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CONTENTS
SECTION
INTRODUCTION/PURPOSE
SCOPE
FIELD OF APPLICATION
DEFINITIONS
4.1
4.2
Experimental Characterization
Rheological Models
4
5
5.1
5.2
7
9
10
11
7.1
7.2
7.3
7.4
7.5
Entrances Losses
Expansion Effects
Contraction Losses
Valves
Bends
12
13
14
14
14
14
VELOCITY PROFILES
17
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9.1
9.2
9.3
10
18
18
18
20
10.1
10.2
10.2
Rheological Behavior
Validity of Experimental Data
Check on Laminar Flow
20
21
21
11
NOMENCLATURE
22
12
REFERENCES
23
FIGURES
1
12
14
15
15
10
16
11
VARIATION OF Us WITH w
16
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12
13
14
17
20
20
24
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INTRODUCTION/PURPOSE
SCOPE
This Guide presents the basis for the prediction of flow rate - pressure drop
relationships for the laminar flow of non-Newtonian fluid through circular pipes
and selected fittings under isothermal conditions. In addition, the prediction of
velocity profiles and hence residence time distributions are covered.
The Scope is subject to the following limitations:
(a)
the fluid is homogeneous and remains so under all conditions, i.e. if the
material is a suspension of solids, then the solids do not settle;
(b)
the fluid is purely viscous in behavior, i.e. it does not exhibit timedependency of a thixotropic or anti-thixotropic kind, nor is it viscoelastic.
This restricts the predictions to fluids the rheological properties of which
may be expressed in the form: shear rate is a function of shear stress;
(c)
(d)
(e)
(2)
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FIELD OF APPLICATION
DEFINITIONS
For a more general description of rheological behavior consult GBHE-PEG-FLO302. This Clause defines the terms used in this Guide.
4.1
Experimental Characterization
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FIGURE 1
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In this form, the data may be used directly for pipeline design using a scale-up
procedure (see Ref. 2). Alternatively, the data can be processed (see Ref. 2) to
yield the basic relationship between shear stress and shear rate, i.e. the
experimental flow curve, as in the case of rotational viscometers considered
above.
4.2
Rheological Models
where K is the 'consistency index' and is the 'powerlaw index'. This model can
describe both shear thinning behavior ( < 1) and shear thickening behavior
( > 1).
If a real fluid approximates to power law behavior then a logarithmic plot of t
against gives a straight line from which may be obtained from the slope, and
K from the intercept.
Very often the data do not give a linear logarithmic plot over the full range of
shear rate. Even so, the model can still be useful if the conditions of shear rate or
stress in the engineering situation under consideration are within the linear
region. A typical example is given in Figure 3.
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For a given fluid, t can be found from the flow curve as for a simple Bingham
plastic fluid. The remaining parameters, and K, may then be determined from
the slope of a logarithmic plot of t . t against as illustrated in Figure 5.
Equation (3) is clearly the most versatile model, since the other two are special
cases of it. This is the model which will be mainly used in this Guide.
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FIGURE 5
Design methods are given for two cases: using shear stress and shear rate data
and using unprocessed data from tubular viscometers.
5.1
For a purely viscous non-Newtonian fluid in laminar flow in a tube assuming there
is no slip at the wall it may be shown that:
where f(t) is the function which defines the rheological behavior of the fluid i.e.:
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(b)
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In order to get a first estimate of the wall shear stress (from which P/L
can be found) evaluate w N, the wall shear rate for a Newtonian fluid at
the same flow rate. from:
(b)
(c)
(d)
(e)
(f)
or:
if Q < Q desired set t = +1 etc. and iterate to give the correct value for Q and
hence t w
(g)
evaluate P from:
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(b)
(c)
(d)
(e)
(f)
(g)
or
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If Q < Q desired set i = + 1 etc. and iterate to give the value of D, which gives
the desired Q.
(h) Choose a standard diameter nearest to this value of D and repeat either
procedures 5.1 or 5.1.2.
5.2
It has been noted earlier in 4.1.2 (and it can be seen from Equations (4) and (6))
3
that for laminar flow of a purely viscous fluid through a tube 32Q/D is function
only of the wall shear stress, DP/4L, and typical results are given graphically in
Figure 2. The methods proposed for pipeline design first involve a polynomial
approximation for the data, i.e.:
Note:
32Q/D3 IS the wall shear rate for a Newtonian fluid. It is not so for a nonNewtonian fluid.
5.2.1 Q from P/L and D
The steps are as follows:
(a)
Calculate DP/4L.
(b)
Calculate 32Q/D
Evaluation DP/4L from polynomial Equation (14) and hence P/L since
D is known.
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(b)
(d)
(e)
(f)
(g)
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Since the generalized Bingham model, Equation (3), is the most versatile only
this will be considered. It can be shown (see Ref. 3) that by using this model in
conjunction with Equation (4) that:
This equation can be used to carry out pipeline design calculations if the three
rheological parameters, t, and K have been determined. Again, three cases
are of interest.
