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Section 17 - Summary of Minimum Requirements

17-1

Section 17
Summary of Minimum Requirements
Mixtures of noxious liquid substances presenting pollution hazards only and which are provisionally assessed under
regulation 3(4) of Annex II of MARPOL 73/78, may be carried under the requirements of this Section applicable
to the appropriate position of the entry in this Section for noxious liquids not otherwise specified (n.o.s.)
Explanatory Notes
UN Number
(column b)

The number relating to each product shown in the recommendations proposed by the United
Nations Committee of Experts on the Transport of Dangerous Goods. UN numbers, where
available, are given for information only.

Pollution Category
(column c)

The letter A, B, C and D means the pollution category assigned to each product under Annex II
of MARPOL 73/78.
I means the product was evaluated and found to fall outside the categories A, B, C or D. A blank
indicates that the product has not yet been evaluated.
Pollution category in brackets indicates that the product is provisionally categorized and that
further data are necessary to complete the evaluation of their pollution hazards. Until the hazard
evaluation is completed, the pollution category assigned is used.

Hazards
(column d)

S means that the product is included because of its safety hazards;


P means that the product is included because of its pollution hazards; and
SPmeans that the product is included because of both its safety and pollution hazards.

Ship Type
(column e)

1
2
3

=
=
=

Ship type 1 (2.1.2)


Ship type 2 (2.1.2)
Ship type 3 (2.1.2)

Tank Type
(column f)

1
2
G
P

=
=
=
=

independent tank (4.1.1)


integral tank (4.1.2)
gravity tank (4.1.3)
pressure tank (4.1.4)

Tank Vents
(column g)

O
C
SR

=
=
=

open venting
controlled venting
safety relief valve

Tank Environmental Inert =


Pad =
Control 1)
D
=
(column h)
V
=

inerting (9.1.2.1)
padding, liquid or gas pad (9.1.2.2)
drying (9.1.2.3)
ventilating, natural or forced (9.1.2.4)

Electrical Equipment T1 to T6
IIA, IIB or IIC
(column i)
NF

=
=
=
=
=

temperature classes 2)
apparatus groups 2)
non-flammable product (10.1.6)
flashpoint not exceeding 60 /C
(closed cup test) (10.1.6)
flashpoint above 60 /C
(closed cup test) (10.1.6)

1)

indicates nil requirements

2)

Temperature classes and apparatus groups as defined in International Electrotechnical Commission Publication 78 (part 1, appendix
D, part 4, 8 and 12). A blank indicates that data are currently not available.

17-2

Section 17 - Summary of Minimum Requirements

Gauging
(column j)

O
R
C
I

=
=
=
=

open gauging (13.1.1.1)


restricted gauging (13.1.1.2)
closed gauging (13.1.1.3)
indirect gauging (13.1.1.3)

Vapour Detection 1)
(column k)

F
T

=
=

flammable vapours
toxic vapours

Fire Protection
(column l)

A
B

=
=

C
D

=
=

alcohol-resistant foam or multi-purpose foam


regular foam, encompasses all foams that are not of an alcohol-resistant
type,including fluoroprotein and aqueous-film-forming foam (AFFF)
water-spray
dry chemical

Dry chemical powder systems, when used, may require an additional water system for boundary
cooling. This is normally provided in sufficient quantities by the standard fire main system
required by regulation II-2/4 of the 1974 SOLAS Convention as amended.
Materials of
Construction
(column m)

N
Z
Y

=
=
=

see 6.2.2
see 6.2.3
see 6.2.4

A blank indicates no special guidance given for materials of construction.


Respiratory and Eye X
Protection 1)
(column n)
Flashpoint
(column r)

1)

Equipment required (see 14.2.8)

Values in ( ) are open cup values, all other values are closed cup values.

=
non-flammable product

indicates nil requirements

Section 17 - Summary of Minimum Requirements

17-3

Footnotes, used in the following table


*1)

For mixtures containing no other components with safety hazards and where the pollution category is C or less.

*2)

In case of a specific n.o.s. cargo assessed as falling within this n.o.s. group that is carried on a ship, this entry,
including the cargos trade name and one or two principle components, should be provided in the shipping
document. Abbreviations used mean:
N.F.

Flashpoint exceeding 60 /C (closed cup test)

F.

Flashpoint not exceeding 60 /C (closed cup test)

n.o.s.

Not otherwise specified

S.T.

Ship type

Cat.

Pollution category

m.p.

Melting point

*3)

For high viscosity or high melting point cargoes.

*4)

Only certain alcohol resistant foams are effective for this product.

a)

Ammonia aqueous (28 % or less)


Applies to ammonia aqueous, 28 % or less but not below 10 %.

b)

Diphenyl methane diisocyanate


Polymethylene polyphenyl isocyanate
If the product to be carried contains flammable solvents such that the flashpoint does not exceed 60 /C (closed cup
test), then special electrical systems and flammable vapour detector are to be provided.

c)

Diphenylmethane diisocyanate
Toluene diisocyanate
Trimethylhexamethylene diisocyanate (2,2,4- and 2,4,4-isomers)
Although water is suitable for extinguishing open air fires involving chemicals to which this footnote applies, water
is not allowed to contaminate closed tanks containing these chemicals because of the risk of hazardous gas
generation.

d)

Formaldehyde solutions (45 % or less)


UN number 1198 only applies if the flashpoint does not exceed 60 /C (closed cup test).

e)

Formaldehyde solutions (45 % or less)


Applies to formaldehyde solutions 45 % or less, but not below 5 %.

f)

Aluminium chloride (30 % or less)/Hydrochloric acid (20 % or less) solution


Hydrochloric acid
Applies to hydrochloric acid not below 10 %.

g)

Maleic anhydride
Dry chemical cannot be used because of the possibility of an explosion.

h)

Nitric acid (70 % and over)


UN number 2032 assigned to red fuming nitric acid.

i)

(Deleted)

17-4

j)

Section 17 - Summary of Minimum Requirements

Tricresyl phosphate (containing 1 % or more ortho-isomer)


UN number assigned to this substance containing more than 3 % of ortho-isomer.

k)

Phosphorus (yellow or white)


Phosphorus, yellow or white, is carried above its autoignition temperature and therefore flashpoint is not appropriate.
Electrical equipment requirements are similar to those for substances with a flashpoint above 60 /C (closed cup test).

l)

Sulphur (molten)
Sulphur (molten) has a flashpoint above 60 /C (closed cup test), however, electrical equipment is to be certified safe
for gases evolved.

m)

Ammonia aqueous (28 % or less)


UN number 2672 refers to 10 - 35 % ammonia solutions.

n)

2- or 3-Chloropropionic acid
UN number 2511 applies to 2-Chloropropionic acid only.

o)

Dinitrotoluene (molten)
Dinitrotoluene is not to be carried in deck tanks.

p)

(Deleted)

q)

Heptanol (all isomers)


Requirements are based on those isomers having a flashpoint of 60 /C (closed cup test) or less; some isomers have
a flashpoint greater than 60 /C (closed cup test), and therefore the requirements based on flammability do not apply
to such isomers.

r)

Undecyl alcohol
Reference to 16.A.2.2 applies to 1-Undecyl alcohol only.

s)

Decyl alcohol (all isomers)


Applies to n-Decyl alcohol only.

t)

Benzene and mixtures having 10 % benzene or more


UN number 1114 applies to Benzene.

u)

Nitropropane (60 %)/Nitroethane (40 %) mixture


Nitroethane
Nitroethane(80%)/Nitropropane(20%)
Dry chemicals are not to be used as fire extinguishing media.

v)

Formic acid
Confined spaces should be tested for both Formic acid vapours and Carbon monoxide gas, a decomposition product.

w)

Xylenes
Applies to p-Xylene only.

x)

Dichlorobenzenes (all isomers)


Applies to p-isomer and mixtures containing p-isomer viscosity of which is 25 mPa @ s and above at 20 /C.

y)

Dichlorobenzenes (all isomers)


Applies to p-isomer and mixtures containing p-isomer melting point of which is 0 /C and above.

Section 17 - Summary of Minimum Requirements

z)

17-5

Dichlorobenzenes (all isomers)


Applies to p-isomer and mixtures containing p-isomer melting point of which is 15 /C and above.

aa)

Nonyl phenol poly (4+) ethoxylates


Applies only to products with melting point of 15 /C and above.

bb)

Oil-like substances
Applies to oil-like substances identified in accordance with the provisions of the unified interpretation of regulation
14 of Annex II of MARPOL 73/78 agreed by the MEPC.

Remark:
Columns p to t are for guidance only. The data included therein have been taken from different publications.
For List of Product refer to pages 17-6 to 17-32.

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17-37

Acetochlor

Boiling Point [/ C]

1715

Auto-Ignition Temperature [/ C]

Acetic anhydride

Flashpoint [/ C]

Acetic acid

Density [kg/ m]

Respiratory and Eye Protection

Materials of Construction

Tank Environmental Control

Fire Protection

Tank Vents

Vapour Detection

Tank Type

Gauging

Ship Type

Flashpoint >60/

Hazards

Apparatus Group

Pollution Category

Product name

Temperature Class

UN Number

Electrical
equipment

CH3COOH

1050

40

485

118

330

140

Special requirements

Chemical
Formula

2G

T1 IIA

Y1,Z

15.11.2 to 15.11.4,
15.11.6 to 15.11.8,
15.19.6

2G

T2 IIA

F-T

Y1

15.11.2 to 15.11.4,
15.11.6 to 15.11.8,
15.19.6

(CH3CO)2O

1080

49

2G

15.19.6

C14H20NO2Cl

1117

>100

15.1, 15.12, 15.17,


15.18, 15.19, 16.6.1 to
16.6.3

(CH3)2C(OH)CN

930

75

688

82

15.12, 15.19.6

CH3CN

780

525

82

15.12.3, 15.13, 15.16.1,


CH2CHCONH2
15.19.6, 16.6.1

1050

102

Acetone cyanohydrin

1541

SP

2G

T1 IIA

Acetonitrile

1648

2G

T2 IIA

F-T

Acrylamide solution (50% or


less)

2074

2G

NF

Acrylic acid

2218

2G

T2 IIA

F-T

Acrylonitrile

1093

SP

2G

T1 IIB

F-T

Adiponitrile

2205

2G

IIB

Alachlor technical (90% or


more)

