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Water Treatment, Storage and Blowdown for Steam Boilers Module 3.9
Module 3.9
Water Treatment, Storage and
Blowdown for Steam Boilers
3.9.1
Water Treatment, Storage and Blowdown for Steam Boilers Module 3.9
Reduce heat transfer rates, leading to overheating and loss of mechanical strength.
Table 3.9.1 shows the technical and commonly used names of the impurities, their chemical
symbols, and their effects.
Atmospheric moisture
Evaporation and transportation
from surface water bodies, land
surface and vegetation
Evaporation
from oceans
Precipitation
Consumptive
use
Well
Water
table
Percolation
Fresh
ground water
3.9.2
Saline
Interface
ground water
Fig. 3.9.1 Typical water cycle
The Steam and Condensate Loop
Water Treatment, Storage and Blowdown for Steam Boilers Module 3.9
Symbol
CaCO3
Ca(HCO3)2
CaSO4
CaCI2
MgCO3
MgSO4
Mg(HCO3)2
NaCI
Na2CO3
NaHCO3
NaOH
Na2SO4
SiO2
Common name
Chalk, limestone
Gypsum, plaster of paris
Magnesite
Epsom salts
Common salt
Washing soda or soda
Baking soda
Caustic soda
Glauber salts
Silica
Effect
Soft scale
Soft scale + CO2
Hard scale
Corrosion
Soft scale
Corrosion
Scale, corrosion
Electrolysis
Alkalinity
Priming, foaming
Alkalinity, embrittlement
Alkalinity
Hard scale
Cardiff
Bristol
London
Brighton
Southampton
Fig. 3.9.2 Regional variations in water quality
Table 3.9.2 Water variation within the UK - All impurities expressed in mg /l calcium carbonate equivalents
Alkaline
Non-alkaline
Total
Total
Non-hardness
Area
hardness
hardness
dissolved
hardness
salts
(temporary)
(permanent)
solids (TDS)
Leeds
12
10
22
24
46
York
156
92
248
62
310
Birmingham
28
72
100
130
230
London
180
192
372
50
422
3.9.3
Water Treatment, Storage and Blowdown for Steam Boilers Module 3.9
Suspended solids - These are substances that exist in water as suspended particles.
They are usually mineral, or organic in origin.
These substances are not generally a problem as they can be filtered out.
Dissolved gases - Oxygen and carbon dioxide can be readily dissolved by water.
These gases are aggressive instigators of corrosion.
Scum forming substances - These are mineral impurities that foam or scum.
One example is soda in the form of a carbonate, chloride, or sulphate.
The amount of impurities present is extremely small and they are usually expressed in any
water analysis in the form of parts per million (ppm), by weight or alternatively in milligrams per
litre (mg /l).
The following sections within this Module describe the characteristics of water.
Hardness
Water is referred to as being either hard or soft. Hard water contains scale-forming impurities
while soft water contains little or none. The difference can easily be recognised by the effect of
water on soap. Much more soap is required to make a lather with hard water than with soft
water.
Hardness is caused by the presence of the mineral salts of calcium and magnesium and it is these
same minerals that encourage the formation of scale.
There are two common classifications of hardness:
o
H20
Water
H2C03
Carbonic acid
CaCO3
Calcium carbonate
Ca(HCO3)2
Calcium bicarbonate
3.9.4
Water Treatment, Storage and Blowdown for Steam Boilers Module 3.9
Heat
CaCO3
Calcium
carbonate
CO2
Carbon
dioxide
H20
water
Similarly, magnesite (magnesium carbonate) is dissolved by carbonic acid to form magnesium bicarbonate:
Mg(HCO3)2
Magnesium
bicarbonate
Heat
MgCO3
Magnesium
carbonate
CO2
Carbon
dioxide
H20
water
Non-alkaline hardness and carbonates (also known as permanent hardness) - This is also
due to the presence of the salts of calcium and magnesium but in the form of sulphates and
chlorides. These precipitate out of solution, due to their reduced solubility as the temperature
rises, and form hard scale, which is difficult to remove.
In addition, the presence of silica in boiler water can also lead to hard scale, which can react
with calcium and magnesium salts to form silicates which can severely inhibit heat transfer
across the fire tubes and cause them to overheat.
Total hardness
Total hardness is not to be classified as a type of hardness, but as the sum of concentrations of
calcium and magnesium ions present when these are both expressed as CaC03. If the water is
alkaline, a proportion of this hardness, equal in magnitude to the total alkalinity and also expressed
as CaC03, is considered as alkaline hardness, and the remainder as non-alkaline hardness.
(See Figure 3.9.5)
Non-alkaline hardness
(permanent)
Alkaline hardness
(temporary)
Total
hardness
Heat
Na2CO3
Sodium
carbonate
Na2CO3
Sodium
carbonate
H20
water
Heat
CO2
Carbon
dioxide
H20
water
2NaOH
Sodium
hydroxide
C02
Carbon dioxie
Non hardness
salts
3.9.5
Water Treatment, Storage and Blowdown for Steam Boilers Module 3.9
Comparative units
When salts dissolve in water they form electrically charged particles called ions.
The metallic parts (calcium, sodium, magnesium) can be identified as cations because they are
attracted to the cathode and carry positive electrical charges.
Anions are non-metallic and carry negative charges - bicarbonates, carbonate, chloride, sulphate,
are attracted to the anode.
Each impurity is generally expressed as a chemically equivalent amount of calcium carbonate,
which has a molecular weight of 100.
pH value
Another term to be considered is the pH value; this is not an impurity or constituent but merely
a numerical value representing the potential hydrogen content of water - which is a measure of
the acidic or alkaline nature of the water. Water, H2O, has two types of ions - hydrogen ions (H+)
and hydroxyl ions (OH-).
If the hydrogen ions are predominant, the solution will be acidic with a pH value between 0 and
6. If the hydroxyl ions are predominant, the solution will be alkaline, with a pH value between 8
and 14. If there are an equal number of both hydroxyl and hydrogen ions, then the solution will
be neutral, with a pH value of 7.
Acids and alkalis have the effect of increasing the conductivity of water above that of a neutral
sample. For example, a sample of water with a pH value of 12 will have a higher conductivity
than a sample that has a pH value of 7.
Table 3.9.3 shows the pH chart and Figure 3.9.7 illustrates the pH values already mentioned
both numerically and in relation to everyday substances.
Table 3.9.3 The pH scale
pH
Hydrogen ion concentration
value
H+
0
100
7
10-7
14
10-14
3.9.6
Nature
Acid
Neutral
Alkaline
Water Treatment, Storage and Blowdown for Steam Boilers Module 3.9
pH value
0
6
7
8
8.4 Sodium bi. carb. solution (0.42% NaHCO3)
9
10
10.6 Ammonia solution (0.017% NH3)
11
12
13
14
3.9.7
Water Treatment, Storage and Blowdown for Steam Boilers Module 3.9
Questions
1. Temporary hardness salts are reduced by:
a| Raising the water temperature
2.
c| Corrosion
d| Acidity
3.
a| Magnesium sulphate
b| Sodium carbonate
c| Sodium bicarbonate
d| Calcium bicarbonate
4.
Which of the following are principal dissolved solids that are scale forming?
b| Calcium bicarbonate
5.
6.
Answers
1: a, 2: c, 3: d, 4: c, 5: b, 6: c
3.9.8