Group

Unit

Group I
Physical

1
2
3
4
5

Group II
Inorganic
chemistry

Group III
organic
chemistry

6
7
8
9
10
11
12
13
14
15
16

Model question papers prepared by Master trainers, Department of PU education, Bangalore.

II-PUC CHEMISTRY
BLUE PRINT FOR MODEL QUESTION PAPER - 1
PartA
Part-B
Part-C
I
II
III
Title
Hours
Marks
10 1
82
83
Mark
Mark
Mark
The Solid state
8
07

Solution
9
07

Electrochemistry
9
08

Chemical Kinetics
9
08

Surface chemistry
6
05
Total of Group -I
41
35
General principles and processes of isolation of
5
04

elements
The p-block elements
11
10

The d and f- block elements
9
08

Co-ordination Compounds
7
07

Total of Group -II
32
29
Haloalkanes and Haloarenes
7
06

Alcohols, phenols and ethers

8
07

Aldehydes, Ketones and carboxylic acids

9
08

Amines
6
05
Biomolecules
7
06

Polymers
5
05
Chemistry in everyday life
5
04

Total of Group -III
47
41
TOTAL
120
105

Part-D
IV & V
11 5
Mark

Total

07
07
08
08
05
35
04

10
08
07
29
06
07
08
05
06
05
04
41
.2

-2II PUC CHEMISTRY (34)

MODEL QUESTION PAPER - 1
Time: 3 hours 15 minutes

Maximum Marks: 70
Instructions:

1. The question paper has four parts: A, B, C and D. All parts are compulsory.
2.
Write balanced chemical equations and draw labelled diagrams wherever required.
3. Use log tables and the simple calculators if necessary.
(Use of Scientific Calculators is not allowed)
PART- A
I. Answer ALL of the following. ( Each questions carries 1 mark)

2.
4.

10 1 = 10

1. State Henrys law.

What is the conclusion drawn when Vant Hoffs factor of a solution is less than one?
3. How molar conductivity varies with dilution?
Mention one criterion for intermolecular collisions of two reactants to be effective.
5. Name the metal that is refined by Van Arkel method.
6. Name the first noble gas compound prepared by Neil Bartlett?
7. Give an example for Heteroleptic complex.
8. Write the IUPAC name for CH3-CH(CH3)-CH2Cl.
CO, HCl
9.
Give the name of the product X.
X
Anhyd AlCl3 / CuCl

10. Name the storage polysaccharide present in animals.

PART- B
II. Answer Any FIVE of the following. ( Each questions carries 2 mark) 5 2 = 10
11. a) Give one example for paramagnetic substance.
b) Which type of binding force existing in ice?
12. Write anodic and cathodic half-cell reactions taking place in Daniel cell.
13. Show that for first order reaction t87.5% = 3 t50%.
14. What is lanthanide contraction? What is the cause for it?
15. How do you convert bromoethane into tertiary-butylethyl ether? Give the chemical equation of the
reaction.
16. What is Stephens reaction? Give the chemical equation of the reaction.
17. What is the therapeutic action of a) Paracetamol b) Barbituricacid.
18. What are anionic detergents? Give an example.
PART- C
III.
Answer Any FIVE of the following. ( Each questions carries3 mark) 5 3 = 15
19.

Explain the extraction of aluminium from purified alumina by Hall-Heroult process.

3
20. Explain manufacture of nitric acid by Ostwalds process.
3
.3

-321. a) How is ozonised oxygen prepared?

2
b) Write the structure of sulphurous acid.
1
22. a) How does phosphorus react with limited amount of chlorine? Give equation.

23.

2
b) What is the product obtained by the reaction between fluorine in excess of bromine?
1
a) 3d Transition metals and their compounds are good catalysts. Give two reasons?
2
b) Give the formula for the calculation of spin only magnetic moment.
1
24. Explain the manufacture of Potassium dichromate from chromite ore.
3
25. Using VBT explain,
i) Geometry of the complex
ii) Type of hybridization, in the complex ion [CoF6] 3-.
iii) Is it an inner or outer orbital complex?
26. a) Draw the structures of cis -trans isomers for [Pt (NH3)2.Cl2].
2
b) How many ions are produced from the aqueous solution of complex K3[Al(C2O4)3]
1

PART D
IV.
Answer Any THREE of the following. ( Each questions carries5 mark) 3 5 = 15
27. a) Calculate the packing efficiency in a Face Centered Cubic lattice.
3
b) If a metal with atomic mass 209 crystallizes in a simple cubic lattice what is the edge length of its unit
cell. (Given d = 91.5 kg m-3).
2
28. a) 5.8g of a non-volatile solute was dissolved in 100g of carbon disulphide
(Molar mass = 76). The
vapour pressure of the solution was found to be 190mmHg. Calculate the molecular mass of the solute.
The vapour pressure of pure carbon disulphide 195 mm Hg.
3
b) What are azeotropes? Give an example.
2
3
29. a) The resistance of M/10 solution is found to be 2.5 X 10 ohms. Calculate molar conductance (Given Cell
constant = 1.15 cm-1).
3
b) Mention two general methods for prevention of corrosion.
2
30. a) Derive an expression for rate constant of a first order reaction.
4
b) What is the effect of positive catalyst on energy of activation?
1
31. a) Mention two factors which affect adsorption of a gas on a solid.
2
b) Is synthesis of ammonia by Habers process, a homogeneous or heterogeneous catalysis?
1
c) State Hardy-Schulze rule. Among Al2(SO4)3 and (NH4)3PO4 which is better coagulating agent for a
negative sol ?
2

.4

-4V. Answer ANY FOUR of the following. ( Each questions carries 5 mark) 4 5 = 20
32. a) Complete the following reaction and write its name
2C6H5Cl + 2Na
? + 2NaCl
2
Dry ether
b) Explain Zaitsev rule with an example.
2
c) A Haloalkane when boiled with aqueous KOH which gives an alcohol having inversed configuration.
Name the mechanism involved in this reaction.
1
33. a) Explain the mechanism involved in the conversion of ethanol into ethene.
3
b) An organic compound with molecular formula C6H6O gives white precipitate with bromine water.
Identify the functional group in the organic compound and write the chemical equation for the reaction.

35.

34. a) Explain Cannizaros reaction with an example.

2
b) Name the product obtained by the reaction of acetyl chloride with dimethylcadmium.
1
c) Explain the reaction between carboxylic acid and PCl5.
2
a)Explain carbylamine reaction by taking methyl amine as an example.
2
b) Why do primary amine have higher boiling point than tertiary amines?
1
c) Give an example for a coupling reaction of diazonium salt and give its chemical equation.
2
36. a) Deficiency of which vitamin leads to night blindness?
1
b) Which hormone is responsible for the hyperthyroidism?
1
c) What is a Zwitter ion of an amino acid? Give its general formula.
2
d) What is a nucleotide?
1
37. a) What are Elastomers? Give example.
2
b) Write the partial structure of nylon 6, 6 and Bakelite.
2
c) What is vulcanization of rubber?
1
.5

-5II PUC CHEMISTRY (34)

SCHEME OF VALUATION FOR MODEL QUESTION PAPER 1
Note: Any other correct alternate answer can be honoured wherever applicable.
I.
PART - A
1.

2.

3.
4.

Henrys law states that the partial pressure of the gas in vapour phase is
proportional to the mole fraction of the gas in the solution.
OR
The mole fraction of the gas in the solution is proportional to the partial
pressure of the gas over the solution.
The solute in the solution undergoes association.
OR
Tb or Tfwill be half of the normal value and molar mass will be twice the
expected value.
It increases with dilution

Marks

1
1

6.

Proper orientation of molecules.

or
Energy of activation of the molecules.
Zirconium OR Zr
OR
Titanium OR Ti
Xenonhexafluroplatinate(IV)

7.

[Co(NH3)4 CO3] Cl OR any suitable example

8.

1-Chloro-2-methylpropane

9.

Benzaldehyde

10.

Glycogen

5.

II.

PART -B

11.

a) O2 OR Compounds of Cu+2 OR Fe+3 OR Cr+3 OR any suitable example.

b) Hydrogen bonding

12.

At anodic : Zn (s)
Zn +2 + 2eAt Cathodic :Cu 2+ + 2e -
Cu (s)

1
1
1
1

13.

Expression of k when 87.5% of react an t is reacted

k=

2.303 100
log
t 87.5%
12.5

k=

2.303
x 0.9031 - - - (1)
t 87.5%

Expression of k when 50% of react an t is reacted

2.303 100
k=
log
t 50%
50
k=

2.303
x 0.3010 - - - (2)
t 50%

K = Equation (1) / Equation (2)

t 87.5% = t 50%
14.

