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17-1
Section 17
Summary of Minimum Requirements
Mixtures of noxious liquid substances presenting pollution hazards only and which are provisionally assessed under
regulation 3(4) of Annex II of MARPOL 73/78, may be carried under the requirements of this Section applicable
to the appropriate position of the entry in this Section for noxious liquids not otherwise specified (n.o.s.)
Explanatory Notes
UN Number
(column b)
The number relating to each product shown in the recommendations proposed by the United
Nations Committee of Experts on the Transport of Dangerous Goods. UN numbers, where
available, are given for information only.
Pollution Category
(column c)
The letter A, B, C and D means the pollution category assigned to each product under Annex II
of MARPOL 73/78.
I means the product was evaluated and found to fall outside the categories A, B, C or D. A blank
indicates that the product has not yet been evaluated.
Pollution category in brackets indicates that the product is provisionally categorized and that
further data are necessary to complete the evaluation of their pollution hazards. Until the hazard
evaluation is completed, the pollution category assigned is used.
Hazards
(column d)
Ship Type
(column e)
1
2
3
=
=
=
Tank Type
(column f)
1
2
G
P
=
=
=
=
Tank Vents
(column g)
O
C
SR
=
=
=
open venting
controlled venting
safety relief valve
inerting (9.1.2.1)
padding, liquid or gas pad (9.1.2.2)
drying (9.1.2.3)
ventilating, natural or forced (9.1.2.4)
Electrical Equipment T1 to T6
IIA, IIB or IIC
(column i)
NF
=
=
=
=
=
temperature classes 2)
apparatus groups 2)
non-flammable product (10.1.6)
flashpoint not exceeding 60 /C
(closed cup test) (10.1.6)
flashpoint above 60 /C
(closed cup test) (10.1.6)
1)
2)
Temperature classes and apparatus groups as defined in International Electrotechnical Commission Publication 78 (part 1, appendix
D, part 4, 8 and 12). A blank indicates that data are currently not available.
17-2
Gauging
(column j)
O
R
C
I
=
=
=
=
Vapour Detection 1)
(column k)
F
T
=
=
flammable vapours
toxic vapours
Fire Protection
(column l)
A
B
=
=
C
D
=
=
Dry chemical powder systems, when used, may require an additional water system for boundary
cooling. This is normally provided in sufficient quantities by the standard fire main system
required by regulation II-2/4 of the 1974 SOLAS Convention as amended.
Materials of
Construction
(column m)
N
Z
Y
=
=
=
see 6.2.2
see 6.2.3
see 6.2.4
1)
Values in ( ) are open cup values, all other values are closed cup values.
=
non-flammable product
17-3
For mixtures containing no other components with safety hazards and where the pollution category is C or less.
*2)
In case of a specific n.o.s. cargo assessed as falling within this n.o.s. group that is carried on a ship, this entry,
including the cargos trade name and one or two principle components, should be provided in the shipping
document. Abbreviations used mean:
N.F.
F.
n.o.s.
S.T.
Ship type
Cat.
Pollution category
m.p.
Melting point
*3)
*4)
Only certain alcohol resistant foams are effective for this product.
a)
b)
c)
Diphenylmethane diisocyanate
Toluene diisocyanate
Trimethylhexamethylene diisocyanate (2,2,4- and 2,4,4-isomers)
Although water is suitable for extinguishing open air fires involving chemicals to which this footnote applies, water
is not allowed to contaminate closed tanks containing these chemicals because of the risk of hazardous gas
generation.
d)
e)
f)
g)
Maleic anhydride
Dry chemical cannot be used because of the possibility of an explosion.
h)
i)
(Deleted)
17-4
j)
k)
l)
Sulphur (molten)
Sulphur (molten) has a flashpoint above 60 /C (closed cup test), however, electrical equipment is to be certified safe
for gases evolved.
m)
n)
2- or 3-Chloropropionic acid
UN number 2511 applies to 2-Chloropropionic acid only.
o)
Dinitrotoluene (molten)
Dinitrotoluene is not to be carried in deck tanks.
p)
(Deleted)
q)
r)
Undecyl alcohol
Reference to 16.A.2.2 applies to 1-Undecyl alcohol only.
s)
t)
u)
v)
Formic acid
Confined spaces should be tested for both Formic acid vapours and Carbon monoxide gas, a decomposition product.
w)
Xylenes
Applies to p-Xylene only.
x)
y)
z)
17-5
aa)
bb)
Oil-like substances
Applies to oil-like substances identified in accordance with the provisions of the unified interpretation of regulation
14 of Annex II of MARPOL 73/78 agreed by the MEPC.
Remark:
Columns p to t are for guidance only. The data included therein have been taken from different publications.
For List of Product refer to pages 17-6 to 17-32.
17-6
17-7
17-8
17-9
17-10
17-11
17-12
17-13
17-14
17-15
17-16
17-17
17-18
17-19
17-20
17-21
17-22
17-23
17-24
17-25
17-26
17-27
17-28
17-29
17-30
17-31
17-32
17-33
17-34
17-35
17-36
17-37
Acetochlor
Boiling Point [/ C]
1715
Auto-Ignition Temperature [/ C]
Acetic anhydride
Flashpoint [/ C]
Acetic acid
Density [kg/ m]
Materials of Construction
Fire Protection
Tank Vents
Vapour Detection
