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organic matter including organisms that are no longer viable (living and actively metabolizing). The system is referred to as an open culture system in which the organisms
are in a dynamic state of change depending on external environmental conditions (see
Microbiology and Biochemistry below).
Wastewater components are biodegraded, sorbed, or remain untreated (recalcitrant
or nondegradable) in the biological reactor. After sufficient time for appropriate biochemical reactions, mixed liquor is transferred to a settling reactor (clarifier) to allow
gravity separation of the MLSS from the treated wastewater. Settled solids are then returned (return activated sludge [RAS]) to the biological reactor to maintain a concentrated biomass for wastewater treatment. Because microorganisms are continuously synthesized in the process, some of the MLSS must be wasted from the system. Wasting is
accomplished by diverting a portion of the RAS or biological reactor solids (waste activated sludge [WAS]) to solids-handling processes. Sludge wasting strategies are used to
increase, decrease, or maintain a selected biomass concentration in the system. This is a
principal mechanism used for process control.
The basic activated-sludge system consists of a number of interrelated components
A single biological reactor or multiple reactors designed for completely mixed
flow, plug flow, or intermediate patterns of flow designed to achieve carbonaceous organic matter removal. If required, these may also provide ammonia oxidation, nitrogen removal, and phosphorus removal depending on target effluent requirements. The primary biological reactors may be preceded by an
aerated, anoxic, or anaerobic selector reactor designed to control bulking, denitrify,
or select polyphosphate uptake microorganisms to promote enhanced phosphorus removal.
Copyright 2006 Water Environment Federation.
Activated Sludge
An oxygen source and equipment to disperse atmospheric, pressurized, or oxygen-enriched air into the biological reactors at a rate sufficient to maintain a positive mixed liquor dissolved oxygen (DO) concentration.
A means to appropriately mix the biological reactor contents to ensure suspension of the MLSS without shearing the floc.
A clarifier to separate, and possibly thicken, the MLSS from the treated wastewater.
A method of collecting settled MLSS within the clarifier and returning it to the
biological reactors.
A means of wasting MLSS from the system.
Activated-sludge system designs are based on the hydraulic retention time (HRT)
in the biological reactor, the amount of time biomass is retained within the system
(mean cell residence time [MCRT]), the organic loading, and the organic load (food) to
biomass (microorganism) ratio (F:M).
MICROBIOLOGY AND BIOCHEMISTRY. The activated-sludge process consists of a mixture of flocculated bacteria, fungi, protozoa, and rotifers maintained in suspension by aeration and mechanical mixing. The primary branches of biology that are
relevant to designers and operators of activated-sludge processes are the naming and
classification of organisms (taxonomy), their metabolic activities (physiology), and their
interrelationships with the surrounding environment (ecology). Taxonomy to the nonbiologist is the most difficult of these branches. Organisms are often classified on the basis of their physical characteristics and metabolic activities. Identification of organisms
is important in diagnosing problems in the process, but this is often left to biologists.
The operator can, however, become acquainted with the most commonly occurring organisms in the process and use simple techniques for identifying important groups of
organisms that may effect the process. For example, the use of microscopic techniques
to identify filamentous organisms in activated sludge has proved useful in diagnosing
and controlling bulking problems (U.S. EPA, 1987a, and Jenkins et al., 1993).
The functioning and activity of organisms (physiology) is important in determining
the role of the consortium of organisms in the process. Classification is often based on energy source, cell carbon source, and requirement for oxygen. Organisms that use sunlight
as their primary source of energy are called phototrophs and all others, using chemicals
as a source of energy, are chemotrophs. Organisms that use inorganic carbon (carbon
dioxide, CO2) are referred to as autotrophs and those using organic carbon are heterotrophs. The energy flow within the organism during metabolism is important relative
to the amount of energy that is captured and the products of metabolism. Energy flows
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(20.1)
(20.2)
For a chemoautotrophic aerobic reaction occurring in nitrifying systems, the overall expression, which consists of a two-step process, might be
Ammonium (NH4+) + O2 + CO2 + Biocarbonate (HCO3) +
Microbes New microbes + H2O + Nitrate (NO3)
(20.3)
Finally, a chemoheterotrophic anoxic reaction that might take place in the clarifier
or in a dedicated anoxic zone of the biological reactor once nitrate is present might be
expressed as
NO3 + Organic matter + Carbonic acid (H2CO3) +
Microbes New microbes + Nitrogen (N2) + H2O + HCO3
(20.4)
It should be emphasized that the reactions described above represent the overall
reaction taking place as a result of the composite metabolism of the entire consortium
of organisms found in the process. The reactions shown are the result of many metabolic steps but consist of two general metabolic processessynthesis and respiration.
