ETOOS & MOTION

(CBSE)

MODEL TEST PAPER-1

SUBJECT - CHEMISTRY
CLASS XII
Duration : 3 hours

M.M. : 70

GENERAL INSTRUCTION :
Q.1 to Q.5 carry one mark each,
Q.5 to Q.10 carry two marks each
Q.11 to Q.22 carry three marks each
Q.23 carry four marks.
Q.24 to Q.26 carry five marks each
SECTION-A
Question number 1 to 5 carry 1 mark each.
Q.1
What is meant by intrinsic semiconductor?
Q.2
Write IUPAC name of the following:
CH 3 C CH CH2Br
Q.3
Q.4

Q.8

(i) Aniline is weaker base than cyclohexylamine.

(ii) Ammonolysis of alkyl halide does not give
corresponding amine in pure state.
Q.9

CH 3
Draw the structure of 2-hydroxy benzaldehyde.
Arrange the following in increasing order of
acidic character:
OH

OH

OH
CH3

Write the equation for the following reaction:

(i) Carbylamine reaction
(ii) Coupling reaction

Q.10

Complete the following reactions:

(i) MnO4 Fe2 H

OH
NO2

O2N

Give reason:

(ii) Cr2O72 Sn2 H

I

NO2
III

II

NO2
IV

SECTION-C
Question number 11 to 22 carry 3 mark each.

Q.5

Why is physical adsorption multilayered?

SECTION-B
Question number 6 to 10 carry 2 mark each.
Q.6
At 300 K, 36 g of glucose (C6H12O6) present per
litre in its solution has osmotic pressure of 4.98
bar. If the osmotic pressure of another solution
is 1.52 bar at the same temperature, calculate
the concentration of the other solution.
Or
Describe how the molecular mass of a substance
can be determined by method based on
measurement of osmotic pressure.
Q.7
For a chemical reaction, a graph is shown:

Q.11

(a) Name the element purified by

(i) Zone refining (ii) van Arkel process
(b) The value of f G for formation of Cr2O3 is
540 kJ mol-1 and that of Al2O3 is 827 kJ mol-1.
Is the reducti on of Cr 2 O 3 possi bl e with
aluminium?

Q.12

Define the following:

(i) Peptization

(ii) Coagulation

(iii) Hardy Schulze rule

In [R]

Q.13

(a) Name two allotropes of sulphur. Which of

them is more stable at room temperature? Which
of them is formed at 369 k?
(b) Why is sulphur paramagnetic in vapour
state?

Time

Q.14

(i) What is order of reaction?

(ii) What are the units of rate constant k for
the reaction?

(i) Name one narcotic used as analgesic.

(ii) Give an example of artificial sweetener which
can be used in cold food and drinks.
(iii) What are cationic detergents?

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PRE-BOARD TEST PAPER - 1

Page # 2
Q.15

Q.16

Q.17

Q.18

Q.19

Q.20

(a) What happens when LiCl is heated with

lithium vapours?
(b) Calculate the number of cation vacancies
when NaCl is doped with 10-3 mol % of SrCl2.
Or
(a) What are ferrimagnetic substances?
Give an example.
(b) In which type of defect, density decreases.
(c) What are 12-16 compounds?
2.5 g of Non-volatile solute is dissolved in 100g
of water, the elevation in boiling point at 1 atm
is 0.2 C. Calculate molecular weight of solute.
[Kb for H2O = 0.52 K kg mol1]
(a) What is meant by activation energy?
(b) The rate of reaction becomes double when
temperature is increased from 300 K to 310 K.
Calculate activation energy.
(a) Why do transition metals show variable
oxidation states?
(b) Name one lanthanoid which is radioactive.
(c) What is meant by lanthanoid contraction?
(i) Write structure of monomer of teflon.
(ii) What are thermoplastics? Give an example.
(iii) Wh'lch of the following is elastomer.
Complete the following reactions:
(i)

SECTION-E
Question number 24 to 26 carry 5 mark each.
Q.24 (a) Give two differences between electrolytic
and electrochemical cells.
(b) M/M2+ (saturated solution of MX2) || M2+
(0.001) | M.
The emf of above cell is 0.059 V. Calculate G
for the given cell.
(c) What is meant by electrochemical series?
Or
(a) Give two differences between metallic and
electrolytic conductance.
(b) A solution of Ni(N03 )2 is electro lysed
between platinum electrodes using a current of
5.0 amperes for 20 minutes. What mass of nickel
will be deposited at the cathode? (Given, Atomic
mass of Ni = 58.7 g mol1, 1F = 96500 C mor1 ).
(c) What are primary cells?
Q.25 (a) Complete the following reactions.
O

(i) CH3 C H + CH3MgBr

O

FeCl3

+ Cl2

(ii) CH 3 CH

CH2

(ii) CH3

CH 3 + KOH(alc.)

CH3

Zn(Hg)
conc.HCl

conc.NaOH
(iii) C6H5CHO

Cl
Acetone
(iii) C2H5Br NaI

Q.21 (a) Distinguish between following compounds

by suitable chemical test:
(i) Methanol and Ethanol
(ii) Phenol and Benzyl alcohol
(b) Convert phenol to picric acid.
Q.22 (a) CrCl3.6H2O gives 2 moles of AgCl when
treated with excess of AgN03 solution. Write
structure formula of the complex. .
(b) Write hybridization, shape and magnetic
property of [Fe(CN)6 ]3 .[Atomic number of
Fe=26].
SECTION-D
Question number 23 carry 4 mark
Q.23 Ramesh takes a lot of junk food, such as burger,
French fries and Pizza. His teacher Mr. Manish
got his medical check up in school and found
that he i s suffering from hypertension.
The doctor gave him advice not to take junk
food and do exercise daily. He should take
balanced diet rich in proteins, vitamins and'
minerals.
(i) What are the values associated with Mr.
Manish?
(ii) Why should children take milk and its
products?
(iii) Which protein is present in milk and egg?
(iv) What is meant by denaturation of proteins?

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H O
'Y'
'X' 3

Q.26

(b) Why do alcohols have higher boiling points

than aldehydes?
(c) What is formaline? Give its use.
Or
(a) Write short notes on the following:
(i) Cannizzaro's reaction
(ii) Aldol condensation
(iii) Wolff Kishner reduction.
(b) Convert :
(i) Acetone to tert. butyl alcohol
(ii) Butan-2-ol to Butan-2-one.
(a) Give two difference between white and red
phospohorus?
(b) Complete the following equations:
(i) HgCl2 + PH3
(ii) NH3 + HCl
(iii) C + (conc.) HNO3
Or
(a) Name one allotrope of oxygen.
(b) Why is ozone more reactive than oxygen?
(c) Why is PH3 less basic than NH3?
(d) Why is ionisation enthalpy of 'N' more than
that of oxygen?
(e) What are interhalogen compounds?

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