Aiats Jee Main 2015 Test-4

Test - 4 (Paper-I) (Code-A) (Answers & Hints)
All India Aakash Test Series for JEE (Main)-2015

Click here for Code-B Solution
Test Date : 11-01-2015
PHYSICS
TEST - 4 (Paper-I) - Code-A
ANSWERS
CHEMISTRY
MATHEMATICS
1.
(2)
31.
(4)
61.
(2)
2.
(4)
32.
(2)
62.
(4)
3.
(3)
33.
(2)
63.
(3)
4.
(4)
34.
(1)
64.
(1)
5.
(3)
35.
(3)
65.
(1)
6.
(2)
36.
(3)
66.
(3)
7.
(2)
37.
(1)
67.
(2)
8.
(1)
38.
(4)
68.
(2)
9.
(2)
39.
(2)
69.
(3)
10.
(4)
40.
(3)
70.
(2)
11.
(3)
41.
(1)
71.
(3)
12.
(2)
42.
(4)
72.
(1)
13.
(2)
43.
(3)
73.
(1)
14.
(2)
44.
(2)
74.
(1)
15.
(2)
45.
(3)
75.
(3)
16.
(1)
46.
(2)
76.
(4)
17.
(1)
47.
(1)
77.
(4)
18.
(2)
48.
(1)
78.
(3)
19.
(4)
49.
(3)
79.
(4)
20.
(2)
50.
(4)
80.
(2)
21.
(4)
51.
(3)
81.
(2)
22.
(1)
52.
(4)
82.
(4)
23.
(2)
53.
(2)
83.
(4)
24.
(2)
54.
(3)
84.
(3)
25.
(4)
55.
(2)
85.
(2)
26.
(1)
56.
(2)
86.
(3)
27.
(1)
57.
(1)
87.
(1)
28.
(2)
58.
(1)
88.
(3)
29.
(4)
59.
(4)
89.
(3)
30.
(4)
60.
(2)
90.
(4)
1/10
PART - A (PHYSICS)
1.
Answer (2)
2.
Answer (4)
6.
Q = dU + W
For isobaric process W = nRT
1
(2P0 P0 )(3V0 V0 ) P0 (3V0 V0 )
2
= 300 J
WABC =
and dU = nCV T
UABC = QABC WAB = 300 J = UAC

WAC = P0(3V0 V0) = 200 J
Answer (3)
Q = 75 + 25 = 100 J
7.
Q = dU + W
Answer (2)
nCdT = nCvdT + W
n(C Cv )dT
T0
C
U
f
v 3
R
2
W
dU = 3W = 75 J
QAC = WAC + UAC = 500 J

3.
Answer (2)
2T0
B
2P0
(C Cv )dT for n = 1
P0
T0
T0
T0
a
Cv
T
Q = Cv(2T0 T0) + CP(4T0 2T0) =
= 6R(2200 800)
Molar heat capacity =
= 6R 1400
8.
x = A cos t
= 6R 600
So A = A cos
cos
W = 6R 1400 6R 600
= 6R 800
and A ( + ) = A cos 2
cos 2
Answer (3)
At t = 0, x1 = 0
A
x
3 A
2
<V> =
t
2/10
... (1)
A
A
= 40,000 J
A
, x2 A sin
6
6 2
Q 19
R
T
6
Answer (1)
= 6R(600 1200)
While WAB = WCD = 0
At t =
19
RT0
2
Total change in temperature form state A to C is

T = 3T0
Work done from B to C = nR(TC TB)
5.
2V0
Total heat absorbed by 1 mole of gas
Answer (4)
Work done from D to A = nR(TA TD)
T0
V0
dT
1
= a ln
RT0
1
4.
4T0
C
9.
... (2)
A ( )
A
2 2
3
Answer (2)
x1 = A cos t and x2 = A sin t
B
A sin t = A cos t
sin t + cos t = 0
1
2
sin t
cos t 0
5
0.825 m
4
l4
7
1.155 m
4
As 4 is greater than 1 m, so allowed resonance

are only 3.
cos t 0
4
cot
l3
14. Answer (2)
0
0
176
165
22

4 2
0 = 22 m/s
3T
8
15. Answer (2)
10. Answer (4)
If mass falls down by x,

so spring extends by 4x.
T
k (4 x )
4
A
T
4
T
2
T
2
1 16k
2 m
T
T
m
k
m
10
5 x2
f (x)
Hence wave function y(x, t) = f(x vt)
y ( x, t )
2y
Suppose 2y is the distance between two rows of the

buildings. The distance travelled by car in 1 second,
5
150
x 30
m
1 =
18
8
The distance travelled by sound in 1 second

l = 165 m
Velocity of pulse v = 2 m/s along positive x-axis.
2l = 330 1 = 330 m
11. Answer (3)

At t = 0, y =
T
4
T = (16k)x
10
5 ( x 2t )2
12. Answer (2)
From the figure y

16. Answer (1)
17. Answer (1)
Vm
VH
H
m
where m
13. Answer (2)

v
0.66 m
f
x
l 2 165 m
2
0V0 HVH
V0 VH
0
.V VH
H 0
4
V0 VH
m
H
0.165 m
l1 =
4
H
1
4
m
3
l2
0.495 m
4
Vm VH
The resonance length are
... (1)
H
1
1200 600 m/s
m
2
3/10