Synthesis is an energy-consuming reaction and results in the production of new biomass. Respiration is an energy-yielding reaction that is linked to synthesis by an imCopyright 2006 Water Environment Federation.
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portant series of energy transfers. The amount of biomass produced and the character
of the products of respiration depend on the terminal electron acceptor. Aerobic reactions are the most efficient, resulting in high biomass yields and low-energy products
that are highly stabilized. Anaerobic reactions are the opposite, producing low biomass
yields and poorly stabilized products. Anoxic reactions fall in between, depending on
the acceptor. Synthesized biomass and storage products may serve as an energy source
to microbes in the system. This metabolism is often referred to as endogenous respiration (respiration of internal reserves as contrasted with exogenous respiration that involves external sources of food). Endogenous respiration reduces the total biomass
yield of the process and becomes more predominant as the solids retention time (SRT)
increases (low loaded, low F:M systems). However, such biomass decreases are at the
expense of additional energy consumption (higher oxygen requirements).
Knowledge of the organisms present in the process and the nature of the biochemical reactions that are occurring is important, but the interrelationships between
organisms and factors controlling growth and activities of the consortia (ecology) is
needed to understand system operation. The process is an open system, creating a dynamic environment of microorganisms. The mix of organisms found in the process is
selected by the environmental conditions produced in the system and by the interactions among organisms. This selection, or enrichment, results in a rigorous culture
that may change rapidly as conditions change because of the rapid rates of growth of
microorganisms. Among the important enrichment factors found in the process are
the operational conditions such as residence time, settling, and recycling that promote
biomass separation; characteristics of the wastewater including carbon/nitrogen/
phosphorus ratios and toxicity; environmental conditions including pH, temperature,
DO concentration, and mixing intensity; and reactor configurations that may affect nutrient and DO concentrations or compositions.
An important feature of the activated-sludge microbial system is its ability to separate by gravity under quiescent conditions. This property is achieved by selecting the
culture that settles, recycling the settled sludge, and operating the process under loading conditions that will select for a flocculent culture. Similarly, if nitrification is desired, process loading, MCRT, and HRT are provided to select for the autotrophic
nitrifying organisms. Enhanced biological-phosphate uptake is achieved by selecting
appropriate populations by holding the population in an anaerobic selector.
Through design and operation, treatment objectives may be achieved by this fundamental concept of enrichment. However, not all observed enrichment reactions are
consciously selected. Bulking, or poor settling, is an example of an undesirable selection of an organism population that continues to challenge operators. Many types of
poor separation problems may arise. These include dispersed growth (no flocculation
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Activated Sludge
priate measures of the total carbonaceous demand. Long-term BOD measurements or
estimates of total oxygen demand must be provided for accurate estimates. It should
also be noted that nitrogenous oxygen demand (nitrification reactions) is often measured as a portion of BOD in analytical determinations. Addition of nitrification inhibitors may be used to separate carbonaceous and nitrogenous demand measurements, if required. Variability in oxygen demand occurs both with time and distance in
the biological reactor (often referred to as temporal and spatial variation). Sufficient
oxygenation capacity must be available to meet much of this variation if a high-quality
effluent is required and to avoid selection of undesirable microbial populations.
With a typical municipal wastewater, a well-designed and operated activatedsludge system should achieve a CBOD effluent quality of 5 to 15 mg/L. Effluent suspended solids (SS) should also typically be less than 15 mg/L. Note that effluent SS
may include a significant fraction of CBOD. To achieve consistent BOD and total suspended solids (TSS) concentrations less than 5 mg/L, some type of tertiary treatment
would be required.
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See the U.S. EPA design manual on nitrogen control (1993) for more information on nitrogen-removal processes and their performance.
Denitrification processes are temperature sensitive, decreasing with decreased
temperature. Adjustment in system MCRT may be required in colder climates to ensure adequate denitrification. The process generates alkalinity, 3.6 mg CaCO3 alkalinity/mg nitrate-nitrogen reduced. Because denitrification may reduce total process oxygen requirements, some credit for this may be taken. Theoretically, 2.86 kg oxygen
demand is satisfied per kilogram (2.86 lb/lb) of nitrate-nitrogen reduced to nitrogen
gas (U.S. EPA, 1993).
Separate-stage and single-sludge denitrification processes can both achieve high
removal of nitrogen, on the order of 85 to 95% for municipal wastewater.
BIOLOGICAL PHOSPHORUS REMOVAL. In the conventional activatedsludge process for municipal wastewater, the biomass will uptake phosphorus for
growth and metabolism in a way that approximately 2% of the biological sludge mass
on a dry weight basis is phosphorus. Phosphorus cannot be transformed to a volatile
gas, therefore its removal is achieved by sludge wasting. Thus, wasting in a conventional plant may result in 10 to 30% removal of phosphorus. The activated-sludge
process may be managed, however, to select for a population of microorganisms that
will store excessive quantities of phosphorus, in the range of 3 to 6%. Wasting of this
phosphorus-enriched sludge can result in effluent phosphorus concentrations less than
1 mg P/L.
