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Article history:
Received 6 September 2008
Received in revised form 14 January 2009
Accepted 2 April 2009
Keywords:
Plastic
Finned-tube heat exchanger
Thermal conductivity
a b s t r a c t
In this paper, two modied types of polypropylene (PP) with high thermal conductivity up to 2.3 W/m K
and 16.5 W/m K are used to manufacture the nned-tube heat exchangers, which are prospected to be
used in liquid desiccant air conditioning, heat recovery, water source heat pump, sea water desalination,
etc. A third plastic heat exchanger is also manufactured with ordinary PP for validation and comparison.
Experiments are carried out to determine the thermal performance of the plastic heat exchangers. It is
found that the plastic nned-tube heat exchanger with thermal conductivity of 16.5 W/m K can achieve
overall heat transfer coefcient of 34 W/m2 K. The experimental results are compared with calculation
and they agree well with each other. Finally, the effect of material thermal conductivity on heat exchanger thermal performance is studied in detail. The results show that there is a threshold value of material
thermal conductivity. Below this value improving thermal conductivity can considerably improve the
heat exchanger performance while over this value improving thermal conductivity contributes very little
to performance enhancement. For the nned-tube heat exchanger designed in this paper, when the plastic thermal conductivity can reach over 15 W/m K, it can achieve more than 95% of the titanium heat
exchanger performance and 84% of the aluminum or copper heat exchanger performance with the same
dimension.
2009 Elsevier Inc. All rights reserved.
1. Introduction
Heat exchanger is one of the basic equipment in industries such
as energy and power engineering, chemical engineering, pharmaceutical engineering, etc. They are also widely used in HVAC applications to achieve comfortable living habitation. Generally heat
exchangers are made of metals because metals are good heat conductors, i.e. they have relatively high thermal conductivities. The
most common problems causing failures in metal heat exchangers
are corrosion and fouling, especially in aggressive environment.
One prospective solution to these problems is to use polymer
materials, such as plastic, to make heat exchangers. Plastic can resist corrosion and fouling, so the fouling thermal resistance of plastic heat exchanger does not rapidly increase and it has a stable heat
transfer performance. Besides, plastic heat exchangers can be manufactured and maintained more easily compared with the metal
ones. The use of plastic heat exchangers can also help lower such
costs as transportation and installation, which consequently lowers the total investment [1,2]. Ever since the 1960s, scientists
and engineers have been studying plastic heat exchangers [3].
From then on, plastic heat exchangers have been successfully used
for heat recovery from polluted and/or corrosive uids [1,4], sea* Corresponding author. Tel.: +86 10 62782982; fax: +86 10 62781610.
E-mail address: lizh@mail.tsinghua.edu.cn (Z. Li).
0894-1777/$ - see front matter 2009 Elsevier Inc. All rights reserved.
doi:10.1016/j.expthermusci.2009.04.001
water desalination [5,6], fuel cells [7], solar water heating [8] and
many other applications [2].
Despite their merits and wide applications, plastics have one
fatal drawback of low thermal conductivity. To overcome this
drawback, many existing plastic heat exchangers adopt the tactic
of small tube/channel diameter and extraordinarily small wall
thickness in order to reduce the conductive thermal resistance.
At the same time, the surface area of per unit volume is considerably improved, which also enhances heat transfer. However, these
tactics limit the plastic heat exchangers type and structure to shelltube heat exchangers, plate heat exchangers and heat exchanger
coils [2].
This limitation is gradually fading away with the progress in
improving plastic thermal conductivity. The thermal conductivity
of modied plastic can achieve up to 20 W/m K or even higher
[9,10]. This makes it possible to develop the nned-tube heat exchanger which is widely used in gasliquid heat transfer applications, such as air conditioning.