Tank Type
Gauging
Ship Type
Flashpoint >60/
Hazards
Apparatus Group
Pollution Category
Product name
Temperature Class
UN Number
Electrical
equipment
CH3COOH
1050
40
485
118
330
140
Special requirements
Chemical
Formula
2G
T1 IIA
Y1,Z
15.11.2 to 15.11.4,
15.11.6 to 15.11.8,
15.19.6
2G
T2 IIA
F-T
Y1
15.11.2 to 15.11.4,
15.11.6 to 15.11.8,
15.19.6
(CH3CO)2O
1080
49
2G
15.19.6
C14H20NO2Cl
1117
>100
(CH3)2C(OH)CN
930
75
688
82
15.12, 15.19.6
CH3CN
780
525
82
1050
102
Acetone cyanohydrin
1541
SP
2G
T1 IIA
Acetonitrile
1648
2G
T2 IIA
F-T
2074
2G
NF
Acrylic acid
2218
2G
T2 IIA
F-T
Acrylonitrile
1093
SP
2G
T1 IIB
F-T
Adiponitrile
2205
2G
IIB
SP
2G
2G
2G
2G
Alcohol (C6-C17)(secondary)
poly (3- 6) ethoxylates
2G
Alcohol (C6-C17)(secondary)
poly (7-12) ethoxylates
2G
Y1
N3,Z
CH2=CHCOOH
1050
(54)
374
140
CH2=CHCN
800
-5
480
77
CN(CH2)4CN
960
(93)
Y1
1120
15.19.6
900
15.19.6, 16.2.6
1000
15.19.6
1000
1000
A, C
Y1
162
930
295
2G
2G
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
(C)
Flashpoint [/ C]
Alkanes (C6-C9)
Density [kg/ m]
15.19.6
600 700
<60
15.19.6, 16.2.6
<1000
>60
960
~70
890
<20
Materials of Construction
Fire Protection
Tank Vents
Vapour Detection
Tank Type
Gauging
Ship Type
Flashpoint >60/
Hazards
Apparatus Group
Pollution Category
Product name
Temperature Class
UN Number
Electrical
equipment
A, B
Special requirements
Chemical
Formula
SP
2G
A, B
Alkyl acrylate-vinylpyridine
copolymer in toluene
2G
15.19.6
Alkyl(C3-C4)benzenes
2G
15.19.6
870
<60
Alkyl(C5-C8)benzenes
2G
15.19.6
~900
>60
Alkyl(C7-C11)phenol poly
(4-12) ethoxylate
2G
1050
240
Alkylbenzene, alkylindane,
alkylindene mixture (each
C12- C17)
2G
15.19.6
860
185
SP
2G
16.2.7, 16.2.8
964
135
400
2G
16.2.7 to 16.2.9
Alkylbenzenesulphonic acid
2584,
2586
Alkylbenzenesulphonic acid,
sodium salt solution
NF
RC6H4SO3H
110
284
1000
Allyl alcohol
1098
SP
2G
T2 IIB
F-T
CH2CHCH2OH
850
21
375
97
Allyl chloride
1100
SP
2G
T2 IIA
F-T
CH2CHCH2Cl
940
<-20
390
45
1G
NF
~1200
2G
CH3C(CH3)NH2CH2OH
930
67
165
2-(2-Aminoethoxy) ethanol
3055
Aminoethylethanolamine
N-Aminoethylpiperazine
2815
2G
(D)
2G
2G
T2 IIA
X f) 15.11
N1
A, D
N2
N1
N2
15.19.6
15.19.6
C4H11NO2
1060
107
NH2C2H4NHC2H4OH
1030
129
365
243
221
C6H15N3
980
107
308
220
Auto-Ignition Temperature [/ C]
Boiling Point [/ C]
NH4HSO3 + H2O
1260 1380
100 103
NH4NO3
~1750
(NH4)2S/H2O
993
22
~1150
(NH4)2S2O3
~1500
15.16.1, 16.6.1 to
16.6.3
Y4
N1
NF
2693
2G
NF
1G
NF
SP
2G
F-T
(C)
2G
NF
Ammonium thiosulphate
solution (60% or less)
(C)
2G
NF
Special requirements
Chemical
Formula
p
NH3 + H2O
16.2.9
38 100
15.19.6
CH3COOC5H11
880
~37
C6H5NH2
1020
76
770
184
1104
2G
Aniline
1547
SP
2G
(C)
2G
SP
2G
Benzenesulphonyl chloride
2G
2225
Y5
T1 IIA
X a)
N4
2G
900
T1 IIA
SP
2683
2672 m)
A, B,
C
Ammonium bisulphite
solution (70% or less)
Flashpoint [/ C]
Density [kg/ m]
Materials of Construction
Fire Protection
Tank Vents
Vapour Detection
Tank Type
Gauging
Ship Type
Flashpoint >60/
Hazards
a
Ammonia aqueous (28% or
less)
Apparatus Group
Pollution Category
Product name
Temperature Class
UN Number
Electrical
equipment
F-T A, B
T
A, D
N1
~130
15.19.6
700
880
-11
555
80
15.19.6
1378
128
252
C6H5SO2Cl
Benzyl acetate
2G
C6H5CH2O2CCH3
1060
Benzyl alcohol
2G
C6H5CH2O
1050
100
436
206
C6H5CH2Cl
1100
~68
585
179
CH2BrCl
1930
68
Benzyl chloride
1738
SP
2G
Bromochloromethane
1887
Butene oligomer
T1 IIA
2G
NF
2G
A, B
A
X
N3
15.19.6
660
15.19.6
(CH3)2COO(CH2)3
883
33
421
126
F-T
15.13, 15.19.6,
16.6.1,16.6.2
C7H12O2
900
37
275
148
15.19.6
1120
199
15.19.6
CH3(CH2)2COOC4H9
870
54
T4 IIB
F-T
(C4H9)2O
770
25
194
141
IIA
F-T A, D
CH2=C(CH3) COOC4H9
900
(54)
290
165
C2H5COOC4H9
870
32
425
146
SP
2G
2G
2G
SP
2G
Inert
2G
Butyl methacrylate
n-Butyl propionate
T2 IIB
166
Tank Type
Ship Type
Hazards
2G
15.19.6
Butyl/Decyl/Cetyl/Eicosyl
methacrylate mixture
2G
A, D
SP
2G
F-T
C4H9NH2
700 750
2G
15.19.6
C6H5(CH2)3CH3
860
~52
15.8.1 to 15.8.7,
15.8.12, 15.8.13,
15.8.16 to 15.8.19,
15.8.21, 15.8.25,
15.8.27, 15.8.29,
15.19.6
H2COCHCH2CH3
890
-20
15.16.1, 15.19.6
CH3(CH2)2CHO
800
-7
230
76
15.11.2 to 15.11.4,
15.11.6 to 15.11.8
CH3(CH2)2COOH
958
72
450
164
15.19.6
15.16.1
Ca(OCl)2
1140
1,2-Butylene oxide,
1914
Pollution Category
UN Number
1149
Flashpoint [/ C]
Density [kg/ m]
2G
Chemical
Formula
Special requirements
Boiling Point [/ C]
Materials of Construction
n-Butyl ether
Auto-Ignition Temperature [/ C]
Fire Protection
Vapour Detection
Gauging
Apparatus Group
Product name
Temperature Class
j
-
Tank Vents
Flashpoint >60/
Electrical
equipment
2709
3022
2820
SP
2G
Inert
T2 IIB
A, C
SP
2G
T3 IIA
F-T
2G
Calcium alkyl(C9)phenol
sulphide/Polyolefin
phosphorosulphide mixture
2G
A, B
Calcium hypochlorite
solution (15% or less)
SP
2G
NF
N1
Y1
N5
183
65
Gauging
Vapour Detection
Fire Protection
Materials of Construction
SP
2G
NF
N5
15.16.1, 15.19.6
2G
A, B
16.2.7, 16.2.8
Camphor oil
SP
2G
Carbolic oil
SP
2G
Carbon disulphide
1131
SP
1G
Pad +
Inert
Carbon tetrachloride
1846
IIA
T6 IIC
920
15.12, 15.19
1060
F-T
CS2
1260
