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65.3
2012
ABSTRACT
In this study of coagulation operation, a comparison was made between the optimum jar test values
for pH, coagulant and coagulant aid obtained from traditional methods (an adjusted one-factor-at-atime (OFAT) method) and with central composite design (the standard design of response surface
methodology (RSM)). Alum (coagulant) and polymer (coagulant aid) were used to treat a water source
with very low pH and high aluminium concentration at Sri-Gading water treatment plant (WTP)
Malaysia. The optimum conditions for these factors were chosen when the nal turbidity, pH after
coagulation and residual aluminium were within 05 NTU, 6.57.5 and 00.20 mg/l respectively.
Traditional and RSM jar tests were conducted to nd their respective optimum coagulation conditions.
It was observed that the optimum dose for alum obtained through the traditional method was 12 mg/l,
while the value for polymer was set constant at 0.020 mg/l. Through RSM optimization, the optimum
dose for alum was 7 mg/l and for polymer was 0.004 mg/l. Optimum pH for the coagulation
operation obtained through traditional methods and RSM was 7.6. The nal turbidity, pH after
coagulation and residual aluminium recorded were all within acceptable limits. The RSM method was
demonstrated to be an appropriate approach for the optimization and was validated by a further test.
Key words
INTRODUCTION
Coagulation is one of the most important processes in water
treatment. It is an effective method for the removal of colloidal particles in surface water. Many researchers have
applied the coagulation process to treat highly turbid
water (Lin et al. ) and natural organic matter (NOM)
(Zhan et al. ) present in surface water. The process is
also capable of removing arsenic (Hering et al. ) and
residual aluminium (Brub & Dorea ) from drinking
water. As a coagulation process has the ability to eliminate
many pollutants from surface and drinking water, the success of the process has a direct impact on the reliability of
treatment plant operations and nal water quality.
The effectiveness of the coagulation process is
highly dependent on many factors, including dosage of coagulant and coagulant aids and also pH of the operation
(Amirtharajah & OMelia ). By far, the most common
doi: 10.2166/wst.2012.561
497
M. Zainal-Abideen et al.
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M. Zainal-Abideen et al.
498
Materials
Alum (liquid aluminium sulphate) and polymer (Nalclear
8173 PULV) respectively were used as the coagulant and
coagulant aid at Sri-Gading WTP. To adjust the raw water
pH to the desired pH, hydrated lime was used. Both alum
and hydrated lime used were obtained from Damini Corporation, Malaysia while polymer was delivered from Usaha
Kimia (Malaysia).
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2012
Experimental setup
Traditional jar test
Raw water sample collected from Sri-Gading WTP was
brought to Universiti Teknologi Malaysia (UTM). This
sample was used to carry out traditional and statistical
designed (CCD RSM) jar test experiments at a bench
scale. Characterization of water quality was carried out in
accordance with Standard Methods (APHA et al. ).
Table 1 summarizes the water quality for the raw water
sample.
Before proceeding to the jar test experiment (conducted
using a Chemix Floc-Tester Model CL-4), the initial pH of
the water sample was adjusted by utilizing 1% hydrated
lime solution. Jar test mixing speeds and time were set according to the WTP practice: rapid mixing of one minute at
200 rpm; rapid mixing for 2 min at 100 rpm; slow mixing
for 3 min at 50 rpm; slow mixing of 10 min at 25 rpm; settling
time of 30 min. Alum, followed by polymer, was added at the
start of the fast (200 rpm) mixing stage. The ranges of initial
pH, alum and polymer concentration used in the jar tests
are explained below in the traditional jar test and RSM jar
test subsections.
Following the 30 min settling period, the pH of the solution was measured with a pH meter (model 410, Thermo
Orion) and samples were withdrawn 2 cm below the water
surface by using a 25 ml glass pipette (Hirschmann,
Germany). Samples were taken for turbidity and residual
aluminium analysis. Turbidity was determined by a turbidity
meter (HI 93703, Hanna Instrument). Residual aluminium
was measured through Aluminon method (adapted from
Standard Methods) using a spectrophotometer (DR 5000,
Hach Company, USA).