The selection process involves an anaerobic step that results in the release of
stored phosphate followed by an aerobic step in which the organisms consume large
amounts of phosphorus. In the anaerobic phase, soluble CBOD is consumed by the
organisms and stored as organic polymers as a future source of energy. The energy
required for this storage step is provided by excess phosphorus stored as polyphosphates in the aerobic stage. As energy is released in the anaerobic phase, the phosphates are released to solution. Once entering the aerobic zone, energy is produced by
the oxidation of the stored organic carbon products and polyphosphate storage is initiated by the organism (U.S. EPA, 1987b, and WEF, 1998). There are many organisms capable of storing excess amounts of phosphorus in their cells. These polyphosphatestoring organisms are found in wastewater and can be easily selected for with proper
system design and operation.
Biological phosphorus removal (BPR) processes for activated-sludge systems will be
described below. With proper design and operation, a BPR system should produce effluent phosphorus concentrations less than 2 mg/L and often less than 1 mg/L. Because
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PROCESS VARIATIONS
The activated-sludge process has been designed in many different modifications. The
process modification selected depends on the treatment objectives, site constraints, operational constraints, client preferences, and design engineer preference and experience, among others. The process can be categorized by loading rates, reactor configuration, feeding and aeration patterns, and other criteria including numerous biological
nutrient removal (BNR) processes.
TABLE 20.1 Typical process loading ranges for the activated-sludge process.
Loading range
MCRT, d
High rate
13
Conventional
515
Low rate
2030
Volumetric loading,
kg BOD/m3
(lb BOD/1000 cu ft)
F:M, kg/kg d
(lb/lb d)
1.6016.0
(1001000)
0.320.64
(2040)
0.160.40
(1025)
0.51.5
(0.51.5)
0.20.5
(0.20.5)
0.050.15
(0.0501.5)
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be more stable and thus require less operational attention. Typically, BOD removal
efficiencies range from 75 to 95% and nitrification is complete. However, these systems
may suffer from significant excursions of effluent suspended solids because of poor
flocculation (pinpoint floc) and clarifier denitrification.
High-rate systems are often used as pretreatment processes in staged biological
treatment systems and are also used where only carbonaceous BOD removal is required. They are characterized by low oxygen requirements and somewhat higher than
normal sludge generation compared to conventional plants. The process may produce
BOD removal efficiencies over a wide range, from less than 50% to as high as 95% depending on loading rate and waste characteristic. Sludge settling can be a problem at
high loading when flocculation does not effectively occur.
Ideal Complete Mix. Ideal, completely mixed flow implies that the composition of the
mixed liquor is the same throughout the reactor volume. The influent wastewater immediately and completely mixes with the reactor contents so that the concentration of
a given component is the same as the effluent concentration. As a result, the mixed
liquor oxygen uptake rate, DO, soluble BOD, VSS, TSS, nitrogen species, phosphorus
concentrations, pH, temperature, and other characteristics are identical throughout the
reactor. Because the concentrations of BOD are at the target effluent concentrations for
the process, the system has the capability of attenuating wide swings in effluent concentration. Completely mixed flow is difficult to achieve, although the use of square or
round reactors with intense mixing can approximate the condition. As discussed later,
it can also be approximated by providing multiple feed points along the reactor periphery. Aeration is provided uniformly throughout the reactor by mechanical aeration
equipment or diffused aeration.
There are several disadvantages to completely mixed reactors. They are often
plagued by filamentous bulking problems. This can be overcome, in part, by using selectors, which provide short term conditioning of the RAS and influent wastewater
ahead of the biological reactor, (see Selectors below). Theoretically, the process also
suffers because degradation kinetics are slower than in plug-flow systems, requiring
longer reactor retention times to achieve comparable effluent quality. These systems are
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Ideal Plug-Flow. In an ideal plug-flow system, the fluid particle entering the system
will move uniformly along the reactor length without dispersing in the fluid (Figure
20.2). The particle will remain in the reactor for a time equal to the theoretical detention
time (Volume [V]/Volumetric flow [Q], V/Q). As a result, the concentration of BOD
and the oxygen uptake will decrease along the reactor length. The TSS and VSS will increase along the reactor length as biomass is produced. This type of flow is approximated by long, narrow reactors with length-to-width ratios greater than 10. Plug-flow
may also be simulated by basins-in-series or by folding rectangular reactors. Like the
complete-mix configuration, it is not practical to produce a true plug-flow system.