In a traditional household air conditioner, water condenses on
the evaporator and results in wetted surface. This may cause slight
corrosion and fouling. However the condenser works in severe outdoor environment where dust accumulation, atmospheric corrosion and fouling are quite common. These problems become
much more serious when using chemical detergent to maintain
the cleanness of evaporator and condenser and inhibitors are re-
923
Nomenclature
a
Ali
Alr
Alf
Alo
A
cp
d
de
Gmax
hi
ho
K
L
_
m
Q_
r
S1, S2
Sf
T
DT
DTm
quired [11,12]. When using plastic heat exchanger, the dust accumulation can slow down due to the low surface energy of plastics.
Also corrosion can be avoided and cheap acid can be used to wash
the heat exchangers [13].
The plastic nned-tube heat exchanger is also expected to be
used in liquid desiccant air conditioning, which is energy efcient
and can utilize low grade thermal energy such as solar energy [14].
So far, the liquid desiccant air conditioning is usually achieved in 2
steps: rst use the liquid desiccant to dehumidify the air in a packing unit and then sensibly cool the air. Actually the two steps can
be integrated, just as Khan [15,16], Yadav [17] did in their research
of the internally cooled/heated liquid desiccant air conditioner. But
the desiccants, mainly lithium bromide (LiBr) and lithium chloride
(LiCl), etc., are corrosive to metals. Only when the dehumidier/
regenerator is anti-corrosion heat exchanger that the compacted
and efcient internally cooled/heated liquid desiccant air conditioner can be put into practice. Saman and Alizadeh [18] and
Lowenstein et al. [19] had already tried the plate type plastic heat
exchanger and gained very good results. However, the plastic
nned-tube heat exchanger may hopefully be a better choice, since
it is more compacted with large heat and mass transfer area and it
can be easily connected with traditional vapor compression system
to function in the efcient hybrid mode.
In this paper, two modied types of polypropylene (PP) with
high thermal conductivity are used to manufacture the nned-tube
heat exchangers, which are prospected to be used in liquid desiccant air conditioning, heat recovery from corrosive exhaust gas,
water source heat pump, sea water desalination, etc. Also a third
plastic heat exchanger is manufactured with ordinary PP for the
purpose of validation and comparison. The thermal conductivity
of the plastic materials is obtained by the laser ash method.
Experiments are carried out to determine the heat transfer performance of the plastic heat exchangers. The experimental results are
compared with calculations. Finally, the effect of thermal conductivity of plastic on heat exchanger performance is studied in detail.
The data and results from this paper may provide some reference
for the design and use of plastic nned-tube heat exchangers.
Greek symbols
b
ratio of outside surface area to inside surface area
n thickness, m
df
g
factor ratio, function of nned-tube surface area and n
efciency
gf
n efciency
k
thermal conductivity, W/m K
l
dynamic viscosity, kg/m s
Subscripts
a
air
Al
aluminum
Cu
copper
e
experimental data (results)
i
heat exchanger inside
in
heat exchanger inlet
max
maximal value
min
minimum value
o
heat exchanger outside
out
heat exchanger outlet
Ti
titanium
w
water
Application background:
AC condenser/evaporator
Liquid desiccant AC(LDAC)
Water source heat pump
etc.
Structure
Material
Fin-tube
mass transfer
heat exchanger
Anti-corrosion
Anti-fouling
Heat transfer
High thermal
conductivity plastic
Molding survey
Material research
Injection molding
Molding restriction
dimensions
Performance calculation
Interaction
dimensions
Heat exchanger
Fig. 1. Plastic heat exchanger design and manufacture ow chart.
924
Table 1
Thermal/physical/chemical properties of thermally conductive polypropylene (PP).
Material
Thermal
conductivity
(W/m K)
Density
(kg/
m3)
Flexural
modulus
(MPa)
Flexural
strength
(MPa)
Tensile
modulus
(MPa)
Tensile
strength
(MPa)
PP-a
PP-b
2.3
16.5
1240
1500
5410
8274
37
52
5620
6206
22
29
Ali p di 1 0:0314 m2
desiccant air conditioning for dehumidifying air/regenerating desiccant. As for the fabrication technologies, injection molding is
especially suitable for the nned-tube heat exchanger manufacture, because the products can weigh from several grams to tens
of kilograms, and the conguration can be complicated with precise dimensions.