15.
16.
17.
18.

III.
19.

20.

The overall decrease in atomic and ionic radii from Lanthanum to Lutetium is
known as Lanthanide Contraction.
It causes radii of 3rd transition series to be very similar with those of the
corresponding members of second transition series.
C2H5Br + (CH3)3C-O-Na (CH3)3C-O-C2H5 + NaBr
Explanation
RCN + SnCl2 + HCl RCH = NH
RCHO +
H
Explanation
a) Decreases body temperature during fever
b) Tranquilizer
The sodium salts of sulphonated long chain alcohols or hydrocarbons are called
anionic detergents.
Example: Sodium lauryl Sulphate
PART C

Diagram
At cathode: Al3+(Molten) + 3e- Al(l)
At anode: C(S) + O2- CO (g) + 2e- or C(S) + 2O2- CO2(g) + 4eCatalytic oxidation of ammonia by atmospheric oxygen.

1
1
1
1

4NH3(g) + 5O2(g)

21.

/
/

Nitiric oxide oxidises into nitrogen dioxide

2NO(g) + O2(g) 2NO2(g)
Nitrogen dioxide dissolves in water to give nitric acid
3NO2(g) + H2O(l) 2HNO3( aq) + NO(g)
a) Explanation

> 2O3

3O2
b)
22.

> 4NO(g) + 6H2O(g)

O
P
H - O -S - O - H

a) Explanation
P4 +6 Cl2 4PCl3
b) BrF5

1
1
1
1
1
1
1
1
1

1
1
1
1

1
1
1

23.

24.

25.

26.

a) 1) Large surface area,

2) Variable valence
b) = n (n + 2

1
1
1

Explanation with
4 FeCr2O4 + 8 Na2CO3 + 7 O2 8 Na2CrO4 + 2 Fe2O3 + 8 CO2
2Na2CrO4 + 2 H+ Na2Cr2O7 + 2 Na+ + H2O
Na2Cr2O7 + 2 KCl K2Cr2O7 + 2 NaCl
Geometry:- Octahedral
Hybridisation:- sp3d2
Type of complex:- Outer orbital complex
a) structure of isomers
b) 4 ions

1
1
1
1
1
1
1+1
1

IV.
27.

a) Packing efficiency =

1
1

= 4x

4 3
r x 100%
3
a3
%

b) a 3 =
=

edge length a = 2 2 r

1
1

=74%

Z .M
N A .d

1x 209
6.023 x1023 x 91.5 x10-3

= 3.359 x10-6 cm
28.

a)

P 0 - P w.M
=
P0
mW

195 - 190 5.8x 76

=
195
m x100

1
1

5.8 x 76 x195
m=
100 x 5
= 171.9 g mol

-1

b) A solution which distils over without change in composition

Example: 95.6% ethanol + 4.4 % water OR any other suitable example.

29

l l
x
A R
1
=1.15 x
2.5 x103

a) k =

= 4.60 x10 -4 ohm -1cm -1

1000 x k
Lm =
M
1000 x 4.60 x10 -4
=
0.1
= 4.60 ohm -1cm 2 mol-1

1
1
1
1

b) i) painting
ii) Electrochemical method
Or any other suitable method
30

a) Consider a first order reaction

RP

Rate = -

d [R]
= k[ R]
dt
1

d[R]
= -k dt
[R]
Integrating the above equation we get

.......... (1)

ln[R] = - k t + I
When t =0 , [R] = [R]0
Equation (1) becomes

ln[R]0 = I
Therefore equation (1) becomes

ln[R] = -k t + ln[R]0
1 [R]0
k = ln
t [R]
[R]0
2.303
k=
log
t
[R]

1
1

b) Energy of activation decreases

V.
31

a) i) Surface area of adsorbent

ii) Nature of adsorbent or adsorbate
or any suitable factor
b) Heterogeneous Catalysis
c) Greater the valency of the flocculating ion added, greater is its power to
cause precipitation
Al2(SO4)3

32
or Biphenyl
Fittig reaction

2
1
1
1
1
1
1

b) In dehydrohalogenation reaction the preferred product is that alkene which

has the greater number of alkyl groups attached to the doubly bonded carbon
atom
CH3CHCHCH3 + KOH(alc)
CH3CH=CHCH3 + KBr + H2O
H

33.

1
1

Br

c) SN2
a) Step: 1 : Formation of protanated alcohol
Equation
Step 2: Formation of Carbocation
Equation
Step 3: Elimination of proton and formation of alkene
Equation
b) The organic compound is phenol
OH
OH
Br
Br

+ 3 Br2

1
1
1
1
1

+ 3 HBr
Br
2,4,6 - tribromophenol

34

a) Statement

2 H - CHO
CH 3OH + H - COONa
NaOH

OR
2C6 H 5CHO + KOH
C 6 H5CH 2 OH + C6 H5 COOK

35.

b) Acetone
c) Explanation
R-COOH + PCl5 R-COCl + POCl3 + HCl
a) Correct Explanation

R - NH 2 + CHCl3 + 3KOH
R - NC + 3KCl +3H 2 O
Heat

b) Due to intermolecular association OR more hydrogen bonding

CuCl /HCl
c) ArN 2 X
ArCl + N 2

36.

Explanation
a) Vitamin A
b) Thyroxin
c) The amino acid forms dipolar ion called Zwitter ion in the aqueous solution.
R - CH - COOH
NH2

Covalent form

37.

R - CH - COO

1
1
1
1
1

1
1
1
1
1
1
1
1
1

+ NH3
Zwitter ion

d) Basic unit of nucleic acid containing one sugar unit ,heterocyclic base and
phosphoric acid is called nucleotide
a) The polymers that have elasticity, like rubber in which polymer chains are
held together by the weakest intermolecular forces are referred to as
elastomers.
Example: natural rubber, neoprene, vulcanized rubber.
b) Nylon:

1
1

Bakelite :

c) Rubber when heated with sulphur with an appropriate additive to a

temperature of 373K to 415K

1
1

MODEL QUESTION PAPER 2 PUC II

Model Question Paper-2

PUC-II

CHEMISTRY
Time: 3 hr-15 min.

Batch-02

Max Marks: 70

Instructions:
i)
ii)

The question paper has four parts, A, B, C and D. All parts are compulsory
Part-A Carries 10 marks
Part-B Carries 10 marks
Part-C Carries 15 marks
Part-D Carries 35 marks
iii) Write balanced equations and draw diagrams wherever required
(Use log tables and the simple commercial calculator if necessary (use of scientific calculator is not allowed)
Part-A
I. Answer all questions,
1.
2.

10 X 1=10

3.

Define the term molality.

How does the enthalpy change during the formation of a non-ideal solution two liquids showing positive
deviation from Raoults law?
What is a primary electrochemical cell?

4.

1130K /Mo
N 2(g) + 3H 2(g) what is the order?
For the reaction 2NH 3(g)

5.
6.
7.
8.
9.
10.

What do you mean by selectivity of a catalyst?

Give the chemical composition of Copper matte.
Name the noble gas that is radioactive?
Write the general equation of the preparation of alkyl chlorides from alcohols using SOCl2.
What are acetals?
Name the water insoluble component of the starch?

Part-B
II. Answer any five of the following each questions carries two marks
11.
12.
13.
14.
15.

5 X 2=10

An element having atomic mass 60 amu. has FCC unit cell. The edge length of the unit cell is 4x 102 pm.
Find the density of the unit cell.
Write two applications of Kohlrausch law.
The half-life period of a certain reaction is directly proportional to initial concentration of the reactant.
predict the order of the reaction and write the expression to calculate the half-life period of the reaction.
Give two consequences of lanthanoids contraction.
Complete the following reaction;
0

Cu/300 C
CH3CH 2 OH
?

i)
ii)
16.
17.
18.

R - COOH
RCH 2 OH . Name the reagent used in the conversion?
How does ketone react with ethylene glycol. Write chemical equation for the reaction.
What are analgesics? Give an example for non-narcotic analgesics.
What are artificial sweeteners? Give an example.

Part-B
III. Answer any five of the following each questions carries three marks

5 X 3=15

19.
20.
21.

On the basis of Ellinghams diagram explain the principle of extraction of iron from its oxide ore.
Explain the principles involved in the manufacture of ammonia by Habers process.
Complete the following equations;

a) 5SO 2 + MnO 4 - + 2H 2 O
5 SO 4 2- + 4H + + ?
b) 5SO 3 + Conc.H 2SO 4
?

