1. Itwas NOT part of Dalton’s atomic theory that atoms (A) are indivisible (B) are characterised by their atomic number (©) of an element have identical properties (D) of an element differ from those of other elements Item 3 refers to the following diagrams. Arradioactive element, M, of mass number A, and atomic number Z, undergoes decay, followed by « decay. The final element, N, will be (a) ® Co) (@) YY ey) (B) © (D) 3. Which of the diagrams above BEST represents an sp? orbital? 4. The electronic configuration of the element with atomic number 20 (Z = 20) is given by (A). 1s? 23 2p! 3st 3pt 4st (B) Is? 2s! 2pé 3st 3p ast (©) 1s? 2st 2p 3s# 3p 4s! dp! (D) Is? 2s 2p6 3st Spf ds! 3a! 5. Which of the following solids has a giant molecular lattice? (A) Carbon dioxide (B) Copper oxide (C) Magnesium oxide (D) Silicon dioxide 02112010/CAPE 2011 GO ON TO THE NEXT PAGE-3- Which of the following describes potassium bromide? (A) A network of covalently bonded atoms (B) A substance which boils at 59 °C and decomposes at high tempera- tures (© A solid with @ very high molar enthalpy of vaporization and, in a liquid state, does not conduct electricity (D) Anon-conducting solid which melts to form a liquid that conducts electricity ‘The equation for the reaction of magnesium, with hydrochloric acid is ‘Mg(s)+ 2H"(aq)—> Mg” (aq) +H,(2) ‘The molar volume ofa gasatr.t.p.=24 dm? ‘The volume of gas produced when 1.2 g of Mg reacts at room temperature and pressure (A) 124m ®) 2.4 dm (©) 120m ©) 24.0dm Which of the following is TRUE about 5 din? of hydrogen and 5 dm? of oxygen at 0°C and 101 kPa? (A) They react to produce 5 dm? of water. (B) They possess the same amount of kinetic energy. (C) They contain the same number of molecules, (D) They react completely with each other. 02112010/CAPE 2011 9, 10, In the following redox reactions involving chromium compounds, whats the oxidation number of chromium in EACH compound? NaOH dilute CxO, —> Nacro, —> Cr,0> and water H,S0, CxO, | NaGro, [C02 @ [3 +6 +6 | 8 6 +6 ©] 38 +6 +6 | 8 +6 4 When 86 g of the ionic salt, CaSO, xH,0, is heated so that all ofits water of crystallisation is driven offand 68.0 gof CaSO, remain, the value of x is (A ot ® 2 © 3 @o 4 GO ON TO THE NEXT PAGE! 11. Which of the following does NOT represent a balanced redox equation? | (A) Za(8) + 2HCI (aq) + ZnCl, (ag)+ He) | (B) — MnO-, (aq) + SFe*(aq) + SH* — Mn’*(ag)+ SPe (aq) 4H,0() | (©) 80,(g) + Br,(l) + 2H,0() + 481 (aq) + $0>*(aq) + 2Br-(aq) (D) _Sn(s) + HNO, (aq) + Sn0,(s) +NO, (2) + H,0() 12. Which of the following gases will behave MOST ideally? (A) Ammonia (®) Helium (© Methane | (@) Oxygen 13. Which of the following diagrams BEST represents the energy changes for an exothermic reaction that proceeds in two stages? j (a) Energy © © Energy Energy Time GO ON TO THE NEXT PAGE 02112010/CAPE 2011“3. 14. The second ionisation energy of calcium is 1150 kJ mol". Which of the following equations represents this statement? kJ mol ~' (A) Calg) > Ca* (g)+2e AH =+1150 | (B) Car(g)>Ca™(g)te> AH = + 1150 (©) Ca*(g) > Ca (g) te- AH =- 1150 (D) Cals) > Ca*(g) + 2e~ AH=+1150 tem 15 refers to the following standard enthalpy of combustion for carbon, hydrogen and octane AB? KS mot | Carbon 304 | Hydrogen 286 5 Octane 5476 | 15. The standard enthalpy of formation, AH , of octane is calculated as, (A) AH (octane) = 8 (394) -9(-286)—$476 KI mot"! (B) AH) (octane) = ~8 (-394) ~9(- 286) - (5476) ki mol (©) AHG (octane) =8 (~394) + 9( 