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Version number:
Supersedes date:
4.00
29/04/2014
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
Ingredient
NUC - Naphthol Spirits
Pin-2(3)-ene
Pin-2(10)-ene
CAS Nbr
64742-48-9
80-56-8
127-91-3
HAZARD STATEMENTS:
H228
H315
H317
H336
Flammable solid.
Causes skin irritation.
May cause an allergic skin reaction.
May cause drowsiness or dizziness.
H411
% by Wt
10 - 30
5 - 10
5 - 10
PRECAUTIONARY STATEMENTS
General:
P102
Keep out of reach of children.
P101
If medical advice is needed, have product container or label at hand.
Prevention:
P210A
P260
P262
P271
P280E
P273
Response:
P333 + P313
P331
P301 + P310
P370 + P378G
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Do not breathe dust/fume/gas/mist/vapours/spray.
Do not get in eyes, on skin, or on clothing.
Use only outdoors or in a well-ventilated area.
Wear protective gloves.
Avoid release to the environment.
If skin irritation or rash occurs: Get medical advice/attention.
Do NOT induce vomiting.
IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician.
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or
carbon dioxide to extinguish.
__________________________________________________________________________________________
Page: 2 of 15
Disposal:
P501
Highly
Flammable
Irritant
Dangerous
for the
environment
Contains:
Pin-2(3)-ene; Pin-2(10)-ene
Risk phrases
R11
R38
R43
R67
R51/53
Safety phrases
S16
S23A
S24
S37
S62
S29
S61
S2
Highly flammable.
Irritating to skin.
May cause sensitisation by skin contact.
Vapours may cause drowsiness and dizziness.
Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Keep away from sources of ignition - No Smoking.
Do not breathe vapour.
Avoid contact with skin.
Wear suitable gloves.
If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or
label.
Do not empty into drains.
Avoid release to the environment. Refer to special instructions/safety data sheets.
Keep out of the reach of children.
Notes on labelling
R65 is not required on the label due to the product's viscosity.
Nota P applied for CASRN 64742-48-9.
2.3. Other hazards
None known.
Ingredient
NUC - Naphthol Spirits
CAS Nbr
64742-48-9
64742-47-8
EU Inventory % by Wt
EINECS 265- 10 - 30
150-3
Classification
Xn:R65 - Nota 4,P (EU)
Xi:R38; R67 (Self Classified)
EINECS 265149-8
10 - 30
8015-86-9
Oxidised Polyethylene
Pin-2(3)-ene
68441-17-8
80-56-8
Pin-2(10)-ene
127-91-3
EINECS 204872-5
5 - 10
8002-74-2
EINECS 232315-6
5 - 10
Conditioners
Turpentine Gum
Trade Secret
5 - 10
9005-90-7
EINECS 232- < 2
688-5
Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
Condition
During combustion.
During combustion.
During combustion.
electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid
flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity
accumulation during transfer.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed. Store away from heat. Store away from acids. Store away
from strong bases. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.
CAS Nbr
Agency
64742-48-9 Manufacturer
determined
8002-74-2 Health and
Safety Comm.
(UK)
Limit type
TWA:100 ppm
Additional comments
TWA(as fume):2
mg/m3;STEL(as fume):6
mg/m3
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron Nitrile
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
65.34 % weight
561.89 g/l
Condition
Route
Dermal
Overall product
InhalationVapor(4 hr)
Ingestion
InhalationVapor
Dermal
Ingestion
Dermal
InhalationDust/Mist
(4 hours)
Ingestion
Ingestion
Ingestion
Dermal
Ingestion
Dermal
Ingestion
Overall product
NUC - Naphthol Spirits
NUC - Naphthol Spirits
NUC - Naphthol Spirits
Distillates (petroleum), hydrotreated light
Distillates (petroleum), hydrotreated light
Distillates (petroleum), hydrotreated light
Carnauba Wax
Oxidised Polyethylene
Paraffin Wax
Paraffin Wax
Conditioners
Conditioners
Species
Value
No data available; calculated ATE2,000 - 5,000
mg/kg
No data available; calculated ATE20 - 50 mg/l
No data available; calculated ATE >5,000 mg/kg
LC50 estimated to be 20 - 50 mg/l
Rabbit
Rat
Rabbit
Rat
Rat
Rat
Rabbit
Rat
Rabbit
Rat
Species
Rabbit
Rabbit
In vitro
data
In vitro
data
Rabbit
Value
Irritant
Mild irritant
Irritant
No significant irritation
Irritant
No significant irritation
Species
Rabbit
Rabbit
Rabbit
Value
No significant irritation
Mild irritant
No significant irritation
No significant irritation
Skin Sensitisation
Name
NUC - Naphthol Spirits
Species
Guinea
pig
Guinea
pig
similar
compoun
ds
Mouse
Value
Not sensitizing
Species
Value
Name
