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MODULE 2
CHEMISTRY 2014
KEDAH
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PAPER 1 ANSWER
Question No.

Answer

Question No.

Answer

26

27

28

29

30

31

32

33

34

10

35

11

36

12

37

13

38

14

39

15

40

16

41

17

42

18

43

19

44

20

45

21

46

22

47

23

48

24

49

25

50

Question
Mark Scheme
No
1 a) Empirical formula : formula that shows the simplest whole number ratio of atoms of
each element in a compound

Marks
1

b)
d)

To allow oxygen from the air to react with magnesium // To

prevent fumes of magnesium oxide from escaping
(i) Mass of magnesium = 19.20 - 18.30 g = 0.9 g

(ii)

Mass of oxygen
= 19.80 - 19.20 g = 0.6 g
Elements
Mg
:
O
No of mole 0.9
:
0.6
24
16
Ratio

(e)

0.0375
0.0375

0.0375
0.0375

1
1
//

(iii) MgO
(i)
Cu // Pb // Sn
(ii) To remove all the air in the combustion tube
(iii) To dry the hydrogen gas // as a drying agent
Total

Question No
2

(a)
(b)
(c)
(d)
(e)
(f)
(g)

(i)
(ii)

Mark
Marks
Scheme
Contact Process
Oleum
SO3 + H2SO4 H2S2O7
450-500 OC
Air (udara)
Nitric acid
Acid rain corrodes the buildings made of calcium carbonate/limestone//
Acid rain corrodes concrete building
Reduce combustion of fossil fuels
Channel waste gases from factory through air filtering systems
(accept any suitable answers)

1
1
1
1
9

1
1
1
1
1
1
1
1
1

Total

Heat released when one mol of water produce from reaction between hydrochoric acid
// acid and sodium hydroxide// alkaline solution.

MARK SCHEME : PAPER 2 MODULE B: CHEMISTRY

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(a)

(b)

(i)

(ii)

(iii)

Heat change = mc
= 200 x 4.2 x 13
= 10 920 J = 10.92 kJ

No. of mol of H+ = 100 x 0.2

1000
= 0.02 mol
// No. of mol of OH- = 100 x 0.2
1000
= 0.02 mol

Heat of neutralisation = 10920

0.02
= 546 000
Heat of neutralization = - 546 kJ mol -1

(c)

correct diagram

-1
H = -546 kJmol

1
1
labelled
(d)

-1

(i)

Between -533 kJ mol

-1

(ii)

Ethanoic acid is a weak acid // ionise partially in water to produce hydrogen ion

Some heat is absorbed for ionization of ethanoic acid.

to 542 kJ mol

Total

(a)

Sulphuric acid
[r: H2SO4]

10

(b)

H2SO4 + 2KOH

K2SO4 + 2H2O

Correct formula reactant and product

Balanced
(c)

(i)

1
1

Able to calculate the volume of Y(V1) acid used with unit

M1V1 = M 2V2
a
b
0.1 (V1) = 0.2(25)
1
2

V1 = 25 cm3 (r : without unit)

(ii)

Able to calculate the mass of salt formed with unit

Number of mol Y acid = MV
1000
=
0.1(25)
1000
=0.0025

Mass of salt formed= 0.0025 x 174

4

(b)
(c)

(d)

(a)

(i)
(ii)
(i)
(ii)
(i)
(ii)
(iii)

Strong acid is an
acid that ionises
completely in
water
to
produce
high
concentration
of
hydrogen
ions.

Ethanoic acid
Ionise partially in water //produce low concentration of hydrogen ions.
2
10 x X = 250 x 0.02
X = 0.5 mol dm-3
water
H+
Zn +2 HCl ZnCl2 + H2
1.correct formula and reactant
2.balancing

1
1
1
1
1
1
1
1
1
Total

10

(a)
(b)

Alkene / alkena

H H H
I I
H CCCH
I I

H H
(c)

(i)

C3H6 + 9/2O2

3CO2 + 3H2O
2

(ii)

Correct formula of reactant and product

Balance equation
Propene produce more soot
% of C in propene is higher than that in propane
% of C in propene;
3 X 12 X 100 = 85.71%
42
% of C in propane:

1
1

3 X 12 X 100 = 81.82%
44
(d)

Propene is an unsaturated hydrocarbon but propane is saturated hydrocarbon //

Propene has double bond but propane has single bond

(e)

Glass wool
soaked with
propanol

Gambarajah berfungsi
label
anak panah : heat
1
= 0.435 g (r :
without unit)

1
1
1

(d)

The solution is heated until saturated /one third of its original volume
Cool the solution slowly
The salt are filtered and dried by pressing them between filter papers.