18. Answer (2)
f 10

l0 = 45 cm. If the mercury displaces by x, then
1 129.6
2L
l0P0 = (l0 + x)P1
... (i)
l0P0 = (l0 x)P2

and P2 = P1 + h0
1 160
and f
2L
... (ii)
f = 100 Hz
l0 P0
l P
0 0 h0
l0 x l x
x = 4.5 cm
19. Answer (4)

The frequency of sound heard by motorist from
reflection
v vm
f1
v vb
.f
23. Answer (2)

I=
ma2
a
and l
3
2
T 2
... (i)
The frequency of sound heard by motorist directly
v vm
f2
v vb
24. Answer (2)
The process 3 1 is an isochoric process. So

w = 0
... (ii)
Beat frequency = f1 f2
2b(v v m )
(v 2 v b2 )
.f
U nCv (T1 T3 )
20. Answer (2)
vi
v
f
Ti
Tf
hi
h
f
Ti
Tf
Q1 + Q2 = Q3 + Q4 + Q5
M3Cw(T2 T) + M2Cb(T2 T)
= M1Ci(0 T1) + M1Lv + M1Cw (T 0)
T M1Ci ( T1 ) M1Lv M3CwT2 M2CbT2
M3Cw M2Cb M1Cw
21. Answer (4)
A TA4 B TB4
= 10.9C
1/ 4
26. Answer (1)
.TA 1934 K
Statement-1 is true, statement-2 is true and

statement-2 is correct explanation for statement-1.
ATA BTB
27. Answer (1)
A B
3

28. Answer (2)
But B A 106
Statement-1 is True, Statement-2 is True; Statement2 is NOT a correct explanation for Statement-1.
B 1.5 106 1.5 m
29. Answer (4)
22. Answer (1)
P0
l0
4/10
3P0 M
20
By the law of calorimetry
373
hf 4.00
5.09 cm
293
3P M
3 P0 M 2P0 M
0
2 0
0 =
2P0
25. Answer (4)
T
hf f hi
Ti

TB A
B
I
2a
2
mgl
3g
P0
h0
l0
Statement-1 is False, Statement-2 is True.

30. Answer (4)
PART - B (CHEMISTRY)
So, weight of CaCO3 in 106 ml hard water
31. Answer (4)
5 10 2
NH4NO3
N2O H2O
NH4NO2
N2 2H2O
= 50 ppm
(NH4 )2 Cr2O7
N2 Cr2O3 4H2O
(NH4 )2 CO3
2NH3 H2O CO2
2Mg(NH4 )PO4
2NH3 Mg2P2O7 H2O
103
106
39. Answer (2)

RCOOR' + NaOH RCOONa + R'OH
Rate = k[RCOOR']'[NaOH]'
Hence, molecularity = 2, order = 2
40. Answer (3)
32. Answer (2)
CH4 = non-polar and low molecular weight
33. Answer (2)
SiH4 = non-polar and high molecular weight
NO + NO2 + (NH4)2SO4 + H2O 2NH4NO2 + H2SO4
2N2 + 4H2O
N2
Electric
C2H2
2HCN
Spark
PH3 = polar but incapable of intermolecular H-bonding

41. Answer (1)
Be2C + 4H2O 2Be(OH)2 + CH4
(CN
is a pseudohalide)
34. Answer (1)

1
Coagulation power
Coagulation Value
NH3 = polar and capable of intermolecular H-bonding
35. Answer (3)

Fe3+ ions coagulate negatively charged blood sol
and seals the cut.
42. Answer (4)

D2O(80) has lower dielectric constant than H2O(82).
It is due to the reason that ionic salts like NaCl
dissolve more in H2O than in D2O.
43. Answer (3)
15Se + SeCl4 + 4AlCl3 2Se8[AlCl4]2
Cl
Se
36. Answer (3)

The sols obtained in two cases will be oppositely
charged, so coagulate each other.
Cl
Now, volume strength (V)
= N 5.6
=
200
5.6 10 V
112
38. Answer (4)
Cl
Cl
44. Answer (2)
37. Answer (1)

34 1000 200
N
17 1120 112
Cl
Cl
OH
OH H
45. Answer (3)
Al
Cl
P4O10
2H2O
(Carbon suboxide)
(BN) x has structure similar to graphite (layer

structure)
46. Answer (2)
Li and H are less dense than kerosene. Other IA
elements are more dense than kerosene.
[H+] = 103 M
[Ca2+] = 5 104 M
Weight of CaCO3 = 5 104 1 100
= 5 102 g
47. Answer (1)

Due to relative higher I.E. and melting point, as
compared to other alkali metals, lithium, reacts very
slowly with water.
5/10

48. Answer (1)
53. Answer (2)
Triethyl borate; (C2H5)3BO3 and Tetraethyl silicate;

(C 2 H 5 ) 4 SiO 4 are formed due to their diagonal
relationship.
49. Answer (3)
O
+
KO
OK
O
C
O
ONa
Minimum weight required to be maintained by 70 kg

man is
R k '[CHCl3 ][Cl2 ]1/ 2
2B(g) 3C(l)
A(g)
t0
P
0
0
t 10 min (P x)
2x
20
t
0
2P
20
4D(s) Inert gas

