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Sulphide ion
3p
3s,3p
3p
3s,3p
3. A graph of second ionization energies of eight elements in the Periodic Table is shown below.
[Faraday constant is 9.65x104 Cmol-1; 1 mole of gas occupies 24.4 dm3 at room temperature]
A. 19.0cm3
B. 37.9 cm3
C. 75.9 cm3
D. 98.1 cm3
5. The standard enthalpy changes,H for several reactions are shown below.
Reaction
Ho/Kj
-286
-1560
-1299
-157
The value of the enthalpy change for the reaction CH CH (g) + H2 (g) CH2 CH2 (g) is
A.
B.
C.
D.
-132 kJ
-154kJ
-468kJ
-3302kJ
16 (a) A diaphragm cell used in the commercial electrolytic production of chlorine and sodium hydroxide is
shown below.
b)
(i)
(ii)
(iii)
Explain why the level of brine in the anode compartment is made higher.
_________________________________________________________________________________
________________________________________________________
(1 mark)
The chlorine gas is collected separately from sodium hydroxide that is formed at the cathode
compartment to prevent a reaction that will occur. Write a balanced equation for the reaction that occurs
when chlorine and sodium hydroxide react at room conditions.
________________________________________________________________________ (1 mark)
c)
(3 marks)
17. Each of three elements X,Y and Z is one of the Period 3 elements-Na, Mg ,Al, Si or P.
ACS /NH
a)
The oxide of element X has high melting point and reacts readily with water.
(i) Identify element X.
________________________________________________________________________ (1 marks)
(ii) Write an equation for the reaction of the oxide of X with water.
________________________________________________________________________ (1 marks)
b)
The oxide of element Y is amphoteric and has very high melting point.
(i) Identify element Y.
________________________________________________________________________
________________________________________________________________________ (1 marks)
(ii) Write equations to illustrate the amphoteric properties of the oxide of Y.
________________________________________________________________________
________________________________________________________________________
c)
(2 marks)
The oxide of element Z has very high melting point. This oxide is an acidic oxide that is insoluble in
water.
(i) Identify element Z.
________________________________________________________________________
________________________________________________________________________
(1 marks)
(ii) What can you deduce about the structure of the oxide of Z?
________________________________________________________________________
________________________________________________________________________
(1 marks)
(1 marks)
SECTION C :[30MARKS]
Answer any TWO questions in this section.
18 a) The standard enthalpy change of reactions for carbon and lead are as follows:
(g) + CO2(g) 2CO (g)
ACSC/NH
172 kJ mol
H=+
-1
H=- 159 kJ
Using the respective values of Hfor the above reactions,explain the relative stability of the oxidation
states of the elements in Group 14 of the Periodic Table.
(4 marks)
b) The Group 14 elements form tetrachlorides MCl4. Discuss the hydrolysis of the
tetrachlorides of the Group 14 elements.
(6 marks)
c) The halogens react with hydrogen to form their respective hydrogen halides.
(i) State the variation of reactivities of the halogens with hydrogen.
(ii) The table below shows the bond energies of the hydrogen halides.
Hydrogen
Halide
Bond
energy(kJmol-1)
( 1marks)
HF
HCl
HBr
HI
+562
+431
+366
+299
Explain the thermal stabilities of the hydrogen halides based on bond energy.
(4marks)
19.a) Glucose, C6H12O6 is a monosaccharide that provides energy in our body. The standard
enthalpy of formation of carbon dioxide, water and glucose are -393.5kJ mol-1,-285.55kJ
mol-1 and -1262.85kJ mol-1 respectively.
i.
Define standard enthalpy of combustion of glucose.
(1marks)
ii.
Draw a labelled energy level diagram related to the enthalpies given above and calculate the
standard enthalpy of combustion of glucose.
(8marks)
b)When 0.0250 mol benzoic acid is burned completely in a bomb calorimeter, the
temperature of the water in the calorimeter increases by 14.4C. Complete combustion of
0.0340 mol 1-propanol in the same bomb calorimeter causes a temperature increase of
12.2C. Calculate:
i.
ii.
20. Lithium, sodium and potassium are elements in Group 1 of the Periodic Table.
a) Explain the ionisation energy trend for lithium, sodium and potassium when going down Group 1.
(5marks)
b) Lithium and sodium burned in oxygen to form products of oxide.
ACS /NH
i.
By writing balanced chemical equations, name the oxides formed from the reaction of and
compare the reactivity of lithium and sodium with oxygen.
(6marks)
ii.
Oxide of lithium and sodium when dissolved in water, formed colourless solutions that
turned purple on universal indicator. Explain these observations.
(4marks)
ACS /NH