1
1
1

(e)

Sodium sulphate//Potassium nitrate//sodium nitrate//sodium chloride//potassium

chloride

11

(a)

(i)

(ii)
(b)

(i)

1.No of mole of helium atoms= 4 mol //1 mol

4
2. No of mole of hydrogen atoms = 2 x 2mol //2 mol
2

1.No of atom of hydrogen is double/twice than helium

2.because no of mole of atom of hydrogen is double/twice than helium
Empirical formula = C5H7 N
Molecular Formula = C10 H14 N2

1
1
1
1

C5H7 N

C10 H14 N2

both contain element carbon,hidrogen and nitrogen

(ii)

(c)

(i)

Contain 5 carbon atoms,7

Contain 10 carbon atoms,17
hidrogen atoms and 1 nitrogen
hidrogen atoms and 2 nitrogen
atom
atom
Shows simplest whole number
Shows actual number of atom of
ratio of atom of each element
each element
1.brown bromine water decolourises
2.nicotine undergoes addition reaction with bromine//c=c react with bromine

Wrong formula
1.AgCl2
2.Mg NO3

1
1+1

1+1
1
1

1
1

(ii)

2AgNO3 + MgCl2 2AgCl + Mg(NO3)2

1.correct formula of reactant and product
2.correct balancing

1
1

(iii)
1. silver nitrate and magnesium chloride are reactants and silver chloride and
magnesium nitrate are products
2. silver nitrate , magnesium chloride and magnesium nitrate are in aqueous solution
but silver chloride in solid form
3. 2 mole of AgNO3 react with 1 mole of MgCl2 to form 2 mole of AgCl and 1mole
of Mg(NO3)2
(Note : point 3 ecf from (c)(ii))
Total

20

TOTAL

11

Section B http://cikguadura.wordpress.com/

1
1
1

8(a)

(i)

2H2O2

2H2O + O2
Correct formula
balanced

1
1

Correct curve axis and units

label expt(A,B) and time (20,40)

1
1
1

(ii)

EkspB

Eksp A

20

(iii)

40

i) Increase the concentration of hydrogen peroxide

ii) 0.1 mol dm-3 /
any suitable higher concentration
3
iii) Volume 25 cm /
any suitable volume to get that match the
concentration

1
1
1

iv) Any suitable application of concentration.

v) How the application is used.

(iv)

functional diagram
Labelled

1
1

(c)

(c)

(i)

1. Rate of reaction of experiment B is higher

2. The presence of catalyst in experiment B

3. the reaction through the alternative path // lower activation energy

4. more colliding particle can achieve the lower activation energy

5. frequency of effective collision is higher.

(ii)

Activation
energy

Eksp B
Eksp A
Correct graph

Section C

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Label experiment (A,B)

Label activation energy

Total

20

or
Between Y and Z

ii.

Covalent

Correct no of shells and electron for each atoms involved

Correct no of atoms// charge for each compund

10

(a)

(b)

(c)

Metal R: magnesium//zinc
Reason: Metal R is more electropositive than iron//
rust//prevent iron from rusting//inhibit rusting of iron nail

1
Iron nail does not
1

Explain:
ii
Metal S: copper//tin//lead//silver//aurum
1
Between element Y and X(sample for ionic)
Reason: Iron is more electropositive than metal S// Iron nail rusts//speed up
1 electron
Atom Y has 1 valence electron and atom X has 6 valence
rusting
+
Atom
2Y+ + 2e
(accept any suitable metal R2 and
S) of Y donate 1 electron each to form 2Y ion // 2Y
Atom X accept 2 electron to form X2- ion // X + 2e
X2To achieve stable octet electron arrangement
Metal: magnesium // zinc// lead // tin
1
+
22 ion Y and ion X attract each other by a strong electrostatic forces
Eg:
Oxidation nombor of Mg increases from 0 +2 //Mg Mg2++2e// Y2X ionic compound 1is formed
Magnesium undergoes oxidation
1
Oxidation nombor of copper(II) ion decreases from +2 0// Cu2+ +2e
Cu
1
Carbon
Carbon
Copper undergoes Between
reductionelement W and X (WX2)(sample for covalent)
1
electrode
electrode
Redox reaction occurs
as oxidation of magnesium and
reduction of copper(II)
1
ions occur simultaneously.
One atom W contribute 4 electrons
Bromine water
Four atom Z contribute 1 electron to share.
One atom W share 4 pairs electron with four atom Z
Four single covalent bond are formed
WZ4 covalent compound is formed
Sulphuric acid