SP

2G

Alcohol (C12-C15) poly(1-6)


ethoxylates

2G

Alcohol (C12-C15) poly


(20+) ethoxylates

2G

Alcohol (C12-C15) poly


(7-19) ethoxylates

2G

Alcohol (C6-C17)(secondary)
poly (3- 6) ethoxylates

2G

Alcohol (C6-C17)(secondary)
poly (7-12) ethoxylates

2G

Y1
N3,Z

15.13, 15.19.6, 16.6.1

CH2=CHCOOH

1050

(54)

374

140

15.12, 15.13, 15.17,


15.19

CH2=CHCN

800

-5

480

77

CN(CH2)4CN

960

(93)

Y1

15.19.6, 16.2.6, 16.2.9,


16A.2.2

1120

15.19.6

900

15.19.6, 16.2.6

1000

15.19.6

1000

15.19.6, 16.2.6, 16.2.9

1000

A, C

Y1

162

930

295

2G

2G

Boiling Point [/ C]

Auto-Ignition Temperature [/ C]

Alkaryl polyethers (C9-C20)

(C)

Flashpoint [/ C]

Alkanes (C6-C9)

Density [kg/ m]

15.19.6

600 700

<60

15.19.6, 16.2.6

<1000

>60

960

~70

890

<20

Respiratory and Eye Protection

Materials of Construction

Tank Environmental Control

Fire Protection

Tank Vents

Vapour Detection

Tank Type

Gauging

Ship Type

Flashpoint >60/

Hazards

Apparatus Group

Pollution Category

Product name

Temperature Class

UN Number

Electrical
equipment

A, B

Special requirements

Chemical
Formula

Alkyl (C7-C9) nitrates

SP

2G

A, B

15.19.6, 15.20, 16.6.1


to 16.6.3

Alkyl acrylate-vinylpyridine
copolymer in toluene

2G

15.19.6

Alkyl(C3-C4)benzenes

2G

15.19.6

870

<60

Alkyl(C5-C8)benzenes

2G

15.19.6

~900

>60

Alkyl(C7-C11)phenol poly
(4-12) ethoxylate

2G

15.19.6, 16.2.6, 16.2.9

1050

240

Alkylbenzene, alkylindane,
alkylindene mixture (each
C12- C17)

2G

15.19.6

860

185

SP

2G

16.2.7, 16.2.8

964

135

400

2G

16.2.7 to 16.2.9

Alkylbenzenesulphonic acid

2584,
2586

Alkylbenzenesulphonic acid,
sodium salt solution

NF

RC6H4SO3H

110

284

1000

Allyl alcohol

1098

SP

2G

T2 IIB

F-T

15.12, 15.17, 15.19

CH2CHCH2OH

850

21

375

97

Allyl chloride

1100

SP

2G

T2 IIA

F-T

15.12, 15.17, 15.19

CH2CHCH2Cl

940

<-20

390

45

Aluminium chloride (30% or


less)/Hydrochloric acid (20%
or less) solution

1G

NF

~1200

2-Amino-2-methyl-1propanol (90% or less)

2G

CH3C(CH3)NH2CH2OH

930

67

165

2-(2-Aminoethoxy) ethanol

3055

Aminoethylethanolamine
N-Aminoethylpiperazine

2815

2G

(D)

2G

2G

T2 IIA

X f) 15.11
N1

A, D

N2

N1

N2

15.19.6
15.19.6

Mixture of AlCl3 and HCl

C4H11NO2

1060

107

NH2C2H4NHC2H4OH

1030

129

365

243

221

C6H15N3

980

107

308

220

Auto-Ignition Temperature [/ C]

Boiling Point [/ C]

NH4HSO3 + H2O

1260 1380

100 103

15.2, 15.11.4, 15.11.6,


15.18, 15.19.6

NH4NO3

~1750

15.12, 15.16.1, 15.17,


15.19, 16.6.1 to 16.6.3

(NH4)2S/H2O

993

22

Mixture of NH4SCN and


(NH4)2S2O3

~1150

(NH4)2S2O3

~1500

15.16.1, 16.6.1 to
16.6.3

Y4

N1

NF

2693

2G

NF

1G

NF

SP

2G

F-T

Ammonium thiocyanate (25%


or less)/Ammonium
thiosulphate (20% or less)
solution

(C)

2G

NF

Ammonium thiosulphate
solution (60% or less)

(C)

2G

NF

Special requirements

Chemical
Formula

p
NH3 + H2O

16.2.9

38 100

15.19.6

CH3COOC5H11

880

~37

15.12, 15.17, 15.19

C6H5NH2

1020

76

770

184

Amyl acetate (all isomers)

1104

2G

Aniline

1547

SP

2G

(C)

2G

Benzene and mixtures having


1114 t)
10% benzene or more *1)

SP

2G

Benzenesulphonyl chloride

2G

2225

Y5

T1 IIA

X a)

Aviation alkylates (C8


paraffins and iso-paraffins
B.Pt. 95-120/C) (bb)

N4

2G

900

T1 IIA

SP

2683

Ammonium sulphide solution


(45% or less)

2672 m)

Ammonium nitrate solution


(93% or less)

A, B,
C

Ammonium bisulphite
solution (70% or less)

Flashpoint [/ C]

Density [kg/ m]

Respiratory and Eye Protection

Materials of Construction

Tank Environmental Control

Fire Protection

Tank Vents

Vapour Detection

Tank Type

Gauging

Ship Type

Flashpoint >60/

Hazards

a
Ammonia aqueous (28% or
less)

Apparatus Group

Pollution Category

Product name

Temperature Class

UN Number

Electrical
equipment

F-T A, B
T

A, D

N1

~130

15.19.6

700

15.12.1, 15.17, 15.19.6,


C6H6
16.2.9

880

-11

555

80

15.19.6

1378

128

252

C6H5SO2Cl

Benzyl acetate

2G

C6H5CH2O2CCH3

1060

Benzyl alcohol

2G

C6H5CH2O

1050

100

436

206

C6H5CH2Cl

1100

~68

585

179

CH2BrCl

1930

68

Benzyl chloride

1738

SP

2G

Bromochloromethane

1887

Butene oligomer

T1 IIA

2G

NF

2G

A, B
A

X
N3

15.12, 15.13, 15.17,


15.19

15.19.6

660

Respiratory and Eye Protection

15.19.6

(CH3)2COO(CH2)3

883

33

421

126

F-T

15.13, 15.19.6,
16.6.1,16.6.2

C7H12O2

900

37

275

148

15.19.6

1120

199

15.19.6

CH3(CH2)2COOC4H9

870

54

T4 IIB

F-T

15.4.6, 15.12, 15.19.6

(C4H9)2O

770

25

194

141

IIA

F-T A, D

15.13, 15.19.6, 16.6.1,


16.6.2

CH2=C(CH3) COOC4H9

900

(54)

290

165

C2H5COOC4H9

870

32

425

146

Butyl acrylate (all isomers)

SP

2G

Butyl benzyl phthalate

2G

Butyl butyrate (all isomers)

2G

SP

2G

Inert

2G

Butyl methacrylate
n-Butyl propionate

T2 IIB

166

Tank Type

Ship Type

Hazards

2G

15.19.6

Butyl/Decyl/Cetyl/Eicosyl
methacrylate mixture

2G

A, D

15.13, 16.6.1, 16.6.2

Butylamine (all isomers)

SP

2G

F-T

15.12, 15.17, 15.19.6

C4H9NH2

700 750

2G

15.19.6

C6H5(CH2)3CH3

860

~52

15.8.1 to 15.8.7,
15.8.12, 15.8.13,
15.8.16 to 15.8.19,
15.8.21, 15.8.25,
15.8.27, 15.8.29,
15.19.6

H2COCHCH2CH3

890

-20

15.16.1, 15.19.6

CH3(CH2)2CHO

800

-7

230

76

15.11.2 to 15.11.4,
15.11.6 to 15.11.8

CH3(CH2)2COOH

958

72

450

164

15.19.6

15.16.1

Ca(OCl)2

1140

Butylbenzene (all isomers)

1,2-Butylene oxide,

1914

Pollution Category

UN Number
1149

Flashpoint [/ C]

Density [kg/ m]

2G

Chemical
Formula

Special requirements

Boiling Point [/ C]

Materials of Construction

n-Butyl ether

Auto-Ignition Temperature [/ C]

Fire Protection

Vapour Detection

Gauging

Apparatus Group

Butyl acetate (all isomers)

Product name

Temperature Class

Tank Environmental Control

j
-

Tank Vents

Flashpoint >60/

Electrical
equipment

2709

3022

Butyraldehyde (all isomers)


Butyric acid

2820

SP

2G

Inert

T2 IIB

A, C

SP

2G

T3 IIA

F-T

2G

Calcium alkyl(C9)phenol
sulphide/Polyolefin
phosphorosulphide mixture

2G

A, B

Calcium hypochlorite
solution (15% or less)

SP

2G

NF

N1

Y1

N5

-10-+10 ~300 44-78


412

183

65

Gauging

Vapour Detection

Fire Protection

Materials of Construction

Respiratory and Eye Protection

SP

2G

NF

N5

15.16.1, 15.19.6

Calcium long-chain alkyl


salicylate (C13+)

2G

A, B

16.2.7, 16.2.8

Camphor oil

SP

2G

Carbolic oil

SP

2G

Carbon disulphide

1131

SP

1G

Pad +
Inert

Carbon tetrachloride

1846

IIA

T6 IIC

920

15.12, 15.19

1060

F-T

15.3, 15.12, 15.19

CS2

1260

<-20

95

46

15.12, 15.17, 15.19.6

CCl4

1590

76

950

>100

860

149

2G

A, B

Cetyl/Eicosyl methacrylate
mixture

2G

A, D

15.13, 16.6.1, 16.6.2

Chlorinated paraffins (C10C13)

2G

15.19

4-Chloro-2-methyl-phenoxyacetic acid, dimethylamine


salt solution

(C)

2G

NF

N1

SP

2G

NF

Y5

2G

T1 IIA

2G

NF

(D)

2G

IIA

SP

2G

Chlorohydrins (crude)
o-Chloronitrobenzene

1578

47

15.19.6

SP

>60

SP

~970

NF

A, B

1134

1200

F-T

2G

1888

Chloroform

SP

Chlorobenzene

1750

Cashew nut shell oil


(untreated)