By definition, this configuration results in high organic load and oxygen uptake
rates at the inlet to the reactor. Oxygen-transfer devices must be capable of high mass
transfer at the inlet. Distribution of oxygen along the reactor may be tapered to follow
oxygen demand. Theoretically, the plug-flow reactor delivers the highest removal rate
per unit volume. It is also less susceptible to filamentous bulking provided that sufficient DO is present at the inlet.
Reactors-in-Series. The reactors-in-series configuration is described as two or more
completely mixed reactors operating in a series configuration. It can be approximated
with baffles or by folding reactors in a sinusoidal fashion. This configuration, with
three or more reactors-in-series, attempts to simulate a plug-flow condition that has a
kinetic advantage over mixed-flow systems as mentioned above. This configuration
also seems to mitigate filamentous bulking.
FIGURE 20.2 Plug flow activated-sludge process with folded biological reactor.
Copyright 2006 Water Environment Federation.
Activated Sludge
Sequencing Batch Reactors. A sequencing batch reactor (SBR) is a fill-and-draw activated-sludge system in which both steps of aeration and clarification take place in the
same reactor. Settling occurs when the air and mixers are turned off and a decanter
provides for the withdrawal of treated effluent. Discrete cycles are used during prescribed, programmable time intervals, and MLSS remains in the reactor during all cycles. For conventional systems, there are five steps that are carried out: fill, react, settle,
decant, and idle (Figure 20.3a). As a result of the batch nature of the process, flow
equalization and multiple reactors must be provided to accommodate continuous-flow
operation. Mixing and aeration are provided by equipment similar to that found in
conventional continuous-flow plants. Specially designed decanters are provided for effluent withdrawal. An intermittent-cycle extended-aeration system allows influent to
be fed continuously to the reactor for all cycles (Figure 20.3b), but effluent is withdrawn
intermittently.
The SBR is typically designed for small-flow applications, 4000 m3/d (1 mgd) or
less, often as extended-aeration systems. Some larger installations have been built,
however, ranging in size from 150 000 to 700 000 m3/d (40 to 185 mgd). The process is
easily adaptable to BNR by programming different sequences of cycles.
Oxidation Ditch. In the typical oxidation ditch, mixed liquor is pumped around an
oval or circular pathway by brushes, rotors, or other mechanical aeration devices and
pumping equipment located at one or more points along the flow circuit (Figure 20.4).
The mixed liquor is moved at a velocity of 0.24 to 0.37 m/s (0.8 to 1.2 ft/sec) in the
channel resulting in a circuit time of less than 15 minutes. Most oxidation ditches are
designed as low-rate processes with long HRTs (approximately 24 hours), therefore,
the cycle time is short and the hydraulic system may be considered to be completely
mixed. Ditches may be designed with a single channel or multiple interconnected concentric channels. They are widely used for small- to medium-sized communities.
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FIGURE 20.3A Typical sequencing batch reactor operation for one cycle.
Activated Sludge
sludge. Thus, the process relies on rapid uptake (biosorption) of BOD followed by a
stabilization step in which the return sludge is aerated to stabilize the sorbed organic
matter. These systems are typically designed to operate in the conventional loading
rate region (SRTs ranging from approximately 3 to 15 days). Because the RAS flow is
only approximately 40 to 70% of the forward flow rate, the total aeration volume is
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smaller than for a conventional biological reactor with equal HRT. As a result of this
modification, the capacity of an existing plant can be increased without adding new
process volume. The process has also found application in communities with high infiltration and inflow during storms. In conventional plants, high flows may wash out
sludge from the system if clarifiers are not oversized. With contact stabilization, the
reaerated sludge is isolated from forward flow and therefore remains in the system
during high-flow events.
The contact-stabilization modification, in its original form, does not provide significant nitrification and may not be effective for wastewater high in soluble BOD.
Some plants have found that the process is effective, however, when the contact time is
increased to 4 to 5 hours (often referred to as a sludge-reaeration process).
Activated Sludge
in diffused air systems, the concept can be practiced with mechanical aeration devices.
Airflow in diffused air systems to a given reactor sector can be controlled by airline
valves with uniform diffuser placement, or preferably by tapering diffuser density. Mixing requirements will typically govern the minimum airflow (or power input) rate near
the effluent end of the reactor. This modification makes most efficient use of power, provides greater operational control, and may be used to inhibit nitrification by reducing
DO concentrations in downstream sectors of the biological reactor.