286) ($476) kJ mol"! ©) At%(octane)= 8 (304) —9( -286)—$476 kJ mol “ GO ON TO THE NEXT PAGE 02112010/CAPE 2011-6- ‘Item 16 refers to the following graphs for the reaction between reactants P, Q and R. P+Q+R- Products nat wa | “iy | i rr 1a } | / | . | | i ————____—__> { 12? (RL 16. The rate equation is (A) Rate=K(P](Q) (B) — Rate=k[P] [QF * (© Rate=k [P} [QR] (D) , Rate=k(P] (QF IR] tem 17 refers to the following table. The reaction X —» Y yields the following rate data. Time (s) (X} (mol dm) 0.0 020 5.0 oa 10.0 0.10 15.0 o.o7t 20.0 0.050 17, The reaction is first order in [X]. What is the rate constant? (A) 0.030s" B) — 0.069s+ (© 1400s* @) 0.46" GO ON TO THE NEXT PAGE. 02112010/CAPE 2011‘tem 18 refers to the diagrams below which show the Maxwell-Boltzmann distribution. 1, T, (a) Ty, © 4 fe 3 £ 2 [ i z g i i z 2 Rinete eaeray T, @) A Uy 5 E a 5 z z Kinetic energy ‘Kinetic energy 18. Which of the diagrams above represents the effect of an increase in temperature from 70 °C (T,) to 80°C (I)? 19. Which of the following statement(s) about 20. Which of the following statements does a catalyst is (are) true? NOT refer toa system in dynamic equilib- rium? 1 Itincreases the equilibrium constant for the forward reaction only. (A) The reaction is reversible. TT _Itinereases the equilibrium constant (B) The amounts of al the species in the for both the forward and backward system remain constant. reactions (©) The concentrations of all reactants Tl. It has no effect on the position of and products are equal. equilibrium, (D) The rate of the forward reaction is equal to the rate of the backward (A) Tonly reaction. (8) Monly (C) Land I only (D) Wand Ml only GO ON TO THE NEXT PAGE 02112010/CAPE 201121. Equilibrium is established in the reaction X (aq) + Y (aq) —=* Z (aq). If the equilibrium concen- trations are [X] = 0.2 mol dm, [Y] = 0.3 mol dm” and [Z] = 0.6 mol di *, which of the following is the value of the equilibrium constant K,? (a) (B) © @) 0.1 mol dm* 0.1 mol dm? 10.0 mol dm? 10.0 mol dm? 22. Baking soda decomposes when heated according to the equation 2 NaHCO, (8) == Na,CO, (8) + H,0(g) + CO, (g). If 100 g of baking soda is heated to 363 K,, the total pressure of the gases is $5.23 kPa. What is the value of K, at 363 K? @ 10s ®) 165.7 () 762.6 ©) 3050 23. In pure ethanol, (C,H,OH), the following equilibrium can exist with ammonium ions, NH, + C,HOH == NH, +C,H,OH," Which of the following combinations describes the function of NH,* and C,H,OH according to the Bronsted-Lowry theory? (a) (8) © (D) Acid Base Conjugate acid Acid 02112010/CAPE 2011 CHO Base Acid Base Conjugate base GO ON TO THE NEXT PAGE24. What is a suitable indicator forthe titration of 0.10 mol dm? acetic acid with 0.10 mol ém* aqueous ammonia? (A) Bromothymol blue (pH range 6.0 - 7.6) (B) Methyl orange (pH range 3.2 - 4.2) (C)_Phenolphthalein (pH range 8.2 - 10.0) (D) There is no suitable indicator. 25. Which of the following graphs shows the change in pH when 0.1 mol dm? HCI (aq) is gradually added to 20 cm? of 0.1 mol dm NaOH (aq)? pH pu 144 14 (A) 7 O7 > 0 20 40 0 20 oe ‘Volume of acid (em?) Volume of acid (em?) pH pH 14 7 4 ®) 7 @O7 0 20 40 0 20 40 ‘Volume of acid (em?) Volume of acid (cm) GO ON TO THE NEXT PAGE 12112010/CAPE 2011-10- 26. Which expression represents the solubility product of iron (III) hydroxide? (A) [Fe] [OH-P (Fe" ory (Fe(OH), (c) [Fe*] 30H-P @) (©) [Fe*] BOH] Items 27 - 28 refer to the following sets of options. Indicator PH of