<-20
95
46
CCl4
1590
76
950
>100
860
149
2G
A, B
Cetyl/Eicosyl methacrylate
mixture
2G
A, D
2G
15.19
(C)
2G
NF
N1
SP
2G
NF
Y5
2G
T1 IIA
2G
NF
(D)
2G
IIA
SP
2G
Chlorohydrins (crude)
o-Chloronitrobenzene
1578
47
15.19.6
SP
>60
SP
~970
NF
A, B
1134
1200
F-T
2G
1888
Chloroform
SP
Chlorobenzene
1750
Ca(OCl)2
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
Tank Vents
Chemical
Formula
Flashpoint [/ C]
Tank Type
Special requirements
Density [kg/ m]
Ship Type
Flashpoint >60/
Hazards
Apparatus Group
Pollution Category
Calcium hypochlorite
solution (more than 15%)
Product name
Temperature Class
UN Number
Electrical
equipment
370
1100
1350
15.11.2, 15.11.4,
15.11.6 to 15.11.8,
15.12.3, 15.19, 16.2.9
CH2ClCOOH
1330
186
132
F-T
A,B
15.19.6
C6H5Cl
1110
28
590
15.12, 15.19.6
CHCl3
1480
F-T
15.12, 15.19
A, B,
D
1200
C6H4ClNO2
1368
61
213
127
>149
246
2G
SP
2G
X
NF
Y1
Boiling Point [/ C]
1754
Auto-Ignition Temperature [/ C]
Chlorosulphonic acid
2511 n) (C) SP
Flashpoint [/ C]
2- or 3-Chloropropionic acid
Density [kg/ m]
Materials of Construction
Fire Protection
Tank Vents
Vapour Detection
Tank Type
Gauging
Ship Type
Flashpoint >60/
Hazards
Apparatus Group
Pollution Category
Product name
Temperature Class
UN Number
Electrical
equipment
CH3CHClCOOH or
CH2ClCH2COOH
1260
107
550
185
15.11.2 to 15.11.8,
15.12, 15.16.2, 15.19
SO2OHCl
1770
158
Special requirements
Chemical
Formula
15.11.2 to 15.11.4,
15.11.6 to 15.11.8,
16.2.7 to 16.2.9
m-Chlorotoluene
2238
SP
2G
F-T A, B
15.19.6
CH3C6H4Cl
1072
162
o-Chlorotoluene
2238
SP
2G
F-T A, B
15.19.6
CH3C6H4Cl
1077
159
p-Chlorotoluene
2238
SP
2G
F-T A, B
15.19.6, 16.2.9
CH3C6H4Cl
1067
166
Chlorotoluene (mixed
isomers)
2238
SP
2G
F-T A, B
15.19.6
ClC6H4CH3
1070
SP
2G
T2 IIA
B, D
15.19.6
SP
2G
T3 IIA
F-T A, D
1G
T2 IIA
SP
2G
Coal tar
15.19.6
880
15-30
555
B, D
15.19.6
~1300
~280
~550
F-T A, D
15.19.6
870
C6H6
2G
16.2.7 to 16.2.9
900
SP
2G
T2 IIA
A, D
15.19.6
1070
SP
2G
T2 IIA
A, D
15.19.6
A
A
SP
SP
2
2
2G
2G
O
O
T1 IIA
X
X
O
O
A, B
A, B
15.19.6
15.19.6
SP
2G
15.19.6
SP
2G
F-T
CH3CHCHCHO
SP
2G
C12H18
2076
Crotonaldehyde
1143
1,5,9-Cyclododecatriene
T3 IIB
162
Creosote (wood)
43
N8
N2
74
1040
1040
80
200 400
1080
C6H4OHCH3
230 330
~220
>81
86
555
191
250
850
13
230
102
890
80
1400
231
1145
2G
Cyclohexanone
1915
2G
2G
Cyclohexanone,
Cyclohexanol mixture
Cyclohexyl acetate
2243
(B)
2G
Cyclohexylamine
2357
SP
2G
1,3-Cyclopentadiene dimer
(molten)
T2 IIA
T3 IIA
C7H14
809
<38
o
15.19.6
t
117
15.19.6, 16.2.9
C6H12
780
-18
260
81
F-T
N5
15.19.6
(CH2)5CO
950
43
430
156
F-T
N5
C6H10O + C6H11OH
950
(32)
290
134
F-T A, C
N1
15.19.6
CH3COOC6H11
970
15.19.6
C6H11NH2
860
2G
980
Cyclopentane (bb)
1146
(C)
2G
15.19.6
C5H10
740
Cyclopentene
2246
(B)
2G
15.19.6
C5H8
750
p-Cymene (bb)
2046
2G
15.19.6
CH3C6H4CH(CH3)2
855
2G
16.2.7 to 16.2.9
CH3(CH2)8CO2H
900
Decanoic acid
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
Flashpoint [/ C]
Tank Type
Ship Type
Hazards
Pollution Category
Cyclohexane (bb)
j
-
Chemical
Formula
Special requirements
Density [kg/ m]
Materials of Construction
g
C
Fire Protection
f
2G
Vapour Detection
e
3
Gauging
d
P
Flashpoint >60/
c
(C)
UN Number
a
Cycloheptane (bb)
Apparatus Group
b
2241
Product name
Temperature Class
Tank Vents
Electrical
equipment
47
177
270
2G
15.19.6
C10H20
740
172
Decyl acetate
(B)
2G
15.19.6
CH3(CH2)9OOCCH3
864
187
Decyl acrylate
SP
2G
A, C,
D
C10H21OOCCH=CH2
890
127
2G
CH3(CH2)8CH2OH
~830
~82
233
Decyloxytetrahydrothiophene
dioxide
SP
2G
15.19.6
1030
130
>100
1902
SP
2G
A, D
973
196
>200
2G
15.19.6
(CH2CH2COOC6H13)2
939
163
Di-n-propylamine
2383
SP
2G
F-T
N2
15.12.3, 15.19.6
C6H15N
718
Dibromomethane
2664
SP
2G
N3
15.12.3, 15.19
CH2Br2
2400
2G
15.19.6, 16.2.6
980
(120)
Decene
Di-(2-ethylhexyl) phosphoric
acid
Di-n-hexyl adipate
Dibutyl hydrogen
phosphonate
T3 IIA
NF
X
N2
N2
(C4H9CH(C2H5)CH2)2HPO4
42
-
99
121
2G
3,4-Dichloro-1-butene
SP
2G
Dichlorobenzene(all isomers)
SP
2G
T1 IIA
Tank Type
Ship Type
Hazards
F-T
F-T
1,6-Dichlorohexane
SP
2G
A, B
A, C,
D
2G
2G
2,4-Dichlorophenoxy acetic
acid, diethanolamine salt
solution
SP
2G
2,4-Dichlorophenoxy acetic
acid, dimethylamine salt
solution (70% or less)
SP
2G
2,4-Dichlorophenoxy acetic
acid, triisopropanolamine salt
solution
SP
2G
1,1-Dichloropropane
1,2-Dichloropropane
1279
1,3-Dichloropropane
1,3-Dichloropropene
2047
119
15.19.6, 16.2.6(x),
16.2.9(y), 16A.2.2 (z)
C6H4Cl2
1304 1460
66
~645
~175
15.19.6
CH3CHCl2
1170
-10
457
57
15.19.6
CH2ClCH2OCH2CH2Cl
1220
55
365
178
15.19.6
(ClCH2C(CH3)H)2O
1130
95
187
605
A, B,
D
T2 IIA
SP
450
T2 IIA
29
1150
1593
A, B,
C
2021
F-T
2,4-Dichlorophenol
161
2G
Dichloromethane
260
2G
42
A, C,
D
760
F-T
2G
(C4H9)2NH
15.19.6
SP
SP
171
2490
1048
Dichloroethyl ether
2,2'-Dichloroisopropyl ether
2362
Pollution Category
UN Number
1,1-Dichloroethane
T2 IIA
C6H4(COOC4H9)2
N4
N5
N5
t
340
1060
CH2Cl2
1330
N1
15.19.6
C6H3Cl2OH
1380
114
NF
N1
15.19.6
C12H17O5NCl2
1280
NF
N1
15.19.6
Cl2C6H3OCH2COON(CH3)2
1230
NF
N1
15.19.6
C17H27O6NCl2
1230
100
