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Activity
1
1.
2.
3.
4.
5.
Answer
6
saturated ;
7
saturated hydrocarbon
8
unsaturated hydrocarbon
9
petroleum
10 carbon dioxide ; water
carbon
organic ; inorganic
inorganic
Hydrogen ; carbon
nonhydrocarbon
a)
b)
c)
molecules. ; freely
d)
1
2
3
4
5
6
7
8
9
10
11
12
14
4
4
single covalent
methane
Cn H2n+2 n= 1,2,3.
refer to F5 textbook page 37
neutral
carbon dioxide , water
sooty
chlorine , bromine
- ane
a)
b)
a) i)
ii)
(iii)
(iv)
v)
vi)
vii)
viii)
chloroethene
2-methylpropene
1-chloropropene
but-2-ene
Hexene = 85.71 %
Hexane can be a good fuel because the percentage of carbon is low hence
produce less soot.
c) * cannot dissolve in water
* cannot conduct electricity
* low melting and boiling point
* neutral
* Produse CO2 and water when burnt in oxygen
d) - Alkene produce more soot - alkane produce less soot
- Alkene decolorized bromine water alkane colour unchange
- Alkene decolourized the purple colour of acidified KMnO4 solution Alkane does not change the purple colour.
9
a) i) isomerisme
(ii)
iv) ethane and propene
Isomer
iii) alkyl group
v) butane
a)
i) hydroxyl / -OH
ii) Cn H2n+1OH
n, 1,2,3,3
iii)
Higher ; OH/hydroxyl
iv)
stronger,
v)
vi)
vii)
Viii)
molecular mass
alkene
solvents, cosmetics
non hydrocarbon / carbon / organic
b) i) methanol
ii) ethanol
iii) propan-1-ol
iv), v) vi) refer to F5 textbook page 56
c) (i) propan-1-ol ; propan-2-ol
(ii) butan-1-ol ;
butan-2-ol ;
2-methylpropan-2-ol
11
2-methylpropan-1-ol;
a)
Physical
properties
Physical state at room
temperature
Smell and colour
Description
First 12 alcohols are liquid at room
temperature
Alcohols are colourless and has a pleasant
smell
Solubility in water
Volatility
Boiling point
b) (i)
C2 H 4 (g) +
(ii) temperature
Pressure
Catalyst
12
a) 1
H2O (g)
CH3CH2OH (g)
: 3000 C
: 60 atm
: phosphoric acid.
In excess oxygen
In limited oxygen
6
7
8
9
10
F
T
F
T
T
13
an organic acid with carboxyl
group COOH ( )
Uses :
- food preservative ( benzoic
acid)
- food flavouring
- ethanoic acid and methanoic
acid are used to coagulate
latex in rubber industry
- making ester and soft drinks
General formula
CnH2n + 1 COOH
CARBOXYLIC
ACIDS
b)
Methanoic acid
Ethanoic acid
O
O
H
II
I
H - C C - OH
II
H C - OH
I
H
Propanoic acid
Butanoic acid
O
H H
I
I
II
H - C - C C - OH
I
H
H H
I
I
H - C - CI
I
H
H
I
H
2-methylbutanoic acid
H
H O
H
II
I
I
I
H - C - C - C C - OH
I
I
I
H H CH
3
O
H
II
I
C C - OH
I
H
c) i) General formula
ii) 60
iii) ethanoic acid
: CnH2n + 1 COOH
O
H
II
I
H - C C - OH
I
H
14
a) hydration ; oxidation
b) refer to F5 textbook page 71
c)
Observation
1
The metal carbonate dissolves,
Efferverscence occurs
Gas turns lime water cloudy
2
15
Magnesium dissolves
Bubbles of gas given off
Gas burns with a pop sound
Inferrence
Carbon
released
dioxide
gas
a)
Formula
HCOOC2H5
Name
Ethyl mathanoate
Carboxylic acid
Methanoic acid
Alcohol
Ethanol
a) CH3 COOCH3
Methyl ethanoate
Ethanoic acid
Methanol
b) CH3 COOC3H7
Propyl ethanoate
Ethanoic acid
propanol
c) C2H5 COOCH3
Methyl
Propanoic acid
Methanol
d) C3 H7COOC3H7
propanoate
Propyl butanoate
Butanoic acid
propanoll
b) i)
methylpropanoate
(ii) ethylbutanoate
(iii)
16
prophylethanoat
a)
Ester is a nonhydrocarbon organic
compound
product of an esterification
reaction between a carboxylic
acid and an alcohol.