1+1+1

c) 2KClO 3
?
MnO2

22.
23.
24.
25.
26.

a) Explain the action of Conc. HCl on KMnO4 crystals

2
b) Write the structure of perchloric acid.
1
a) Transition metals show variable oxidation states. Explain
2
b) Which metal of 3d-series exhibit maximum number of oxidation state?
1
How is K2Cr2O7 manufactured from chromite ore.
3
Using valence bond theory (VBT), account for the geometry, type of hybridization and magnetic property
of [NiCl4]23
Define linkage isomerism of co-ordination compounds. Give an example
3

Part-D
IV. Answer any three of the following, each question carries five marks
27.

28.

5 X 3=15

a) Calculate the packing efficiency in BCC lattice

b) Calculate the number of particles per unit cell in FCC

3
2

a) Acetone boils at 56.38oC and a solution of 1.41g of an organic compound in 20 g of acetone boils at
56.88oC. Calculate the molar mass of the organic compound (Given Kb for acetone =1.67 K kg/mol).
3
b) what is reverse Osmosis, mention one important application of it.
2

a) Standard EMF of the cell;

Cu Cu2+(1M)
Ag+(1M) Ag is 0.46 V at 25 oC. Find the value of
standard free energy change for the reaction that occurs in the cell.
3
b) Draw the neat labeled diagram of SHE and write its symbolic representation.
2
30. a) Derive the integrated rate equation for a zero order reaction
3
b) Give any two differences between order and molecularity of reaction
2
29.

31.

a) Write any two differences between lyophilic sols and lyophobic sols
b) What are the differences between physisorption and chemisorption
c) Give an example for homogeneous catalysis

V. Answer any four of the following, each question carries five marks
32.

2
2
1

4 X 5=20

a) i) Name the organic product formed when chloroalkane is heated with concentrated solution of
sodium iodide (NaI) in acetone?
ii) Write the chemical equation for the above reaction
iii) Name the above reaction

(1+1+1)

b) Explain Fittigs reaction with an equation

33.

a) Organic compounds A, B and C are aliphatic saturated hydroxyl compounds when they react with
Lucas reagent (anhyd.ZnCl2 + conc. HCl ), the following observations are made
i) Compound A gave turbidity immediately
(1+1+1)
ii) Compound B gave turbidity after five minutes
iii) Compound C gave turbidity only on heating, Identify the type of compounds A, B and C.

H
b) Complete the equation: C 6 H5 COOH + HOC6 H 5
?

c) Name the main organic product formed when anisole is reacted with HI
34. a) Which of the following organic compound undergoes Cannizzaros reaction?
i) CH3CHO ii) HCHO
b) Write the mechanism of addition of HCN to a carbonyl compounds

1
1
1
2

c) Explain the conversion of carboxylic acid into an acid amide. Give the general chemical equation
2
35.

a) Explain Mendius reduction with an equation.

2
b)When aniline is treated with HNO2 at 273-278 K, benzene diazonium chloride is formed. Write the
equation and name the reaction.
2
c) What is Hinsbergs reagent?

36.

a) Write the Haworths structure of sucrose

b) What are non-essential amino acids?

2
1

c) Name the heterocyclic N-containing base present only in DNA but not in RNA.

d) Vitamin-C cannot be stored in the body. Give reason.

37.

a) Which among the following is a homopolymer and a co-polymer,

i) Nylon-6,6 ii) PVC

b) How is Buna-N prepared ?. Write the equation

c) Give one example for a non-biodegradable polymer

1.
2.
3.
4.
5.
6.
7.

9.
10.

II -PUC Chemistry ( 34)

Scheme of Valuation for model question paper -2
Batch-02
PART-A
No. of moles solute present in 1 kg of solvent
H= +Ve or Enthalpy increases or heat is absorbed
A primary cell is one that cannot be recharged
Zero
It is the ability of catalyst to direct a reaction to yield a particular product
Cu2S + traces of FeS or Cuprous sulphide + traces of ferrous sulphide
Radon

Acetals are gem-alkoxy alkanes in which two alkoxy groups are present
on the terminal carbon atom
Amylopectin

1
1
1
1
1
1
1

1
1
1

PART-B
II.
1

12.

13.

i)The degree of dissociation and dissociation constant of weak electrolyte

(AB) Type can be calculated
ii) Using this law, omfor both weak and strong electrolytes can be calculated
a) Zero order

1
1
1
1

1
14.

15.

Due to lanthanide contraction

i) Similarity in atomic sizes of elements of second and third transition series
ii) The separation of lanthanides in pure state become difficult

1
1

i)

16.

ii) LiAlH4 in the presence of THF

Ketal is formed,

17.

Analgesics are the chemical substances which relieve body pains

1
1

1
1

Ex. Aspirin or paracetamol

These are low calorie substances used as sweetening agents to replace sugar
Ex. Saccharin/ Aspartame/ Alitame/ Sucralose
PART-C

18.
III.
19.

1
1
1
1

a) At 1073 K, GoVsT line for

Intersects the
1
o
o
Line. Above 1073K, G of
becomes less than G of
and hence carbon itself is oxidized to CO. Therefore, carbon becomes very good
reducing agent for the reduction of FeO to Fe at the temperature range of
900K-1500K.

b) At temperature, below 800 K, Go for

is less than

, therefore, CO is a better reducing agent for the reduction of Fe2O3 to FeO

20.

i)
ii) According to Le-Chaterliers principle, the forward reaction is favored by
low temperature and high pressure
iii) Optimum conditions in the process are 700 K atm. And Fe catalyst containing
K2O and Al2O3 promoter

1
1
1

21.

22.

a) When KMnO4 is treated with conc. HCl. Chlorine is liberated

1

23.

24.

b)
a)i) ns and (n-1)d subshells have almost same energy
ii) Both ) ns and (n-1)d electrons involve in bonding
b) Mn or Manganese
i) Chromite ore in to sodium chromate

1
1
1
1

ii)Sodium chromate in to sodium dichromate

1
iii) sodium dichromate in to potassium dichromate
1
i) Ni2+ ; [Ar] 3d8 4so

25.

3d8

4s
ii) On approach of Cl ligands;

4p

SP3 hybridization

2-

iii) [NiCl4] formation;

SP3 hybrid orbitals

filled by electrons donated by ligands
3
Geometry; Due to SP hybridization, the complex has tetrahedral structure
1
Magnetic propery; The complex is paramagnetic due to the presence of two
1
unpaired electrons
26. Linkage isomerism is one in which two co-ordination compounds have the same
2
molecular composition but differ in the mode of attachment of ligands to the central
metal atom/ion.
Ex: [Co (NH3)5 (NO2)] Cl2 and [Co (NH3)5 (ONO)] Cl2
1
PART-D
27. a) Edge length a=4r/3 r = radius of sphere
1
Packing efficiency = (volume of the sphere x 2 volume of unit cell) x 100
1
= (4/3 r3 x 2 x 100) a3
= (4/3 r3 x 2 x 100) 4r/3
1
= 68%
b) No. of particles per unit cell of FCC

1
1
(No. of corner particles) +
(No. of facial particles)
8
2
1
1
=
x8+
x6 =1+3=4
8
2
=

28. a) Tb= Kb x molality

Tb= Kb x (m solute/ M solute) x 1000 / m solvent
(56.88-56.38) = 1.67 x (1.41/ M solute) x 1000/20
M solute = 235.47
b) It is the process of movement of solvent molecules from higher concentration to
lower concentration by applying pressure greater than osmotic pressure
Application; It is used in desalination of sea water
29. a) Go = -nFEo cell n = 2
= -2 x 96500 x 0.46
= -108080 joules or -108.08 kjoules
b) For diagram
SHE: Pt, H2 (1 bar) / H+ (1M)
30. a) Consider a zero order reaction
RP

1
1

1
1
1
1
1

F = 96500 C, Eo = 0.46 V
2
1

Rate = K [R]0
Rate = K x 1 where K- rate constant or velocity constant
Rate = -d[R]/dt
-d[R]/dt = K => d[R] = - K dt
d [R] = - K dt
[R] = - Kt + I.(1)
I- integration constant
To find I, when t=0, [R] = [R0]
[R0] = -K x 0 + I
I = [ R0]
Substituting in eq (1)
[R] =- Kt + [R0]
K= [R0] [R]/ t
b)Molecularity
Order of a reaction
2
i)It isalways related to reaction
i) It may or may not related to reaction
stoichiometry
stoichiometry
ii) It isalways whole number
ii) It can be whole number or fraction or even zero
31. a) Lyophilic sols
Lyophobic sols
i) Dispersed phase has greater
i) Dispersed phase has no
affinity for dispersion medium
affinity for dispersion medium
ii) Reversible
ii) irreversible
or any other differences
b) Physisorption
Chemisorption
i) Adsorbate and adsorbent
i) Adsorbate and adsorbent
are held together by weak van der
are held together by strong chemical
waals forces
bonds
ii) Reversible
ii) irreversible
or any two suitable differences
c)

or any other suitable examples

32.a) i) Iodoalkane is formed

ii)

1
1

Finkelstein reaction
b) When haloarene is heated with sodium metal in dry ether medium, higher
aromatic hydrocarbons is formed
C6H5-X + 2Na + C6H5-X
C6H5-C6H5 + 2NaX
Dry ether
33. a) i) A = Tertiary alcohol
B = Secondary alcohol
C = Primary alcohol

1
1

1+1+1

Phenyl benzoate
c) Phenol
34. a) HCHO

1
1

b)

HCN + OH -

CN- + H2O

OC

CN-

H+

OH

C
CN

CN

1
c)

R-COOH

Heat

NH3

R-CONH2

R-COONH4
-H2O

Explanation:

When carboxylic acid is heated with ammonia it gives acid amide.