CH2ClCH2CH2Cl
1160
15
555
97
555
SP
2G
SP
2G
T1 IIA
T1 IIA
N5
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
SP
Flashpoint [/ C]
15.19.6
j
X
Chemical
Formula
Special requirements
Density [kg/ m]
Dibutylamine
Materials of Construction
Fire Protection
2G
Vapour Detection
Gauging
Flashpoint >60/
Apparatus Group
Dibutyl phthalate
Product name
Temperature Class
Tank Vents
Electrical
equipment
F-T A, B
15.12, 15.19.6
F-T A, B
15.12, 15.19.6
40
210
94
1200
2G
T1 IIA
F-T A, B
15.12, 15.19.6
CH3CHClCH2Cl
1160
15
SP
2G
T2 IIA
F-T A, B
CHCl=CHCH2Cl
1230
29
96
104
SP
2G
2,2-Dichloropropionic acid
2G
2G
T1 IIA
1G
Inert
T4 IIB
2G
(B) SP
2G
Diethanolamine
Diethyl ether
1155
Diethyl phthalate
A, B,
F-T
D
1090
(138)
660
269
C2H5OC2H5
704
-45
180
35
436
208
N2
F-T
N7
N3
1118
152
(C2H5)2SO4
1180
104
15.12, 15.19.6
(C2H5)2NH
706
<-25
310
56
15.19.6
(C2H5)2NCH2CH2OH
890
(60)
260
161
15.19.6, 16.2.9
(C2H5)2C6H3NH2
960
15.19.6
C6H4(C2H5)2
865
56
430
180
NH2C2H4NHC2H4NH2
954
102
395
207
252
2G
T2 IIA
F-T
N1
2G
T2 IIA
F-T A, C
N1
SP
2G
B, C,
D
N4
N2
2G
2G
Diglycidyl ether of
bisphenol A
2G
Diglycidyl ether of
bisphenol F
2G
Diisobutyl phthalate
(C) SP
Diisobutylamine
2361
Diisobutylene
2050
190
C6H4(CO2C2H5)2
15.19.6, 16.2.6
1160
15.19.6, 16.2.6
1160
2G
15.19.6, 16.2.6
C6H4(COOCH2CH(CH3)2)2
1040
196
327
2G
F-T
A, C,
D
15.12.3, 15.19.6
((CH3)2CHCH2)2 NH
745
29
139
101
N1
2G
15.19.6
C8H16
723
-7
SP
2G
T2 IIA
N2
16.2.7 to 16.2.9
(CH3CHOHCH2)2NH
989
127
SP
2G
T2 IIA
F-T
N2
15.12, 15.19
((CH3)2CH)2NH
720
-7
Diisopropylbenzene (all
isomers)
2G
15.19.6
C6H4(C3H7)2
857
77
Dimethyl adipate
2G
15.19.6, 16.2.9
Diisopropylamine
1158
299
T2 IIA
Diisopropanolamine
82-149
15.19.6
SP
SP
19
(HOC2H4)2NH
1200
1390
CH3CCl2COOH
Y5
2686
15.11.2, 15.11.4,
15.11.6 to 15.11.8
1154
2049
Diethylaminoethanol
2079
Diethylamine
Diethylenetriamine
1594
Diethylbenzene
Chemical
Formula
Special requirements
Diethyl sulphate
2,6-Diethylaniline
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
Flashpoint [/ C]
Dichloropropene/Dichloropro
pane mixtures
Density [kg/ m]
Materials of Construction
Fire Protection
Tank Vents
Vapour Detection
Tank Type
Gauging
Ship Type
Flashpoint >60/
Hazards
Apparatus Group
Pollution Category
Product name
Temperature Class
UN Number
Electrical
equipment
1070
249
285
82
203
Chemical
Formula
Special requirements
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
Flashpoint [/ C]
Tank Type
Ship Type
Hazards
(B) SP
j
X
Density [kg/ m]
Materials of Construction
g
O
Fire Protection
f
2G
Vapour Detection
e
3
Gauging
d
P
Flashpoint >60/
Pollution Category
UN Number
a
Dimethyl glutarate
Apparatus Group
c
C
Product name
Temperature Class
Tank Vents
Electrical
equipment
p
CH3O2C(CH2)3CO2CH3
1070
(CH3O)2P(O)H
1200
147
162
C6H4(COOCH3)2
1190
146
282
16.2.9
CH3O2CCH2CH2CO2CH3
1120
15.12.1, 15.17
CH3CON(CH3)2
940
66
165
N1
15.12, 15.19.6
(CH3)2NH + H2O
~700
< -18
<400
54
45
2G
A, D
Dimethyl phthalate
2G
Dimethyl succinate
2G
N,N-Dimethylacetamide
solution (40% or less)
2G
N4
F-T
A, C,
D
15.12.1
1160
SP
2G
Dimethylamine solution
(greater than 45% but not
greater than 55%)
1160
SP
2G
F-T
A, C,
D
N1
(CH3)2NH + H2O
~800
< -18
<400
Dimethylamine solution
(greater than 55% but not
greater than 65%)
1160
SP
2G
F-T
A, C,
D
N1
(CH3)2NH + H2O
~850
< -18
<400
N,N-Dimethylcyclohexylamine
2264
SP
2G
F-T
A,C
N1
(CH3)2NC6H11
850
39
215
162
N2
135
T2 IIA
15.19.6
(CH3)2NCH2CH2OH
890
(41)
220
15.19.6
HCON(CH3)2
950
58
440
16.2.8, 16.2.9
C10H20O2
902
13
C6H3(NO2)2CH3
1328
150
312
285
Dimethylethanolamine
2051
2G
T3 IIA
F-T A, D
Dimethylformamide
2265
2G
T2 IIA
F-T A, D
(C)
2G
Dimethyloctanoic acid
153
254
Dinitrotoluene (molten)
1600
SP
2G o)
1,4-Dioxane
1165
2G
F-T
15.12, 15.19
O(CH2)4O
1036
12
375
101
Dipentene
2052
2G
15.19.6
C10H16
847
45
237
175
Diphenyl
2G
15.19
C6H5-C6H5
1040
113
570
256
Diphenyl ether
2G
15.19.6
(C6H5)2O
1075
115
618
259
Diphenyl ether/Diphenyl
phenyl ether mixture
2G
15.19.6
T2 IIB
1200
Diphenylamine, reaction
product with 2,2,4-Trimethyl
pentene
Diphenylamines, alkylated
Diphenylmethane
diisocyanate
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
Flashpoint [/ C]
Chemical
Formula
Special requirements
p
Mixture of C6H5-C6H5 and
(C6H5)2O
1060
2G
15.19
(A) SP
2G
15.19
980
>180
2G
15.19.6
1010
356
1230
249
15.19.6, 16.2.6
1300
A
2489
Density [kg/ m]
Materials of Construction
Fire Protection
Tank Vents
Vapour Detection
Tank Type
Gauging
Ship Type
Flashpoint >60/
Hazards
a
Diphenyl/Diphenyl ether
mixtures
Apparatus Group
Pollution Category
Product name
Temperature Class
UN Number
Electrical
equipment
(B) SP
2G
b)
A,B,
T b) C c),
D
N5
2G
(B)
2G
15.19.6
836
>100
1160
C12H24
>200
230
760
213
15.19.6
15.13
CH2=C(CH3)COO (CH2)11CH3
870
132
133
A,D
CH2=C(CH3)COOC12-15
860
110
290
A, D
N2
15.19.6
2G
B, C,
D
N4
15.19.6
2G
15.19
163
154
2G
15.19.6
Dodecyl alcohol
2G
SP
2G
Dodecyl methacrylate
2G
Dodecyl/Pentadecyl
methacrylate mixture
2G
Dodecylamine/Tetradecylami
ne mixture
SP
2G
Dodecyldimethylamine/Tetra