The plastic materials used in this paper are two modied types
of polypropylene (PP) which are commercially available. Their
thermal/physical/chemical properties are listed in Table 1, where
the symbols of PP-a and PP-b stand for modied polypropylene
with thermal conductivity of 2.3 W/m K and 16.5 W/m K, respectively. The thermal conductivity values are obtained through testing the injection products by the laser ash technique using a
NETZSCH instrument, of which the maximum experimental uncertainty is 5%.
The heat exchanger dimensions are optimized by parametric
studies of n height, n thickness and spacing between ns. But
the nal dimensions are within the limitation of injection technology and the material for injection. For example, the thinner the n,
1
2
Alr p do 1 nf df 0:0366 m
p 2
Alf 2 nf a2 do 0:21 m2
4
Alo Alr Alf 0:2466 m2
2
3
4
nf
1
Sf df
Fig. 3. Plastic nned-tube heat exchangers: (a) tubes linked by elbows; (b) plastic heat exchangers made from different PP (1 ordinary PP; 2 modied PP-a; 3 modied PP-b).
Q_ K i Ai DT m K o Ao DT m
Ki
1
1
hi
ri
di
2k
ln ddo
i
ro
bg
1
ho bg
where
Alo
Ali
Alr Alf gf Alr Alf gf
g
Alo
Alr Alf
b
8
9
2
J 1 mr2 K 1 mr1 J 1 mr 1 K 1 mr 2
gf
ml1 r2 =r 1 J 0 mr1 K 1 mr2 J 1 mr 2 K 0 mr 1
10
where
l r2 r1
a
r 2 p
hi di
0:023 Re0:8 Pr0:4
kw
11
12
13
14
Nu
1=3 0:14
hi di
d
l
1:86Re Pr1=3
L
kw
ltw
15
The air side heat transfer coefcient ho for the square-n, in-line
tube rows arrangement is obtained by Eq. (16) [21]:
0:67
0:2
ho de
Gmax de
S1 do
0:251
ka
la
do
0:2
0:4
S1 do
S1 d o
1
Sf
S2 d o
16
where
q.
de Alr do Alf Alf =2 nf Alr Alf
17
_ a cp;a DT a
Q_ Q_ a m
_
_
_ w cp;w DT w
Q Qw m
18
19
Eqs. (6), (18) and (19) are also integrated by log mean temperature difference (LMTD) DTm. Although the heat exchanger is in
crossow conguration, when the crosses between the hot and
cold uid are more than four times, it can be regarded as a counterow one [23], so DTm is calculated as:
The values of Ai, Ao, Ar, Af are calculated in Section 2.1 and the n efciency gf is calculated by Eq. (10):
s
2 ho
m
k df
Nu
925
20
3. Experiment
3.1. Experimental apparatus
The plastic heat exchanger is tested as a part of a ductwork, as
shown in Fig. 4. Two ducts are anged on the plastic heat exchanger inlet and outlet. These ducts are mainly used to rectier the air
ow to achieve a regular ow eld, which will be helpful for air
velocity measurement. The experimental tests are carried out in
an environment chamber and an air condition sensor which measures dry-bulb and wet-bulb temperatures is placed before duct
A to control the inlet air temperature and humidity. During the
experimental runs, the air relative humidity is kept within 30% to
make sure there will be no condensation on the heat exchanger
surface. At the heat exchanger inlet and outlet, air temperatures
are measured by thermocouples.
926
Table 2
Testing conditions of experimental runs.
Ta (C)
Tw (C)
Set value
Low: 670
Middle: 710
High: 755
0.12
26
30
34
8
12
16
+10%
1.8
1.6
-10%
1.4
Qw (kW)
Parameters
1.2
1
0.8
0.6
ordinary PP
modified PP-
modified PP-
0.4
0.2
0
0
Qa (kW)
Fig. 5. Energy equilibrium between air and water.
iment accuracy. In experiments, the air side inlet and outlet temperatures Ta,in, Ta,out and water side inlet and outlet temperatures
Tw,in, Tw,out are measured. Also, the air and water ow rates are
measured. With these parameters, the energy changes of the air
side and water side of each experimental run can be calculated
by Eqs. (18) and (19). Fig. 5 shows the energy equilibrium between
air and water of the three heat exchangers that made of different
PP materials. The relative errors are within 10%.