Chloroacetic acid (80% or


less)

Ca(OCl)2

Boiling Point [/ C]

Tank Environmental Control

Auto-Ignition Temperature [/ C]

Tank Vents

Chemical
Formula
Flashpoint [/ C]

Tank Type

Special requirements

Density [kg/ m]

Ship Type

Flashpoint >60/

Hazards

Apparatus Group

Pollution Category

Calcium hypochlorite
solution (more than 15%)

Product name

Temperature Class

UN Number

Electrical
equipment

C16 , C18 and C20 Methacrylates

370

1100
1350

15.11.2, 15.11.4,
15.11.6 to 15.11.8,
15.12.3, 15.19, 16.2.9

CH2ClCOOH

1330

186
132

F-T

A,B

15.19.6

C6H5Cl

1110

28

590

15.12, 15.19.6

CHCl3

1480

F-T

15.12, 15.19

A, B,
D

15.12, 15.17, 15.18,


15.19, 16.2.6, 16.2.9,
16A.2.2

1200
C6H4ClNO2

1368

61
213

127

>149

246

2G

SP

2G

X
NF

Y1

Boiling Point [/ C]

1754

Auto-Ignition Temperature [/ C]

Chlorosulphonic acid

2511 n) (C) SP

Flashpoint [/ C]

2- or 3-Chloropropionic acid

Density [kg/ m]

Respiratory and Eye Protection

Materials of Construction

Tank Environmental Control

Fire Protection

Tank Vents

Vapour Detection

Tank Type

Gauging

Ship Type

Flashpoint >60/

Hazards

Apparatus Group

Pollution Category

Product name

Temperature Class

UN Number

Electrical
equipment

CH3CHClCOOH or
CH2ClCH2COOH

1260

107

550

185

15.11.2 to 15.11.8,
15.12, 15.16.2, 15.19

SO2OHCl

1770

158

Special requirements

Chemical
Formula

15.11.2 to 15.11.4,
15.11.6 to 15.11.8,
16.2.7 to 16.2.9

m-Chlorotoluene

2238

SP

2G

F-T A, B

15.19.6

CH3C6H4Cl

1072

162

o-Chlorotoluene

2238

SP

2G

F-T A, B

15.19.6

CH3C6H4Cl

1077

159

p-Chlorotoluene

2238

SP

2G

F-T A, B

15.19.6, 16.2.9

CH3C6H4Cl

1067

166

Chlorotoluene (mixed
isomers)

2238

SP

2G

F-T A, B

15.19.6

ClC6H4CH3

1070

SP

2G

T2 IIA

B, D

15.19.6

Coal tar naphtha solvent

SP

2G

T3 IIA

F-T A, D

Coal tar pitch (molten)

1G

T2 IIA

Cobalt naphthenate in solvent


naphtha

SP

2G

Coal tar

15.19.6

880

15-30

555

B, D

15.19.6

~1300

~280

~550

F-T A, D

15.19.6

870

C6H6

2G

16.2.7 to 16.2.9

900

Creosote (coal tar)

SP

2G

T2 IIA

A, D

15.19.6

1070

SP

2G

T2 IIA

A, D

15.19.6

A
A

SP
SP

2
2

2G
2G

O
O

T1 IIA

X
X

O
O

A, B
A, B

15.19.6
15.19.6

SP

2G

15.19.6

SP

2G

F-T

15.12, 15.16.1, 15.17,


15.19.6

CH3CHCHCHO

SP

2G

15.13, 15.19, 16.6.1,


16.6.2

C12H18

Cresols (all isomers)


Cresylic acid, dephenolized
Cresylic acid, sodium salt
solution

2076

Crotonaldehyde

1143

1,5,9-Cyclododecatriene

T3 IIB

162

1180 120 -150 336


1300

Coconut oil fatty acid

Creosote (wood)

43

N8

N2

74

1040
1040

80

200 400

1080
C6H4OHCH3

230 330

~220
>81
86

555

191
250

850

13

230

102

890

80

1400

231

1145

2G

Cyclohexanone

1915

2G

2G

Cyclohexanone,
Cyclohexanol mixture
Cyclohexyl acetate

2243

(B)

2G

Cyclohexylamine

2357

SP

2G

1,3-Cyclopentadiene dimer
(molten)

T2 IIA

T3 IIA

C7H14

809

<38

o
15.19.6

t
117

15.19.6, 16.2.9

C6H12

780

-18

260

81

F-T

N5

15.19.6

(CH2)5CO

950

43

430

156

F-T

N5

C6H10O + C6H11OH

950

(32)

290

134

F-T A, C

N1

15.19.6

CH3COOC6H11

970

15.19.6

C6H11NH2

860

2G

15.19.6, 16.2.6, 16.2.9,


C5H6
16A.2.2

980

Cyclopentane (bb)

1146

(C)

2G

15.19.6

C5H10

740

Cyclopentene

2246

(B)

2G

15.19.6

C5H8

750

p-Cymene (bb)

2046

2G

15.19.6

CH3C6H4CH(CH3)2

855

2G

16.2.7 to 16.2.9

CH3(CH2)8CO2H

900

Decanoic acid

Boiling Point [/ C]

Auto-Ignition Temperature [/ C]

Flashpoint [/ C]

Tank Type

Ship Type

Hazards

Pollution Category

Cyclohexane (bb)

j
-

Chemical
Formula

Special requirements

Density [kg/ m]

Respiratory and Eye Protection

Materials of Construction

g
C

Fire Protection

f
2G

Vapour Detection

e
3

Gauging

d
P

Flashpoint >60/

c
(C)

UN Number
a
Cycloheptane (bb)

Apparatus Group

Tank Environmental Control

b
2241

Product name

Temperature Class

Tank Vents

Electrical
equipment

47

177
270

2G

15.19.6

C10H20

740

172

Decyl acetate

(B)

2G

15.19.6

CH3(CH2)9OOCCH3

864

187

Decyl acrylate

SP

2G

A, C,
D

15.13, 15.19.6, 16.6.1,


16.6.2

C10H21OOCCH=CH2

890

127

Decyl alcohol (all isomers)

2G

15.19.6, 16.2.9 (s)

CH3(CH2)8CH2OH

~830

~82

233

Decyloxytetrahydrothiophene
dioxide

SP

2G

15.19.6

1030

130

>100

1902

SP

2G

A, D

973

196

>200

2G

15.19.6

(CH2CH2COOC6H13)2

939

163

Di-n-propylamine

2383

SP

2G

F-T

N2

15.12.3, 15.19.6

C6H15N

718

Dibromomethane

2664

SP

2G

N3

15.12.3, 15.19

CH2Br2

2400

2G

15.19.6, 16.2.6

980

(120)

Decene

Di-(2-ethylhexyl) phosphoric
acid
Di-n-hexyl adipate

Dibutyl hydrogen
phosphonate

T3 IIA

NF
X

N2

N2

(C4H9CH(C2H5)CH2)2HPO4

42
-

99
121

2G

3,4-Dichloro-1-butene

SP

2G

Dichlorobenzene(all isomers)

SP

2G

T1 IIA

Tank Type

Ship Type

Hazards

F-T

F-T

1,6-Dichlorohexane

SP

2G

A, B
A, C,
D

2G

2G

2,4-Dichlorophenoxy acetic
acid, diethanolamine salt
solution

SP

2G

2,4-Dichlorophenoxy acetic
acid, dimethylamine salt
solution (70% or less)

SP

2G

2,4-Dichlorophenoxy acetic
acid, triisopropanolamine salt
solution

SP

2G

1,1-Dichloropropane
1,2-Dichloropropane

1279

1,3-Dichloropropane
1,3-Dichloropropene

2047

119

15.19.6, 16.2.6(x),
16.2.9(y), 16A.2.2 (z)

C6H4Cl2

1304 1460

66

~645

~175

15.19.6

CH3CHCl2

1170

-10

457

57

15.19.6

CH2ClCH2OCH2CH2Cl

1220

55

365

178

15.19.6

15.12, 15.17, 15.19

(ClCH2C(CH3)H)2O

1130

95

187

605

A, B,
D

T2 IIA

SP

450

T2 IIA

29

1150

1593

15.12.3, 15.17, 15.19.6 C4H6Cl2

A, B,
C

2021

F-T

2,4-Dichlorophenol

161

2G

Dichloromethane

260

2G

42

A, C,
D

760

F-T

2G

(C4H9)2NH

15.19.6

SP

SP

171

2490

1048

Dichloroethyl ether

2,2'-Dichloroisopropyl ether

2362

Pollution Category

UN Number
1,1-Dichloroethane

T2 IIA

C6H4(COOC4H9)2

N4

N5

N5

t
340

1060

CH2Cl2

1330

N1

15.19.6

C6H3Cl2OH

1380

114

NF

N1

15.19.6

C12H17O5NCl2

1280

NF

N1

15.19.6

Cl2C6H3OCH2COON(CH3)2

1230

NF

N1

15.19.6

C17H27O6NCl2

1230

100

CH2ClCH2CH2Cl

1160

15

555

97

555

SP

2G

SP

2G

T1 IIA

T1 IIA

N5

Boiling Point [/ C]

Auto-Ignition Temperature [/ C]

SP

Flashpoint [/ C]

15.19.6

j
X

Chemical
Formula

Special requirements

Density [kg/ m]

Dibutylamine

Respiratory and Eye Protection

Materials of Construction

Fire Protection

2G

Vapour Detection

Gauging

Flashpoint >60/

Apparatus Group

Tank Environmental Control

Dibutyl phthalate

Product name

Temperature Class

Tank Vents

Electrical
equipment

F-T A, B

15.12, 15.19.6

F-T A, B

15.12, 15.19.6

40
210
94

1200

2G

T1 IIA

F-T A, B

15.12, 15.19.6

CH3CHClCH2Cl

1160

15

SP

2G

T2 IIA

F-T A, B

15.12, 15.17 to 15.19

CHCl=CHCH2Cl

1230

29

96
104

SP

2G

2,2-Dichloropropionic acid

2G

2G

T1 IIA

1G

Inert

T4 IIB

2G

(B) SP

2G

Diethanolamine
Diethyl ether

1155

Diethyl phthalate

A, B,
F-T
D

1090

(138)