6.1
(b)
6.2
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(b)
(c)
Evaluate Q from Equation (15), compare this value of Q with the desired
value of Q and iterate on 'w to give the correct value of tw
6.3
(b)
(c)
(d)
(e)
These are not necessarily insignificant especially for relatively short pipes.
Whereas comprehensive data exist for a large range of fittings for low viscosity
Newtonian fluids in turbulent flow, the data for viscous Newtonian liquids and for
non-Newtonian fluids are very sparse. In general the losses for shear thinning
fluids could be expected to be less than for a Newtonian fluid with the same low
shear-rate viscosity. For shear thickening fluids this converse is likely and special
care is therefore necessary. Some of the more Important fittings will be
considered in turn.
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7.1
Entrance Losses
The pressure drop in the entrance region of a pipe is greater than that for fully
developed flow in an equal length of pipe due to:
(a)
(b)
excessive fluid friction due to the high velocity gradients near the wall.
and Nen is the excess mechanical energy loss due to the entrance, expressed as
a number of velocity heads, i.e. the excess head loss is:
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FIGURE 6
since this gives a slight conservative estimate. The range 0 < n < 2 covers most
fluids of commercial interest.
7.1.2 Fluids not obeying the power law
No theoretical studies have been found for fluids which do not approximate to
power law behavior. Experimental studies on a Bingham plastic slurry (see Ref.
6) indicated a value of Nen of 1.2, i.e. similar to that for Newtonian fluids. It is
therefore proposed that the fluid be represented as closely as possible by a
power law and the appropriate value of n used to determine N en .
7.2
Expansion Effects
Expansion losses can be predicted theoretically (see Refs. 2 & 3). For a power
law fluids the excess loss in an expansion from D1 to D2, expressed as a number
of velocity heads, is given by:
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FIGURE 7
7.3
Contraction Losses
7.4
Valves
Globe valves, even when open, have a large loss and it is recommended that
these should not be used with viscous non-Newtonian fluids. Gate valves are to
be preferred and when these are fully open It is proposed that the same
contraction as given in Equation (22) should again be used i.e.:
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7.5
Bends
No data have been found for losses in bends for non-Newtonian fluids. However,
for laminar flow. the losses should be small and it is proposed that they be
neglected.
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FIGURE 8
FIGURE 9
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This is then used in the procedures described in 5.2 in place of Equation (14) for
pipeline design based on tubular viscometer data.
A similar method has to be employed to derive the true flow curve, i.e. = f(t)
from tubular viscometer data under conditions of wall slip.
VELOCITY PROFILES
Hence:
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(b)
(c)
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9.2
Again only the generalized Bingham model, Equation (25), will be considered at
this is the most general. For this the velocity profile is given by:
From equation (28) u(r) can be evaluated directly if K, n, and P/L are
known.
It should be noted that when n = 1, = 0 and K = this reduces to:
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9.3
and therefore the residence time of fluid elements will depend on their radial
position, the element at the centre line having the shortest residence time.
Let f(t) dt be the fraction of the total output, Q, which has been in the pipe for
times between t and t + dt. Then:
This leads to
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We can define the cumulative distribution function F(t) as the fraction of the
outflow which has residence times less than t, ie. F(t) is defined by:
where t(o) is the residence time of the central filament (which is the minimum).
For a Newtonian fluid this gives:
The function F(t) IS shown graphically for power law fluids in Figure 13.
In general, for any time-independent fluid f(t) and F() can be found numerically
from the velocity profile derived in 9.1 and 9.2 by numerical integration.
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10
10.1
Rheological Behavior
These design procedures are only valid for purely viscous fluids and any
significant time dependency or viscoelasticity could give rise to serious errors.
The well established methods of rheological characterization will allow such
behavior to be observed.
10.1.1
Time dependency
FIGURE 14
10.1.2
Viscoelasticity
It is important to check that the experimental data have been obtained over the
range of shear stress and/or shear rate which the fluid will experience in the fullscale pipeline. It is particularly important to note that for large pipelines data at
low shear rates may be required and the data should at least cover the range of
shear rates w to w/4.
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10.3
These design procedures apply only to laminar flow and it is necessary to check
that this restriction applies.
This can be done by calculating a Reynolds number.
where the effective viscosity e is defined by:
An alternative criterion is based on the velocity profile, where the condition for
laminar flow is (Ref. 8):
This reduces to the accepted condition that Re < 2000 for laminar flow.
The added complication of using this criterion is not considered necessary at this
stage.
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
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Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
12
REFERENCES
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8)
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com
Refinery Process Stream Purification Refinery Process Catalysts Troubleshooting Refinery Process Catalyst Start-Up / Shutdown
Activation Reduction In-situ Ex-situ Sulfiding Specializing in Refinery Process Catalyst Performance Evaluation Heat & Mass
Balance Analysis Catalyst Remaining Life Determination Catalyst Deactivation Assessment Catalyst Performance
Characterization Refining & Gas Processing & Petrochemical Industries Catalysts / Process Technology - Hydrogen Catalysts /
Process Technology Ammonia Catalyst Process Technology - Methanol Catalysts / process Technology Petrochemicals
Specializing in the Development & Commercialization of New Technology in the Refining & Petrochemical Industries
Web Site: www.GBHEnterprises.com