0
i
0
i
0
i
P + i = 210
Also, 2P + 20 + i = 430
On solving, P = 200, x = 100
Hence, 10 minute must be t1/2.
56. Answer (2)
51. Answer (3)
F+
R k (K c )1/ 2 [Cl2 ]1/ 2 CHCl3
P x + 2x + 20 + i = 330
200 70
140 mg
100
2.303
400
t
log
K
140
55. Answer (2)
50. Answer (4)
[Cl]2
[Cl2 ]
Fact.
ONa
Structure of NaHCO3
R k[Cl][CHCl3 ],K c
54. Answer (3)
ONa
H
If step 2 were RDS
Step 2 is RDS
(structure of KHCO3)
Cl
Cl
Fact.
Cl
F
F
F
Cl
Cl + F
Cl
57. Answer (1)
Cl
Cl
Cl
52. Answer (4)
has high
So,
1
0n
Cl2
pungent
smelling gas
(White turbidity)
2FeSO4 H2SO4 Cl2

Fe2 (SO4 )3 2HCl
n
ratio.
p
11H
0
1
58. Answer (1)

1
0n
CaOCl2 H2 O
Ca(OH)2
H2S Cl2
2HCl
3
1H
11H
0
1
59. Answer (4)

Due to high
e
ratio, H is less stable than He.
p
60. Answer (2)

Due to availability of vacant d-orbitals on Si, silanes
are more reactive than methane.
PART - C (MATHEMATICS)
61. Answer (2)
S1 x2 + y2 + x + y = 0
1
1
,f
and c = 0
2
2
S2 x2 + y2 + x y = 0
g
6/10
g'
1
1
,f '
and c' = 0
2
2
Now
2gg ' 2ff ' 2
1 1
1 1
. 2. . 0 c c '
2 2
2 2

Therefore, S = 0 and S' = 0 intersect orthogonally so
that

66. Answer (3)
( x 2)2 ( y 3)2
eccentricity =
x 1
3 2 4 ( 3) 7
5
5
The equation of the normal with slope m is

y = mx 10m 5m3
a
ae 5
e
The combined equation of the pair of lines
mx y
y 2 (20 x )
0
10m 5m3
2a
a
Subtends a right angle at the vertex then coefficient

of x2 + coefficient of y2 = 0
(10m + 5m3)y2 20x(mx y) = 0
20m
10m 5m3
So length of major axis is
Now AB < 5
2
16
3 x 4y 1
4 x 3y 2
5
5

1
10
2
a2
16
a
=2
Radius of director circle of axillary circle of

20
64. Answer (1)

Vertex A(a, b) will be mirror image of ex-centre
about x + y 2 = 0
20
3
4
8
at points A , 4 and B , 8
a
a
63. Answer (3)
ellipse =
10
3
The line y = ax intersects the lines y = 4 and y = 8
m 2
b2
a
5
2
67. Answer (2)
m2 + 2 4 = 0
= 10,
1
2
Length of perpendicular from focus to directrix is
62. Answer (4)
a2
Focus (2, 3), directrix 3x 4y + 7 = 0 and
y 2 tan ( x 1)
2
1 3 x 4y 7
4
5
a 2 b 4 2(2 4 2)
4
1
1
2
a2=4
a = 6, b + 4 = 4
i.e. a
52 42
a2
1
16 9
a2
4
4
and a
3
3
68. Answer (2)

On solving
2.4 x
1
sin1
= 2 tan 4 x
2
2
2
1 16 x
1
1 2(4 x )
2 tan 4 x sin
2
1 (4 x )
2 tan1 y sin1
A(a, b) = A(6, 0)
b=0
65. Answer (1)
Truth value of (p q) (q p) is always true.
16
0
9
2y
1 y2
y 1
As 4x 1
1
1
,x ,
4
4
7/10

(4) x2 6 = 2 cos t
69. Answer (3)
y2 + 2 = 2(1 + cos t)
The given lines are

x2 (y 1)2 = 0
x2 6 = y2
(x + y 1)(x y + 1) = 0
Therefore, the given lines are x y + 1 = 0 and
x+y1=0
Whose angle bisectors are
x y 1
2
x y 1
2
x2 y2 = 6
72. Answer (1)
1 x2 1 x2
1 x2 1 x2
tan
By componendo and dividendo
That is y 1 = 0 and x = 0, thus the vertices of the

triangle are (0, 1) (0, 5) (4, 1)
2 1 x2
2 1 x
1
4 4 = 8 sq. units
2
1 x2
70. Answer (2)
1 x
cos sin
cos sin
cos sin
cos sin
1 sin 2
=
1 sin 2
The ends of a latus rectum are
b 2
L ' ae,
b2
L ae,
Since LL' subtends right angle at the centre then

b 2
a
ae
b2

b 4
. a
1
ae
a 2 (a 2 e 2 )
(e 2 1)2
e2
x 2 sin 2
73. Answer (1)
x
1 x
1
x
e2
3 5
2
5 1
2
(1 x 2 )x 2
So,
tan1
x
1 x2
tan1
1
= tan
(e2 1)2 = +e2

e4 3e2 + 1 = 0
x
1
2
1
x
tan 1 x
1
x3
1
x 2 (1 x 2 )
x4 1 x2
( x 2 x 4 1)x
1 1
= tan
x
3
4
x=1
74. Answer (1)
71. Answer (3)
By hypothesis, the given lines are parallel

2
2
2
1
1
1
x
y
(1)