660

269

C2H5OC2H5

704

-45

180

35

436

208

N2

F-T

N7

N3

1118

152

(C2H5)2SO4

1180

104

15.12, 15.19.6

(C2H5)2NH

706

<-25

310

56

15.19.6

(C2H5)2NCH2CH2OH

890

(60)

260

161

15.19.6, 16.2.9

(C2H5)2C6H3NH2

960

15.19.6

C6H4(C2H5)2

865

56

430

180

NH2C2H4NHC2H4NH2

954

102

395

207

252

2G

T2 IIA

F-T

N1

2G

T2 IIA

F-T A, C

N1

SP

2G

B, C,
D

N4

N2

2G

2G

Diglycidyl ether of
bisphenol A

2G

Diglycidyl ether of
bisphenol F

2G

Diisobutyl phthalate

(C) SP

Diisobutylamine

2361

Diisobutylene

2050

190

C6H4(CO2C2H5)2

15.19.6, 16.2.6

1160

15.19.6, 16.2.6

1160

2G

15.19.6, 16.2.6

C6H4(COOCH2CH(CH3)2)2

1040

196

327

2G

F-T

A, C,
D

15.12.3, 15.19.6

((CH3)2CHCH2)2 NH

745

29

139
101

N1

2G

15.19.6

C8H16

723

-7

SP

2G

T2 IIA

N2

16.2.7 to 16.2.9

(CH3CHOHCH2)2NH

989

127

SP

2G

T2 IIA

F-T

N2

15.12, 15.19

((CH3)2CH)2NH

720

-7

Diisopropylbenzene (all
isomers)

2G

15.19.6

C6H4(C3H7)2

857

77

Dimethyl adipate

2G

15.19.6, 16.2.9

Diisopropylamine

1158

299

T2 IIA

Diisopropanolamine

82-149

15.19.6

SP

15.4, 15.14, 15.19

SP

19

(HOC2H4)2NH

1200
1390

CH3CCl2COOH

Y5

2686

15.11.2, 15.11.4,
15.11.6 to 15.11.8

1154

2049

Diethylaminoethanol

2079

15.12, 15.17 to 15.19

Diethylamine

Diethylenetriamine

1594

Diethylbenzene

Chemical
Formula

Special requirements

Mixture of C3H4Cl2 and


C3H6Cl2

Diethyl sulphate

2,6-Diethylaniline

Boiling Point [/ C]

Auto-Ignition Temperature [/ C]

Flashpoint [/ C]

Dichloropropene/Dichloropro
pane mixtures

Density [kg/ m]

Respiratory and Eye Protection

Materials of Construction

Tank Environmental Control

Fire Protection

Tank Vents

Vapour Detection

Tank Type

Gauging

Ship Type

Flashpoint >60/

Hazards

Apparatus Group

Pollution Category

Product name

Temperature Class

UN Number

Electrical
equipment

1070

249
285

82
203

Dimethyl hydrogen phosphite

Chemical
Formula

Special requirements

Boiling Point [/ C]

Auto-Ignition Temperature [/ C]

Flashpoint [/ C]

Tank Type

Ship Type

Hazards

(B) SP

j
X

Density [kg/ m]

Respiratory and Eye Protection

Materials of Construction

g
O

Fire Protection

f
2G

Vapour Detection

e
3

Gauging

d
P

Flashpoint >60/

Pollution Category

UN Number
a
Dimethyl glutarate

Apparatus Group

Tank Environmental Control

c
C

Product name

Temperature Class

Tank Vents

Electrical
equipment

p
CH3O2C(CH2)3CO2CH3

1070

(CH3O)2P(O)H

1200

147

162

C6H4(COOCH3)2

1190

146

282

16.2.9

CH3O2CCH2CH2CO2CH3

1120

15.12.1, 15.17

CH3CON(CH3)2

940

66

165

N1

15.12, 15.19.6

(CH3)2NH + H2O

~700

< -18

<400

54
45

2G

A, D

Dimethyl phthalate

2G

Dimethyl succinate

2G

N,N-Dimethylacetamide
solution (40% or less)

2G

N4

F-T

A, C,
D

15.12.1

Dimethylamine solution (45%


or less)

1160

SP

2G

Dimethylamine solution
(greater than 45% but not
greater than 55%)

1160

SP

2G

F-T

A, C,
D

N1

15.12, 15.17, 15.19

(CH3)2NH + H2O

~800

< -18

<400

Dimethylamine solution
(greater than 55% but not
greater than 65%)

1160

SP

2G

F-T

A, C,
D

N1

15.12, 15.14, 15.17,


15.19

(CH3)2NH + H2O

~850

< -18

<400

N,N-Dimethylcyclohexylamine

2264

SP

2G

F-T

A,C

N1

15.12, 15.17, 15.19.6

(CH3)2NC6H11

850

39

215

162

N2

135

T2 IIA

15.19.6

(CH3)2NCH2CH2OH

890

(41)

220

15.19.6

HCON(CH3)2

950

58

440

16.2.8, 16.2.9

C10H20O2

902

13

15.12, 15.17, 15.19,


15.21

C6H3(NO2)2CH3

1328

150

312

285

Dimethylethanolamine

2051

2G

T3 IIA

F-T A, D

Dimethylformamide

2265

2G

T2 IIA

F-T A, D

(C)

2G

Dimethyloctanoic acid

153
254

Dinitrotoluene (molten)

1600

SP

2G o)

1,4-Dioxane

1165

2G

F-T

15.12, 15.19

O(CH2)4O

1036

12

375

101

Dipentene

2052

2G

15.19.6

C10H16

847

45

237

175

Diphenyl

2G

15.19

C6H5-C6H5

1040

113

570

256

Diphenyl ether

2G

15.19.6

(C6H5)2O

1075

115

618

259

Diphenyl ether/Diphenyl
phenyl ether mixture

2G

15.19.6

T2 IIB

1200

Diphenylamine, reaction
product with 2,2,4-Trimethyl
pentene
Diphenylamines, alkylated
Diphenylmethane
diisocyanate

Boiling Point [/ C]

Auto-Ignition Temperature [/ C]

Flashpoint [/ C]

Chemical
Formula

Special requirements

p
Mixture of C6H5-C6H5 and
(C6H5)2O

1060

2G

15.19

(A) SP

2G

15.19

980

>180

2G

15.19.6

1010

356

15.12, 15.16.2, 15.17,


15.19.6, 16.2.6, 16.2.9, CH2(C6H4NCO)2
16A.2.2

1230

249

15.19.6, 16.2.6

1300

A
2489

Density [kg/ m]

Respiratory and Eye Protection

Materials of Construction

Tank Environmental Control

Fire Protection

Tank Vents

Vapour Detection

Tank Type

Gauging

Ship Type

Flashpoint >60/

Hazards

a
Diphenyl/Diphenyl ether
mixtures

Apparatus Group

Pollution Category

Product name

Temperature Class

UN Number

Electrical
equipment

(B) SP

2G

b)

A,B,
T b) C c),
D

N5

Diphenylol propaneepichlorohydrin resins

2G

Dodecene (all isomers)

(B)

2G

15.19.6

836

>100

1160

C12H24

>200

230

760

213

15.19.6, 16.2.6, 16.2.9,


CH3(CH2)10CH2OH
16A.2.2

15.19.6

15.13

CH2=C(CH3)COO (CH2)11CH3

870

132

133

A,D

15.13, 16.6.1, 16.6.2

CH2=C(CH3)COOC12-15

860

110

290

A, D

N2

15.19.6

2G

B, C,
D

N4

15.19.6

2G

15.19

163

154

2G

15.19.6

15.12, 15.17, 15.19

Dodecyl alcohol

2G

Dodecyl diphenyl ether


disulphonate solution

SP

2G

Dodecyl methacrylate

2G

Dodecyl/Pentadecyl
methacrylate mixture

2G

Dodecylamine/Tetradecylami
ne mixture

SP

2G

Dodecyldimethylamine/Tetra
decyld imethylamine mixture

SP

Dodecylphenol

Drilling brines (containing


zinc salts)

X
NF

Epichlorohydrin

2023

SP

2G

IIB

F-T

Ethanolamine

2491

2G

T2 IIA

F-T

N2

259
-

790

C12H25C6H4OH

940

CH2OCHCH2Cl

1180

21

HOCH2CH2NH2

1018

(93)

385

116
171

Ethyl methacrylate

2277

(D)

2G

Chemical
Formula

Density [kg/ m]

Tank Type

Boiling Point [/ C]

Respiratory and Eye Protection

A,D

2G

Ship Type

Auto-Ignition Temperature [/ C]

Materials of Construction

F-T

2G

T2 IIB

Special requirements

Flashpoint [/ C]

Fire Protection

Vapour Detection

Gauging

Apparatus Group

T2 IIA

1180

Temperature Class

Tank Environmental Control

Tank Vents

2271

Ethyl butyrate

Hazards

15.19.6

Ethyl amyl ketone

Pollution Category

910

UN Number

CH2=C(CH3)COOC2H5

(27)

100

120

2G

(A) SP

2G

IIA

F-T

15.19.6

(C3H7)CH=C(C2H5)CHO

850

68

175

(C) SP

1G

T2 IIA

F-T C, D

15.12, 15.14, 15.19.6

C2H5NH2

689

-49

384

17

15.12, 15.14, 15.17,


15.19

C2H5NH2

800

-30

15.19.6

C6H5C2H5

867

15

15.12.3, 15.19.6

C2H5NH(CH2)3CH3

740

15.19.6

C2H5C6H11

787

35

262

55

15.19.6

C8H17N

850

46

245

167

15.12, 15.17, 15.19

425

129

(C) SP
B

2G

F-T

A,C

2G

N-Ethylbutylamine

(C) SP

2G

F-T

Ethylcyclohexane (bb)

(C)

2G

2G

F-T

F-T A, D

N2
N1

N1
N1

SP

2G

T2 IIA

(D)

2G

IIB

X
-

Ethylene dibromide

1605

SP

2G

NF

Ethylene dichloride

1184

SP

2G

T2 IIA

(C)

2G

Ethylene glycol butyl ether


acetate

15.13, 15.19.6, 16.6.1,


16.6.2

2G

1135

15.13, 15.19.6, 16.6.1,


16.6.2

Ethylene chlorohydrin

44

880

SP

Ethylene cyanohydrin

820

C3H7CO2C2H5

N-Ethylcyclohexylamine

CH3CH2CO(CH2)4CH3

15.19.6

F-T

1917

1175

15.19.6

Ethyl acrylate

Ethylbenzene

350

2270

15.19.6

Ethylamine solutions (72% or


less)