1
35. a) Reduction of nitriles by sodium in alcohol to get a primary amine is called
Mendius reduction.
1

R-CN + 4 (H)

Na/alcohol

R-CH2 -NH2

b)
273-278K
C6 H5 -NH2 + NaNO2 + 2 HCl

C6H5-N2Cl + NaCl + H2O

Diazotization
c) Benzene sulphonyl chloride or C6H5SO2Cl
36.a)

1
2

b) Amino acids which can be synthesized by human body are called non-essential
amino acids
c) Thymine
d)
Excess of vitamin-C is excreted through urine
37. i) Nylon-6,6 Copolymer
ii)
PVC Homopolymer
b) When 1, 3-butadiene is heated with acrylonitrile in presence of sodium, Buna-N
is formed.
H2C

CH

C
H

CH2

H2C

CH
CN

1
1

Na
Heat

H2C

C
H

CH

1
1
1
1
1
1
CH2 CH2 CH
CN

1
c) PVC or any suitable example

MODEL QUESTION PAPER 3 PUC II

Model paper 3
II PUC CHEMISTRY (34)
Time: 3hours 15 minutes

Maximum marks: 70

Instructions:
1. The question paper has four parts: A, B, C and D. All parts are compulsory.
2. Write balanced chemical equations and draw labeled diagrams wherever required.
3. Use log tables and the simple calculator if necessary.
(Use of scientific calculators is not allowed)
PART-A
I. Answer ALL of the following. (Each question carries 1 mark)
(Answer each question in one word or in one sentence)

10x1=10

1. What is the effect of increase in temperature on the solubility of gas in a liquid?

2. Define osmotic pressure .
3. Mention the concentration of H+ ions in the solution used in SHE .
4. From the following plot, predict the order of the reaction.
ln[R]0
k = - slope
ln[R]
0
5. 2SO2(g)+O2(g)

t
NO2SO
(g) (g). Is this reaction an example for Homogenous or
3

Heterogeneous catalysis.
6. Name the depressant used in separation of ZnS from PbS by froth floatation process.
7. Which noble gas does not occur in nature?
8. R-X + NaI

Dry Acetone
R-I + NaX. This reaction is known as

9. Give reason: Acetic acid is soluble in water.

10. Among the following which is a fat soluble vitamin
Vitamin-B12, Vitamin-C, Vitamin-D.
PART-B
II.Answer any FIVE of the following. (Each question carries 2 marks)
11. Give two differences between p-type & n-type semiconductors.
12. What is limiting molar conductivity? Represent graphically the variation in molar
conductivity with concentration for acetic acid.

5x2=10

13. Rate constant of a first order reaction is 6.93X10-3 min-1. Calculate the half-life period.
14. i) What is actinide contraction?
ii) Which is the common oxidation state exhibited by actinides?
15. How do you prepare diethyl ether by dehydration of ethanol?
16. How do you convert benzamide to benzoic acid?
17. Give one example each for i) Tranquilizer ii) Antiseptic.
18. What is saponification with an example.
PART-C
III. Answer any FIVE of the following. (Each question carries 3 marks)

5x3=15

19. How copper is refined by electrolytic method.

20. i) Write the structure & mention basicity of hypo phosphorous acid.
ii) Which gas is liberated when zinc reacts with dil HNO3?
21. Draw the flow chart for the manufacture of sulphuric acid by Contact process.
Name the catalyst used in the process
22. i)Give any two reasons for the anomalous behaviour of fluorine
ii)Give one example of interhalogen compounds
23. What are interstitial compounds?
Write any two characteristics of interstitial compounds
24. i) Write the two chemical equations to show the inter conversion of chromates &
dichromates in aqueous solution
ii)Complete the equation : 5C2O42- + 2MnO4- + 16H+
25. With the help of valence bond theory account for the geometry &
magnetic property of [Co(NH3)6]3+
26. i)What is an ambidentate ligand?
Name the type of structural isomerism that arises in the co-ordination compound
containing such a ligand
ii) Give the IUPAC name of K2[Zn(OH)4]

3
2
1
3
2
1
1
2
2
1
3
1
1
1

PART-D
IV. Answer any FIVE of the following. (Each question carries 3 marks)

3x5=15

27. a) Calculate the packing efficiency in a CCP crystal lattice

b) What is the number of particles per unit cell of a simple cube.
28. a) Calculate the osmatic pressure of 0.05% urea solution in water at 200c.
Given R =0.0821Latm mol-1K-1. Molar mass of urea = 60g mol-1
b) Give two general characteristics of an ideal solution of two liquids
29.a)Calculate the emf of the cell in which the following reaction takes place
Ni(S)+2Ag+(0.002M) Ni2+(0.160M) + 2Ag(S), Given that E0Cell = 1.05V
b) A galvanic cell after use is recharged by passing current through it.
What type of cell is it? Give an example

30.a) Rate constant of a reaction at 300K & 400K are 0.034S-1& 0.136S-1 respectively.
Calculate the activation energy for the reaction [ Given: R = 8.314JK-1mol-1]

4
1
3
2
3
2

b) Derive the expression for half-life of zero order reaction

31. a) Mention two applications of adsorption
b) What are emulsions? Give an example for O/W emulsion
c) What is the cause for Brownian movement?
V. Answer any FIVE of the following. (Each question carries 3 marks)

2
2
2
1
4x5=20

32. a) Explain SN2 mechanism with an example

b) Name the product formed when chloromethane reacts with (i)aqueous KOH &
(ii)alcoholicAgCN
c) Give an example of polyhalogen compound
33. a) Explain esterification reaction between acetic acid & ethyl alcohol as example
b) Boiling point of alcohol is greater than the boiling point of hydrocarbons of
comparable molar masses, Why?
c) What is the effect of NO2 group on the acidic strength of phenol? Give reason
34. a) Explain Etard reaction
b) Name the products A & B in the following reaction
2CH3CHO

dilNaOH

H2O

2
2
1
2
1
2
2
2

c) Name the reagent used in the decarboxyaltion of carboxylic acid

35. a) How do you convert benzene diazonium chloride into chlorobenzene.
Name the reaction
b)Explain Hoffmann Bromamide reaction with an example
36. a) Write the Haworth structure of maltose
b) What are hormones? Give one biological function of insulin
c) What are nucleosides?
37. a) Name the monomers of Nylon-6,6
b) How is Neoprene prepared? Give equation
c) Give an example for thermoplastic polymer.