1
t
t
4
a
b
t (t 2 1)
(2) x 2 y 2 (et e t )2 (et e t )2 4
t = 1
8/10
(t 2 1)2
t2 1
75. Answer (3)

Centre of the circle is (2, 4) and the radius is 5. The
line meets the circle in two distinct points this
implies that
| 3(2) 4(4) k |
32 42
Let x2 + y2 + 2gx + 2fy + c = 0

y2 = 4ax
yx
y4
2g 2
1
y 2fy c 0
4a
(4a )
2
= 16
b2 = 4
a2(e2
y1 + y2 + y3 + y4 = 0
5
4
80. Answer (2)

Putting x = at2 in the equation of the ellipse, we get
X = ae and Y = 0
xy
1)
yx
4
1 e2
16
5
2
0, x y
x y 2 10
y2
b2
1, y2 = b2(1 t4)
= b2(1 t2) (1 + t2)

This will give real value of y if
1 t2 0
81. Answer (2)
Let m1 and m2 be the slope of lines of first pair
2 x 2 10
x 10
1
m1 and m be the slope of lines of second
2
pair.
77. Answer (4)

From geometry OA1OA2 = OB1.OB2
OB1 OB2
.
1
OA1 OA2
Comparing pair of lines

(y m1x) (y m2x) with y2 + 2hxy 9x2 = 0
and pair of lines
1
x with ay2 + 10xy + x2 = 0

(y m1x) y
m
m1m2 = 1
78. Answer (3)
We get m1 = 1 and m2 = 9
sin1 sin 8 = sin1 sin(3 8) = 3 8 = t

tan1tan
a2t 4
|t| 1
5
e2
4
then
... (ii)
y2
y2
2
2fy c 0
y 2g.
4a
4a
X2 Y2
1
16
4
b2
... (i)
Solving (i) and (ii), we get
76. Answer (4)
a2
1
2
79. Answer (4)
35 < k < 15
f ( t ) t 3 t
Then f(sin1 sin 8) = 1 a
25 < 10 + k < 25
Let
1
2
f(t) + f(t) = 1
|10 + k| < 25
yx
3
Then f(t) = t t
8=
tan1tan(8
3) = 8 3 = t
a=9
h = 4
9/10
82. Answer (4)

Area =
(3 x 1)2 2 x
|3x + 1| < 2 x
(2 x) < 3x + 1 < 2 x
2 11
3 1
3 1
3 1
11( 3 1)
33 11
85. Answer (2)
2 + x < 3x + 1
3x + 1 < 2 x
3 < 2x
4x < 1
3
x
2
f (x)
1
4
( cot 1( x )
4 cot 1( x )
4 cot 1( x )
422
= 4
4 cot ( x )
83. Answer (4)

Equation of tangent is y = 2 x 4a 2 b 2
1
Equality when cot ( x )
This is normal to the circle x2 + y2 + 4x + 1 = 0

This tangent passes through (2, 0)
x 1
0 4 4a 2 b 2
86. Answer (3)

Statement-2 is not always true for two parallel line.
4a2 + b2 = 16
87. Answer (1)
Using AM GM, we get
4a2 b2
Using diametrical form of circle with A(x1, y1) and

B(x2, y2) as diameter.
2 2
4a b
88. Answer (3)

Length of semi-latus rectum
ab 4
2l1l 2
= l l
1
2
84. Answer (3)

2
2
Vertices of triangle are (0, 0), m , 2 , m , 2

1 2
m1 m2
Area = 2 m m
1 2
( 3 2)
m1 m2
1
= Harmonic mean of l1 and l2

89. Answer (3)
First law is De-Morgan's law
Statement II neither tautology nor contradiction.
90. Answer (4)
cos1 x1 + cos1 x2 + .......... + cos1 xn = n
m1m2 3 1
cos1 x1 = cos1 x2 = ...... = cos1 xn =

x1 = x2 = x3 .... = xn = 1
(m1 m2 ) (m1 m2 )2 4m1m2
n
2
( 3 2)2 4( 3 1)
Then sin1 x1 + sin1 x2 ..... + sin1 xn =
11 4 3 4 3 11
Statement-1 is not correct and statement-2 is correct

from definition.

10/10
Test - 4 (Paper-I) (Code-B) (Answers & Hints)

Click here for Code-A Solution
Test Date : 11-01-2015
PHYSICS
TEST - 4 (Paper-I) - Code-B
ANSWERS
CHEMISTRY
MATHEMATICS
1.
(4)
31.
(2)
61.
(2)
2.
(2)
32.
(3)
62.
(3)
3.
(2)
33.
(2)
63.
(4)
4.
(1)
34.
(4)
64.
(4)
5.
(4)
35.
(3)
65.
(2)
6.
(2)
36.
(4)
66.
(2)
7.
(4)
37.
(3)
67.
(4)
8.
(2)
38.
(1)
68.
(3)
9.
(1)
39.
(1)
69.
(4)
10.
(1)
40.
(2)
70.
(4)
11.
(2)
41.
(3)
71.
(3)
12.
(2)
42.
(2)
72.
(1)
13.
(2)
43.
(3)
73.
(1)
14.
(2)
44.
(4)
74.
(1)
15.
(3)
45.
(1)
75.
(3)
16.
(4)
46.
(3)
76.
(2)
17.
(2)
47.
(2)
77.
(3)
18.
(1)
48.
(4)
78.
(2)
19.
(2)
49.
(1)
79.
(2)
20.
(2)
50.
(3)
80.
(3)
21.
(3)
51.
(3)
81.
(1)
22.
(4)
52.
(1)
82.
(1)
23.
(3)
53.
(2)
83.
(3)
24.
(4)
54.
(2)
84.
(4)
25.
(2)
55.
(4)
85.
(2)
26.
(4)
56.
(2)
86.
(4)
27.
(4)
57.
(4)
87.
(3)
28.
(2)
58.
(1)
88.
(3)
29.
(1)
59.
(1)
89.
(1)
30.
(1)
60.
(2)
90.
(3)
1/10
PART - A (PHYSICS)
1.
Answer (4)
By the law of calorimetry