Selectors. The use of a selector preceding the biological reactor has effectively controlled filamentous bulking in activated-sludge plants that experience epidemics of
poor-settling sludge. The selector may be aerobic, anoxic, or anaerobic and is normally
compartmentalized (Figure 20.7). The basic principle of using a selector is to create environmental conditions that promote the growth of bacteria that settle well over those
that do not. In brief, mixed liquors that are low in DO, or F:M, tend to favor filamentous
microorganisms that interfere with effective settling. Many of these organisms can be
put at a disadvantage if mixed liquor is subjected to periods of high F:M. Organisms with
the greatest ability to rapidly uptake soluble organic matter and store it for later use
during low concentration conditions tend to be ones that flocculate and settle better.
Selectors, because of the high organic load imposed on them, are relatively small
with short HRTs (10 to 30 minutes for aerobic selectors and somewhat longer for
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OTHER MODIFICATIONS
HIGH-PURITY OXYGEN. High-purity oxygen may be used in place of air for activated-sludge aeration. Pure oxygen is fed concurrently with wastewater in reactors that
are typically covered (Figure 20.8). Oxygen feed is controlled by maintaining constant
pressure in the closed reactors. A DO of 4 to 10 mg/L is typically maintained in the
mixed liquor. Less than 10% of the inlet oxygen vents from the last stage of the unit. In
the past, these systems were operated at high MLSS concentrations and short HRTs
thereby requiring less area for the facility. Today, these systems are typically designed
with loading comparable to those of conventional activated-sludge processes. One significant advantage for the process is that it essentially eliminates stripping potential
volatile organic compounds from the mixed liquor. Because the headspace gases are
Copyright 2006 Water Environment Federation.
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recycled, the CO2 concentrations in the gas phase are high and, as a result, alkalinity can
be consumed in the mixed liquor causing a pH decrease. This can be a problem for systems that are designed for nitrification, often requiring separate stages for CBOD removal and nitrification.
The covered reactors have provisions for warning of potential explosions that
could result from presence of combustible gases from the wastewater. Precautions are
also taken in the selection of construction materials because of the corrosive and reactive
nature of the oxygenCO2 gases.
The dissolution of oxygen into the mixed liquor is typically accomplished with
mechanical surface aerators or by submerged sparged turbine systems. The three types
of oxygen separation devices in use today are the cryogenic air-separation process,
pressure swing adsorption (PSA), and vacuum swing adsorption (VSA). The PSAsystem has been used in the past and remains in some plants, but the VSA is a more
cost-effective system today (WEF, 1998).
COUPLED SYSTEMS. To enhance performance and increase the capacity of biological reactors, the practice of adding inert support media to the biological reactor was
developed decades ago. The inert media supports a fixed-growth biomass that augments the mixed liquor microbial population. The early application used panels of asbestos sheeting placed in the biological reactor. More recent application includes the
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COMBINED SYSTEMS. Most combined systems use a fixed-growth process in series with a suspended-growth system. Typically, the combined system includes a
biotower and a biological reactor or aerated channel. Occasionally a rotating biological
contactor process may be used as the fixed-growth system. Combined systems are
used when designers attempt to compensate for weaknesses of one of the systems by
combining the two. For example, fixed-growth processes are known to resist shock
loads and provide low maintenance requirements. By combining this with activated
sludge, a process known to produce high-quality effluents with the ability to be operated under a variety of different modes, designers have found that the overall system
can achieve a high degree of treatment for certain wastewaters and environmental
constraints.
A number of processes are currently used in the U.S. and may be categorized into
two groups: those that have low to moderate organic loading to the fixed-growth reactor and those with high organic loads (roughing filters). Figure 20.9 illustrates alternative methods for returning RAS or reaeration that are common practices for combined
systems. Terms used to distinguish process modes are also presented. The commonly
used combined systems include activated biofilter, tricking filter/solids contact, rough-
FIGURE 20.9 Schematic flowsheet for combined processes (BF = biofilter, RAS = return
activated sludge, and WAS = waste activated sludge).
Copyright 2006 Water Environment Federation.
Activated Sludge
ing filter/activated sludge, biofilter/activated sludge, and trickling filter/activated
sludge. Details about these systems can be found in WEF (1998).
Single-Sludge Ammonia Oxidation. For ammonia oxidation, the single-sludge system employed achieves both CBOD removal and ammonia oxidation (Figure 20.10).
Referred to as a single-stage nitrification process, this system is being used more frequently in the U.S. because of its simple design, ease of operation, and lower capital
costs. The biological reactor can be designed as a conventional plug-flow, completely
mixed, contact-stabilization, step-feed, or oxidation-ditch configuration. To achieve nitrification, higher MCRTs are required to ensure adequate nitrifier populations.