1
3
2
2
2
1
2
2
1

Scheme of valuation for model question paper 3 (ZIET)

Note : Any other correct alternative answers can be honored wherever applicable
Q.No
I
1
2
3
4
5
6
7
8
9
10

Value points
PART-A
Decreases
External pressure to be applied on the solution side just to stop the flow solvent from its
side to solution side across SPM
1M or 1 Molar
First order
Homogenous
Sodium cyanide or NaCN
Radon or Rn
Finkelstein reaction
Due to the formation of hydrogen bond (H-bond) b/w acetic acid molecules & water
Vitamin-D

II
11

12

Marks
1
1
1
1
1
1
1
1
1
1

PART-B
p-type
1. Doped with trivalent atoms(B,Al)
2. Negative charges (electrons) contributes
to conduction

n-type
1. Doped with pentavalent atoms(P,As,Sb)
2. Holes contributes to conduction

Molar conductivity at infinite dilution

m
1

13
t1/2 =
t1/2 =

1
.

t1/2 = 100 min

14

(i)The steady decrease in atomic size of the actinides with increase in the atomic number
(ii)+3

1
1

15

When ethanol is heated with Con H2SO4 at 414K, diethyl ether is formed
1

H2SO4
CH3CH2OCH2CH3
413K

CH3CH2OH

1
OR

OR

Self explanatory equation

16

When benzamide is heated with dil acid hydrolysis takes place to form benzoic acid
1

CONH2

COOH

H3O+

OR
OR
Self explanatory equation
2
17

18

(i) Noradrenaline OR Equanil OR Chlordiazepoxide OR Meprobamate OR Any other suitable

example
(ii) Dettol OR Chloroxylenol OR Tincture of iodine OR Terpineol OR Furacine OR Soframicine
OR Any other suitable example
When fat is heated with aqueous NaOH solution, soap is formed

O
ll
CH2 O C C17H35
O
ll
CH O C C17H+353NaOH

3C17H35COONa + CH OH

Self explanatory equation

PART-C
Impure copper is made as anode & thin sheet of pure copper is made as cathode. Acidified
copper sulphate solution is taken as electrolyte
On passing electric current, pure copper deposits on the cathode
At anode : Cu Cu2+ + 2e
At cathode : Cu2+ + 2e Cu
(i)

CH2 OH
OR

20

1
1

CH2 OH

O
ll
CH2 O C C17H35

III
19

OR
2

1
1
1

O
ll
P
OH
H

Basicity = 1
1
(ii) Nitrous oxide OR N2O
1
21

Air

Oleum

22

23

24

25

Sulphur

Dust

Washing &

Burner

Precipitator

Cooling Tower

Absorption

Catalytic
Converter

Pre

Tower

Drying
Tower

Arsenic
purifier

Heater

(ii) Vanadium pentoxide

(i) Smallest size, Highest electronegativity, Non availability of d-orbitals, High ionization
enthalpy, low F-F bond dissociation enthalpy (any two)

(ii) ClF3, ICl, BrF5 OR any other suitable example

The compounds formed by the trapping of small atoms like H, C, N etc into the crystal lattice
of metals
Characteristics
1. High m.p. than the pure metal
2. Very hard
3. Chemically inert
4. Retain metallic conductivity
(any two)

2CrO42- + 2H+ Cr2O72- + H2O

Cr2O72- + 2OH- 2CrO42- + H2O

1
1

2Mn2+ + 8H2O + 10CO2

E C of Co3+ = 3d6 or

3d

4s

4p

d2sp3 hybridized orbitals

of Co3+
[Co(NH3)6]3+
Geometry : Octahedral
Magnetic property : Diamagnetic

3d

6 pairs of electrons
from 6 NH3

1
1

26

IV
27

(i) Ligands which can ligate through two different atoms OR Uni dentate ligands have more
than one donar atom OR Any other correct stateemnt
Linkage isomerism

(ii)Potassium tetrahydroxidozincate(II)

PART-D
a)
Let a is the edge length of the cube,

a =2 2ar

Each unit cell in hcp has effectively 4 spheres. Total volume of four sphere is equal to 4 X

(4/3) r3 and volume of the cube is a3 or (22ar)3

Packing efficiency =

Packing efficiency =

= 74%

b)1 or One
28

a)
1

= 0.2atm
b)
1.Obeys Raoults law
2. H of mixing is zero
3. V of mixing is zero
4. Does not forms azeotropic mixtures
5. (A-B) interactions are same as that of (A-A) or (B-B) interactions

1
1

6. Measured VP = VP predicted by Raoults law

(Any two)

29

a)
=

log

1
.

= 1.05 -

log

( .

= 0.914V
b) Secondary cell
Example : Lead-storage battery or Nicad storage cell or any other example
(Any one)
30

a) log
.

or Ea =

log

1
1

.
.

Ea =

= 13834Jmol-1 or 13.8KJmol-1

b) W K T rate constant (k) expression for zero order reaction

k=

or t =

When t = t1/2, [R] =

t1/2 =

31

a) In gas mask or Control of humidity or Removal of colouring matter from solutions or

Production of high vaccum or In heterogeneous catalysis or Separation of inert gases or In
curing diseases or In froth floatation process or Adsorption indicators or In chromatographic
analysis
( any two)

b) Liquid-Liquid colloidal system OR dispersion of finely divided droplets in another liquid OR

Any other suitable definition

Example : Milk, vanishing cream or any other suitable example
c) Due to the collision of the dispersed phase particles with molecules of the dispersion
medium.

V
32

1
1

PART-D
a)

H
l
H C Cl
l
H

OH +

H
HO

C
H

Cl

H
l
HO C H + Cl
l
H

b) (i) Methanol or Methyl alcohol

(ii) Methyl carbylamine or N-Methyl carbylamine or Methyl isocyanide or
Isocyanomethane or Methyl isonitrile

1
1

c) CH2Cl2 or CHCl3 or CCl4 or Freons or DDT or any other suitable example

33

a) When acetic acid is heated with ethyl alcohol in the presence of Con H2SO4 as dehydrating
agent, ethyl acetate is formed.
CH3COOH + C2H5OH

Con HCH
2SO
4
3COOC2H5 + H2O
OR

34

1
1

1
OR

Self explanatory equation

b) H-bonding

c) Increases
Since NO2 is electron withdrawing group OR Due to I effect

1
1

a) When toluene treated with CrO2Cl2& CS2, followed by hydrolysis benzaldehyde is formed.

CH3

H
l
C=O

1.CrO2Cl2/CS2

2. H2O
OR

OR

35

Self explanatory equation

b) A = Aldol or 3-hydroxybutanal
B = Chrotanaldehyde or But-2-enal

1
1

c) Sodalime

a) When benzene diazonium chloride reacts with Cuprous chloride in HCl, chlorobenzene is
formed

+
N2Cl

Cu2Cl2/HCl

Cl
+ N2

OR

OR

Self explanatory equation

1
Name of the reaction : Sandmeyers reaction
1

OR
a) When benzene diazonium chloride reacts with Copper in the presence of HCl,
chlorobenzene is formed

+
N2Cl

Cl
Cu/HCl

+ N2 + HCl
OR
OR

Self explanatory equation

1
Name of the reaction : Gatterman reaction
1
b) When amide reacts with bromine in the presence of aqueous/alcoholic NaOH, primary
amine is formed.

R-CONH2 + Br2 + 4NaOH R-NH2 + Na2CO3 + 2NaBr + 2H2O

OR
OR

Self explanatory equation

OR

36

By taking R = CH3 OR C6H5 as example

a)

CH2OH
H

H
OH

CH2OH
O

H
O

OH
H

OH

H
OH
H

H
OH
OH

b) Biochemical messengers or Chemical substances secreted by endocrine (ductless) glands

1
Regulates the blood sugar level
1

37

c) Pentose sugar + Nitrogen base

a) Hexamethylenediamine

1
1

Adipic acid

1
b) Neoprene is formed by the free radical polymerization of chloroprene
1

Cl
l
n CH2 = C CH = CH2

Cl
l
CH2 C = CH CH2

c) Polyethylene or PVC or Polystyrene or Polyvinyls or any other suitable example

(any one)

II-PUC CHEMISTRY
BLUE PRINT FOR MODEL QUESTION PAPER - 4

Group

Group-I
Physical

Group-II
Inorganic

Unit

Title

Marks

Part-A

Part B

Part C

II

III

10x1 mark

8x2 mark

8x3 mark

Part D

Total

IV & V
11x5 mark

The Solid state

Solution

1,2

Electrochemistry

Chemical kinetics

Surface chemistry

Total of Group-I

41

36

19

11

10

20,21,22

10

23,24

25,26

General principles and processes of isolation of

elements

The p-block elements

The d and f-block elements

Coordination compounds

32

28

Total of Group-II
Group-III
Organic

Hours

10

Haloalkanes and haloarenes

11

Alcohols, phenols and ethers

27

28

12

29

13

30

31

11

36

14

28
8
15

32

33

12

Aldehydes, ketones and carboxylic acids

13

Amines

14

Biomolecules

15

Polymers

16

Chemistry in everyday life

47

41

120

105

Total of Group-III
TOTAL

16

10

34

35

36

37

5
4

17,18

41
10

10

15

35

105

CHEMISTRY ( 34) NEW SCHEME

MODEL QUESTION PAPER NO.4
TIME 3HOURS 15 MINUTES

MAX.MARKS.70

Instructions :
i. The question paper has four parts. All the four parts are compulsory
ii. PART A carries 10 marks , each question carries one marks.
PART-B carries 10 marks . each question carries two marks
PARRT C carries 15 marks . each question carries three marks
PART-D carries 35 marks . each question carries five marks
iii) write balanced chemical equations and draw diagrams wherever necessary
iv) use log table and simple calculators if necessary
(use of scientific calculator is not allowed)
PART-A
I ANSWER ALL THE QUESTIONS. EACH QUESTION CARRIES ONE MARK 1X10=10
1.
2.
3.
4.