920

2G

1036

CH2=CHCOOC2H5

Ethylamine

2-Ethyl-3-propylacrolein

s
380

Ethyl-3-ethoxypropionate

r
49

1172

j
-

2-Ethoxyethyl acetate

Product name

970

Flashpoint >60/

Electrical
equipment

F-T A, B

N4

38
432

136
110

ClCH2CH2OH

1210

55

HOCH2CH2CN

1040

129

15.12, 15.19.6, 16.2.9

BrCH2CH2Br

2170

515

132

15.19

ClCH2CH2Cl

1250

13

440

84

117

C4H9OCH2OOCCH3

942

88

192

(CH3COO)2C2H4

1106

96

188

1010

49

Ethylene glycol diacetate

2G

Ethylene glycol methyl ether


acetate

2G

Ethylene glycol monoalkyl


ethers

2G

15.19.6

900

2983

SP

1G

Inert

T2 IIB

F-T A, C

Ethylenediamine

1604

SP

2G

T2 IIA

F-T

2-Ethylhexyl acrylate
2-Ethylhexylamine

2276

Ethylidenenorbornene

SP

2G

SP

2G

SP

2G

o-Ethylphenol

(A) SP

2G

Ethyltoluene

(B)

2G

SP

2G

Ferric chloride solutions

2582

Ferric nitrate/nitric acid


solution

T3 IIB

T1 IIA

F-T

N4

~430

27

15.19.6, 16.2.9

NH2CH2CH2NH2

900

34

385

116

15.13, 15.19.6, 16.6.1,


16.6.2

CH2=CHCOOC8H17

890

(82)

245

229

15.12, 15.19.6

C4H9CH(C2H5)CH2NH2

790

(60)

265

169

15.12.1, 15.16.1,
15.19.6

C9H12

900

38

272

148

15.19.6

HOC6H4C2H5

1040

78

15.19.6

C2H5C6H4CH3

860

60

475

15.11, 15.19.6, 16.2.9

Mixture of FeCl2 and FeCl3

1410

Mixture of Fe(NO3)2 and


Fe(NO3)3 in HNO3

1290

1110

50

420

97

1220

42

520

101

2G

NF

15.11, 15.19

SP

1G

NF

15.11

Formaldehyde solutions (45% 1198 d),


or less)
2209

SP

2G

T2 IIB

F-T

Formic acid

2G

T1 IIA

T v)

2G

F-T

Fumaric adduct of rosin,


water dispersion
Furfural

1199

SP

2G

Furfuryl alcohol

2874

2G

2G

Glutaraldehyde solutions
(50% or less)

T2 IIB

NF

<-20

1779

~845

SP

1778

Mixture of (CH2)2O and


CH3CHOCH2

Fluorosilicic acid (20-30%) in


water solution

NF

F-T A, D

N2

15.8, 15.12, 15.14,


15.19

N2

Boiling Point [/ C]

Respiratory and Eye Protection

Auto-Ignition Temperature [/ C]

Materials of Construction

Chemical
Formula
Flashpoint [/ C]

Fire Protection

Special requirements

Density [kg/ m]

Vapour Detection

Flashpoint >60/

Apparatus Group

Tank Environmental Control

a
Ethylene oxide/propylene
oxide mixture with an
ethylene oxide content of not
more than 30% in weight

Product name

Temperature Class

Tank Vents

Tank Type

Ship Type

Hazards

Pollution Category

UN Number

Gauging

Electrical
equipment

X e) 15.16.1, 15.19.6, 16.2.9 HCHO + H2O


X

15.11.2 to 15.11.4,
15.11.6 to 15.11.8,
15.19.6

15.19.6, 16.2.6

15.16.1, 15.19.6

Y2,
Y3

15.16.1

HCOOH

205

1060
C4H3OCHO

1160

60

~315

162

C4H3OCH2OH

1129

65

391

170

HOC(CH2)3COH

1120

188

15.19.6

C7H16

15.19.6

C7H15OH

2G

(C)

2G

2G

1206

Heptene (all isomers) (bb)


Heptyl acetate
1783

Boiling Point [/ C]

Respiratory and Eye Protection

Auto-Ignition Temperature [/ C]

Materials of Construction

Chemical
Formula
Flashpoint [/ C]

Fire Protection

Special requirements

Density [kg/ m]

Vapour Detection

Flashpoint >60/

Apparatus Group

15.19.6

Temperature Class

Tank Environmental Control

Tank Vents

Tank Type

Ship Type

Hazards

Pollution Category

UN Number

Heptanol (all isomers) (q)

Hexamethylenediamine
solution

Glycidyl ester of C10


trialkylacetic acid
Heptane (all isomers) (bb)

Product name

Gauging

Electrical
equipment

680

-4

223

~820

~60

~156

~6

190

80

123

1100

2G

15.19.6

C7H14

711

(B)

2G

15.19.6

C7H15OOCCH3

880

SP

2G

15.19.6, 16.2.9

H2N(CH2)6NH2

900

N2

98

Hexamethyleneimine

2493

SP

2G

15.19.6

C6H12NH

880

Hexane (all isomers) (bb)

1208

(C)

2G

15.19.6

C6H14

659

-23

(C)

2G

15.19.6

C6H12

680

<-20

64

15.19.6

CH3COOC6H13

870

59

164

HCl+H2O

1010 1210

Hexene (all isomers) (bb)

F-T A, C

N1

255

138

260

69

Hexyl acetate

1233

2G

Hydrochloric acid

1789

1G

NF

Hydrogen peroxide solutions


(over 60% but not over 70%)

2015

SP

2G

NF

15.5.1 to 15.5.13,
15.19.6

H2O2

1288

Hydrogen peroxide solutions


(over 8% but not over 60%)

2014,
2984

SP

2G

NF

15.5.14 to 15.5.26,
15.18, 15.19.6

H2O2

1245

2-Hydroxy-4-(methylthio)butanoic acid

2G

16.2.7, 16.2.8

2-Hydroxyethyl acrylate

SP

2G

15.12, 15.13, 15.19.6,


16.6.1, 16.6.2

Icosa(oxypropane-2,3-diyl)s

2G

16.2.6, 15.19.6

966

230

>350

>250

15.12, 15.16.2, 15.17,


15.19.6

C12H18H2O2

1060

158

430

310

C10H22N2

930

115

380

247

X f) 15.11

Isophorone diisocyanate

2290

SP

2G

A, B,
D

N5

Isophoronediamine

2289

2G

N2

110

~1200
CH2=CHCOOCH2CH2OH

1104

SP

2G

SP

2G

Isopropyl ether

1159

2G

Isopropylamine

1221

SP

(C)

Lactonitrile solution (80% or


less)

Lauric acid

Boiling Point [/ C]

Auto-Ignition Temperature [/ C]

1218

Flashpoint [/ C]

Isoprene

Density [kg/ m]

Respiratory and Eye Protection

Materials of Construction

Tank Environmental Control

Fire Protection

Tank Vents

Vapour Detection

Tank Type

Gauging

Ship Type

Flashpoint >60/

Hazards

Apparatus Group

Pollution Category

Product name

Temperature Class

UN Number

Electrical
equipment

CH2C(CH3)CHCH2

680

-48

220

34

CH3CHOHCH2NH2

960

(71)

335

159

720

-18

440

67

(CH3)2CHNH2

690

<-20

400

32

C6H11CH(CH3)2

~800

Special requirements

Chemical
Formula

15.13, 15.14, 15.19.6,


16.6.1, 16.6.2

16.2.8, 16.2.9

15.4.6, 15.13.3, 15.19.6 (CH3)2CHOCH(CH3)2

15.12, 15.14, 15.19

15.19.6, 16.2.7, 16.2.8

15.1, 15.12, 15.17 to


15.19, 16.2.6, 16.6.1 to CH3CHOHCN
16.6.3

988
860

T3 IIB

T2 IIA

F-T

Inert

2G

2G

SP

1G

A, C,
D

2G

15.19.6, 16.2.6, 16.2.9,


CH3(CH2)10COOH
16A.2.2

Liquid chemical wastes

SP

2G

F-T

15.12, 15.19.6, 20.5.1

1100 1400

Long-chain alkaryl polyether


(C11-C20)

2G

A, B

16.2.7, 16.2.8

~1000

>60

Long-chain poly-etheramine
in alkyl(C2-C4)benzenes

2G

15.19.6, 16.2.7, 16.2.8

930

48

Long-chain poly-etheramine
in aromatic solvent

2G

15.19.6, 16.2.7, 16.2.8

Magnesium long-chain alkyl


salicylate (C11+)

2G

A, B

16.2.7, 16.2.8

~1000

>60

2G

A g),
C

(COCH)2O

934

SP

2G

NF

2G

T2 IIB

SP

2G

NF

2G

Isopropanolamine

Isopropylcyclohexane (bb)

Maleic anhydride

2215

Mercaptobenzothiazol,
sodium salt solution
Mesityl oxide

1229

Metam sodium solution


Methacrylic acid

2531

T2 IIA

F-T C, D

N2
N2

Y1

N1

15.9.6, 16.2.9

C7H4NS2Na + H2O
(CH3)2C=CHCOCH3

F-T

15.19.6

N1

15.19.6

Y1

15.13, 16.6.1

182184

225

>232

60

103

475

202

1250

107

857

32

346

130

1210
CH2=C(CH3)COOH

1015

77

161

SP

2G

2G

2G

1919

SP

2G

Methyl butyrate

1237

(C)

2G

Methyl formate

1243

2G

F-T

2G

2G

F-T

(B)