Q1 + Q2 = Q3 + Q4 + Q5
But B A 106
M3Cw(T2 T) + M2Cb(T2 T)
= M1Ci(0 T1) + M1Lv + M1Cw (T 0)

T M1Ci ( T1 ) M1Lv M3CwT2 M2CbT2
M3Cw M2Cb M1Cw
6.
The process 3 1 is an isochoric process. So

w = 0
3.
ma
3
7.
3P0 M
20
and l
T 2
The frequency of sound heard by motorist from

reflection
v vm
f1
v vb
a
2
I
2a
2
mgl
3g
v vm
f2
f
v vb
h0
l0
8.
l0 = 45 cm. If the mercury displaces by x, then

l0P0 = (l0 + x)P1
and P2 = P1 + h0
l0 P0
l P
0 0 h0
l0 x l x
x = 4.5 cm
A TA4 B TB4
ATA BTB
2/10
(v 2 v b2 )
1 129.6
2L
... (i)
and f
1 160
2L
... (ii)
f = 100 Hz
9.
Answer (1)
H
m
where m
1/ 4
2b(v v m )
f 10
Vm
VH
Answer (4)
... (ii)
Answer (2)
l0P0 = (l0 x)P2

TB A
B
... (i)
Beat frequency = f1 f2
P0
l0
.f
The frequency of sound heard by motorist directly
P0
5.
hi
h
f
Ti
Tf
Answer (4)
Answer (1)
373
hf 4.00
5.09 cm
293
Answer (2)
I=
4.
Answer (2)
T
hf f hi
Ti
Answer (2)
3P M
3 P M 2P M
U nCv (T1 T3 ) 0 0 = 0
2 0
0
2P0
B 1.5 106 1.5 m
vi
v
f
Ti
Tf
= 10.9C
2.
B
3
.TA 1934 K
m
H
... (1)
0V0 HVH
V0 VH
0
.V0 VH
H
4
V0 VH
.f
14. Answer (2)
H
1
4
m
Vm VH
15. Answer (3)

H
1
1200 600 m/s
m
2
10
At t = 0, y =
5 x2
f (x)
10. Answer (1)
Velocity of pulse v = 2 m/s along positive x-axis.
11. Answer (2)
Hence wave function y(x, t) = f(x vt)
l
A
2y
10
y ( x, t )
5 ( x 2t )2
16. Answer (4)

If mass falls down by x,
so spring extends by 4x.
Suppose 2y is the distance between two rows of the

buildings. The distance travelled by car in 1 second,
5
150
x 30
m
1 =
18
8
T = (16k)x
The distance travelled by sound in 1 second
T
k (4 x )
4
2l = 330 1 = 330 m
l = 165 m
From the figure y
x
l 2 165 m
2
12. Answer (2)
0
0
176
165
22

0 = 22 m/s
13. Answer (2)
v
0.66 m
f
The resonance length are
l1 =
0.165 m
4
l2
3
0.495 m
4
l3
5
0.825 m
4
7
l4
1.155 m
4
As 4 is greater than 1 m, so allowed resonance

are only 3.
T
4
T
2
T
2
1 16k
2 m
2
T
4
T
T
m
k
m
17. Answer (2)

x1 = A cos t and x2 = A sin t
B
A sin t = A cos t
sin t + cos t = 0
1
2
sin t
1
2
cos t 0
cos t 0
cot
t
4 2
3T
8
18. Answer (1)

x = A cos t
So A = A cos
cos
... (1)
A
A
3/10

and A ( + ) = A cos 2
cos 2
... (2)

Work done from D to A = nR(TA TD)
A ( )
A
= 6R(600 1200)
= 6R 600
2
3
While WAB = WCD = 0

W = 6R 1400 6R 600
19. Answer (2)
= 6R 800
= 40,000 J
2P0
2T0
B
P0
T0
23. Answer (3)
4T0
C
Q = dU + W
nCdT = nCvdT + W
V0
2V0
Total heat absorbed by 1 mole of gas

Q = Cv(2T0 T0) + CP(4T0 2T0) =
Q 19
R
T
6
19
RT0
2
1
= a ln
RT0
1
24. Answer (4)
1
(2P0 P0 )(3V0 V0 ) P0 (3V0 V0 )
2
= 300 J
QAC = WAC + UAC = 500 J
dU = 3W = 75 J
25. Answer (2)
Q = 75 + 25 = 100 J
26. Answer (4)