5.
6.
7.
8.
9.
10.

11.
12.
13.
14.

Define VantHaffs factor.

What are isotonic solutions ?
Mention the S.I unit for molar conductivity.
For the reaction A+B products .the rate becomes doubled when concentra on of only A is
increased by two times, the rate is increased by four times, when the concentration of B alone
is doubled what is the order of the reaction?
Name the enzyme used in the inversion of cane sugar
Name the method used for refining of Zirconium.
Complete the reaction XeF4+O2F2 A+O2
Identify A
What is a Recemic mixture-?
Name the product obtained when acetaldehyde reacts with Hydroxyl amine.
Name the nitrogenous base present in RNA only.
PART-B
II ANSWER ANY FIVE OF THE FOLLOWING EACH QUESTION CARRIES TWO MARKS.
5X2=10
MARKS
Silver forms CCP lattice and x-ray studies of its crystals show that the edge length of its unit
cell is 408.6 pm . calculate the density of silver ( Atomic mass of Ag= 107.9u)
What is corrosion? Mention a general method to prevent it.
Write the Arrhenius equation and mention what each term stands for.
Any two differences between lanthanides and Actinides.

15. How does Acetyl chloride react with Anisol in presence of anhydrous aluminum chloride
catalyst. Write the chemical equation of the reaction.
16. What are the effects of the electron withdrawing and electron donating groups on acidity of
carboxylic acids
17. What are antacids? Give an example.
18. What are food preservatives ? Give one example

PART C
III ANSWER ANY FIVE OF THE FOLLOWING EACH QUESTION CARRIES THREE MARKS
15

5X3=

19. How is pure alumina obtained from Bauxite by leaching process?

20. Write the reactions that takes place during the manufacture of nitric acid by Ostwalds process.
21. i) what happens when potassium chlorate is heated in presence of MnO2. write the equation for
the reaction also
ii) draw the structure of sulphuric acid.
22. i) How is chlorine prepared by using MnO2 ?
ii) complete the reaction
NH3+Cl2(excess)
23. d-block elements form co-ordination compounds . Give reasons.
24. How is potassium dichromate prepared from the chromite ore?
25. Mention the geometry, magnetic property and type of hybridization in [Ni(cn)4]2- complex.
26. Write any three postulates of Werners theory of complexes.
PART-D
IV ANSWER ANY THREE OF THE FOLLOWING . EACH QUESTION CARRIES FIVE MARKS
3X5= 15
27. a. calculate the packing efficiency in body centered cubic crystals
b. calculate the number of particles per unit cells in f.c.c.
28. a. the boiling point of benzene is 353.23K .when 1.80 g of a non volatile , non

(3)
(2)

electrolytic solute was dissolved in 90 g of benzene , the boiling point was

raised to 354.11 K calculate the molar mass of the solute [ Kb for benzene =2.53K.kg mol-1]
(3)
b. write two differences between ideal and non ideal solutions of two liquids
(2)
29. a). calculate the standard free energy change for the following reaction occurring in the galvanic
cell at 298K
3Mg(s) + 2Al3+ (aq) 3Mg2+(aq) +2 Al (s)

Given EMg2+/Mg = - 2.37 V and EAl3+/Al=-1.66V

(4)

b. what is primary battery?

30. a. Derive the integrated rate equation for the rate constant of a first order reaction (4)
b. what is pseudo first order reaction ?

(1)

31. a. complete and balance the following reactions

SO2 +

H2 S oxidation

FeCl3 + H2O hydrolysis

(2)

b. Mention two characteristics of enzyme catalysis

(2)

c. What is the sign of S for the adsorption of gas on solids ?

V ANSWER ANY FOUR OF THE FOLLOWING . EACH QUESTION CARRIES FIVE MARKS
4X5=20
32. a. Explain SN1 mechanism by taking tertiary butyl bromide as an example
b. What is Wurtz Fittings reaction ? Give an example

(3)
(2)

33. a. How is phenol manufactured by cumene process. Give the chemical equations of the reaction
involved .
(3)
b. How do you prepare ethanol by using the Grignard Reagent?
34. a. How is Benzol chloride converted into benzaldehyde ? Name the reaction

(2)
(3)

b. Write the chemical equation for the reaction between dilute NaOH and acetalhyde, mention the
name of the product formed .
(2)
35. a. Explain how is Hinbergs reagent is used to distinguish the primary, secondary and tertiary
amines
b. Write the chemical reactions involved in the conversion of aniline into phenol
36. a. What are carbohydrates ?and how are they classified ?

(2)
(3)

b. What is a peptide bond ? How many peptide bonds are present

in a tetra peptide ?

(2)

37. a. i) what are condensation polymers ? Give an example.

ii)Give the IUPAC name of the monomer of natural rubber.
b. What are Biodegradable polymers ? Give an example

(3)
(2)

Scheme of Valuation
Q.N
O

VALUE POINT

MARK
S

Two solutions having same osmotic pressure at a given temperature

Sm2 mol-1 or Scm2 mol-1

Two

Invertase

Van Arkel method

A=XeF6 or Xenonhexaflouride

A mixture containing two enantiomers in equal proportions will have zero optical
rotation.

Acetaldoxime

10

Uracil

1
PART -B

11

Formula d=zM
-------a3 NA substitution with correct answer(10.5 x 103 kgm-3)
OR

10.5 g cm-3
1
12

A metal is oxidized by loss of es and formation of oxides

Any one method of prevention of corrosion ( coating, painting, tinning, cathodic

13

protection)

Arrhenins Equation k=A.e-Ea/RT OR log ek=logeA Ea

---RT
Where k= rate constant, A=Arrhenius constant Ea= Activation energy, T= temperature,
R= gas constant (any one)

1
14

Lanthanides
1.Binding energies of 4f es are higher

Actinides
1. Binding energies of 5f es are

Lower
2. They do not form complexes easily

2. They have tendency to form

complexes
ANY ONE SUITABLE ANSWER
15

16

17

18

Electron with drawing group increases acidic strength

Electron donating group decreases acidic strength

Chemical substances which are used in the treatment of acidity

Ranitidine( (Zantac) OR ANY OTHER EXAMPLE

Chemical substances which prevent spoilage of food due to microbial growth

Ex: Table salt, sugar, vegetable oils, OR any other suitable example

PART-C
19

Al2O3 + 2 NaOH + 3H2O 2Na [ Al (OH)4]

2Na[Al(OH)4 + CO2 Al2O3. x H2O + 2NaHCO3
Al2O3. x H2O 1470k

Al2O3. +x H2O.

Each equation carries one mark

OR COMPLETE EXPLANATION IN THREE STEPS

3

20

4NH3+ 5O2 Pt/Rh

4NO + 6H2O

500k,9bar

2NO + O2

2NO2

3NO2 +H2O 2HNO3 + NO

1
1

OR COMPLETE EXPLANATION IN THREE STEPS

21

(i)
Statement
2KClO3 Mno2 2KCl + 3O2

OR SELF EXPLANATION ON REACTION

1

22

(i)

Heating MnO2 with conc. HCl

MnO2 + 4 HCl MnCl2 + Cl2+ 2H2O
OR
Self explanation on reaction\

1
1

(ii)

NH3 + Cl2(excess) NCl3 + 3HCl

2
1

23

24

Small size of metal ions

High ionic charges

Availability of d- orbitals

4FeCr2O4 + 8Na2CO3 7O2

Na2CrO4 + 2Fe2O3 +8CO2

2Na2CrO4 +2H+ Na2CrO7 + 2Na++H2O

Na2CrO7 +2KClK2Cr2O7 +2NaCl

OR COMPLETE EXPLANATION IN THREE STEPS

25

26

Square planner complex

Diamagnetic

dsp2 Hybridisation

(i)
(ii)
(iii)

Coordination compounds metals show two types of valencies primary

and secondary
Primary valencies are ionisable
Secondary valencies are non-ionisable
OR ANY OTHER POSTULATES

1
1

PART -D
27

(a) Up to a = 4 /3 OR r=

Packaing efficiency= volume offupied by 2 spheres x 100 %

Total volume of unit cell
Substitution and correct answer (68%)
(b) Total no. of particles due to corners 1/8x8=1
Total no.of particles due to faces 6x = 3 &
Total no.of particles per unit cell 3+1 = 4