decyld imethylamine mixture
SP
Dodecylphenol
X
NF
Epichlorohydrin
2023
SP
2G
IIB
F-T
Ethanolamine
2491
2G
T2 IIA
F-T
N2
259
-
790
C12H25C6H4OH
940
CH2OCHCH2Cl
1180
21
HOCH2CH2NH2
1018
(93)
385
116
171
Ethyl methacrylate
2277
(D)
2G
Chemical
Formula
Density [kg/ m]
Tank Type
Boiling Point [/ C]
A,D
2G
Ship Type
Auto-Ignition Temperature [/ C]
Materials of Construction
F-T
2G
T2 IIB
Special requirements
Flashpoint [/ C]
Fire Protection
Vapour Detection
Gauging
Apparatus Group
T2 IIA
1180
Temperature Class
Tank Vents
2271
Ethyl butyrate
Hazards
15.19.6
Pollution Category
910
UN Number
CH2=C(CH3)COOC2H5
(27)
100
120
2G
(A) SP
2G
IIA
F-T
15.19.6
(C3H7)CH=C(C2H5)CHO
850
68
175
(C) SP
1G
T2 IIA
F-T C, D
C2H5NH2
689
-49
384
17
C2H5NH2
800
-30
15.19.6
C6H5C2H5
867
15
15.12.3, 15.19.6
C2H5NH(CH2)3CH3
740
15.19.6
C2H5C6H11
787
35
262
55
15.19.6
C8H17N
850
46
245
167
425
129
(C) SP
B
2G
F-T
A,C
2G
N-Ethylbutylamine
(C) SP
2G
F-T
Ethylcyclohexane (bb)
(C)
2G
2G
F-T
F-T A, D
N2
N1
N1
N1
SP
2G
T2 IIA
(D)
2G
IIB
X
-
Ethylene dibromide
1605
SP
2G
NF
Ethylene dichloride
1184
SP
2G
T2 IIA
(C)
2G
2G
1135
Ethylene chlorohydrin
44
880
SP
Ethylene cyanohydrin
820
C3H7CO2C2H5
N-Ethylcyclohexylamine
CH3CH2CO(CH2)4CH3
15.19.6
F-T
1917
1175
15.19.6
Ethyl acrylate
Ethylbenzene
350
2270
15.19.6
920
2G
1036
CH2=CHCOOC2H5
Ethylamine
2-Ethyl-3-propylacrolein
s
380
Ethyl-3-ethoxypropionate
r
49
1172
j
-
2-Ethoxyethyl acetate
Product name
970
Flashpoint >60/
Electrical
equipment
F-T A, B
N4
38
432
136
110
ClCH2CH2OH
1210
55
HOCH2CH2CN
1040
129
BrCH2CH2Br
2170
515
132
15.19
ClCH2CH2Cl
1250
13
440
84
117
C4H9OCH2OOCCH3
942
88
192
(CH3COO)2C2H4
1106
96
188
1010
49
2G
2G
2G
15.19.6
900
2983
SP
1G
Inert
T2 IIB
F-T A, C
Ethylenediamine
1604
SP
2G
T2 IIA
F-T
2-Ethylhexyl acrylate
2-Ethylhexylamine
2276
Ethylidenenorbornene
SP
2G
SP
2G
SP
2G
o-Ethylphenol
(A) SP
2G
Ethyltoluene
(B)
2G
SP
2G
2582
T3 IIB
T1 IIA
F-T
N4
~430
27
15.19.6, 16.2.9
NH2CH2CH2NH2
900
34
385
116
CH2=CHCOOC8H17
890
(82)
245
229
15.12, 15.19.6
C4H9CH(C2H5)CH2NH2
790
(60)
265
169
15.12.1, 15.16.1,
15.19.6
C9H12
900
38
272
148
15.19.6
HOC6H4C2H5
1040
78
15.19.6
C2H5C6H4CH3
860
60
475
1410
1290
1110
50
420
97
1220
42
520
101
2G
NF
15.11, 15.19
SP
1G
NF
15.11
SP
2G
T2 IIB
F-T
Formic acid
2G
T1 IIA
T v)
2G
F-T
1199
SP
2G
Furfuryl alcohol
2874
2G
2G
Glutaraldehyde solutions
(50% or less)
T2 IIB
NF
<-20
1779
~845
SP
1778
NF
F-T A, D
N2
N2
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
Materials of Construction
Chemical
Formula
Flashpoint [/ C]
Fire Protection
Special requirements
Density [kg/ m]
Vapour Detection
Flashpoint >60/
Apparatus Group
a
Ethylene oxide/propylene
oxide mixture with an
ethylene oxide content of not
more than 30% in weight
Product name
Temperature Class
Tank Vents
Tank Type
Ship Type
Hazards
Pollution Category
UN Number
Gauging
Electrical
equipment
15.11.2 to 15.11.4,
15.11.6 to 15.11.8,
15.19.6
15.19.6, 16.2.6
15.16.1, 15.19.6
Y2,
Y3
15.16.1
HCOOH
205
1060
C4H3OCHO
1160
60
~315
162
C4H3OCH2OH
1129
65
391
170
HOC(CH2)3COH
1120
188
15.19.6
C7H16
15.19.6
C7H15OH
2G
(C)
2G
2G
1206
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
Materials of Construction
Chemical
Formula
Flashpoint [/ C]
Fire Protection
Special requirements
Density [kg/ m]
Vapour Detection
Flashpoint >60/
Apparatus Group
15.19.6
Temperature Class
Tank Vents
Tank Type
Ship Type
Hazards
Pollution Category
UN Number
Hexamethylenediamine
solution
Product name
Gauging
Electrical
equipment
680
-4
223
~820
~60
~156
~6
190
80
123
1100
2G
15.19.6
C7H14
711
(B)
2G
15.19.6
C7H15OOCCH3
880
SP
2G
15.19.6, 16.2.9
H2N(CH2)6NH2
900
N2
98
Hexamethyleneimine
2493
SP
2G
15.19.6
C6H12NH
880
1208
(C)
2G
15.19.6
C6H14
659
-23
(C)
2G
15.19.6
C6H12
680
<-20
64
15.19.6
CH3COOC6H13
870
59
164
HCl+H2O
1010 1210
F-T A, C
N1
255
138
260
69
Hexyl acetate
1233
2G
Hydrochloric acid
1789
1G
NF
2015
SP
2G
NF
15.5.1 to 15.5.13,
15.19.6
H2O2
1288
2014,
2984
SP
2G
NF
15.5.14 to 15.5.26,
15.18, 15.19.6
H2O2
1245
2-Hydroxy-4-(methylthio)butanoic acid
2G
16.2.7, 16.2.8
2-Hydroxyethyl acrylate
SP
2G
Icosa(oxypropane-2,3-diyl)s
2G
16.2.6, 15.19.6
966
230
>350
>250
C12H18H2O2
1060
158
430
310
C10H22N2
930
115
380
247
X f) 15.11
Isophorone diisocyanate
2290
SP
2G
A, B,
D
N5
Isophoronediamine
2289
2G
N2
110
~1200
CH2=CHCOOCH2CH2OH
1104
SP
2G
SP
2G
Isopropyl ether
1159
2G
Isopropylamine
1221
SP
(C)
Lauric acid
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
1218
Flashpoint [/ C]
Isoprene
Density [kg/ m]
Materials of Construction
Fire Protection
Tank Vents
Vapour Detection
Tank Type
Gauging
Ship Type
Flashpoint >60/
Hazards
Apparatus Group
Pollution Category
Product name
Temperature Class
UN Number
Electrical
equipment
CH2C(CH3)CHCH2
680
-48
220
34
CH3CHOHCH2NH2
960
(71)
335
159
720
-18
440
67
(CH3)2CHNH2
690
<-20
400
32
C6H11CH(CH3)2
~800
Special requirements
Chemical
Formula
16.2.8, 16.2.9
988
860
T3 IIB
T2 IIA
F-T
Inert
2G
2G
SP
1G
A, C,
D
2G
SP
2G
F-T
1100 1400
2G
A, B
16.2.7, 16.2.8