Table 1
Water quality parameters for raw water sample from Sri-Gading WTP
W
pH
Turbidity (NTU)
Colour (TCU)
Fe (mg/l)
Al (mg/l)
Temperature ( C)
Mn (mg/l)
NH3 (mg/l)
TDS (mg/l)
4.04
5.46
30
0.52
1.75
22.6
0.07
0.15
87
M. Zainal-Abideen et al.
499
Table 2
Table 4
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2012
CCD and response results for the study of three experimental variables in coded
units
Factors
Responses
Factors
Residual
Run
Responses
Alum
Initial
Polymer
Turbidity
Settling
aluminium
(mg/l)
pH
(mg/l)
(NTU)
pH
(mg/l)
Run
2
Turbidity
Settling
Residual
(NTU)
pH
aluminium (mg/l)
1.17
7.00
0.18
7.6
0.02
0.23
6.59
0.11
10
7.6
0.02
0.00
6.64
0.11
0.71
6.73
0.07
12
7.6
0.02
0.00
6.80
0.12
1
0.63
6.70
0.31
14
7.6
0.02
0.42
6.62
0.14
2
0.13
6.79
0.09
16
7.6
0.02
0.29
6.87
0.14
1
1.07
6.64
0.26
18
7.6
0.02
0.28
6.64
0.13
2
1.80
6.33
0.14
1.26
6.58
0.17
1.03
6.68
0.07
0.72
6.67
0.08
10
1
1
0.00
6.71
0.14
11
1.05
6.82
0.19
12
1
1
0.61
6.74
0.13
13
0.64
6.75
0.08
14
1.00
6.77
0.10
15
1
0.87
6.88
0.16
16
1
1
1
0.90
7.13
0.11
17
1
1
0.71
6.99
0.19
18
0.61
6.72
0.09
Table 3
2
1
15.5
B, initial pH
6.5
6.9
7.5
24
8.1
30
8.5
0.004
0.01
0.016
0.02
M. Zainal-Abideen et al.
500
Table 5
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Model
F value
Response
Prob > F
LOF
Prob > F
R2
Adjusted R 2
AP
SD
CV
PRESS
Turbidity
3.82
0.0455
0.1164
0.3376
0.2493
6.034
0.35
41.66
2.44
Settling pH
5.63
0.0096
0.0050
0.5469
0.4499
8.040
0.13
1.92
0.44
Residual aluminium
6.03
0.0059
0.2995
0.8085
0.6744
6.696
0.35
12.30
5.05
LOF: lack of t; AP: adequate precision; SD: standard deviation; CV: coefcient of variation; PRESS: prediction error sum of squares.
1
p 3:42 0:084A 0:050B 0:012C 0:42AB
Residual Al
0:22BC 0:40A2 0:36B2
501
Figure 1
M. Zainal-Abideen et al.
Design-expert plot; predicted vs. actual values plot for (a) turbidity, (b) settling pH, (c) 1=
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2012
p
Residual aluminium of coagulated water sample through RSM jar test.
Figure 2
Design-Expert plot; overlay plot for optimal region at polymer 0.004 mg/l.
M. Zainal-Abideen et al.
502
Table 6
Optimal conditions
Response
Predicted
Measureda
A 7 mg/l; B 7.6;
C 0.004 mg/l
Turbidity
(NTU)
0.64
0.83 0.20
Settling pH
7.00
7.21 0.02
Residual
aluminium (mg/l)
0.13
0.15 0.04
The measured values are expressed as means standard deviations of three indepen-
dent experiments.
the RSM jar test, both methods gave water turbidity below
1 NTU. The pH values after ocs settlement acquired
through both methods were lower than their initial pH settings and met the optimum condition. The residual
aluminium concentrations from both traditional and RSM
jar tests were below 0.20 mg/l.
CONCLUSIONS
The quest for optimum coagulation operational pH, alum
and polymer dosages through RSM has been successful. It
proved that the RSM jar test generated lower optimum
alum and polymer dosages than the traditional jar test and
was still able to produce comparable and acceptable quality
of coagulated water in terms of pH after ocs settlement, turbidity and residual aluminium. The interaction between
these factors and responses in coagulation process were
clearly demonstrated through RSM.
RSM jar testing requires a greater number of runs compared with the adjusted OFAT or traditional jar test. Should
the actual OFAT jar test is be implemented at Sri-Gading
WTP, similar number of runs may have to be conducted as
the polymer dosing and the initial pH for coagulation
must also be varied. Nevertheless, the purpose of this investigation is not to replace the traditional jar test by RSM but is
a part of an investigation to form an empirical relationship
between raw water quality parameters and the best coagulation conditions obtained through traditional and RSM
methods in term of pH and chemical dosing.
ACKNOWLEDGEMENTS
The authors thank Syarikat Air Johor (Holdings) Sdn. Bhd.
for providing nancial support and giving permission to
work with Sri-Gading WTP in order to carry out this study
successfully.
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2012
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