21. Answer (3)
27. Answer (4)
At t = 0, x1 = 0
A
, x2 A sin
6
6 2
A
x
3 A
2
<V> =
t
6
22. Answer (4)
Work done from B to C = nR(TC TB)
= 6R(2200 800)
= 6R 1400
4/10
Cv dT
T
WAC = P0(3V0 V0) = 200 J
C
U
f
v 3
R
W
2
At t =
(C Cv )dT for n = 1
UABC = QABC WAB = 300 J = UAC
and dU = nCV T
T0
WABC =
For isobaric process W = nRT
T0
20. Answer (2)

Q = dU + W
T0
n(C Cv )dT
T0
Total change in temperature form state A to C is

T = 3T0
Molar heat capacity =

28. Answer (2)
Statement-1 is True, Statement-2 is True; Statement2 is NOT a correct explanation for Statement-1.
29. Answer (1)
30. Answer (1)
PART - B (CHEMISTRY)
31. Answer (2)
37. Answer (3)
2B(g) 3C(l)
A(g)
t0
P
0
0
t 10 min (P x)
2x
20
t
0
2P
20
4D(s) Inert gas

0
i
0
i
0
i
O
+
Also, 2P + 20 + i = 430
ONa
C
O
C
ONa
38. Answer (1)
32. Answer (3)
Triethyl borate; (C2H5)3BO3 and Tetraethyl silicate;

(C 2 H 5 ) 4 SiO 4 are formed due to their diagonal
relationship.
Fact.
33. Answer (2)
If step 2 were RDS
39. Answer (1)

2
[Cl]
[Cl2 ]
R k[Cl][CHCl3 ],K c
Due to relative higher I.E. and melting point, as

compared to other alkali metals, lithium, reacts very
slowly with water.
R k (K c )1/ 2 [Cl2 ]1/ 2 CHCl3
40. Answer (2)
1/ 2
R k '[CHCl3 ][Cl2 ]
Li and H are less dense than kerosene. Other IA

elements are more dense than kerosene.
Step 2 is RDS
34. Answer (4)
41. Answer (3)
CaOCl2 H2 O
Ca(OH)2
H2S Cl2
2HCl
Cl2
pungent
smelling gas
(BN) x has structure similar to graphite (layer

structure)
42. Answer (2)
(White turbidity)
2FeSO4 H2SO4 Cl2

Fe2 (SO4 )3 2HCl
35. Answer (3)
F+
Cl
Cl
Cl
F
Cl
Cl + F
Cl
OH
P4O10
2H2O
Cl
2.303
400
log
K
140
(Carbon suboxide)
15Se + SeCl4 + 4AlCl3 2Se8[AlCl4]2
Cl
Cl
Minimum weight required to be maintained by 70 kg

man is
200 70
140 mg
100
43. Answer (3)
36. Answer (4)
H
OH H
Structure of NaHCO3
Hence, 10 minute must be t1/2.
ONa
On solving, P = 200, x = 100
OK
(structure of KHCO3)
P x + 2x + 20 + i = 330
KO
P + i = 210
Cl
Se
Cl
Cl
Cl
Cl
Cl
Al
Cl
44. Answer (4)

D2O(80) has lower dielectric constant than H2O(82).
It is due to the reason that ionic salts like NaCl
dissolve more in H2O than in D2O.
45. Answer (1)
Be2C + 4H2O 2Be(OH)2 + CH4
5/10

46. Answer (3)

53. Answer (2)
CH4 = non-polar and low molecular weight
NO + NO2 + (NH4)2SO4 + H2O 2NH4NO2 + H2SO4
SiH4 = non-polar and high molecular weight
2N2 + 4H2O
NH3 = polar and capable of intermolecular H-bonding

PH3 = polar but incapable of intermolecular H-bonding
47. Answer (2)
Electric
N2 C2H2
2HCN
Spark
(CN is a pseudohalide)
RCOOR' + NaOH RCOONa + R'OH

Rate = k[RCOOR']'[NaOH]'
54. Answer (2)
Hence, molecularity = 2, order = 2
55. Answer (4)
48. Answer (4)
NH4NO3
N2O H2O
[H+] = 103 M
[Ca2+] = 5 104 M
Weight of CaCO3 = 5
104
1 100
=5
102
So, weight of CaCO3 in

=
5 10 2
103
10
106
ml hard water
NH4NO2
N2 2H2 O
(NH4 )2 Cr2O7
N2 Cr2O3 4H2O
(NH4 )2 CO3
2NH3 H2O CO2
2Mg(NH4 )PO4
2NH3 Mg2P2O7 H2O
= 50 ppm
56. Answer (2)
49. Answer (1)
Due to availability of vacant d-orbitals on Si, silanes

are more reactive than methane.
34 1000 200
N
17 1120 112
57. Answer (4)
Now, volume strength (V)
= N 5.6
200
5.6 10 V
=
112
50. Answer (3)

The sols obtained in two cases will be oppositely
charged, so coagulate each other.
Due to high
e
ratio, H is less stable than He.
p
58. Answer (1)

1
0n
11H
59. Answer (1)
51. Answer (3)

Fe3+ ions coagulate negatively charged blood sol
and seals the cut.
52. Answer (1)
Coagulation Value
1
Coagulation power
0
1
3
1H
has high
So,
1
0n
n
ratio.
p
11H
0
1
60. Answer (2)

Fact.
PART - C (MATHEMATICS)
61. Answer (2)
4
f ( x ) ( cot 1( x )
4 cot 1( x )
4 cot 1( x )
422
= 4
4 cot 1( x )
6/10
1
Equality when cot ( x )
x 1