~1000
>60
Long-chain poly-etheramine
in alkyl(C2-C4)benzenes
2G
930
48
Long-chain poly-etheramine
in aromatic solvent
2G
2G
A, B
16.2.7, 16.2.8
~1000
>60
2G
A g),
C
(COCH)2O
934
SP
2G
NF
2G
T2 IIB
SP
2G
NF
2G
Isopropanolamine
Isopropylcyclohexane (bb)
Maleic anhydride
2215
Mercaptobenzothiazol,
sodium salt solution
Mesityl oxide
1229
2531
T2 IIA
F-T C, D
N2
N2
Y1
N1
15.9.6, 16.2.9
C7H4NS2Na + H2O
(CH3)2C=CHCOCH3
F-T
15.19.6
N1
15.19.6
Y1
15.13, 16.6.1
182184
225
>232
60
103
475
202
1250
107
857
32
346
130
1210
CH2=C(CH3)COOH
1015
77
161
SP
2G
2G
2G
1919
SP
2G
Methyl butyrate
1237
(C)
2G
Methyl formate
1243
2G
F-T
2G
2G
F-T
(B)
2G
2G
IIA
F-T
A, B,
D
N6
IIA
N4
Methacrylonitrile
3079
N-(2-Methoxy-1-methyl
ethyl)-2-ethyl-6-methyl
chloroacetanilide
Methyl acrylate
1247
Methyl salicylate
2-Methyl-2-hydroxy-3-butyne
2-Methyl-5-ethylpyridine
2300
T2 IIA
CH3CN
789
13
Chemical
Formula
N4
15.19, 16.2.6
N4, Z
F-T A, B
F-T
15.19.6
C15H22ClNO2
1120
>100
510
282
F-T
CH2=CHCOOCH3
957
-3
415
80
15.19.6
C5H10O2
890
14
HCO2CH3
980
-19
15.19.6
CH3CO(CH2)6CH3
820
CH2=C(CH3)COO
940
10
430
101
15.19.6
CH4OHCOOCH3
1185
101
454
222
15.19.6
(CH3)2C(OH)CH
867
25
15.19.6
T1 IIB
T2 IIA
2G
A, D
SP
2G
A, D
1235
SP
2G
F-T
A, C,
D
Methylamyl acetate
1233
(C)
2G
Methylamyl alcohol
2053
(C)
2G
Methylcyclohexane (bb)
2296
(C)
2G
Special requirements
2-Methyl-6-ethylaniline
(B) SP
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
Materials of Construction
Flashpoint [/ C]
Fire Protection
Density [kg/ m]
Vapour Detection
Flashpoint >60/
a
Methacrylic resin in ethylene
dichloride
Apparatus Group
Product name
Temperature Class
Tank Vents
Tank Type
Ship Type
Hazards
Pollution Category
UN Number
Gauging
Electrical
equipment
920
(74)
970
102
231
430
49
900
~-10
15.19.6
C8O2H16
860
(43)
15.19.6
C6OH14
808
(41)
15.19.6
CH3C6H11
770
-4
15.19.6
(B)
2G
2G
Methylnaphthalene (molten)
SP
2G
A, D
N2
15.19.6
104
NC5H3(CH3)(C2H5)
CH3NH2
Methyldiethanolamine
32
(CH3)(C2H5)C6H3NH2
15.12, 15.17, 15.19
Methylcyclopentadiene dimer
102
456
195
N1
90
C12H16
934
60
CH3N(C2H4OH)2
1040
>100
178
146
132
285
101
78-183
N4
15.12.3, 15.19.6
25
Density [kg/ m]
Tank Type
Ship Type
Hazards
Pollution Category
q
950
Chemical
Formula
Special requirements
p
(C5H4N)CH3
Boiling Point [/ C]
g
C
Auto-Ignition Temperature [/ C]
f
2G
Flashpoint [/ C]
Materials of Construction
e
2
Fire Protection
Gauging
d
S
Vapour Detection
Flashpoint >60/
c
D
UN Number
a
2-Methylpyridine
Apparatus Group
b
2313
Product name
Temperature Class
Tank Vents
Electrical
equipment
t
54
3-Methylpyridine
2313
SP
2G
A, C
N4
15.12.3, 15.19
NCHC(CH3)CHCHCH
940
40
4-Methylpyridine
2313
2G
F-T
N4
NCHCHC(CH3)CHCH
957
57
alpha-Methylstyrene
2303
SP
2G
T1 IIB
F-T
A,
D *4)
C6H5C(CH3)CH2
906
54
574
166
15.19.6
(CH2)4ONH
1000
(38)
310
129
Pb(C2H5)4
~1800
145
180
C10H8
540
218
Morpholine
2054
2G
T2 IIA
1649
SP
1G
T4 IIA
Naphthalene (molten)
2304
T1 IIA
N2, Z
F-T A, C
535
128
145
SP
2G
A, D
15.19.6
Naphthenic acids
2G
15.19.6
Neodecanoic acid
2G
16.2.8
C9H19COOH
H2SO4 + HNO3
~1800
90
1796
2031,
2032 h)
2031
1140
80
~960
>60
920
2G
NF
SP
2G
NF
15.11, 15.19
HNO3
~1500
84
SP
2G
NF
15.11, 15.19
HNO3
~1420
122
C6H5NO2
1200
88
480
211
C2H5NO2
1050
30.5
414
114
32
416
112133
(C) SP
Nitrobenzene
1662
SP
2G
T1 IIA
Nitroethane
2842
(D)
2G
IIB
F-T A (u)
N4
15.16.1, 15.19.6,
16.6.1, 16.6.2, 16.6.4
Nitroethane(80%)/Nitropropane(20%)
1993
2G
IIB
F-T A (u)
N4
1030
o-Nitrophenol (molten)
1663
SP
2G
A, D
NO2C6H4OH
1300
1- or 2-Nitropropane
2608
2G
F-T
15.19.6
CH3CH2CH2NO2 or
(CH3)2CHNO2
1000
990
T2 IIB
A, D
214
(49) (39) ~420
131
120
2G
1010
34
421
112
Chemical
Formula
Special requirements
15.19.6
Mixture of CH3CH2CH2NO2
and CH3CH2NO2
A, B
NO2C6H4CH3
1299
106
F-T
A u)
N4
o- or p-Nitrotoluenes
1664
SP
2G
1920
(C)
2G
B,C
15.19.6
C9H20
722
30
2G
15.19.6
CH3(CH2)6CH=CH2
743
25
15.19.6
IIB
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
Flashpoint [/ C]
Density [kg/ m]
Materials of Construction
Fire Protection
Tank Vents
Vapour Detection
Tank Type
Gauging
Ship Type
Flashpoint >60/
Hazards
a
Nitropropane (60%) /
Nitroethane (40%) mixture
Apparatus Group
Pollution Category
Product name
Temperature Class
UN Number
Electrical
equipment
(C)
2G
2G
Nonylphenol
2G
15.19.6
Nonylphenol poly(4+)-ethoxylates
2G
2G
15.19
2G
15.19.6
2G
15.19.6, (16.2.6,
16.2.9) *3)
2G
15.19.6, (16.2.6)*3),
16.2.9, 16A.2.2
2G
15.19.6
2G
15.19.6, (16.2.6,
16.2.9) *3)
238
206
151
150
~870
67
CH3(CH2)7CH2OH
829
74
215
C9H19C6H4OH
950
141
315
1040
(16.2.7 to 16.2.9)*3)
15.19
2G
15.19.6
2G
15.19.6, (16.2.6,
16.2.9) *3)
2G
15.19.6, (16.2.6)*3),
16.2.9, 16A.2.2
2G
15.19.6
2G
15.19.6, (16.2.6,
16.2.9) *3)
2G
15.19.6, (16.2.6)*3),
16.2.9, 16A.2.2
2G
(16.2.7 to 16.2.9)*3)
2G
2G
2G
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
Materials of Construction
Chemical
Formula
Flashpoint [/ C]
Fire Protection
15.19.6, (16.2.6)*3),
16.2.9, 16A.2.2
Special requirements
Density [kg/ m]
Vapour Detection
Flashpoint >60/
Apparatus Group