FIGURE 20.10
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Single-Sludge Nitrogen Removal. For nitrogen removal, which requires that nitrification precedes denitrification, several single-sludge systems have been used. One of the
most simple and widely used processes is the LudzackEttinger process (Figure 20.11)
which provides an anoxic zone that precedes an aerobic zone. The RAS is directed to the
anoxic zone where it mixes with influent wastewater that serves as the organic carbon
source for denitrification. In a modification, mixed liquor is pumped from the aerobic
zone back to the anoxic zone. The Wuhrmann, or postdenitrification process (Figure
20.12), provides aerobic treatment followed by an anoxic zone. Organic carbon must be
added to the anoxic process (either as an organic supplement, such as methanol, or by
bypassing some influent wastewater directly to the anoxic zone), or endogenous carbon
must be relied on in the anoxic zone. In the single-stage, conventional system, effective
denitrification may be achieved by alternating aeration (on and off) in the biological reactor or oxidation ditch.
Another single-sludge process incorporates four stages in the Bardenpho
process (Figure 20.13). An anoxic zone precedes an aerobic zone followed by an additional anoxic and aerobic zone. The RAS is cycled to the first anoxic zone and mixed
liquor is recycled from the first aerobic zone to the first anoxic zone. The second aerobic zone is used primarily to strip nitrogen gases from the process and to prevent phosphorus release in the clarifier. This process produces a higher removal of nitrogen as
compared with the two-stage processes above. To succeed, however, it depends on the
oxidizable nitrogen-to-carbon ratio in the influent wastewater (WEF, 1998).
The oxidation ditch configuration has also been used for nitrificationdenitrification. To succeed, these systems must be designed and operated to provide sufficient
anoxic volume upstream of the aeration device. Simultaneous nitrificationdenitrifica-
FIGURE 20.11 Modified LudzackEttinger process for nitrogen removal (WAS = waste
activated sludge).
Copyright 2006 Water Environment Federation.
Activated Sludge
FIGURE 20.12 Wuhrmann process for nitrogen removal (RAS = return activated sludge
and WAS = waste activated sludge).
tion also occurs in these systems. Typically, in the oxidation ditch the rates of removal
are low because of the relatively long SRTs required for nitrification, the low concentrations of CBOD, and the marginal concentrations of DO for nitrification. A large mass
of mixed liquor in the system compensates for this low rate, however. Performance can
be highly variable.
Sequencing batch reactors also find application as a single-sludge nitrogen removal alternative. To obtain nitrogen removal, fill-and-react phases are subdivided
into static fill, mixed fill, and mixed react. Carbon oxidation and nitrification occur in
the aeration phase, while denitrification takes place in the anoxic fill-and-react phases.
Organic carbon for denitrification is available at the beginning of each cycle.
FIGURE 20.13 Four-stage Bardenpho process for nitrogen removal (WAS = waste
activated sludge).
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FIGURE 20.14 A/O process (RAS = return activated sludge and WAS = waste
activated sludge).
Copyright 2006 Water Environment Federation.
Activated Sludge
FIGURE 20.15
PhoStrip process.
then pumped to the anaerobic reactor in which it mixes with influent wastewater. These
side stream fermenters can be incorporated in the primary clarifier, or may be separate
unit processes. Occasionally, sufficient acids are produced from primary sludge gravity
thickeners.
An SBR may also be used to biologically enhance phosphorus removal. Biological
removal will occur when the operating cycle includes an anoxic period to eliminate nitrates and an anaerobic period to induce phosphorus release. Further removal by chemical precipitation may be needed if low effluent phosphorus concentrations are required
because of presence of some residual nitrate. Typically, the cycle will be fill, anaerobic
stir, aerobic mix, anoxic stir, settle, and decant.
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FIGURE 20.16
sludge).
The UCT process and its modifications were developed to reduce the effect of RAS
nitrates on the anaerobic stage. In this three-stage process, RAS is returned to the
anoxic stage and mixed liquor is recycled from the aerobic stage to the anoxic stage and
from the anoxic stage to the anaerobic stage (Figures 20.18a and b). In a modification of
the process, the anoxic stage is subdivided into two compartments so that RAS is
cycled to the first and internal recycle of mixed liquor flows to the second. Internal re-
FIGURE 20.17 Modified Bardenpho process for phosphorus and nitrogen removal
(WAS = waste activated sludge).
Copyright 2006 Water Environment Federation.
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FIGURE 20.18A University of Cape Town and VIP processes for phosphorus and
nitrogen removal (WAS = waste activated sludge).
cycling of anoxic mixed liquor comes from the first compartment. This configuration
was proposed to reduce the HRT in the anoxic reactor.
The VIP is similar in configuration to the UCT process. The significant differences
are that the VIP uses multiple, completely mixed series compartments for the anoxic
zone and the process operates at a shorter SRT than the UCT process (5 to 10 days versus 13 to 25 days).