1x2
1x2

1
1
1
1
1

1
1
1
1
1

Potassium
iodide solution
1
Maximum mark
Diagram:
b)
1.label
2.functional apparatus

Covalent Compound
Low melting and boiling points
Held by weak
intermolecular
Suggested chemical:Potassium
iodide
solution
forcesagent)
(or any suitable reducing
Need more energy to overcome
the forces

1
Ionic Compound d
1
High melting and boiling points
Held by strong electrostatic
forces
1
Need less energy to overcome
the forces

12

1+1
1+1
1+1

or
Covalent Compound
Ionic Compound
Cannot conduct electricity in any Cannot conduct electricity in
state
solid state
Can

1+1

conduct
electricity
in
molten and
aqueous
state
Consist of molecules
Neutral particles

Consist of ions
Charged particles//Move freely in
molten and aqueous state

mark
TOTAL

6
20

Procedure:
1. Dilute sulphuric acid is poured into a U-tube.
2. Using a dropper, potassium bromide solution is added at one arm and
bromine water at another arm.
4. Carbon electrode is placed in each side of the U-tube.
5. The electrodes are connected to a galvanometer by using connecting
wires//
The external circuit is completed.
6. Any changes that can be observed are recorded.

Half-equations:
2I- I2 + 2e
Br2 + 2e 2Br-

1
1
1
1
1

1
1
Max 10
Total

END OF MARK SCHEME

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20

1
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MODULE B :KIMIA PAPER 3: Mark Scheme

Questions
Mark Scheme
1(a)
Able to state the three variables correctly
Sample answer
- Manipulated Variable: metals in contact with Fe//P,Q,R
- Responding Variable: rusting//blue spots//pink spots
- Constant Variable: iron nail//electrolyte
Able to state any two variables correctly

1(b)

Mark
3

Able to state any one variables correctly

No response or wrong response

Able to state the relationship between the manipulated variable and the
responding variable and state the direction correctly.

Sample answer
The further the distance between two metals in electrochemical
series, When less electropositive metal in contact with iron, the
higher is the intensity/more of blue spots/rust
Able to state the relationship between the manipulated variable and the
responding variable without stating the direction

Sample answer
When different metal in contact with iron, the more blue spot/rust formed
Able to give an idea of hypothesis

Sample answer
Pair of metal willproduce rust.
No response or wrong response

Able to make inference correctly.

1(c)
Sample answer
Set
I
II
III

Inference
Metal P is less elctropositive than iron
Metal Q is the most electropositive.
Metal R is more electropositive than iron

1(d)

Able to state 2 inference correctly

Able to state 1 inference correctly

No response or wrong response

Able to give the operational definition for rusting correctly with the

following
aspects:
i.what you do
ii.what you observe
Sample answer
When less electropositive metal in contact with iron, blue spot form
Able to give the operational definition for rusting incompletely with
any one of the following aspects: i.what you do
ii.what you observe

Sample answer
Metal is put into jelly blue spot form

1(e)

Able to give an idea of operational definition for rusting

Sample answer
Metal rust
No response or wrong response

Able to compare the difference between 1 day and 2 days correctly

Sample answer
The size/quantity of blue spot increase with time
Able to compare the difference between 1 day and 2 days
Sample answer
More blue spot form

Sample answer

Blue spot form

1(f)

1(g)

No response or wrong response

Able to arrange the four metals correctly

Sample answer P,
Fe, R, Q
Able to arrange any three metals in sequence correctly
Sample answers
Fe, R, Q , // P, Fe, R
Able to arrange any two metals correctly
Sample answers
P, Fe// Fe, R// R, Q

No response or wrong response

Able to predict the metal correctly

Sample answer
Copper/Cu // Silver/Ag
Able to predict the metal less correctly
Sample answer