1
28

(a) Formula : M2 = 1000x W2 x Kb

Substitution:
M2 = 1000 x 1.8 x 2.53
0.88 x 90

M2 = 58 g mol-1
[ NO UNIT DEDUCT ONE MARK]
(c) Ideal solution
Hmix =0
Vmix =0

non ideal solution

Hmix O
Vmix O

OR ANY OTHER DIFFERENCES

29

(a) E cell = ER --- EL

= -- 1.66+ 2.37
= 0.71 V
G = -- nF E cell
= -- 6x96500x 0.71
= - 411090 J OR - 411.09kJ
(b) Battery can not be reused

1
1
30

(a) RP
Rate = - d[R] = k[R] OR
dt
d[R] = - kdt
[R]
Integrating euation
Ln[R] = -kt+I --------------------(1)
To calculate I :
T=o, R=[R]0

ln[R]o =-kxo+I
OR
ln[R]0=I
substitutionequation (1)
ln [R] = -kt + ln [R]0
Rearranging
Ln[R] = - kt
OR
[R]0
K= 1/t. ln [R]0
OR
[R]
K= 2.303 log10 [R]0
t
[R]
(b) Order of reaction is one and molecularity is two or more than two

1
1
1

31

(a) i. SO2 + 2H2S doubel decomposition

FeCl3 + 3H2O

Hydrolysis

AS2 S3 +3H2O

Fe(OH)3 + 3HCl.
1

(b) Characteristics are

(i)
Highly efficient
(ii)
Highly specific in nature
OR
ANY OTHER REVELENT CHARACTERISTIC (FOR EACH ONE MARK)
(c) S decreases OR S is negative

1
PART-V
32

1
(a)

Step-1

+ Br -

(CH3)3 CBr slow

Step-2

+OH - fast

(CH3)3 COH

Mentioning first order kinetics

(b) Alkylhalide reacts with anyl halide gives alkylarenes when treated with
sodium indry ether
1

OR self-explanation with equation

1

2
(a) Explanation

33

OR
Step wise reaction carries
(b) HCHO+ CH3 Mg Br CH3CH2OBr
Methanal
CH3CH2OMgBr + HOH CH3CH2OH+Mg(OH)Br
Ethanol
34

(a)

H2
Pd-BaSO4

Benzoyl
chloride
Rosenmund reduction

Benzaldehyde

(b) 2CH3CHO dil NaOH CH3-CH-CH2CHO

OH

Ethanal
3-Hydroxybutanal
(ALDOL)

CH3-CH=CH-CHO
But-2 enal

2
35

(a) Hinsbergd reagent reacts with 1 amine gives a product which is soluble in
alkali
(b) Hinsbergs reagent reacts with 2 amine gives a product which is insoluble
in alkali
Hinsbergs reagemt doesnot react with 3 amine
C6H5NH2 + NaNO2+2HCl 273-278 k C6H5N2+Cl- + NaCl + 2H2O
C6H5N2+Cl- + H2OC6H5OH + N2 + HCl

1
1
1
1
1

36

(a) Optically active polyhydroxy aldehydes or ketones or the compounds which 1

produce such units on hydrolysis
2
Classified as monosaccharides, oligo saccharides, polysaccharides
(b) Elimination of a water molecule from two molecules of similar or different
amino acids and formation of CONH- bond
3 peptide bond

1
37

(a) i. condensation reaction between two different bifunctional or trifunctional

monomeric units
Nylon6,6 or Any other example
ii. isoperene or 2-methyl-1,3-butadiene
(b) polymers cause acute environmental problems and remain undegraded for
long time
Nylon-2-nylon-6 or any other example

1
1
1

II-PUC CHEMISTRY
BLUE PRINT FOR MODEL QUESTION PAPER - 4

Group

Group-I
Physical

Group-II
Inorganic

Unit

Title

Marks

Part-A

Part B

Part C

II

III

10x1 mark

8x2 mark

8x3 mark

Part D

Total

IV & V
11x5 mark

The Solid state

Solution

1,2

Electrochemistry

Chemical kinetics

Surface chemistry

Total of Group-I

41

36

19

11

10

20,21,22

10

23,24

25,26

General principles and processes of isolation of

elements

The p-block elements

The d and f-block elements

Coordination compounds

32

28

Total of Group-II
Group-III
Organic

Hours

10

Haloalkanes and haloarenes

11

Alcohols, phenols and ethers

27

28

12

29

13

30

31

11

36

14

28
8
15

32

33

12

Aldehydes, ketones and carboxylic acids

13

Amines

14

Biomolecules

15

Polymers

16

Chemistry in everyday life

47

41

120

105

Total of Group-III
TOTAL

16

10

34

35

36

37

5
4

17,18

41
10

10

15

35

105

CHEMISTRY ( 34) NEW SCHEME

MODEL QUESTION PAPER NO.4
TIME 3HOURS 15 MINUTES

MAX.MARKS.70

Instructions :
i. The question paper has four parts. All the four parts are compulsory
ii. PART A carries 10 marks , each question carries one marks.
PART-B carries 10 marks . each question carries two marks
PARRT C carries 15 marks . each question carries three marks
PART-D carries 35 marks . each question carries five marks
iii) write balanced chemical equations and draw diagrams wherever necessary
iv) use log table and simple calculators if necessary
(use of scientific calculator is not allowed)
PART-A
I ANSWER ALL THE QUESTIONS. EACH QUESTION CARRIES ONE MARK 1X10=10
1.
2.
3.
4.

5.
6.
7.
8.
9.
10.

11.
12.
13.
14.

Define VantHaffs factor.

What are isotonic solutions ?
Mention the S.I unit for molar conductivity.
For the reaction A+B products .the rate becomes doubled when concentra on of only A is
increased by two times, the rate is increased by four times, when the concentration of B alone
is doubled what is the order of the reaction?
Name the enzyme used in the inversion of cane sugar
Name the method used for refining of Zirconium.
Complete the reaction XeF4+O2F2 A+O2
Identify A
What is a Recemic mixture-?
Name the product obtained when acetaldehyde reacts with Hydroxyl amine.
Name the nitrogenous base present in RNA only.
PART-B
II ANSWER ANY FIVE OF THE FOLLOWING EACH QUESTION CARRIES TWO MARKS.
5X2=10
MARKS
Silver forms CCP lattice and x-ray studies of its crystals show that the edge length of its unit
cell is 408.6 pm . calculate the density of silver ( Atomic mass of Ag= 107.9u)
What is corrosion? Mention a general method to prevent it.
Write the Arrhenius equation and mention what each term stands for.
Any two differences between lanthanides and Actinides.

15. How does Acetyl chloride react with Anisol in presence of anhydrous aluminum chloride
catalyst. Write the chemical equation of the reaction.
16. What are the effects of the electron withdrawing and electron donating groups on acidity of
carboxylic acids
17. What are antacids? Give an example.
18. What are food preservatives ? Give one example

PART C
III ANSWER ANY FIVE OF THE FOLLOWING EACH QUESTION CARRIES THREE MARKS
15

5X3=

19. How is pure alumina obtained from Bauxite by leaching process?

20. Write the reactions that takes place during the manufacture of nitric acid by Ostwalds process.
21. i) what happens when potassium chlorate is heated in presence of MnO2. write the equation for
the reaction also
ii) draw the structure of sulphuric acid.
22. i) How is chlorine prepared by using MnO2 ?
ii) complete the reaction
NH3+Cl2(excess)
23. d-block elements form co-ordination compounds . Give reasons.
24. How is potassium dichromate prepared from the chromite ore?
25. Mention the geometry, magnetic property and type of hybridization in [Ni(cn)4]2- complex.
26. Write any three postulates of Werners theory of complexes.
PART-D
IV ANSWER ANY THREE OF THE FOLLOWING . EACH QUESTION CARRIES FIVE MARKS
3X5= 15
27. a. calculate the packing efficiency in body centered cubic crystals
b. calculate the number of particles per unit cells in f.c.c.
28. a. the boiling point of benzene is 353.23K .when 1.80 g of a non volatile , non

(3)
(2)

electrolytic solute was dissolved in 90 g of benzene , the boiling point was

raised to 354.11 K calculate the molar mass of the solute [ Kb for benzene =2.53K.kg mol-1]
(3)
b. write two differences between ideal and non ideal solutions of two liquids
(2)
29. a). calculate the standard free energy change for the following reaction occurring in the galvanic
cell at 298K
3Mg(s) + 2Al3+ (aq) 3Mg2+(aq) +2 Al (s)

Given EMg2+/Mg = - 2.37 V and EAl3+/Al=-1.66V

(4)

b. what is primary battery?

