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Outline
References
1. Malina J.F. & Pohland F.G., Design of Anaerobic Process for
the Treatment of Industrial and Municipal Waste
(TD755.D457)
2. Grady C.P. & Lim H.C., Biological Wastewater Treatment
(TD755G733)
3. Wheatley A, Anaerobic Digestion: a Waste Treatment
Technology (TD796.5.A532)
4. Kiely G., Environmental Engineering , 1997, Irwin/McGrawHill
5. Prof. Bungays Website
Temperature
pH
Alkalinity
Wastewater Concentration
Temperature of Wastewater
Higher temperature, shorter digester retention time
As low as 8 C
Mesophilic (30-40 C)
See Table 2.5 & 2.6. Compare known concentration with table
and assess if process inhibition a serious problem
pH:
Toxicity:
Rapidity of Changes:
Loading:
Is the mass of organic matter added per unit volume per unit
time
Given, loading should not exceed 6.4kgVS/m3/day
Secondary treatment
i.
ii.
iii.
pH
Toxicity
Treatment Efficiency
Loading
Application Ranges:
< 50mg/l COD carbon absorption
50 4000mg/l COD Aerobic Digestion
>4000mg/l COD Anaerobic Digestion High Rate/Low Rate
> 50,000mg/l COD Evaporation & Incineration, Wet Combustion
Process Design
Operations Monitoring & Problems
Basically:
Suspended growth- good for
wastewater containing high
concentration of particulate
biodegradable material
Supported growth- wastewater
containing mainly soluble
organics
Hybrid - for intermediate
levels of particulates
Gas Production
Tank Configuration
Mixing Systems
Heating Systems
Design criteria:
Want retention time of sludge sufficient to achieve the
specific reduction in volatile solids content (digestion) in the
digested sludge.
This degree of digestion depends on the ultimate disposal of the
digested sludge (more later). Also the organic loading rate, ie the
concentration of solids in the feed controls the volume of the
reactor.
Basically,
b) SRT:
The reactor:
Typically cylindrical with diameters of 5 to 50m and heights 3 to
25m made of steel. Bottom slopes (min 6:1) to the centre to
concentrate digested sludge.
Europe likes the eggs-shaped digesters.
See Figure 5.10 & 5.12
Once reactor is sized, heating and mixing system are
considered.
Mixing Configuration:
Some natural mixing from rising gas and thermal convection
currents.
Figure 4.2 (Ref 3)
Required to:
Basic methods:
recirculation of sludge
recirculation of gas through sludge
Heating Configuration:
Important to maintain temperature as constant as possible. Sharp
fluctuation detrimental for methane forming bacteria especially.
Fluctuation kept to +/- 1 C/day.
Optimum growth temperature range.
More costly for the thermophilic range.
Fouling a problem, heat exchangers must be cleaned regularly.
High concentration of solids, heating requirement reduced from
less water.
Basic methods:
direct combustion
CO2 content
Alkalinity:
From the carbonic acid-CO2 system.
Indicate buffering capacity of system. Higher alkalinity, more stable
pH and tolerance to fluctuation in volatile acid concentration.
Volatile acid should be low < 100mg/l (Ref 3), normal 200400mg/l (Ref 4) Mainly acetic acid if stable. Stressed digester
butyric and propionic will increase. Some volatile acid can be
inhibitory.
pH at 7.0 maintained
Causes of Imbalance
Incinerated