Product name
Temperature Class
Tank Vents
Tank Type
Ship Type
Hazards
Pollution Category
UN Number
Gauging
Electrical
equipment
Tank Type
Ship Type
Hazards
Pollution Category
Boiling Point [/ C]
g
C
Auto-Ignition Temperature [/ C]
Materials of Construction
f
2G
Flashpoint [/ C]
Fire Protection
e
3
Chemical
Formula
Special requirements
Density [kg/ m]
Gauging
d
P
Vapour Detection
Flashpoint >60/
c
(C)
UN Number
a
Octane (all isomers) (bb)
Apparatus Group
b
1262
Product name
Temperature Class
Tank Vents
Electrical
equipment
703
13
220
126
CH3(CH2)6CH2OH
830
~70
~185
CH3(CH2)5CH=CH2
720
21
~125
15.19.6
CH3(CH2)6CH3
15.19.6
15.19.6, 16.2.9
2G
2G
n-Octyl acetate
2G
CH3COO(CH2)7CH3
869
82
199
CH3(CH2)6CHO or
C4H9CH(C2H5)CHO
820
52
163
Octyl aldehydes
1191
(B)
2G
2G
15.19.6
~750
0-38
2G
15.19.6
~700
-20
alpha-Olefins (C6-C18)
mixtures
2G
~800
0-25
SP
2G
15.11.2 to 15.11.8,
15.12.1, 15.16.2, 15.17, H2SO4 + SO3
15.19, 16.2.7, 16.2.8
<1980
Oleylamine
SP
2G
15.19.6
828
~93
2G
A, B
16.2.7 to 16.2.9
870
15.19.6, 16.2.9
C6H12O3
990
36
238
125
CHCl2CCl3
1680
16
CH3CH=CH-CH=CH2
680
-43
>200
42
36
Oleum
1831
NF
Paraldehyde
1264
SP
2G
T3 IIB
Pentachloroethane
1669
SP
2G
NF
1,3-Pentadiene
SP
2G
F-T A, B
130
>100
(C)
2G
15.14, 15.19.6
CH3(CH2)3CH3
626
-49
308
2G
15.14, 15.19.6
CH3CH2CH2CH=CH2
656
-18
~270 30-37
n-Pentyl propionate
2G
15.19.6
Cl2C=CCl2
1625
121
C6H5OH
1070
82
715
182
988
149
1265
Perchloroethylene
1897
SP
2G
NF
Phenol
2312
SP
2G
T1 IIA
2G
1-Phenyl-1-xylylethane (bb)
15.12.1, 15.12.2,
15.19.6
A, B
290
2G
SP
1G
Pad + (V
or Inert)
NF
- k)
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
1805
Flashpoint [/ C]
Phosphoric acid
Density [kg/ m]
Materials of Construction
Fire Protection
Tank Vents
Vapour Detection
Tank Type
Gauging
Ship Type
Flashpoint >60/
Hazards
Apparatus Group
Pollution Category
Product name
Temperature Class
UN Number
Electrical
equipment
H3PO4
1500 1700
200
1820
282
580
Special requirements
Chemical
Formula
15.11.1 to 15.11.4,
15.11.6 to 15.11.8
15.7, 15.19
2214
SP
2G
A, D
16.2.7 to 16.2.9
C6H4(CO)2O
1530
152
Pine oil
1272
2G
16.2.7, 16.2.8
C10H16
970
78
>180
alpha-Pinene
2368
T1 IIA
285
2G
15.19.6
C10H16
864
32
70
beta-Pinene
2G
15.19.6
C10H16
877
47
73
Poly(2+)cyclic aromatics
2G
A, D
15.19.6
~900
>60
2G
1100
1020
2G
16.2.7, 16.2.8
Polyethylene polyamines
(C) SP
2G
N2
16.2.9
(C) SP
2G
Y4
N5
NF
1050
>150
1460
1190
218
Polymethylene polyphenyl
isocyanate
2G
X b)
T b)
2G
A, B
16.2.7, 16.2.8
(C)
2G
900
Polyolefinamine in aromatic
solvent
(C)
2G
900
2G
NF
SP
2G
NF
1814
2G
N8
>200
-
~200
38-44
>425
148
1500
150
~1300
very
high
~1000
16.2.9
15.19.6
KOH
2G
SP
2G
IIA
Tank Type
Ship Type
Hazards
49
CH3CH2COOH
990
50
485
141
(C2H5CO)2O
1020
(74)
C3H5N
780
35
97
~860
-18
47
F-T
15.11.2 to 15.11.4,
15.11.6 to 15.11.8,
15.19.6
T1 IIA
Propionic anhydride
2496
SP
2G
T2 IIA
Propionitrile
2404
SP
1G
T1 IIB
n-Propyl chloride
1278
2G
n-Propylamine
1277
SP
2G
Inert
F-T A, D
SP
2G
F-T C, D
Y1
Y1
F-T A, D
F
o
16.2.9
N2
15.12, 15.19
C3H7NH2
720
<-20
~320
49
N1
15.12, 15.19
(CH3)2CHNH2
782
- 26
402
47,8
C6H5CH2CH2CH3
860
<-20
430
34
550
115
2G
15.19.6
2G
15.19.6
SP
2G
Inert
720
CH3CHOCH2
830
2850
2G
15.19.6
760
Propylene trimer
2057
2G
15.19.6
740
40
Pyridine
1282
2G
15.19.6
980
17
1000
1050
N4
Rosin
2G
2G
15.19.6
2G
NF
16.2.6
2G
NF
1819
167
15.19.6
Propylene tetramer
155
T1 IIA
t
188
A, B
F-T A, C
(C)
T2 IIB
207
2G
1280
<-20
Propylene oxide
(74)
810
1150
N2
(CH2)2OCO
A, D
1848
T2 IIA
>80
Propionic acid
iso-Propylamine(70% or less)
solution
980
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
1275
Flashpoint [/ C]
beta-Propiolactone
Propionaldehyde
H2NCH2CH2CH2OH
j
X
Chemical
Formula
Special requirements
Density [kg/ m]
Materials of Construction
g
O
Fire Protection
f
2G
Vapour Detection
e
3
Gauging
d
SP
Flashpoint >60/
Pollution Category
UN Number
a
n-Propanolamine
Apparatus Group
c
C
Product name
Temperature Class
Tank Vents
Electrical
equipment
N1
C5H5N
CH3(CH2)13-16SONa
1070
1550
~100
-
Flashpoint [/ C]
Auto-Ignition Temperature [/ C]
Boiling Point [/ C]
1500
170
15.12.3, 15.19
Na2Cr2O7.2H2O + H2O
1720
120
15.19.6
1300
1300
SP
2G
NF
N1
16.2.7
2G
NF
SP
2G
NF
2G
NF
2428
Flashpoint >60/
a
Sodium borohydride (15% or
less)/Sodium hydroxide
solution
Apparatus Group
Product name
Temperature Class
NaClO3
Materials of Construction
Fire Protection
100
Vapour Detection
Gauging
1400
Tank Vents
NaBH4-NaOH
Tank Type
Ship Type
Hazards
Pollution Category
UN Number
Density [kg/ m]
Electrical
equipment
N2
Special requirements
Chemical
Formula
2693
2G
NF
Sodium hydrosulphide
solution (45% or less)
2949
SP
2G
V or Pad
(Gas)
NF
1300
SP
2G
F-T
N1
1282
10
NaOH
10001530
Sodium hydrosulphide/
Ammonium sulphide solution
Na2S2O4.2H2O
38 121
1824
2G
NF
N8
1791
SP
2G
NF
N5
15.16.1
NaOCl
1220
SP
2G
NF
15.12.3.1, 15.12.3.2,
15.16.1, 15.19
NaNO2
1200
SP
2G
15.19.6, 16.2.6
1050
205
2G
1200
SP
2G
NF
N5
1427
150
>100
Gauging
Vapour Detection
Fire Protection
Materials of Construction
2G
NF