2G

2G

IIA

F-T

A, B,
D

N6

IIA

N4

Methacrylonitrile

3079

N-(2-Methoxy-1-methyl
ethyl)-2-ethyl-6-methyl
chloroacetanilide
Methyl acrylate

Methyl heptyl ketone


Methyl methacrylate

1247

Methyl salicylate
2-Methyl-2-hydroxy-3-butyne
2-Methyl-5-ethylpyridine

2300

T2 IIA

CH3CN

789

13

Chemical
Formula

N4

15.19, 16.2.6

N4, Z

15.12, 15.13, 15.17,


15.19

F-T A, B

F-T

15.19.6

C15H22ClNO2

1120

>100

510

282

F-T

15.13, 15.19.6, 16.6.1,


16.6.2

CH2=CHCOOCH3

957

-3

415

80

15.19.6

C5H10O2

890

14

15.12, 15.14, 15.19

HCO2CH3

980

-19

15.19.6

CH3CO(CH2)6CH3

820

15.13, 15.19.6, 16.6.1,


16.6.2

CH2=C(CH3)COO

940

10

430

101

15.19.6

CH4OHCOOCH3

1185

101

454

222

15.19.6

(CH3)2C(OH)CH

867

25

15.19.6

T1 IIB

T2 IIA

2G

A, D

SP

2G

A, D

1235

SP

2G

F-T

A, C,
D

Methylamyl acetate

1233

(C)

2G

Methylamyl alcohol

2053

(C)

2G

Methylcyclohexane (bb)

2296

(C)

2G

Methylamine solutions (42%


or less)

Special requirements

2-Methyl-6-ethylaniline

(B) SP

Boiling Point [/ C]

Respiratory and Eye Protection

Auto-Ignition Temperature [/ C]

Materials of Construction

Flashpoint [/ C]

Fire Protection

Density [kg/ m]

Vapour Detection

Flashpoint >60/

a
Methacrylic resin in ethylene
dichloride

Apparatus Group

Tank Environmental Control

Product name

Temperature Class

Tank Vents

Tank Type

Ship Type

Hazards

Pollution Category

UN Number

Gauging

Electrical
equipment

920

(74)

970

102

231

430

49

900

~-10

15.19.6

C8O2H16

860

(43)

15.19.6

C6OH14

808

(41)

15.19.6

CH3C6H11

770

-4

15.19.6

(B)

2G

2G

Methylnaphthalene (molten)

SP

2G

A, D

N2

15.19.6

104

NC5H3(CH3)(C2H5)
CH3NH2

Methyldiethanolamine

32

(CH3)(C2H5)C6H3NH2
15.12, 15.17, 15.19

Methylcyclopentadiene dimer

102
456

195

N1

90

C12H16

934

60

CH3N(C2H4OH)2

1040

>100

178

146
132
285

101
78-183

N4

15.12.3, 15.19.6

25

Density [kg/ m]

Tank Type

Ship Type

Hazards

Pollution Category

q
950

Chemical
Formula

Special requirements

p
(C5H4N)CH3

Boiling Point [/ C]

g
C

Auto-Ignition Temperature [/ C]

Respiratory and Eye Protection

f
2G

Flashpoint [/ C]

Materials of Construction

e
2

Fire Protection

Gauging

d
S

Vapour Detection

Flashpoint >60/

c
D

UN Number
a
2-Methylpyridine

Apparatus Group

Tank Environmental Control

b
2313

Product name

Temperature Class

Tank Vents

Electrical
equipment

t
54

3-Methylpyridine

2313

SP

2G

A, C

N4

15.12.3, 15.19

NCHC(CH3)CHCHCH

940

40

4-Methylpyridine

2313

2G

F-T

N4

15.12.3, 15.19, 16.2.9

NCHCHC(CH3)CHCH

957

57

alpha-Methylstyrene

2303

SP

2G

T1 IIB

F-T

A,
D *4)

15.13, 15.19.6, 16.6.1,


16.6.2

C6H5C(CH3)CH2

906

54

574

166

15.19.6

(CH2)4ONH

1000

(38)

310

129

15.6, 15.12, 15.18,


15.19

Pb(C2H5)4

~1800

145

180

C10H8

540

218

Morpholine

2054

2G

T2 IIA

Motor fuel anti-knock


compounds (containing lead
alkyls)

1649

SP

1G

T4 IIA

Naphthalene (molten)

2304

T1 IIA

N2, Z

F-T A, C

535

128
145

SP

2G

A, D

15.19.6

Naphthenic acids

2G

15.19.6

Neodecanoic acid

2G

16.2.8

C9H19COOH
H2SO4 + HNO3

~1800

90

Nitrating acid (mixture of


sulphuric and nitric acids)

1796

Nitric acid (70 % and over)

2031,
2032 h)

Nitric acid (less than 70%)

2031

1140

80

~960

>60

920

2G

NF

15.11, 15.16.2, 15.17,


15.19

SP

2G

NF

15.11, 15.19

HNO3

~1500

84

SP

2G

NF

15.11, 15.19

HNO3

~1420

122

15.12, 15.17 to 15.19,


16.2.9

C6H5NO2

1200

88

480

211

C2H5NO2

1050

30.5

414

114

32

416

112133

(C) SP

Nitrobenzene

1662

SP

2G

T1 IIA

Nitroethane

2842

(D)

2G

IIB

F-T A (u)

N4

15.16.1, 15.19.6,
16.6.1, 16.6.2, 16.6.4

Nitroethane(80%)/Nitropropane(20%)

1993

2G

IIB

F-T A (u)

N4

15.16.1, 15.19.6, 16.6.1


C2H5NO2 / C3H7NO2
to 16.6.3

1030

o-Nitrophenol (molten)

1663

SP

2G

A, D

15.12, 15.19.6, 16.2.6,


16.2.9, 16A.2.2

NO2C6H4OH

1300

1- or 2-Nitropropane

2608

2G

F-T

15.19.6

CH3CH2CH2NO2 or
(CH3)2CHNO2

1000
990

T2 IIB

A, D

214
(49) (39) ~420

131
120

2G

1010

34

421

112

Chemical
Formula

Special requirements

15.19.6

Mixture of CH3CH2CH2NO2
and CH3CH2NO2

A, B

15.12, 15.17, 15.19,


16.2.9

NO2C6H4CH3

1299

106

F-T

A u)

N4

o- or p-Nitrotoluenes

1664

SP

2G

Nonane (all isomers) (bb)

1920

(C)

2G

B,C

15.19.6

C9H20

722

30

2G

15.19.6

CH3(CH2)6CH=CH2

743

25

15.19.6

Nonene (all isomers)


Nonyl acetate

IIB

Boiling Point [/ C]

Auto-Ignition Temperature [/ C]

Flashpoint [/ C]

Density [kg/ m]

Respiratory and Eye Protection

Materials of Construction

Tank Environmental Control

Fire Protection

Tank Vents

Vapour Detection

Tank Type

Gauging

Ship Type

Flashpoint >60/

Hazards

a
Nitropropane (60%) /
Nitroethane (40%) mixture

Apparatus Group

Pollution Category

Product name

Temperature Class

UN Number

Electrical
equipment

(C)

2G

Nonyl alcohol (all isomers)

2G

Nonylphenol

2G

15.19.6

Nonylphenol poly(4+)-ethoxylates

2G

15.19.6, 16.2.6, 16.2.9,


16A.2.2 aa)

Noxious liquid, F., ( 2)


n.o.s.(trade name..,contains..)
S.T. 1, Cat. A*2)

2G

15.19

Noxious liquid, F., ( 4)


n.o.s.(trade name..,contains..)
S.T. 2, Cat. A*2)

2G

15.19.6

Noxious liquid, F., ( 7)


n.o.s.(trade name..,contains..)
S.T. 2, Cat. B*2)

2G

15.19.6, (16.2.6,
16.2.9) *3)

Noxious liquid, F., ( 8)


n.o.s.(trade name..,contains..)
S.T. 2, Cat. B,m.p. 15/C+*2)

2G

15.19.6, (16.2.6)*3),
16.2.9, 16A.2.2

Noxious liquid, F., (10)


n.o.s.(trade name..,contains..)
S.T. 3,Cat. A *2)

2G

15.19.6

Noxious liquid, F., (13)


n.o.s.(trade name..,contains..)
S.T. 3,Cat. B *2)

2G

15.19.6, (16.2.6,
16.2.9) *3)

238
206

151
150

~870

67

CH3(CH2)7CH2OH

829

74

215

C9H19C6H4OH

950

141

315

1040

(16.2.7 to 16.2.9)*3)

15.19

2G

15.19.6

2G

15.19.6, (16.2.6,
16.2.9) *3)

2G

15.19.6, (16.2.6)*3),
16.2.9, 16A.2.2

2G

15.19.6

Noxious liquid, N.F.,(11)


n.o.s.(trade name..,contains..)
S.T. 3,Cat. B*2)

2G

15.19.6, (16.2.6,
16.2.9) *3)

Noxious liquid, N.F.,(12)


n.o.s.(trade name..,contains..)
S.T. 3,Cat. B, m.p. 15/C+*2)

2G

15.19.6, (16.2.6)*3),
16.2.9, 16A.2.2

Noxious liquid, N.F.,(15)


n.o.s.(trade name..,contains..)
S.T. 3 ,Cat.C *2)

2G

(16.2.7 to 16.2.9)*3)

2G

Noxious liquid, F., (16)


n.o.s.(trade name..,contains..)
S.T. 3,Cat. C *2)

2G

Noxious liquid, N.F., ( 1)


n.o.s.(trade name..,contains..)
S.T. 1,Cat. A *2)

2G

Noxious liquid, N.F., ( 3)


n.o.s.(trade name..,contains..)
S.T. 2,Cat. A *2)

Noxious liquid, N.F., ( 5)


n.o.s.(trade name..,contains..)
S.T. 2,Cat. B *2)

Noxious liquid, N.F., ( 6)


n.o.s.(trade name..,contains..)
S.T. 2,Cat. B, m.p. 15/C+*2)

Noxious liquid, N.F., ( 9)


n.o.s.(trade name..,contains..)
S.T. 3,Cat. A *2)

Boiling Point [/ C]

Respiratory and Eye Protection

Auto-Ignition Temperature [/ C]

Materials of Construction

Chemical
Formula
Flashpoint [/ C]

Fire Protection

15.19.6, (16.2.6)*3),
16.2.9, 16A.2.2

Special requirements

Density [kg/ m]

Vapour Detection

Flashpoint >60/

Apparatus Group

Noxious liquid, F., (14)


n.o.s.(trade name..,contains..)
S.T. 3,Cat. B, m.p. 15/C+*2)

Product name

Temperature Class

Tank Environmental Control

Tank Vents

Tank Type

Ship Type

Hazards

Pollution Category

UN Number

Gauging

Electrical
equipment

Tank Type

Ship Type

Hazards

Pollution Category

Boiling Point [/ C]