change Colour Change . Acid — Alkali (A) Methyl orange 35 red + yellow (B) Litmus 6.0 red > blue (©) Bromothymol blue 7.0 yellow —> blue (BD) Phenolphthatein 95 colourless —> pink Which is the equivalence point indicator for titrating a 27. strong acid against a strong base? 28. weak acid against a strong base? 29. Using standard electrode potentials, which of the following reactions would be MOST feasible? (A) ~ Za(s) + Cu*(aq) + Zn** (aq) + Culs) (B) —Zn(s) + Pb*(aq) —+ Zn** (aq) + Pb(s) (©) Pb(s) + Zn*(aq) — Pb** (aq) + Zn(s) (D) —Culs) + Zn™(aq) > Cu* (aq) + Zn(s) | Item 30 refers to the cell diagram below. 30. Which of the following will cause an inerease in cell potential? (A) __ Increasing concentration of Zn" ions only (B) Decreasing concentration of Zn**(aq) ions and increasing concentration of Cu’* (aq) ions (©) Decreasing concentration of Cu* ions only (D) Adding NaOH to Cu® solution and increasing the concentration of Zn** ions Zn(s)| Zn2*(aq)|] Cur (aapfcusy | | | GO ON TO THE NEXT PAGE i 02112010/CAPE 201131, 32. 33, 34, Gecl, +H) IL Sn + 2HCl —— SaCl+ Hg) WL. Pb +2HCl ——> PbCl, + Hg) (A) Lonly (®) _Tonly (©) Mlonly (D) and Il only Which pair of properties increases on descending the Group II elements? 1 Atomic radii Tl, _Ionisation energy HL Electronegativity TV. Tonic radii (A) Land Ml only (B) Land IV only (Q Wand Ml only (D) Wand IV only 02112010/CAPE 2011 35, 36. 37. 38, Group II elements of the periodic table have (A) high melting points but low density (B) high electrical conductivity but low density (©) high melting points and high electrical conductivity (D) low melting points and poor electrical conductivity Which of the following chlorides of Group IV elements is the BEST electrical conductor? (A) PbCl, @) sicl, (© Gel, (Dp) cel, In which of the following options are the halide ions placed in order of INCREASING reducing power? (A) BrCl, @®) GBra- © ayer ©) Clyi5Br When AgNO,(aq) is added to fluoride ions followed by NH,(aq) the result is (A) no precipitate (B) white silver fluoride (©) yellow silver fluoride (D) cream-coloured ammonium fluoride GO ON TO THE NEXT PAGE39, 40. a. “& ®) © © Items 39 - 40 refer to the following options. 42. (A) Ligand (B) Catalyst (© Complex (D) Coordination number Match each item below with one of the options above, each of which may be used ‘once, more than once or not at all. The species containing ions or molecules linked t6 a central atom by coordinate bonds 4B ‘The species donating electron pairs to the central atom Which diagram represents the electronic configuration of Cu"? Note: [Ar] = Is*, 2s?, 2p, 38%, 3p 3d 4s an ti tit} ty] a 4 3a 4s walt] tia] tit 4 3a 4s 4 tan [| | | t 4 45 3d 4s ot a An unknown salt solution containing a single anion is tested with Iead (II) nitrate solution followed by dilute FINO,. A white precipitate is observed which dissolves in acid with effervescence. These observa- tions indicate the presence of (A) COX and cr (B) $0, and SoZ (©) $02-and CO () 80,-andcr Which of the following metals give a green flame when heated? (A) Magnesium (B) Calcium (©) Sodium (D) Copper Items 44 - 45 refer to the following options. (A) Acentral ion in a complex (B) Aligand (©) Anoctahedral complex (D) Atetrahedral complex Match each item below with one of the options above. Each option may be used ‘more than once, once or not at all. [Co(H,0),P* CHNH, IF YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORK ON THIS TEST. 02112010/CAPE 2011