NUC - Naphthol Spirits
NUC - Naphthol Spirits
Route
In vivo
In Vitro
In Vitro
Value
Not mutagenic
Some positive data exist, but the data are not
sufficient for classification
Not mutagenic
Not sensitizing
Sensitising
Sensitising
Respiratory Sensitisation
Name
__________________________________________________________________________________________
Page: 9 of 15
Carcinogenicity
Name
NUC - Naphthol Spirits
Route
Dermal
Species
Mouse
Inhalation
Dermal
Human
and
animal
Mouse
Value
Some positive data exist, but the data are not
sufficient for classification
Some positive data exist, but the data are not
sufficient for classification
Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name
Route
Value
Species
Test result
Inhalation
Rat
NOAEL 2.4
mg/l
Exposure
Duration
during
organogenesis
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name
Route
Target Organ(s)
Value
Species
Test result
Inhalation
central nervous
system depression
Human
and
animal
NOAEL Not
available
Inhalation
respiratory irritation
Inhalation
nervous system
Distillates (petroleum),
hydrotreated light
Inhalation
central nervous
system depression
Distillates (petroleum),
hydrotreated light
Inhalation
respiratory irritation
Exposure
Duration
NOAEL Not
available
Dog
NOAEL 6.5
mg/l
Human
and
animal
NOAEL Not
available
4 hours
NOAEL Not
available
Route
Target Organ(s)
Value
Species
Test result
Exposure
Duration
6 months
Inhalation
nervous system
Rat
LOAEL 4.6
mg/l
Inhalation
kidney and/or
bladder
Rat
LOAEL 1.9
mg/l
13 weeks
Inhalation
respiratory system
90 days
Inhalation
NOAEL 5.6
mg/l
12 weeks
Inhalation
Multiple
animal
species
Rat
NOAEL 0.6
mg/l
Multiple
animal
species
NOAEL 1.3
mg/l
90 days
Aspiration Hazard
Name
NUC - Naphthol Spirits
Distillates (petroleum), hydrotreated light
Pin-2(3)-ene
Value
Aspiration hazard
Aspiration hazard
Aspiration hazard
__________________________________________________________________________________________
Page: 10 of 15
Pin-2(10)-ene
Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
CAS Nbr
80-56-8
80-56-8
Distillates
(petroleum),
hydrotreated
light
NUC Naphthol
Spirits
64742-47-8
Paraffin Wax
Paraffin Wax
Paraffin Wax
Conditioners
8002-74-2
8002-74-2
8002-74-2
Trade Secret
Pin-2(10)-ene
127-91-3
Turpentine
Gum
9005-90-7
Oxidised
Polyethylene
68441-17-8
64742-48-9
Organism
Water flea
Fathead
minnow
Type
Experimental
Experimental
Exposure
48 hours
96 hours
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Water flea
Experimental 48 hours
Green algae
Experimental 96 hours
Rainbow trout Experimental 96 hours
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
EC50
EC50
LC50
>10,000 mg/l
>1,000 mg/l
>1,000 mg/l
Test result
Protocol
CAS Nbr
Test type
Duration
Study Type
__________________________________________________________________________________________
Page: 11 of 15
Pin-2(3)-ene
80-56-8
NUC Naphthol
Spirits
64742-48-9
Distillates
64742-47-8
(petroleum),
hydrotreated
light
Carnauba Wax 8015-86-9
Pin-2(3)-ene
80-56-8
Paraffin Wax
8002-74-2
Conditioners
Trade Secret
Pin-2(10)-ene
127-91-3
Turpentine
Gum
9005-90-7
Oxidised
Polyethylene
68441-17-8
Experimental
Photolysis
Data not
N/A
available or
insufficient for
classification
Data not
N/A
available or
insufficient for
classification
Modeled
28 days
Biodegradation
Other methods
N/A
N/A
N/A
BOD
82 % weight
Experimental 28 days
Biodegradation
Estimated
28 days
Biodegradation
BOD
92 % weight
BOD
40 % weight
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Duration
N/A
Study Type
N/A
Test result
N/A
Protocol
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Log Kow
23.45
Other methods
Log Kow
4.83
Other methods
N/A
CAS Nbr
64742-47-8
NUC Naphthol
Spirits
64742-48-9
Trade Secret
80-56-8
Test type
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Modeled
Bioaccumulati
on
Experimental
Bioconcentrati
__________________________________________________________________________________________
Page: 12 of 15
Pin-2(10)-ene
127-91-3
Paraffin Wax
8002-74-2
Turpentine
Gum
9005-90-7
Oxidised
Polyethylene
68441-17-8
on
Data not
N/A
available or
insufficient for
classification
Estimated
Bioconcentrati
on
Data not
N/A
available or
insufficient for
classification
Data not
N/A
available or
insufficient for
classification
N/A
N/A
N/A
Log Kow
10.2
N/A
N/A
N/A
N/A
N/A
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification
requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
__________________________________________________________________________________________
Page: 15 of 15