Sodium tartrates/sodium
succinates solution
2G
A, B
(B)
2G
SP
2G
2G
X l)
2055
T1 IIA
Y5
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
Tank Vents
Chemical
Formula
Flashpoint [/ C]
Tank Type
Special requirements
490
145
Density [kg/ m]
Ship Type
Flashpoint >60/
Hazards
Apparatus Group
Pollution Category
Product name
Temperature Class
UN Number
Electrical
equipment
q
1220
1400
>93
15.19.6
NaSCN
~1000
A, B N4,Z
C6H5CHCH2
A, B
15.19.6, 16.2.6
F-T
15.10
1800
~165
445
338
910
32
>60
Sulphur (molten)
2448
1G
V or Pad
(Gas)
Sulphuric acid
1830
SP
2G
NF
H2SO4
1560 1840
1832
SP
2G
NF
H2SO4 + H2O
~1100
2G
1000
180
(C)
2G
16.2.7 to 16.2.9
1000
SP
2G
15.19.6, 16.2.6
1150
2G
1040
F-T
Tetrachloroethane
1702
SP
2G
Tetraethylenepentamine
2320
2G
Tetrahydrofuran
2056
2G
2G
Tetrahydronaphthalene (bb)
T3
NF
T3 IIB
N1
15.19.6
165
>100
100
C2H2Cl4
1600
HN(C2H4NHC2H4NH2)2
1000
(163)
146
CH2(CH2)2CH2O
890
-20
321
64
C10H12
981
71
384
206
333
2G
Toluene (bb)
2G
1294
Toluene diisocyanate
2078
SP
2G
Toluenediamine
1709
SP
2G
o-Toluidine
1708
16.2.9, 16A.2.2
C6H2(CH3)4
896
15.19.6
C6H5CH3
866
536
111
N4
CH3C6H3(NCO)2
1200
132
620
251
N1
CH3C6H3(NH2)2
~1000
450
280
T1 IIA
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
Flashpoint [/ C]
Density [kg/ m]
Materials of Construction
Fire Protection
Tank Vents
Vapour Detection
Tank Type
Gauging
Ship Type
Flashpoint >60/
Hazards
a
Tetramethylbenzene (all
isomers)
Apparatus Group
Pollution Category
Product name
Temperature Class
UN Number
Electrical
equipment
A,
F-T C c),
D
A, D
Special requirements
Chemical
Formula
197
SP
2G
C7H9N
1000
85
Tributyl phosphate
2G
15.19.6
(C4H9)3PO
978
146
1,1,2-Trichloro-1,2,2trifluoroethane
2G
CCl2FCClF2
1420
C6H3Cl3
1460
CH3CCl3
1325
NF
15.19.6, 16.2.9,
16A.2.2
480
200
292
48
1,2,4-Trichlorobenzene
2321
SP
2G
A, B
1,1,1-Trichloroethane
2831
2G
SP
2G
15.12.1, 15.19.6
CHCl2CH2Cl
1440
113
ClCH=CCl2
1462
410
87
1,1,2- Trichloroethane
Trichloroethylene
1710
75
A, B,
D
CH2ClCHClCH2Cl
1390
82
304
156
A, B
15.12.3, 15.19
(CH3C6H4O)3PO
1180
238
385
440
15.19.6
(CH3C6H4O)3PO
1160
225
410
420
845
>110
2G
SP
2G
SP
2G
Tricresyl phosphate
(containing less than 1%
ortho-isomer)
2G
Tridecanoic acid
2G
2574 j)
213
SP
Tricresyl phosphate
(containing 1% or more
ortho-isomer)
1,2,3-Trichloropropane
NF
110
T2 IIA
T2 IIA
312
2323
SP
2G
Triethylamine
1296
SP
2G
2G
2G
Triethylbenzene
Triethylenetetramine
2259
Triisopropylated phenyl
phosphates
T2 IIA
T2 IIA
N1
F-T A, B
15.12.1, 15.19.6
(CH3CH2)3PO3
970
54
F-T A, C
N2
15.12, 15.19.6
(C2H5)3N
730
-17
15.19.6
C6H3(C2H5)3
860
111
2G
2,2,4-Trimethyl-1,3pentanediol-1-isobutyrate
2G
Trimethylacetic acid
2G
Trimethylbenzene (all
isomers)
N1
F-T A, D
F-T A, C
NH2(C2H4NH)2C2H4NH2
15.19.6
15.12.1, 15.16.2,
15.19.6
Y1
N1
p
(CH2CH2OH)3N
15.11.2 to 15.11.8
89
335
278
135
200 245
(CH3O)3P
1050
27
111
(CH3)2CHCH(OH)C(CH3)2
CH2OOCCH(CH3)2
960
118
182
(CH3)3CCOOH
910
71
164
54
169
SP
2G
920
2G
15.19.6
C6H3(CH3)3
C11H18N2O2
15.19.6
C9H22N2
870
876
2328
SP
2G
A,
C c)
Trimethylhexamethylenediam
ine (2,2,4-and 2,4,4-isomers)
2327
2G
A,C
1,3,5-Trioxane
2G
A ,D
15.19.6
Trixylyl phosphate
2G
15.19
((CH3)2C6H3O)3PO
1150
232
2G
15.19.6
C10H16
880
32
Undecanoic acid
2G
16.2.6, 16.2.9
CH3(CH2)9COOH
890
1-Undecene
2G
15.19.6
CH2=CH(CH2)8CH3
700
1299
157
230
980
Trimethylhexamethylenediiso
cyanate (2,2,4-and 2,4,4isomers)
Turpentine
t
360
1100 1400
N1
Boiling Point [/ C]
2G
1297
Trimethylamine solution
(30% or less)
r
179
2329
q
1130
j
X
Trimethyl phosphite
Auto-Ignition Temperature [/ C]
Tank Type
Ship Type
Hazards
Triethyl phosphite
Flashpoint [/ C]
IIA
Chemical
Formula
Special requirements
Density [kg/ m]
Materials of Construction
g
O
Fire Protection
f
2G
Vapour Detection
e
3
Gauging
d
S
Flashpoint >60/
Pollution Category
UN Number
a
Triethanolamine
Apparatus Group
c
D
Product name
Temperature Class
Tank Vents
Electrical
equipment
very
high
104
350
232
1170
253
284
Undecyl alcohol
2G
Urea/Ammonium nitrate
solution (containing aqua
ammonia)
SP
2G
SP
2G
Inert
Valeraldehyde(all isomers)
2058
X
NF
T3 IIB
F-T
N4
15.19.6, 16.2.9,
16A.2.2 (r)
CH3(CH2)9CH2OH
Boiling Point [/ C]
Auto-Ignition Temperature [/ C]
Chemical
Formula
Flashpoint [/ C]
Special requirements
Density [kg/ m]
Materials of Construction
Fire Protection
Tank Vents
Vapour Detection
Tank Type
Gauging
Ship Type
Flashpoint >60/
Hazards
Apparatus Group
Pollution Category
Product name
Temperature Class
UN Number
Electrical
equipment
q
834
93
1300
810
12
~215
103
CH3COOCH=CH2
930
-8
427
73
CH2=CHOC2H5
754
-45
200
36
880
>80
309
Vinyl acetate
1301
SP
2G
T2 IIA
1302
SP
1G
Inert
T3 IIB
F-T
SP
2G
A, B
T2 IIA
F-T
N5
CH2=CCl2
1210
(-10)
460
32
IIA
A, B
N1
C6H4(CH3)CH=CH2
890
54
494
170
15.19.6
750
~40
232
27
Vinyl neodecanoate
N6
Vinylidene chloride
1303
2G
Inert
Vinyltoluene
2618
SP
2G
1300
(B)
2G
Xylenes (bb)
1307
2G
C6H4(CH3)2
~890
(CH3)2C6H3OH
1020
Xylenol
2261
A, B
15.19.6, 16.2.9,
16A.2.2
A, B
16.2.7, 16.2.8
~1000
>60
A, B
15.19.6, 16.2.7
~1000
>60
SP
2G
(C)
2G
2G
IIA