Respiratory and Eye Protection

g
C

Auto-Ignition Temperature [/ C]

Materials of Construction

f
2G

Flashpoint [/ C]

Fire Protection

e
3

Chemical
Formula

Special requirements

Density [kg/ m]

Gauging

d
P

Vapour Detection

Flashpoint >60/

c
(C)

UN Number
a
Octane (all isomers) (bb)

Apparatus Group

Tank Environmental Control

b
1262

Product name

Temperature Class

Tank Vents

Electrical
equipment

703

13

220

126

CH3(CH2)6CH2OH

830

~70

~185

CH3(CH2)5CH=CH2

720

21

~125

15.19.6

CH3(CH2)6CH3

15.19.6

15.19.6, 16.2.9

Octanol (all isomers)

2G

Octene (all isomers)

2G

n-Octyl acetate

2G

CH3COO(CH2)7CH3

869

82

199

CH3(CH2)6CHO or
C4H9CH(C2H5)CHO

820

52

163

Octyl aldehydes

1191

(B)

2G

Olefin mixtures (C5-C15)

2G

15.19.6

~750

0-38

Olefin mixtures (C5-C7) (bb)

2G

15.19.6

~700

-20

alpha-Olefins (C6-C18)
mixtures

2G

15.19.6, 16.2.6, 16.2.9

~800

0-25

SP

2G

15.11.2 to 15.11.8,
15.12.1, 15.16.2, 15.17, H2SO4 + SO3
15.19, 16.2.7, 16.2.8

<1980

Oleylamine

SP

2G

15.19.6

828

~93

Palm kernel acid oil

2G

A, B

16.2.7 to 16.2.9

870

15.19.6, 16.2.9

C6H12O3

990

36

238

125

15.12, 15.17, 15.19.6

CHCl2CCl3

1680

16

15.13, 15.19.6, 16.6.1


to 16.6.3

CH3CH=CH-CH=CH2

680

-43

>200

42
36

Oleum

1831

NF

Paraldehyde

1264

SP

2G

T3 IIB

Pentachloroethane

1669

SP

2G

NF

1,3-Pentadiene

SP

2G

F-T A, B

130
>100

(C)

2G

15.14, 15.19.6

CH3(CH2)3CH3

626

-49

308

Pentene (all isomers) (bb)

2G

15.14, 15.19.6

CH3CH2CH2CH=CH2

656

-18

~270 30-37

n-Pentyl propionate

2G

15.19.6
Cl2C=CCl2

1625

121

C6H5OH

1070

82

715

182

988

149

Pentane (all isomers) (bb)

1265

Perchloroethylene

1897

SP

2G

NF

Phenol

2312

SP

2G

T1 IIA

2G

1-Phenyl-1-xylylethane (bb)

15.12.1, 15.12.2,
15.19.6

15.12, 15.19, 16.2.7 to


16.2.9

A, B

290

2G

SP

1G

Pad + (V
or Inert)

NF
- k)

Boiling Point [/ C]

Phosphorus, yellow or white

Auto-Ignition Temperature [/ C]

1805

Flashpoint [/ C]

Phosphoric acid

Density [kg/ m]

Respiratory and Eye Protection

Materials of Construction

Tank Environmental Control

Fire Protection

Tank Vents

Vapour Detection

Tank Type

Gauging

Ship Type

Flashpoint >60/

Hazards

Apparatus Group

Pollution Category

Product name

Temperature Class

UN Number

Electrical
equipment

H3PO4

1500 1700

200

1820

282

580

Special requirements

Chemical
Formula

15.11.1 to 15.11.4,
15.11.6 to 15.11.8

15.7, 15.19

Phthalic anhydride (molten)

2214

SP

2G

A, D

16.2.7 to 16.2.9

C6H4(CO)2O

1530

152

Pine oil

1272

2G

16.2.7, 16.2.8

C10H16

970

78

>180

alpha-Pinene

2368

T1 IIA

285

2G

15.19.6

C10H16

864

32

70

beta-Pinene

2G

15.19.6

C10H16

877

47

73

Poly(2+)cyclic aromatics

2G

A, D

15.19.6

~900

>60

Polyalkyl (C18-C22) acrylate


in xylene

2G

15.19.6, 16.2.7, 16.2.8

1100

1020

Polyalkylene oxide polyol

2G

16.2.7, 16.2.8

Polyethylene polyamines

(C) SP

2G

N2

16.2.9

Polyferric sulphate solution

(C) SP

2G

Y4

N5

15.12, 15.16.2, 15.19.6

NF

1050

>150

1460

1190

218

Polymethylene polyphenyl
isocyanate

2G

X b)

T b)

Polyolefin phosphorosulphide, barium derivative


(C28-C250)

2G

A, B

16.2.7, 16.2.8

Polyolefinamine in alkyl(C2C4) benzenes

(C)

2G

15.19.6, 16.2.7, 16.2.8

900

Polyolefinamine in aromatic
solvent

(C)

2G

15.19.6, 16.2.7, 16.2.8

900

Potassium chloride solution


(10% or more)

2G

NF

SP

2G

NF

Potassium hydroxide solution


Potassium oleate

1814

2G

N8

>200
-

~200
38-44

>425

148

1500

150

~1300

very
high

~1000
16.2.9
15.19.6

KOH

2G

SP

2G

IIA

Tank Type

Ship Type

Hazards

49

CH3CH2COOH

990

50

485

141

(C2H5CO)2O

1020

(74)

C3H5N

780

35

97

~860

-18

47

F-T

15.16.1, 15.17, 15.19.6 C2H5CHO

15.11.2 to 15.11.4,
15.11.6 to 15.11.8,
15.19.6

T1 IIA

Propionic anhydride

2496

SP

2G

T2 IIA

Propionitrile

2404

SP

1G

T1 IIB

n-Propyl chloride

1278

2G

n-Propylamine

1277

SP

2G

Inert

F-T A, D

SP

2G

F-T C, D

Y1

Y1

F-T A, D
F

o
16.2.9

N2

15.12, 15.19

C3H7NH2

720

<-20

~320

49

N1

15.12, 15.19

(CH3)2CHNH2

782

- 26

402

47,8

C6H5CH2CH2CH3

860

<-20

430

34

550

115

2G

15.19.6

2G

15.19.6

SP

2G

Inert

15.8, 15.12.1, 15.14,


15.19

720
CH3CHOCH2

830

2850

2G

15.19.6

760

Propylene trimer

2057

2G

15.19.6

740

40

Pyridine

1282

2G

15.19.6

980

17

1000
1050

N4

Rosin

2G

15.19.6, 16.2.6, 16.2.9,


16A.2.2

Rosin soap (disproportionated) solution

2G

15.19.6

Sodium alkyl (C14-C17)


sulphonates 60-65% solution

2G

NF

16.2.6

2G

NF

1819

167

15.19.6

Propylene tetramer

Sodium aluminate solution

155

T1 IIA

t
188

15.12, 15.17 to 15.19

A, B

F-T A, C

(C)

T2 IIB

207

2G

1280

<-20

Propylene oxide

(74)

810

Propylene dimer (bb)

1150

N2

Propylbenzene (all isomers)

(CH2)2OCO

A, D

1848

T2 IIA

>80

Propionic acid

iso-Propylamine(70% or less)
solution

980

Boiling Point [/ C]

Auto-Ignition Temperature [/ C]

1275

Flashpoint [/ C]

beta-Propiolactone
Propionaldehyde

H2NCH2CH2CH2OH

j
X

Chemical
Formula

Special requirements

Density [kg/ m]

Respiratory and Eye Protection

Materials of Construction

g
O

Fire Protection

f
2G

Vapour Detection

e
3

Gauging

d
SP

Flashpoint >60/

Pollution Category

UN Number
a
n-Propanolamine

Apparatus Group

Tank Environmental Control

c
C

Product name

Temperature Class

Tank Vents

Electrical
equipment

N1

C5H5N

CH3(CH2)13-16SONa

1070
1550

~100
-

Flashpoint [/ C]

Auto-Ignition Temperature [/ C]

Boiling Point [/ C]

1500

170

15.12.3, 15.19

Na2Cr2O7.2H2O + H2O

1720

120

15.19.6

1300

1300

SP

2G

NF

N1

16.2.7

2G

NF

Sodium dichromate solution


(70% or less)

SP

2G

NF

Sodium hydrogen sulphide


(6% or less) / Sodium
carbonate (3% or less)
solution

2G

NF

Sodium chlorate solution


(50% or less)

2428

Flashpoint >60/

a
Sodium borohydride (15% or
less)/Sodium hydroxide
solution

Apparatus Group

Product name

Temperature Class

Respiratory and Eye Protection

NaClO3

Materials of Construction

15.9, 15.16.1, 15.19.6

Fire Protection

100

Vapour Detection

Gauging

Tank Environmental Control

1400

Tank Vents

NaBH4-NaOH

Tank Type

Ship Type

Hazards

Pollution Category

UN Number

Density [kg/ m]

Electrical
equipment

N2

Special requirements

Chemical
Formula

Sodium hydrogen sulphite


solution (45% or less)

2693

2G

NF

Sodium hydrosulphide
solution (45% or less)

2949

SP

2G

V or Pad
(Gas)

NF

15.16.1, 15.19.6, 16.2.9 NaSH2H2O

1300

SP

2G

F-T

N1

15.12, 15.14, 15.16.1,


15.17, 15.19, 16.6.1 to
16.6.3

Mixtureof NaHS and (NH4)2S


in H2O

1282

10

NaOH

10001530

Sodium hydrosulphide/
Ammonium sulphide solution

Na2S2O4.2H2O

38 121

Sodium hydroxide solution

1824

2G

NF

N8

Sodium hypochlorite solution


(15% or less)

1791

SP

2G

NF

N5

15.16.1

NaOCl

1220

SP

2G

NF

15.12.3.1, 15.12.3.2,
15.16.1, 15.19

NaNO2

1200

Sodium petroleum sulphonate

SP

2G

15.19.6, 16.2.6

1050

205

Sodium silicate solution

2G

1200

Sodium sulphide solution


(15% or less)

SP

2G

Sodium nitrite solution

NF

N5

15.16.1, 15.19.6, 16.2.9

1427

150

>100

Gauging

Vapour Detection

Fire Protection

Materials of Construction

Respiratory and Eye Protection

2G

NF

Sodium tartrates/sodium
succinates solution

2G

A, B

(B)