In PhoStrip II, denitrification is accomplished by adding an anoxic prestripper
ahead of the anaerobic phosphorus stripper for the RAS stream. Sufficient SRT is provided in the aerobic compartment for nitrification.
The SBR process can remove both nitrogen and phosphorus by proper selection of
the cycles and cycle times. The seven cycles often used for this purpose are static fill,
mixed fill, anaerobic react, aerobic react, anoxic react, settle, and decant. Chemical precipitation of phosphorus may be required if low concentrations of phosphorus are desired because of the presence of residual nitrate in the system.
FIGURE 20.18B Modified University of Cape Town process for phosphorus and nitrogen
removal (WAS = waste activated sludge).
Copyright 2006 Water Environment Federation.
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MULTIPLE-SLUDGE SYSTEMS. Multiple-sludge systems, in contrast to singlesludge systems, isolate sludges for separate treatment tasks. These systems may involve two or three separate sludges. These configurations are used for nitrification and
nitrogen-removal objectives. In these systems, fixed-growth processes may be used in
one or both stages of the process.
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In a third process, the anoxic system precedes the aerobic system, thus providing
sufficient BOD for denitrification. An additional recycle stream supplies nitrate to the
anoxic system. Some bleed-through of nitrate will occur in this process depending on
flow rates of the recycle streams.
A triple-sludge system is designed with separate carbon oxidation, nitrification,
and denitrification processes and three separate clarifiers. This system is seldom used
and suffers from disadvantages of adding exogenous carbon, high capital cost, and operational complexity.
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AERATION SYSTEMS. The supply of oxygen to the biological reactor represents the
largest single energy consumer in the activated-sludge facility (50 to 90%). Over the years,
oxygen-transfer equipment has evolved to a point where engineers have a wide selection
of efficient equipment to meet the needs of all types of facilities. Oxygen-transfer devices are used not only to supply oxygen to the process but also to mix the aerobic compartments of the reactor. Typically, there are two types of aeration devices, diffusedaeration systems and mechanical-aeration systems. Each will be discussed below.
Diffused Aeration. Diffused aeration is defined as the injection of air or oxygen below the liquid surface. The air or oxygen is supplied by low-head blowers with pressures typically up to 210 kPa absolute (30 psia) or 105 kPa gauge (15 psig). Hybrid
devices, including jets and u-tube aerators, which combine gas injection with mechanical pumping or mixing, are also included in this category.
Diffusers include both porous and nonporous devices. Details about these devices
can be found in WEF (1998). The porous diffusers, often referred to as fine-pore or finebubble diffusers, are highly efficient and are currently the most widely used of the
diffused-air systems. They are typically produced from ceramic materials, porous plastics, or perforated membranes. Nonporous systems include an array of diffusers that
have larger orifices ranging from holes in pipes to specially designed valved orifices. Diffusers are placed near the floor of the biological reactor and may be configured in a grid
arrangement, along one or both longitudinal sides. Air is delivered in a piping system
from the blowers to downcomers that carry the air down to headers along the bottom
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of the reactor. Valves in the air system are used to control airflow to individual reactors or sectors of reactors. Diffusers may be placed in uniform densities or arranged in
tapered configurations. The diffuser type, pattern of diffuser layout, reactor geometry,
submergence, and airflow rate all influence oxygen-transfer performance. Maintenance of porous diffusers is greater than for the large-orifice diffusers. Clogging and
fouling of the fine pores requires occasional cleaning, which can be provided by automatic gas-cleaning systems in situ or by draining the reactors and cleaning with highpressure hosing or acid spritzing (WEF, 1998).
AIR DELIVERY. The three basic components of the air-delivery system are air filters
or conditioners, blowers, and piping. Air filters remove particulates such as dust from
the inlet air to the blowers and protect both the blowers and diffusers from mechanical
damage or clogging. The degree of air cleaning depends on the inlet air quality, the
type of blower, and the diffusers.
Today, many types of dynamic or positive displacement (PD) blowers are used.
The dynamic, or centrifugal, blowers which are considered constant-pressure machines,
are the most efficient and easiest to operate at variable airflow rates, are quieter than
PD blowers, and require less maintenance. Their disadvantages include a limited operating pressure range and reduced delivered air volumes with any increase in backpressure caused by diffuser clogging. The PD blower is a constant-volume device capable of operating over a wide range of discharge pressures. They have a lower initial
cost and require relatively simple control procedures. More details on blowers can be
found in WEF (1998), U.S. EPA (1989) and WPCF (1984).