62. Answer (3)
65. Answer (2)
2
2
Vertices of triangle are (0, 0), m , 2 , m , 2

1 2
m1 m2
m1m2
Area = 2
(y m1x) (y m2x) with y2 + 2hxy 9x2 = 0

and pair of lines
1
x with ay2 + 10xy + x2 = 0

(y m1x) y
m2
(m1 m2 ) (m1 m2 )2 4m1m2
We get m1 = 1 and m2 = 9
( 3 2) 4( 3 1)
11 4 3 4 3 11
3 1
3 1
1
m1 and m be the slope of lines of second
2
Comparing pair of lines
m1m2 3 1
2 11
Let m1 and m2 be the slope of lines of first pair
pair.
( 3 2)
1
m1 m2
Area =
3 1
a=9
h = 4
66. Answer (2)
Putting x = at2 in the equation of the ellipse, we get
11( 3 1)
a2t 4
a2
33 11
y2
b2
1, y2 = b2(1 t4)
= b2(1 t2) (1 + t2)
63. Answer (4)
This will give real value of y if

2
Equation of tangent is y = 2 x 4a b
This is normal to the circle x2 + y2 + 4x + 1 = 0

This tangent passes through (2, 0)
b2
67. Answer (4)

y2
= 16
= 4ax
... (i)
... (ii)
Solving (i) and (ii), we get
Using AM GM, we get
4a2 b2
|t| 1
Let x2 + y2 + 2gx + 2fy + c = 0
0 4 4a 2 b 2
4a2
1 t2 0
y2
y2
2
2fy c 0
y 2g.
4a
4a
4a2 b2
y4
2g 2
1
y 2fy c 0
4a
(4a )
2
ab 4
y1 + y2 + y3 + y4 = 0
64. Answer (4)
68. Answer (3)
(3 x 1) 2 x
sin1 sin 8 = sin1 sin(3 8) = 3 8 = t

tan1tan 8 = tan1tan(8 3) = 8 3 = t
|3x + 1| < 2 x
(2 x) < 3x + 1 < 2 x
3
Then f(t) = t t
2 + x < 3x + 1
3x + 1 < 2 x
3 < 2x
4x < 1
3
x
2
1
4
1
2
f ( t ) t 3 t
1
2
f(t) + f(t) = 1
Then f(sin1 sin 8) = 1 a
7/10

73. Answer (1)
69. Answer (4)

From geometry OA1OA2 = OB1.OB2
x
1 x
OB1 OB2
.
1
then
OA1 OA2
1
x
1
(1 x 2 )x 2
So,
m1m2 = 1
70. Answer (4)
Let
yx
yx
tan1
X2 Y2
1
16
4
x
1 x2
tan1
1
= tan
5
4
a2 = 16
b2 = 4
X = ae and Y = 0
xy
b2 = a2(e2 1)
yx
4
1 e2
16
5
e2
4
5
4
2
0, x y
x y 2 10
1
x3
1
x
2
x
tan 1 x
1
1
2
2
(1
)
x
x
x4 1 x2
( x 2 x 4 1)x
1 1
= tan
x
3
4
x=1
74. Answer (1)
1 x2 1 x2
1 x2 1 x2
tan
By componendo and dividendo

2 x 2 10
x 10
71. Answer (3)
Centre of the circle is (2, 4) and the radius is 5. The
line meets the circle in two distinct points this
implies that
| 3(2) 4(4) k |
32 42
|10 + k| < 25
25 < 10 + k < 25
2 1 x2
2 1 x
1 x2
1 x
cos sin
cos sin
cos sin
cos sin
1 sin 2
=
1 sin 2
x 2 sin 2
75. Answer (3)
2
2
2
2
1
1
1
x
y
(1) t t 1
t
t
4
a
b
35 < k < 15
(2) x 2 y 2 (et e t )2 (et e t )2 4
72. Answer (1)

By hypothesis, the given lines are parallel
t (t 2 1)
t = 1
8/10
(t 2 1)2
t2 1
(4) x2 6 = 2 cos t
y2 + 2 = 2(1 + cos t)
x2 6 = y2
x2 y2 = 6

76. Answer (2)
The ends of a latus rectum are
2 tan1 y sin1
b2
L ae,
b2

b 4
. a
1
ae
a 2 (a 2 e 2 )
The line y = ax intersects the lines y = 4 and y = 8

4
8
at points A , 4 and B , 8
a
a
Now AB < 5
a2
16
(e2 1)2 = +e2
e4 3e2 + 1 = 0
52 42
a2
1
16 9
a2
5 1
2
4
4
and a
3
3
( x 2)2 ( y 3)2
1 3 x 4y 7
4
5
(y
1)2
eccentricity =
=0
(x + y 1)(x y + 1) = 0
1
2
Length of perpendicular from focus to directrix is
Therefore, the given lines are x y + 1 = 0 and

x+y1=0
3 2 4 ( 3) 7
5
5
Whose angle bisectors are
a
ae 5
e
x y 1
x y 1
2
That is y 1 = 0 and x = 0, thus the vertices of the

triangle are (0, 1) (0, 5) (4, 1)
1
4 4 = 8 sq. units
2
2a
a
a
5
2
10
3
So length of major axis is
78. Answer (2)

