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2011
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Introduction
Platinum casting is still a mystery for many manufacturers. Many casters who
have done well casting gold and other metals experience difficulties when casting
platinum. Some of these problems can be blamed on the tree designs and spruing
techniques. Because of the unique flow characteristics of platinum, tree designs
used successfully in gold casting may not work well in the actual platinum casting process.
This paper will try to demystify some of these issues and provide a better understanding to the small caster. It will include a discussion of tree designs for torch
casting and for induction casting. Alloy performance, casting temperature parameters and such will also be part of the paper. Finally, a step-by-step torch-casting
procedure is included, pointing out common mistakes and misconceptions along
the way.
Torch Casting
When casting platinum with a torch, there are several things to consider. The
type of torch used, the gas used to melt the platinum, the crucible and the casting
machine all play important roles.
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When choosing a torch for melting, many models will do the job. If a torch with
a multi-port tip is chosen, it is important that the torch tip is screwed on, rather
than soldered. The heat reflected during melting platinum can melt the solder and
the torch tip can come off and fall into the crucible. This is very dangerous and
should be avoided (Figure 1).
Figure 1
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Figure 2
One of the problems associated with this method is the fact that it can be very hazardous. The person with the torch is unable to see the other person approaching
with the flask and that can be a problem. Another is that the flask is being heated
up rapidly by the melting of the platinum and, thus, a correct and consistent casting temperature is impossible to achieve.
To solve this problem, several things can be done.
The first thing is a modification of the actual casting machine. The pressure plate
is modified so that a cradle can be used to hold the flask (Figure 3).
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Figure 3
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Secondly, the spring that holds the flask against the pressure plate is removed
(Figure 4).
Figure 4
During the melting process, the flask rests on the cradle and the actual crucible is
pulled all the way back, so that the expelled heat from the pour hole is away from
the flask. When the platinum is liquid, the crucible is pushed toward the flask and
the arm, which will do the casting, is released.
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The actual tree design for this type of casting is changed from the standard center sprue design to one with the waxes now attached to a T-bar (Figure 5) with
the waxes on each side of it. This design will prevent the expelled heat from the
crucible to come near the actual castings and, thus, any damage during melting is greatly reduced. The T-bar diverts the flow of metal to create an indirect
filling which is also beneficial, as debris from the crucible will rarely reach the
actual casting and is confined to the button. This method also applies to casting
machines that are horizontal and encased, such as the Degussa caster.
Figure 5
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Figure 6
Induction Casting
In a commercial casting scheme, induction casting is the method of choice. In
this method, the platinum is heated and melted to a precise temperature and,
thus, casting will always be more consistent than with torch casting. Tree designs
depend on the type of casting machine and method. The trees for center-pour
machines, such as the Schultheiss or Yashida machines, are different than the
normal centrifugal machines.
Platinum casting is so different from the casting of any other metal that many
casters have already found issues during the burnout that will negatively affect
the casting success.
The main issue is the presence of carbon during the cast, which can contaminate
the platinum and cause brittleness.
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This carbon comes from improper burnout and usually occurs during the first
phases of the process. It is important that the flasks dry properly, either in or
outside of the kiln. Then, in a slow process, the temperature is raised and held at
a level that allows the wax to drip out of the flasks and is collected and removed
from the kiln before the actual high ramp begins.
This is an extra step that many casters avoid. They usually prefer to burn everything, including the absorbent paper, by simply leaving the flasks in the kiln and
raising the temperature. This may cause the development of carbon black, which
can become a cause of contamination during casting.
The weight of platinum casts range from 150 to 600 grams, with the majority
weighing 300 grams or less. Tree designs for platinum castings are diverse and
plentiful.
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Traditionally, many casters attach their waxes to a very thick center tree at an
angle of 45 degrees (Figure 7). While this works very well for gold castings, it is
not really the method of choice for platinum.
Figure 7
Platinum has a very high density and a different flow pattern from gold. It wants
to chill immediately after leaving the crucible. Therefore, it is common practice
to super-heat platinum for casting by 100200C (212392F). During the casting
process, the liquid platinum races to the very end of the tree and then fills the
cavities through back-flow. This means that, during the filling process, platinum
has to reverse flow directions to fill the 45-degree cavities. This causes a great deal
of turbulence and can lead to no-fills or partial fills. This situation can easily be
remedied by attaching the waxes at an almost right angle in relationship to the
sprue.
One of the major disadvantages of a thick center sprue is the low-product yield.