Gold/Au

1(h)

Able to give an idea of predicting the metal

Sample answer
Mercury/Hg

No response or wrong response

Able to classify all the six metals correctly

Sample answer

Metal which are more

electropositive than iron
Logam yang lebih elektropositif
daripada besi

Magnesium
Aluminium
Zinc

Metal
which
are
electropositive than

less
iron

Logam yang kurang elektropositif

daripada besi

Copper
Tin
Silver

Able to classify any 4 metals correctly

Able to classify any two metals correctly
If reverse

2
1

1(i)

No response or wrong response

Able to state all observations correctly

Sample answer

Electrode/Electrolyte

Observation

Elektrod/Elektrolit

Pemerhatian

Negative terminal

Becomes thinner//corrodes

Terminal negatif

Positive terminal
Terminal positif

Electrolyte
Elektrolit

1(j)

Becomes thicker// brown solid

deposited.
Intensity
of
blue
decreases//blue to light blue

colour

Able to state any two observations correctly

Able to state any one observation correctly

No response or wrong response

1
0

Able to record all readings accurately with one decimal place and unit
Answer
Set I : 2.2 V
Set II : 3.4 V
Set III : 1.4 V
Able to record all readings correctly without unit or any two
readings correctly with unit. Sample answer
Set I : 2.2 //2.20
Set II : 3.4 // 3.40

Set III : 1.4 // 1.40

1(k)

Able to record at least one reading

No response or wrong response

1
0

Able to construct a table that consists of:

1.Headings for manipulated and responding variables with unit
2. List all the variables
Sample answer

Pairs of Metal
Fe/P
Fe/Q
Fe/R

Voltage (V)
2.2
1.4
3.4

Able to construct a table that consists of:

1.Headings for manipulated and responding variables without unit
2. List all the variables
Sample answer
Pairs of Metal
Fe/P
Fe/Q
Fe/R

Voltage
2.2
1.4
3.4

Able to construct a table that consists of:

1.Headings for manipulated and responding variables

Sample answer
Pairs of Metal

2(a)

2(b)

Voltage

No response or wrong response

Able to give the problem statement correctly

Sample answer
Does soap more effective than detergent for cleansing action in hard water?
Able to give the problem statement
Sample answer
Does soap more effective than detergent ?
Able to give an idea of the problem statement.
Sample answer
Does soap more effective ?
No response or wrong response

Able to state all variables correctly

Sample answer
Manipulated variable: Detergent ,soap
Responding Variable: effectiveness of cleansing action
Fixed variable : hard water//mass/volume of detergent and

soap//volume of water
Able to state any two variables correctly

Able to state any one variable correctly

2(c)

2(d)

2(e)

No response or wrong response

Able to state the hypothesis correctly

Sample answer
Detergent is more effective than soap in hard water
Able to state the hypothesis
Sample answer
Detergent is more effective
Able to give an idea of the hypothesis
Sample answer
Detergent is for cleaning action
No response or wrong response

Able to list the materials and apparatus completely

Sample answer
Materials
1. dirty cloth/socks
2. soap and detergent
3. hard water
Apparatus
1. Beaker/basin
2. Measuring cylinder
3. Spoon/spatula
Able to list the materials and apparatus
Sample answer
Materials
1. cloth
2. soap and detergent
3. hard water
Apparatus
4. Beaker/basin/container

Able to give an idea of materials and apparatus

Sample answer
1. detergent/soap
2. cloth
3. water
No response or wrong response

Able to state all steps of procedure correctly

Sample answer
1.Pour 100-200 ml of hard water into a beaker
2.Add/put 1-2 spoon of detergent into the beaker
3.Soak/dip a dirty cloth in the beaker
4.Leave for 30 minutes
5.Record the observation
6. Repeat steps 1-5 using soap.

2(f)

Able to state the steps 1,2,3 and 5

Able to state steps 1.2 and 3

No response or wrong response

1
0

Able to construct a table that consists of:

1.Headings for manipulated and responding variables
2. List all the variables
Sample answer
Type of cleaning agent
Observation/Effectiveness

Detergent
Soap
Able to construct a table that consists of:
1.Headings for manipulated and responding variables

Sample answer
Type of cleaning agent

Observation

No response or wrong response

PERATURAN PEMARKAHAN
TAMAT
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