On solving
Focus (2, 3), directrix 3x 4y + 7 = 0 and
The given lines are
16
0
9
80. Answer (3)
77. Answer (3)

x2
i.e. a
3 5
e2
2
e
y 1
1
1
,x ,
4
4
16
e2
1 y2
79. Answer (2)
Since LL' subtends right angle at the centre then
(e 2 1)2
2y
As 4x 1
b 2
L ' ae,
b 2
a
ae
2.4 x
1
sin1
= 2 tan 4 x
2
2
1 16 x 2
1
1 2(4 x )
2 tan 4 x sin
2
1 (4 x )
20
3
81. Answer (1)

Truth value of (p q) (q p) is always true.
82. Answer (1)
Vertex A(a, b) will be mirror image of ex-centre
about x + y 2 = 0
9/10
a 2 b 4 2(2 4 2)
4
1
1
2
g'
1
1
,f '
and c' = 0
2
2
Now
a2=4
2gg ' 2ff ' 2
a = 6, b + 4 = 4
A(a, b) = A(6, 0)
1 1
1 1
. 2. . 0 c c '
2 2
2 2
Therefore, S = 0 and S' = 0 intersect orthogonally so
b=0
that
83. Answer (3)

2
3 x 4y 1
4 x 3y 2
5
5

1
10
2
y 2 tan ( x 1)
2
x 1
a2 = 10, b2 = 2
Radius of director circle of axillary circle of
ellipse =
86. Answer (4)

cos1 x1 + cos1 x2 + .......... + cos1 xn = n
20
cos1 x1 = cos1 x2 = ...... = cos1 xn =
84. Answer (4)
x1 = x2 = x3 .... = xn = 1
The equation of the normal with slope m is

y = mx 10m 5m3
Then sin1 x1 + sin1 x2 ..... + sin1 xn =
The combined equation of the pair of lines
n
2
Statement-1 is not correct and statement-2 is correct

from definition.
mx y
y 2 (20 x )
0
10m 5m3
87. Answer (3)
Subtends a right angle at the vertex then coefficient

of x2 + coefficient of y2 = 0
First law is De-Morgan's law

Statement II neither tautology nor contradiction.
(10m + 5m3)y2 20x(mx y) = 0
88. Answer (3)
20m
10m 5m3
Length of semi-latus rectum

2l1l 2
= l l
1
2
m2 + 2 4 = 0
m 2
85. Answer (2)
S1 x2 + y2 + x + y = 0
1
1
g ,f
and c = 0
2
2
S2 x2 + y2 + x y = 0
= Harmonic mean of l1 and l2

89. Answer (1)
Using diametrical form of circle with A(x1, y1) and
B(x2, y2) as diameter.
90. Answer (3)
Statement-2 is not always true for two parallel line.

10/10

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Test - 4 (Paper-I) (Code-A) (Answers & Hints)

All India Aakash Test Series for JEE (Main)-2015

All India Aakash Test Series for JEE (Main)-2015

Test Date : 11-01-2015

TEST - 4 (Paper-I) - Code-A

All India Aakash Test Series for JEE (Main)-2015

Test - 4 (Paper-I) (Code-A) (Answers & Hints)

UABC = QABC WAB = 300 J = UAC

QAC = WAC + UAC = 500 J

Q = Cv(2T0 T0) + CP(4T0 2T0) =

Molar heat capacity =

Total change in temperature form state A to C is

Work done from B to C = nR(TC TB)

Total heat absorbed by 1 mole of gas

Work done from D to A = nR(TA TD)

Test - 4 (Paper-I) (Code-A) (Answers & Hints)

All India Aakash Test Series for JEE (Main)-2015

As 4 is greater than 1 m, so allowed resonance

14. Answer (2)

15. Answer (2)

10. Answer (4)

If mass falls down by x,

Hence wave function y(x, t) = f(x vt)

Suppose 2y is the distance between two rows of the

The distance travelled by sound in 1 second

Velocity of pulse v = 2 m/s along positive x-axis.

11. Answer (3)

12. Answer (2)

From the figure y

13. Answer (2)

The resonance length are

All India Aakash Test Series for JEE (Main)-2015

Test - 4 (Paper-I) (Code-A) (Answers & Hints)

l0P0 = (l0 + x)P1

l0P0 = (l0 x)P2

19. Answer (4)

23. Answer (2)

The frequency of sound heard by motorist directly

24. Answer (2)

The process 3 1 is an isochoric process. So

20. Answer (2)

21. Answer (4)

26. Answer (1)

Statement-1 is true, statement-2 is true and

27. Answer (1)

Statement-1 is true, statement-2 is true and

B 1.5 106 1.5 m

29. Answer (4)

22. Answer (1)

By the law of calorimetry

25. Answer (4)

Statement-1 is False, Statement-2 is True.

Test - 4 (Paper-I) (Code-A) (Answers & Hints)

All India Aakash Test Series for JEE (Main)-2015

31. Answer (4)

39. Answer (2)

32. Answer (2)

CH4 = non-polar and low molecular weight

33. Answer (2)

SiH4 = non-polar and high molecular weight

NO + NO2 + (NH4)2SO4 + H2O 2NH4NO2 + H2SO4

PH3 = polar but incapable of intermolecular H-bonding

34. Answer (1)

NH3 = polar and capable of intermolecular H-bonding