Many times, over 75% of the cast is consumed by the sprue and button. Add to
that occasional no-fills, and it becomes clear that there is need for a better way.
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Figure 8
The advantage of this method is greater product yield. The disadvantage is a tendency for no- or partial fills. This is commonly used when there are few castings
needed. The area where the sprue meets the cone can be a source of turbulence.
Since the space between the different ring sprues can be very thin, the platinum
entering the cone with great pressure can destroy these small walls of investment
and drag investment along into the cast. This can lead to unusable castings and
other casting defects. A remedy for this can be the Diabolo.
Diabolo
This spruing system requires a diabolo-shaped wax sprue (Figure 9). The model
of this is made from carving wax. Making an RTV mold from that model, and the
bases, can be made from injection waxes and used as sprue base every time with
little preparation. This system was invented by Tino Volpe, who used it to better
direct metal flow and to reduce scrap.
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Figure 9
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With this method, the waxes to be cast are attached on the outer edge of the top
and the entire tree is then invested. The unique shape of the Diabolo creates a
directional guide for the metal to flow and assures good fill. As the investment is
poured, the inverted cone in the wax base forms an upright cone after burn-out.
The sprues of each ring will be around the outer side of that cone. When the metal
is slung into the flask, the cone gives it additional direction while, at the same time,
reducing turbulence (Figure 10). With a traditional button the metal slams into the
investment at high speed, causing a tremendous amount of turbulence. The cone
deflects the metal into a flared path that has better flow into the openings of the
gate. It also allows some cooling of the metal, because a good amount of superheat is needed to get it out of the crucible and across the gap into the mold. At this
time, the platinum should cool a bit, so that it is not too hot as it settles in the part
cavity. This will make a better surface and the castings come out clean.
Figure 10
While the shape of this spruing system would seem to require lots of metal to fill,
the exact opposite is actually true. Typically, the final button will appear to be a
ring with the castings attached, where the rest of the Diabolo is not required to
fill (Figure 11). This results in less scrap.
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Figure 11
Figure 12
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This wax sprue is then used to attach the waxes for casting. The waxes are placed
in a circular motion around the top edge of the wheel and turned for the flow
dynamic of the liquid platinum (Figure 13). The arrangement allows for the rapid
removal of the cast rings and allows for easy cleaning and re-use. Most platinum
alloys can be immediately re-cast after the removing of the investment. In many
cases, HF is used but, in recent years, this has often been replaced by sodium
hydroxide or caustic potash. The importance of clean metal cannot be stressed
enough, especially when it comes to melting platinum.
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Figure 13
If the metal is weighed properly, it is possible to cast this tree without all the
additional metal needed for the button. The castings appear to be sitting on a ring
(Figure 14).
Figure 14
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Figure 15
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Among the advantages of this sprue design is the fact that the ratio between
button metal and actual product is remarkably improved, which results in more
product (Figure 16).
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Figure 16
In this system, as is demonstrated in other trees, the waxes are placed at an almost
90-degree angle from the sprue. Also, the center sprue is reinforced with copper
or silver wire, which is removed during the burn-out. It is possible to cast large
trees with great success. It has been found, through many casting trials, that the
best results are obtained when the tree is arranged to favor the trailing edge of the
rotation (Figures 17 and 18).
At the last Santa Fe Symposium, Apollonius Apple Nooten-Boom II explained
the principle of low pressure casting using the thin, tall sprue configurations I
used. He succeeded in explaining what was actually happening in a very scientific
yet understandable way.
By adding gravity into the equation, he found that by rotating the tree 90 degrees
in the casting cradle, he could achieve a low pressure situation where gravity, centrifugal force and trailing edge all present ideal conditions for 100% fill. The platinum will reach the uppermost cavity and the filling of the casting will be successful
as there is very little turbulence and resistance. I encourage you to read Apples
paper to see the detailed explanation. With this kind of tree, a large yield is possible
and fine detail castings can be achieved at remarkably low temperatures.
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Figures 17 and 18
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Figure 19
Figure 20
When invested and burned out, all rings will be pointing up at about 45 degrees
(Figure 21).
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Figure 21
When cast, the platinum rushes against the top plate and reverses direction. This
will bleed off turbulence and the voids will fill evenly.
All the shrinkage will take place on the stem and the disc and the surface of the
castings will be superior. As in other sprue designs, this master sprue can be made
from metal and then molded, so that for every tree, one simply shoots a wax for
the base
Shell Casting
Figure 22
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One casting system used is shell casting, where the wax patterns are embedded in
a ceramic shell. The trees used for this casting method are somewhat different and
the product is arranged to favor the trailing edge of the rotation during casting.