Each is widely used and has distinct applications. Surface aerators are typically
float, bridge, or platform mounted and some may be equipped with submerged draft
tubes for deep reactor applications. The radial low-speed aerators have gained increased
use recently and are considered good mixing devices that are more efficient than highspeed aerators. Axial flow, high-speed aerators are typically used in stabilization lagoons
where dispersed growth is found and shearing of biological floc is not an issue. They also
may suffer from freezing problems in cold climates. Aspiration devices use a motor-driven
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Mixing. In the activated-sludge process mixing is important for maintaining the MLSS
in suspension. In most applications, the aerators serve as both oxygen-transfer devices
and mixers. Except at the effluent end of plug-flow reactors, oxygen requirements typically control aerator design and operation. However, at the effluent end of plug-flow reactors and in some low-loaded, completely mixed systems, mixing may be the controlling factor, especially during low-flow conditions. In most cases the aeration system is
used for mixing in these situations, however, use of low-speed, submerged-propeller,
horizontal mixing devices (such as banana blade mixers) to move mixed liquor horizontally along the reactor is another option. A combination of this mechanical mixing with
aeration may result in significant power savings when mixing controls the process.
For mixing anoxic and anaerobic compartments of biological reactors, both submerged propeller or turbine mixers have been used. These devices mix without breaking the water surface and are capable of maintaining biological solids in suspension at
minimal energy inputs. The number and placement of these units is critical to effective
suspension of MLSS.
CLARIFICATION. Separation of MLSS from the liquid stream is vital to the operation and performance of activated-sludge systems. This is typically achieved by gravity
separators, although recently some work has been done with membranes. Clarification
not only separates the MLSS but in some situations may be designed to thicken the settled sludge before returning it to the aeration process or to wasting (WAS).
Clarifier shapes include rectangular, square, circular, and others, such as hexagonal or octagonal. There seems to be no observable difference in performance at average
or peak flow because of shape alone (WEF, 1998). Sludge is typically removed by
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chain-and-flight collectors in rectangular clarifiers. Hydraulic suction using floatingor bridge-mounted mechanisms has been used. Circular clarifier mechanisms with hydraulic pickups use mechanical seals to allow continuous solids withdrawal. Mechanical plows are also used on these rotary collectors. Interchannel clarifiers have been
used in some small-flow oxidation ditch applications. A clarifier is installed directly in
the ditch, thereby eliminating the need for a separate clarifier. Scum and sludge are returned directly to the ditch by hydraulic means.
Clarifier depth continues to be a debated issue relative to its importance in performance. There are many factors that will affect the selection of depth including clarifier
diameter, collector characteristics, sludge withdrawal point, and inlet design. Typically, minimum clarifier depths of 3.7 to 4.6 m (12 to 15 ft) are recommended. Deeper
clarifiers may be desired for large-diameter clarifiers, but no deeper than 4.6 to 5.0 (15
to 16 ft). Clarifier performance also depends on solids loading rate, surface overflow
rate, inlet design, effluent weir arrangement, and settling characteristics of the MLSS.
Clarifier performance and characteristics are reviewed in WEF (1998), WEF (2005), and
Ekama et al. (1997).
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REFERENCES
Ekama, G.A.; Barnard, J.L.; Gnthert, F.W.; Krebs, P.; McCorquodale, J.A.; Parker, D.S.;
and Wahlberg, E.J. (1997) Secondary Settling Tanks: Theory, Modelling, Design and Operation. Int. Assn. Water Qual., Sci. Tech. Rep. Ser., London.
Jenkins, D.; Richard, M.G.; and Daigger, G.T. (1993) Manual on the Causes and Control of
Activated Sludge Bulking and Foaming. 2nd Ed., Lewis Publishing, Chelsea, Mich.
U.S. Environmental Protection Agency (1987a) Summary ReportThe Causes and Control
of Activated Sludge Bulking and Foaming. EPA-625/8-87-012, Office of Research and
Development, Washington, D.C.
U.S. Environmental Protection Agency (1987b) Design ManualPhosphorus Removal.
EPA-625/1-87-001, Center for Environmental Research Information, Cincinnati, Ohio.
U.S. Environmental Protection Agency (1989) Design ManualFine Pore Aeration Systems. EPA-625/1-89-023, Center for Environmental Research Information, Cincinnati, Ohio.
U.S. Environmental Protection Agency (1993) ManualNitrogen Control. EPA-625/
R-93-010, Office of Research and Development, Office of Water, Washington, D.C.
Water Environment Federation (1998) Design of Municipal Wastewater Treatment Plants.
Manual of Practice No. 8, 4th Ed., Water Environment Federation: Alexandria, Va.
Water Environment Federation (2005) Clarifier Design, 2nd Ed.; Manual of Practice
No. FD-8; McGraw-Hill: New York.
Water Pollution Control Federation (1984) Prime Movers. Manual of Practice No. OM-5,
Washington, D.C.