2G

SP

2G

2G

X l)

Sodium thiocyanate solution


(56% or less)
Styrene monomer

2055

Sulpho hydrocarbon longchain (C18+) alkylamine


mixture

T1 IIA

Y5

15.16.1, 15.19.6, 16.2.9

Boiling Point [/ C]

Tank Environmental Control

Auto-Ignition Temperature [/ C]

Tank Vents

Chemical
Formula
Flashpoint [/ C]

Tank Type

Special requirements

490

145

Density [kg/ m]

Ship Type

Flashpoint >60/

Hazards

Apparatus Group

Pollution Category

Sodium sulphite solution


(25% or less)

Product name

Temperature Class

UN Number

Electrical
equipment

q
1220

1400

>93

15.19.6

NaSCN

~1000

A, B N4,Z

15.13, 15.19.6, 16.6.1,


16.6.2

C6H5CHCH2

A, B

15.19.6, 16.2.6

F-T

15.10

1800

~165

445
338

910

32
>60

Sulphur (molten)

2448

1G

V or Pad
(Gas)

Sulphuric acid

1830

SP

2G

NF

15.11, 15.16.2, 16.2.8,


16.2.9

H2SO4

1560 1840

Sulphuric acid, spent

1832

SP

2G

NF

15.11, 15.16.2, 16.2.8,


16.2.9

H2SO4 + H2O

~1100

Tall oil (crude and distilled)

2G

15.19.6, 16.2.6, 16.2.9,


16A.2.2

1000

180

Tall oil fatty acid (resin acids


less than 20%)

(C)

2G

16.2.7 to 16.2.9

1000

Tall oil fatty acid, barium salt

SP

2G

15.19.6, 16.2.6

1150

Tall oil soap (disproportionated) solution

2G

15.19.6, 16.2.6, 16.2.9

1040

15.12, 15.17, 15.19.6

F-T

Tetrachloroethane

1702

SP

2G

Tetraethylenepentamine

2320

2G

Tetrahydrofuran

2056

2G

2G

Tetrahydronaphthalene (bb)

T3

NF
T3 IIB

N1

15.19.6

165

>100
100

C2H2Cl4

1600

HN(C2H4NHC2H4NH2)2

1000

(163)

146

CH2(CH2)2CH2O

890

-20

321

64

C10H12

981

71

384

206

333

2G

Toluene (bb)

2G

1294

Toluene diisocyanate

2078

SP

2G

Toluenediamine

1709

SP

2G

o-Toluidine

1708

16.2.9, 16A.2.2

C6H2(CH3)4

896

15.19.6

C6H5CH3

866

536

111

N4

15.12, 15.16.2, 15.17,


15.19, 16.2.9

CH3C6H3(NCO)2

1200

132

620

251

N1

15.12, 15.17, 15.19,


16.2.7, 16.2.9

CH3C6H3(NH2)2

~1000

450

280

T1 IIA

Boiling Point [/ C]

Auto-Ignition Temperature [/ C]

Flashpoint [/ C]

Density [kg/ m]

Respiratory and Eye Protection

Materials of Construction

Tank Environmental Control

Fire Protection

Tank Vents

Vapour Detection

Tank Type

Gauging

Ship Type

Flashpoint >60/

Hazards

a
Tetramethylbenzene (all
isomers)

Apparatus Group

Pollution Category

Product name

Temperature Class

UN Number

Electrical
equipment

A,
F-T C c),
D

A, D

Special requirements

Chemical
Formula

197

SP

2G

15.12, 15.17, 15.19

C7H9N

1000

85

Tributyl phosphate

2G

15.19.6

(C4H9)3PO

978

146

1,1,2-Trichloro-1,2,2trifluoroethane

2G

CCl2FCClF2

1420

C6H3Cl3

1460

CH3CCl3

1325

NF

15.19.6, 16.2.9,
16A.2.2

480

200
292
48

1,2,4-Trichlorobenzene

2321

SP

2G

A, B

1,1,1-Trichloroethane

2831

2G

SP

2G

15.12.1, 15.19.6

CHCl2CH2Cl

1440

113

ClCH=CCl2

1462

410

87

1,1,2- Trichloroethane
Trichloroethylene

1710

75

A, B,
D

15.12, 15.17, 15.19

CH2ClCHClCH2Cl

1390

82

304

156

A, B

15.12.3, 15.19

(CH3C6H4O)3PO

1180

238

385

440

15.19.6

(CH3C6H4O)3PO

1160

225

410

420

15.19.6, 16.2.6, 16.2.9,


CH3(CH2)11COOH
16A.2.2

845

>110

2G

SP

2G

SP

2G

Tricresyl phosphate
(containing less than 1%
ortho-isomer)

2G

Tridecanoic acid

2G

2574 j)

213

SP

Tricresyl phosphate
(containing 1% or more
ortho-isomer)

15.12, 15.16.1, 15.17,


15.19.6

1,2,3-Trichloropropane

NF

110

T2 IIA

T2 IIA

312

2323

SP

2G

Triethylamine

1296

SP

2G

2G

2G

Triethylbenzene
Triethylenetetramine

2259

Triisopropylated phenyl
phosphates

T2 IIA
T2 IIA

N1

F-T A, B

15.12.1, 15.19.6

(CH3CH2)3PO3

970

54

F-T A, C

N2

15.12, 15.19.6

(C2H5)3N

730

-17

15.19.6

C6H3(C2H5)3

860

111

2G

2,2,4-Trimethyl-1,3pentanediol-1-isobutyrate

2G

Trimethylacetic acid

2G

Trimethylbenzene (all
isomers)

N1

F-T A, D

F-T A, C

NH2(C2H4NH)2C2H4NH2

15.19.6

15.12.1, 15.16.2,
15.19.6

Y1
N1

p
(CH2CH2OH)3N

15.11.2 to 15.11.8

15.12, 15.14, 15.19,


16.2.9

89

335

278

135
200 245

(CH3O)3P

1050

27

111

(CH3)2CHCH(OH)C(CH3)2
CH2OOCCH(CH3)2

960

118

182

(CH3)3CCOOH

910

71

164

54

169

SP

2G

920

2G

15.19.6

C6H3(CH3)3

15.12, 15.16.2, 15.17,


15.19.6

C11H18N2O2

15.19.6

C9H22N2

870

876

2328

SP

2G

A,
C c)

Trimethylhexamethylenediam
ine (2,2,4-and 2,4,4-isomers)

2327

2G

A,C

1,3,5-Trioxane

2G

A ,D

15.19.6

Trixylyl phosphate

2G

15.19

((CH3)2C6H3O)3PO

1150

232

2G

15.19.6

C10H16

880

32

Undecanoic acid

2G

16.2.6, 16.2.9

CH3(CH2)9COOH

890

1-Undecene

2G

15.19.6

CH2=CH(CH2)8CH3

700

1299

157
230

980

Trimethylhexamethylenediiso
cyanate (2,2,4-and 2,4,4isomers)

Turpentine

t
360

1100 1400

N1

Boiling Point [/ C]

2G

1297

Trimethylamine solution
(30% or less)

r
179

2329

q
1130

j
X

Trimethyl phosphite

Auto-Ignition Temperature [/ C]

Tank Type

Ship Type

Hazards

Triethyl phosphite

Flashpoint [/ C]

IIA

Chemical
Formula

Special requirements

Density [kg/ m]

Respiratory and Eye Protection

Materials of Construction

g
O

Fire Protection

f
2G

Vapour Detection

e
3

Gauging

d
S

Flashpoint >60/

Pollution Category

UN Number
a
Triethanolamine

Apparatus Group

Tank Environmental Control

c
D

Product name

Temperature Class

Tank Vents

Electrical
equipment

very
high
104

350

232

1170
253
284

Undecyl alcohol

2G

Urea/Ammonium nitrate
solution (containing aqua
ammonia)

SP

2G

SP

2G

Inert

Valeraldehyde(all isomers)

2058

X
NF
T3 IIB

F-T

N4

15.19.6, 16.2.9,
16A.2.2 (r)

CH3(CH2)9CH2OH

Boiling Point [/ C]

Auto-Ignition Temperature [/ C]

Chemical
Formula
Flashpoint [/ C]

Special requirements

Density [kg/ m]

Respiratory and Eye Protection

Materials of Construction

Tank Environmental Control

Fire Protection

Tank Vents

Vapour Detection

Tank Type

Gauging

Ship Type

Flashpoint >60/

Hazards

Apparatus Group

Pollution Category

Product name

Temperature Class

UN Number

Electrical
equipment

q
834

93

1300

15.4.6, 15.16.1, 15.19.6 CH3(CH2)3CHO

810

12

~215

103

15.13, 15.19.6, 16.6.1,


16.6.2

CH3COOCH=CH2

930

-8

427

73

15.4, 15.13, 15.14,


15.19, 16.6.1, 16.6.2

CH2=CHOC2H5

754

-45

200

36

15.13, 15.16.1, 15.19.6,


C4O2R1R2R3
16.6.1, 16.6.2

880

>80

309

Vinyl acetate

1301

SP

2G

T2 IIA

Vinyl ethyl ether

1302

SP

1G

Inert

T3 IIB

F-T

SP

2G

A, B

T2 IIA

F-T

N5

15.13, 15.14, 15.19.6,


16.6.1, 16.6.2

CH2=CCl2

1210

(-10)

460

32

IIA

A, B

N1

15.13, 15.19.6, 16.6.1,


16.6.2

C6H4(CH3)CH=CH2

890

54

494

170

15.19.6

750

~40

232

27

Vinyl neodecanoate

N6

Vinylidene chloride

1303

2G

Inert

Vinyltoluene

2618

SP

2G

White spirit, low (15-20%)


aromatic

1300

(B)

2G

Xylenes (bb)

1307

2G

15.19.6, 16.2.9 (w)

C6H4(CH3)2

~890

(CH3)2C6H3OH

1020

Xylenol

2261

A, B

15.19.6, 16.2.9,
16A.2.2

A, B

16.2.7, 16.2.8

~1000

>60

A, B

15.19.6, 16.2.7

~1000

>60

SP

2G

Zinc alkaryl dithio-phosphate


(C7-C16)

(C)

2G

Zinc alkyl dithio- phosphate


(C3-C14)

2G

IIA

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