Most of the system is proprietary (Figure 22).
Alloy Performance
Pt950/Co
While it is generally agreed that Pt/Co is a fine casting alloy, there are some
things to consider when using it:
Cobalt is not a precious metal
Cobalt will oxidize
Cobalt is magnetic
These things have been somewhat of a stumbling block when it comes to platinum
casting and many jewelers use one or more of these as a reason to not use Pt/Co.
Pt950/Co is still in use in many parts of the world, as well as the U.S., and it produces very fine and detailed castings. It has good hardness and scratch resistance.
Pt950/Ir
This alloy is very soft and, thus, not very suitable for casting or machining. As it
readily work-hardens, it is designed mainly for hand fabrication and die striking.
However, many manufacturers like it especially when the ring is engraved or
bead-set all over.
Pt950/Ru
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This is the platinum alloy that is preferred for high-end pieces. The Koh-I-Noor
diamond and the Hope diamond are set with this fine platinum alloy. Many
famous jewelers have made this their exclusive alloy. Some casters complain
about the fact that it takes more skill and process control to cast with this alloy,
but with todays machines, the proper parameters and techniques, very fine castings are being produced.
Pt900/Ir
This alloy has been around in the U.S. for many years and is still loved by many
designers and manufacturers. It has good working strength and color. Even
though it is slightly softer than Pt950/Ru and Pt950/Co, it has very favorable
features that allow for fine castings and good performance. It is easy to weld and
work-hardens rapidly.
Pt950/Ir
This is actually a fabrication alloy. Because of its low as-cast hardness of 80 HV, it is
not suitable for casting, unless secondary manufacturing takes place to harden it.
Casting Temperatures
For high-speed casting using the torch, the best results are achieved at about a
260C (500F) flask temperature. At this cold flask temperature, the platinum will
have the best surface quality. It is interesting to note that this investment used for
high-speed casting is very flexible and can be cast anywhere from room temperature to 870C (1600F).
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For regular platinum casting using Pt950/Ru, the metal should be super-heated
by 200C (392F) and the flask temperature should be around 760C870C
(1400F1600F). Lower flask temperatures can result in porosity.
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1. Using a clear plastic flask, the attached sprue base is prepared and the T-bar
is attached horizontally using 3mm wax spruing wire.
2. Wax rings are attached to each end of the T-bar. It is important that the
connection is smooth and free of edges and such. This will reduce turbulence
during casting.
3. At this time, the kiln is being heated to 926C (1700F).
4. Using masking tape, the top of the plastic flask is extended by about 2 inches.
This is designed to keep the investment from boiling over the top during
de-airing. Attach the sprue base with the two waxes to the flask.
5. After measuring and weighing the proper amount of powder and liquid, the
investment is blended using a regular household blender. This should be
done within a two-minute time window. Refrigerating the liquid will extend
working time.
6. De-bubble the investment under vacuum until it rises and drops. Pour the
mix into the plastic flask. De-bubble the flask one more time. The entire
process should be done within 34 minutes. The investment will set in
15 minutes. Thermal reaction will cause the investment to get as hot as
72C (160F).
7. Push the investment form out of the plastic flask and place it into the hot
kiln. Turn the kiln off. The heat contained in the kiln will remove the wax in
as little as 20 minutes.
8. Let the kiln temperature drop to anywhere between 538C and 260C (1000F
and 500F) and cast. A cooler flask will give a smoother surface. I have cast
as cold as room temperature.
9. Place the flask-less form into the cradle of the wound-up machine.
10. Pull the crucible back as far as possible. Be sure to protect your eyes. Melt the
platinum rapidly and thoroughly. Be sure it rolls nicely within the crucible.
11. Push the crucible against the form. Be sure the holes line up and release the
spring.
12. After the machine comes to a halt, catch the form with your glove, as it wants
to fall out since the centrifugal force that held it in position is no longer present.
13. Break the form and remove the casting. Break off as much investment as
possible and then soak the casting in warm sodium hydroxide or sodium
potash to remove the remaining investment.
Acknowledgements
My thanks to Tino Volpe, Michael Epstein and Daniel Ballard, TI Research.
Photo Credits
Figure 5: Daniel Ballard
Figure 6: TI Research
Figure 19: Teresa Fry
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