30. a. Derive the integrated rate equation for the rate constant of a first order reaction (4)
b. what is pseudo first order reaction ?

(1)

31. a. complete and balance the following reactions

SO2 +

H2 S oxidation

FeCl3 + H2O hydrolysis

(2)

b. Mention two characteristics of enzyme catalysis

(2)

c. What is the sign of S for the adsorption of gas on solids ?

V ANSWER ANY FOUR OF THE FOLLOWING . EACH QUESTION CARRIES FIVE MARKS
4X5=20
32. a. Explain SN1 mechanism by taking tertiary butyl bromide as an example
b. What is Wurtz Fittings reaction ? Give an example

(3)
(2)

33. a. How is phenol manufactured by cumene process. Give the chemical equations of the reaction
involved .
(3)
b. How do you prepare ethanol by using the Grignard Reagent?
34. a. How is Benzol chloride converted into benzaldehyde ? Name the reaction

(2)
(3)

b. Write the chemical equation for the reaction between dilute NaOH and acetalhyde, mention the
name of the product formed .
(2)
35. a. Explain how is Hinbergs reagent is used to distinguish the primary, secondary and tertiary
amines
b. Write the chemical reactions involved in the conversion of aniline into phenol
36. a. What are carbohydrates ?and how are they classified ?

(2)
(3)

b. What is a peptide bond ? How many peptide bonds are present

in a tetra peptide ?

(2)

37. a. i) what are condensation polymers ? Give an example.

ii)Give the IUPAC name of the monomer of natural rubber.
b. What are Biodegradable polymers ? Give an example

(3)
(2)

Scheme of Valuation
Q.N
O

VALUE POINT

MARK
S

Two solutions having same osmotic pressure at a given temperature

Sm2 mol-1 or Scm2 mol-1

Two

Invertase

Van Arkel method

A=XeF6 or Xenonhexaflouride

A mixture containing two enantiomers in equal proportions will have zero optical
rotation.

Acetaldoxime

10

Uracil

1
PART -B

11

Formula d=zM
-------a3 NA substitution with correct answer(10.5 x 103 kgm-3)
OR

10.5 g cm-3
1
12

A metal is oxidized by loss of es and formation of oxides

Any one method of prevention of corrosion ( coating, painting, tinning, cathodic

13

protection)

Arrhenins Equation k=A.e-Ea/RT OR log ek=logeA Ea

---RT
Where k= rate constant, A=Arrhenius constant Ea= Activation energy, T= temperature,
R= gas constant (any one)

1
14

Lanthanides
1.Binding energies of 4f es are higher

Actinides
1. Binding energies of 5f es are

Lower
2. They do not form complexes easily

2. They have tendency to form

complexes
ANY ONE SUITABLE ANSWER
15

16

17

18

Electron with drawing group increases acidic strength

Electron donating group decreases acidic strength

Chemical substances which are used in the treatment of acidity

Ranitidine( (Zantac) OR ANY OTHER EXAMPLE

Chemical substances which prevent spoilage of food due to microbial growth

Ex: Table salt, sugar, vegetable oils, OR any other suitable example

PART-C
19

Al2O3 + 2 NaOH + 3H2O 2Na [ Al (OH)4]

2Na[Al(OH)4 + CO2 Al2O3. x H2O + 2NaHCO3
Al2O3. x H2O 1470k

Al2O3. +x H2O.

Each equation carries one mark

OR COMPLETE EXPLANATION IN THREE STEPS

3

20

4NH3+ 5O2 Pt/Rh

4NO + 6H2O

500k,9bar

2NO + O2

2NO2

3NO2 +H2O 2HNO3 + NO

1
1

OR COMPLETE EXPLANATION IN THREE STEPS

21

(i)
Statement
2KClO3 Mno2 2KCl + 3O2

OR SELF EXPLANATION ON REACTION

1

22

(i)

Heating MnO2 with conc. HCl

MnO2 + 4 HCl MnCl2 + Cl2+ 2H2O
OR
Self explanation on reaction\

1
1

(ii)

NH3 + Cl2(excess) NCl3 + 3HCl

2
1

23

24

Small size of metal ions

High ionic charges

Availability of d- orbitals

4FeCr2O4 + 8Na2CO3 7O2

Na2CrO4 + 2Fe2O3 +8CO2

2Na2CrO4 +2H+ Na2CrO7 + 2Na++H2O

Na2CrO7 +2KClK2Cr2O7 +2NaCl

OR COMPLETE EXPLANATION IN THREE STEPS

25

26

Square planner complex

Diamagnetic

dsp2 Hybridisation

(i)
(ii)
(iii)

Coordination compounds metals show two types of valencies primary

and secondary
Primary valencies are ionisable
Secondary valencies are non-ionisable
OR ANY OTHER POSTULATES

1
1

PART -D
27

(a) Up to a = 4 /3 OR r=

Packaing efficiency= volume offupied by 2 spheres x 100 %

Total volume of unit cell
Substitution and correct answer (68%)
(b) Total no. of particles due to corners 1/8x8=1
Total no.of particles due to faces 6x = 3 &
Total no.of particles per unit cell 3+1 = 4

1
28

(a) Formula : M2 = 1000x W2 x Kb

Substitution:
M2 = 1000 x 1.8 x 2.53
0.88 x 90

M2 = 58 g mol-1
[ NO UNIT DEDUCT ONE MARK]
(c) Ideal solution
Hmix =0
Vmix =0

non ideal solution

Hmix O
Vmix O

OR ANY OTHER DIFFERENCES

29

(a) E cell = ER --- EL

= -- 1.66+ 2.37
= 0.71 V
G = -- nF E cell
= -- 6x96500x 0.71
= - 411090 J OR - 411.09kJ
(b) Battery can not be reused

1
1
30

(a) RP
Rate = - d[R] = k[R] OR
dt
d[R] = - kdt
[R]
Integrating euation
Ln[R] = -kt+I --------------------(1)
To calculate I :
T=o, R=[R]0

ln[R]o =-kxo+I
OR
ln[R]0=I
substitutionequation (1)
ln [R] = -kt + ln [R]0
Rearranging
Ln[R] = - kt
OR
[R]0
K= 1/t. ln [R]0
OR
[R]
K= 2.303 log10 [R]0
t
[R]
(b) Order of reaction is one and molecularity is two or more than two

1
1
1

31

(a) i. SO2 + 2H2S doubel decomposition

FeCl3 + 3H2O

Hydrolysis

AS2 S3 +3H2O

Fe(OH)3 + 3HCl.
1

(b) Characteristics are

(i)
Highly efficient
(ii)
Highly specific in nature
OR
ANY OTHER REVELENT CHARACTERISTIC (FOR EACH ONE MARK)
(c) S decreases OR S is negative

1
PART-V
32

1
(a)

Step-1

+ Br -

(CH3)3 CBr slow

Step-2

+OH - fast

(CH3)3 COH

Mentioning first order kinetics

(b) Alkylhalide reacts with anyl halide gives alkylarenes when treated with
sodium indry ether
1

OR self-explanation with equation

1

2
(a) Explanation

33

OR
Step wise reaction carries
(b) HCHO+ CH3 Mg Br CH3CH2OBr
Methanal
CH3CH2OMgBr + HOH CH3CH2OH+Mg(OH)Br
Ethanol
34

(a)

H2
Pd-BaSO4

Benzoyl
chloride
Rosenmund reduction

Benzaldehyde

(b) 2CH3CHO dil NaOH CH3-CH-CH2CHO

OH

Ethanal
3-Hydroxybutanal
(ALDOL)

CH3-CH=CH-CHO
But-2 enal

2
35

(a) Hinsbergd reagent reacts with 1 amine gives a product which is soluble in
alkali
(b) Hinsbergs reagent reacts with 2 amine gives a product which is insoluble
in alkali
Hinsbergs reagemt doesnot react with 3 amine
C6H5NH2 + NaNO2+2HCl 273-278 k C6H5N2+Cl- + NaCl + 2H2O
C6H5N2+Cl- + H2OC6H5OH + N2 + HCl

1
1
1
1
1

36

(a) Optically active polyhydroxy aldehydes or ketones or the compounds which 1

produce such units on hydrolysis
2
Classified as monosaccharides, oligo saccharides, polysaccharides
(b) Elimination of a water molecule from two molecules of similar or different
amino acids and formation of CONH- bond
3 peptide bond

1
37

(a) i. condensation reaction between two different bifunctional or trifunctional

monomeric units
Nylon6,6 or Any other example
ii. isoperene or 2-methyl-1,3-butadiene
(b) polymers cause acute environmental problems and remain undegraded for
long time
Nylon-2-nylon-6 or any other example

1
1
1