contain carbon,
hydrogen and oxygen
the functional
group is COOor carboxylate
group
ESTERS
The general formula is
CnH2n+1COOCmH2m+1
uses of ester,
as food flavouring
to pleasant aromas for
making perfumes
as organic solvents for
glue, varnish and paint
b) i) bananas
(ii) oranges
(iii) pineapples
17
18
a) i) alcohol
b)
ii) alkene
iii)
I)
a)
b)
c)
d)
e)
f)
lipid
ester
glycerol , fatty acids
solid , liquid
carbon
ester link
carboxylic acid
iv) ester
g)
h)
i)
j)
triglycerides
chloroform
energy
saturated, harden , stroke, High blood
pressure, heart attack
k) hydrogenation
l) margarine
Oils
Fats
plants
Animals
Melting point C
< 20 / lower
> 20 / higher
Liquid
low
high
Examples
Butter , lard
Molecular structure
Contain a high
percentage of
unsaturated carboxylic
acid
Contain a high
percentage of saturated
carboxylic acid
III) Similarities
In terms of
Molecular formula
19
similarities
Type of compound
Type of bond
a)
Sterilisation - The fresh fruit bunches are sterilized is large pressure vessels at
140o C for 60-90 min. The heat from the steam kills fungus and bacteria
20
(a )
(i) -Bacteria from the air slowly attack the protein on the membrane of the
colloidal particles to produce lactic acids.
-ionisation of lactic acids produce hydrogen ions, H+
-H+ ions from the acids neutralize the negatively charged membranes of
the bcolloidal particles. Repelling forces between colloidal particles
disappear.
-collisions of these neutral particles cause their membranes to break up,
rubber polymers are set free.
-the free rubber polymers combine together to form large lumps.
(ii)
- Positively charged H+ ions from the acids neutralise the negatively
charged membranes of the colloidal particles. Repelling forces between
colloidal particles disappear.
-collisions of these neutral particles cause their membranes to break up,
rubber polymers are set free.
-The free rubber polymers combine together to form large lumps.
(iii )
-Hydroxide ions, OH- from the aqueous ammonia solution neutralise the
lactic acids produced by the bacteria in the latex.
-the negatively charged on the membrane of the colloidal particles
remain.
-the repelling forces between the particles keep them apart.
-no coagulation of latex occurs
(b)
Aspect
Structure
Oxidation
Resistance of heat
Strengh
Elasticity
21
Unvulcanised rubber
More C=C- bonds in
rubber molecule
Easily oxidised
Non-resistant
Easily melt and
decomposed
Soft and easily
changes shape
Less elastic
Easily stretched but
difficult to return to its
original shape
Vulcanised rubber
Less C=C bonds
Resist oxidation
More resistance
stronger
More elastic
Difficult to be stretched
but readily returns to
its original shape
(a) 1,2-dibromopropane
(b) (i) Propene gas and acidified potassium manganate(VII) solution
(ii) C3H6 + (O) + H2O C3H6(OH)2
(c) (i) Hydrogenation
(ii) Nickel
(d) (i) A mixture propane gas (C3H8) and chlorine gas (Cl2) is exposed to
ultraviolet light.
(ii) Steamy fumes are produced.
(e)
(f) (i)
(g)
Polymerisation
2 (a)
CnH2n + 2
; n = 1, 2, 3, .....
(b)
carboxyl group //
- COOH
(c)
10