4.2. Overall heat transfer coefcient
For every one of experimental runs, with the measured air and
water temperature parameters, the heat ow rate Q_ can be calculated by Eqs. (18) and (19) and the LMTD DTm in Eq. (20) can be calculated as:
DT m
DT max DT min
lnDT max lnDT min
T a;in T w;out T a;out T w;in
lnT a;in T w;out lnT a;out T w;in
21
927
Table 3
Overall heat transfer coefcient of the plastic heat exchangers.
2
1.8
Material
Ki Ai = Ko Ao (kW/
K)
Ki (W/m2
K)
Ko (W/m2
K)
PP
670
710
755
670
710
755
670
710
755
0.03387
0.03411
0.03507
0.07120
0.07318
0.07406
0.1285
0.1300
0.1306
70.20
70.69
72.70
147.56
151.67
153.49
266.32
269.43
270.67
8.94
9.00
9.26
18.79
19.31
19.55
33.91
34.31
34.47
1.6
Qe
(kW)
1.4
1.2
PP-a
1
0.8
PP-b
0.6
0.4
ordinary PP
modified PP-
modified PP-
0.2
0
0 2 4 6 8 10 12 14 16 18 20 22 24 26
Tm,e (C)
2
1.8
1.6
1.2
2
1
0.8
0.6
0.4
0.2
0
50
40
Ko (W/m K)
Qe
(kW)
1.4
30
prediction
ordinary PP
modified PP-
modified PP-
20
10
ordinary PP
modified PP-
modified PP-
0 2 4 6 8 10 12 14 16 18 20 22 24 26
10
Tm,e (C)
1.6
Qe
(kW)
1.4
1.2
prediction
ordinary PP
modified PP-
modified PP-
20
0.8
0.6
10
15
0 2 4 6 8 10 12 14 16 18 20 22 24 26
Tm,e (C)
Fig. 6. Experimental results of heat ux and LMTD, with linear tting curves: (a) air
ow rate: 670 m3/h; (b) air ow rate: 710 m3/h; (c) air ow rate: 755 m3/h.
25
30
50
30
20
prediction
ordinary PP
modified PP-
modified PP-
10
20
(W/mK)
40
2
ordinary PP
modified PP-
modified PP-
Ko (W/m K)
30
30
10
0.2
25
50
0.4
20
40
1.8
Ko (W/m K)
15
(W/mK)
10
15
20
25
30
(W/mK)
Fig. 7. Comparison of predicted and experimental results of outside overall heat
transfer coefcient as the function of thermal conductivity: (a) air ow rate:
670 m3/h; (b) air ow rate: 710 m3/h; (c) air ow rate: 755 m3/h.
928
40
Ko (W/m K)
30
20
Ti, = 22 W/mK
Al, = 236 W/mK
Cu, = 398 W/mK
10
50
100
150
200
250
300
350
400
(W/mK)
Fig. 8. Theoretical relation between overall heat transfer coefcient and thermal
conductivity.
Table 4
Performance comparison between heat exchanger made of different materials.
Heat exchanger materials
k (W/m K)
Ko (W/m2 K)
Ko
K o;Ti
Ko
K o;Al
Ko
K o;Cu
Modied PP
15
16
17
18
22
236
398
33.56
33.89
34.19
34.46
35.34
39.69
39.9
0.950
0.959
0.967
0.975
1
1.12
1.13
0.846
0.854
0.861
0.868
0.890
1
1.01
0.841
0.849
0.857
0.864
0.886
0.995
1
Titanium (Ti)
Aluminum (Al)
Copper (Cu)
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