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I. Abstract
Chemical reactions vary and are different in nature. One of which is the oxidation-reduction
reaction, where a substance is being oxidized while another is being reduced. Organic compounds
behave the same way. In organic chemistry, redox reactions are focused on the carbon atom.
Oxidation of carbon means that there is an increase in number of carbon-oxygen bonds or a
decrease in number of carbon-hydrogen bonds; and reduction is the total opposite. In this
experiment, a reaction involving both oxidation and reduction on benzaldehyde will be observed
called Cannizzaro reaction.
II. Keywords: oxidation-reduction reaction, Cannizzaro reaction, base-catalyzed reaction
III. Introduction
One of the notable organic reactions
in chemistry is the Cannizzaro reaction,
named after its discoverer, Stanislao
Cannizzaro. It is limited to aldehydes lacking
alpha hydrogen centers. It produces an
alcohol and carboxylic acid at minimal
amounts, accounting only 50% to the yield
even under ideal conditions. It is a basecatalyzed reaction, which begins with the
nucleophilic attack of OH- on the carbonyl
center. The resulting anion attacks another
molecule of aldehyde, transferring a hydride
ion. In the final step, the acid and alkoxide
ions formed exchange a proton. All in all, the
discovery of Cannizzaro has proven to be one
of the most important reactions in synthetic
organic chemistry.
IV. Methodology
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Walter Aljhon Espiritu
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Rafaelle Silong
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Glenn Vincent Tumimbang
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