
id=vid:691&guest=true (accessed Jun 24, 2015).